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En este estudio, nos centraremos en analizar los Accidentes de Trabajo a nivel general en los países de la UE27, cuyo número de accidentes fue de 3140950 en 2019 y el cómo se le ha dado cada vez más importancia a dicho tema, viéndose reflejado en las diferentes modificaciones de la Directiva 89/391/CEE o Directiva Marco de la Unión Europea. Además, nos fijaremos también en el caso de España, cuyo número de accidentes en 2019 fue de 489643 y también se ve reflejado en las diversas actualizaciones de la Ley de Prevención de Riesgos Laborales (LPRL). También realizaremos una revisión bibliográfica sobre las principales características y condiciones de los trabajadores así de cómo evoluciona la siniestralidad laboral tanto en, los países de la Unión europea (UE27), como en España., Grado en Administración y Dirección de Empresas

Air pollution coming from industrial activities is a matter of interest since their emissions can seriously affect to the human health of nearby populations. A more detailed study about industrial emissions is required in order to discriminate different activities contributing to pollutant sources. In this sense, gaseous pollutants (NO2, SO2 and O3) and PM10 levels has been studied in a complex industrial area in the southwest of Spain (La Rabida and the nearby city of Huelva) during the period 1996-2017. Hourly, daily, monthly and annual variations of PM10 and gaseous pollutants concentrations point to the industrial activity as the main SO2 source. Furthermore, traffic and resuspension emissions contribute to the NO2 and PM10 levels, respectively. Results from chemical composition of PM10 at both sites during the period 2015-2017 are characterized by high concentrations of the crustal components derived from natural and local resuspension. Arsenic is found to be the main geochemical anomaly at La Rabida (annual mean of 7 ng m-3), exceeding the European annual target of 6 ng m-3, which supposes a risk for the nearby population. An emission source from Cu-smelter has been identified in La Rabida and Huelva. A second source corresponding to emissions from polymetallic sulfides handling in a port area has been described for the first time in La Rabida. In addition, arsenic speciation results have identified three different As impacts scenarios as a function of the dominant wind direction, the SO2 episodes and the As extraction efficiency: impact of the Cu-smelter, impact of the bulk polymetallic sulfides and a mixed impact of both sources.

Wear in train and rail components in the Barcelona subway system includes brake pads, catenary wires, wheels, railways, and motor brushes. These components were characterised to evaluate their contribution to ambient particulate matter (PM) levels in two platforms (conventional F-L3 and new S-L9). The observed chemical compositions of these components were used to interpret the mineralogical, chemical, and leachability patterns of subway platform particulate matter (PM). The use of sulphides such as molybdenite (MoS 2 ), pyrite (FeS 2 ), stibnite Sb 2 S 3 ) rich in toxic elements such as in Cu, Ni, As, Hg, Cd, and Pb and abrasives such barite (BaSO 4 ) and zinzite (ZnO) in the brake pad composition, the composition of the catenary rich in Cu (98% metallic-Cu) with traces of Hg and that of the wheel/rail (98% metallic-Fe) with traces of As results in the production of fine PM particles of As, Hg, Cu, and Sb in ambient air PM in platform as a consequence of the abrasion/friction and sparking processes. The temperature reached in the aforementioned processes give rise to fine condensed and water-soluble As species (most likely As 2 O 3 and As 2 O 5 ). Moreover, the stibnite (Sb 2 S 3 ) Hg-rich lateral brake pads used in L9 also contribute to fine and relatively soluble Sb and Hg oxides. Sulphide-rich brake pads significantly increase and change the occurrence mode of the Zn, Cu, Mn, Cr, Pb, and Ni present in PM by oxidation of brake-bearing metal sulphide to relatively water-soluble sulphate and oxide species. These changes in the mode of occurrence and speciation of elements in the PM of subway platforms points to the need for in-depth PM speciation studies, as well as the need for substituting conventional friction materials with low-metal materials—such as graphite pantographs/catenaries and rubber wheels and low toxic sulphides in brake pads—to reduce exposure to metals during subway commuting. © 2019