1. Study of positional isomerism in N-propyl and Iso-propyl alcohol using ultrasonic technique
- Author
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Rupali Thete, Satish J. Sharma, and S. Rajagopalan
- Subjects
History ,Materials science ,Attenuation ,Relaxation (NMR) ,Analytical chemistry ,Alcohol ,Computer Science Applications ,Education ,Nitrobenzene ,Solvent ,chemistry.chemical_compound ,chemistry ,Ultrasonic attenuation ,Ultrasonic velocity ,Ultrasonic sensor - Abstract
In the present work, positional Isomerism is studied in the binary mixtures of n-propyl alcohol and Iso-propyl alcohol in nitrobenzene as the common solvent. Ultrasonic velocity and attenuation measurements using pulse–echo technique operated at 10 MHz have been taken at various concentrations of both alcohols in nitrobenzene, from 283.15K - 293.15K. It is observed that both the systems exhibit critical nature and show non-linear variation both in ultrasonic velocity of propagation and attenuation. Ultrasonic attenuation at lower concentrations of n-propyl alcohol in nitrobenzene reveals the dominant structural relaxation as compared to that of Iso-propyl alcohol in nitrobenzene.
- Published
- 2021