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A key challenge in helium (He) exploration is determining the efficacy of surficial soil gas surveys. While soil gas surveys can detect helium, the mechanisms leading to these signals are often poorly understood, hindering reliable interpretation for exploration purposes. Here we present the results of seven new He soil gas surveys (n = 1974) at the Akah Nez Field, Beautiful Mountain Field, Porcupine Dome area, Rattlesnake Field, Tom area, Tohache Wash area, and White Rock area, on the Colorado Plateau, Four Corners area, United States. Utilizing 2D seismic, well logs, and geophysical potential field data, structural maps were constructed of potential He reservoirs at depth and relationships were examined. Given geospatial relationships are being examined using the soil gas survey data, it is important to understand the mechanism that allows subsurface He to migrate upwards into the soil. In several fields interpreted basement faults act as migration conduits from the basement to the surface (i.e., leaky reservoir seals), and in other cases there is evidence for reservoir flank/crest fracturing likely due to differential compaction. Based on the regional geologic history, advective systems are likely responsible for the observed He soil gas signatures. Additionally, based on the Tohache Wash data (most prospective He area) an effective and risk-reducing novel technique is presented that constructs a predictive He exploration model utilizing soil gas geochemistry, high-resolution geophysical data, well data and seismic data using Bayesian ANOVA techniques, which may be translated to areas outside of the Four Corners area, United States. [ABSTRACT FROM AUTHOR]

Soil autotoxic chemosensory substances have emerged as the predominant environmental factors constraining the growth, quality, and yield of Codonopsis pilosula in recent years. Among a vast array of chemosensory substances, benzoic acid constitutes the principal chemosensory substance in the successive cultivation of C. pilosula. However, the exploration regarding the stress exerted by benzoic acid on the growth and development of C. pilosula remains indistinct, and there is a scarcity of research on the mechanism of lobetyolin synthesis in C. pilosula. In the current research, it was discovered that exposure to benzoic acid at a concentration of 200 mmol/L conspicuously attenuated the plant height, root length, total length, fresh weight, root weight, root thickness, chlorophyll content, electrolyte osmolality, leaf intercellular CO2 concentration (Ci), net photosynthesis rate (Pn), transpiration rate (Tr), and leaf stomatal conductance (Gs) of C. pilosula. Benzoic acid (200 mmol/L) significantly enhanced the activity of root enzymes, including superoxide dismutase (SOD), malondialdehyde (MDA), and peroxidase (POD), as well as the accumulation of polysaccharides and lobetyolins (polyacetylene glycosides) in the roots of C. pilosula. In this study, 58,563 genes were assembled, and 7946 differentially expressed genes were discovered, including 4068 upregulated genes and 3878 downregulated genes. The outcomes of the histological examination demonstrated that benzoic acid stress augmented the upregulation of genes encoding key enzymes implicated in the citric acid cycle, fatty acid metabolism, as well as starch and sucrose metabolic pathways. The results of this investigation indicated that a moderate amount of benzoic acid could enhance the content of lobetyolin in C. pilosula and upregulate the expression of key coding genes within the signaling cascade to improve the resilience of C. pilosula lobetyolin against benzoic acid stress; this furnished a novel perspective for the study of C. pilosula lobetyolin as a potential substance for alleviating benzoic acid-induced stress. [ABSTRACT FROM AUTHOR]

In this review article, the main techniques for spectroscopic studies of gases in field conditions are considered. The issues related to the study of gas emissions from soils and the determination of their concentrations are analysed. The main types of spectroscopy used in portable devices for soil gas analysis, along with their design features and sampling approaches, are provided. Various studies aimed at optimising the operation of devices for analysing gases emitted from the soil, taking into account agronomic, agrochemical, and ecological specifics, are also presented. The effect of using different types of lasers and reflecting elements on the accuracy of optical measurements and the sensitivity to various substances in the gases is analysed. [ABSTRACT FROM AUTHOR]

We measured dark CO2 fluxes and CH4 emissions from two naturally vegetated ecosystems of the Mezquital Valley irrigated with wastewater from Mexico City. The ecosystems were characterized by high groundwater levels; the vegetation was represented mainly by saltgrass in the first plot and chairmaker's bulrush in the second. A dark chamber technique was used for the study from August 2008 to June 2009. For the two studied plots, mean values (mean ± SE) for dark ecosystem CO2 fluxes (Rtot), soil CO2 emission (Rsoil), and heterotrophic respiration (Rhet) were 26 ± 5, 14 ± 3 and 12 ± 3 mg C m–2 h–1, respectively, The annual cumulative fluxes Rtot, Rsoil and Rhet equal to 234, 127 and 103 g C m–2 y–1, respectively. The contribution of Rsoil to Rtot, and Rhet to Rsoil varied significantly over the study period, with no clear relationship to seasonal dynamics. The observed low CO2 fluxes may be due to soil salinization resulting from wastewater flooding. The fluxes of CH4 were observed in the flooded plot, with peaks up to 370 µg C m–2 h–1. The fluxes of CH4 were significantly higher when plants were present in the measurement chamber than when there were no plants, confirming the important role of plant cover in CH4 transport. Unlike CH4 fluxes, CO2 fluxes show seasonal dynamics, mainly due to their strong dependence on temperature. The observed results may be useful for properly estimating the global C budget and the contribution of saline soils to C fluxes. [ABSTRACT FROM AUTHOR]

Soil CO2 concentration and flux measurements are important in diverse fields, including geoscience, climate science, soil ecology, and agriculture. However, practitioners in these fields face difficulties with existing soil CO2 gas probes, which have had problems with high costs and frequent failures when deployed. Confronted with a recent research project's need for long-term in-soil CO2 monitoring at a large number of sites in harsh environmental conditions, we developed our own CO2 logging system to reduce expense and avoid the expected failures of commercial instruments. Our newly developed soil probes overcome the central challenge of soil gas probes—surviving continuous exposure to soil moisture while remaining open to soil gases—via three approaches: a 3D printed housing (economical for small-scale production) following design principles that correct the usual water permeability flaw of 3D printed materials; passive moisture protection via a hydrophobic, CO2-permeable PTFE membrane; and active moisture protection via a low-power micro-dehumidifier. Our CO2 instrumentation performed well and yielded a high-quality dataset that includes signals related to a prescribed fire as well as seasonal and diel cycles. We expect our technology to support underground CO2 monitoring in fields where it is already practiced and stimulate its expansion into diverse new fields. [ABSTRACT FROM AUTHOR]

Climate change and aridification have increased the risk of salinization and organic carbon loss in dryland soils. Enrichment using biochar and organic fertilizers has the potential to reduce salt toxicity and soil carbon loss. However, the effects of biochar and organic fertilizers on CO2 and CH4 emissions from saline soils in dryland areas, as well as their microbial mechanisms, remain unelucidated. To clarify these issues, we performed a 5-month incubation experiment on typical soda-type saline soil from the western part of the Songnen Plain using five treatments: control treatment (CK), 5% urea (U), straw + 5% urea (SU), straw + 5% urea + microbial agent (SUH), and straw + 5% urea + biochar (SUB). Compared with the SU treatment, the SUH and SUB treatments reduced cumulative CO2 emissions by 14.85% and 35.19%, respectively. The addition of a microbiological agent to the SU treatment reduced the cumulative CH4 emissions by 19.55%, whereas the addition of biochar to the SU treatment increased the cumulative CH4 emissions by 4.12%. These additions also increased the relative abundances of Proteobacteria, Planctomycetes, and Ascomycota. Overall, the addition of biochar and organic fertilizer promoted CO2 emissions and CH4 uptake. This was mainly attributed to an improved soil gas diffusion rate due to the addition of organic materials and enhanced microbial stress due to soil salinity and alkalinity from the release of alkaline substances under closed-culture conditions. Our findings have positive implications for enhancing carbon storage in saline soils in arid regions. [ABSTRACT FROM AUTHOR]

The grassland biome is an important sink for atmospheric methane (CH4), a major greenhouse gas. There is considerable uncertainty in the grassland CH4 sink capacity due to diverse environmental gradients in which grasslands occur, and many environmental conditions can affect abiotic (e.g., CH4 diffusivity into soils) and biotic (e.g., methanotrophy) factors that determine spatial and temporal CH4 dynamics. We investigated the relative importance of a soil's gas diffusivity versus net methanotroph activity in 22 field plots in seven sites distributed across the US Great Plains by making approximately biweekly measures during the growing seasons over 3 years. We quantified net methanotroph activity and diffusivity by using an approach combining a gas tracer, chamber headspace measurements, and a mathematical model. At each plot, we also measured environmental characteristics, including water‐filled pore space (WFPS), soil temperature, and inorganic nitrogen contents, and examined the relative importance of these for controlling diffusivity and net methanotroph activity. At most of the plots across the seven sites, CH4 uptake rates were consistently greatest when WFPS was intermediate at the plot level. Our results show that variation in net methanotroph activity was more important than diffusivity in explaining temporal variations in net CH4 uptake, but the two factors were equally important for driving spatial variation across the seven sites. WFPS was a significant predictor for diffusivity only in plots with sandy soils. WFPS was the most important control on net methanotroph activity, with net methanotroph activity showing a parabolic response to WFPS (concave down), and the shape of this response differed significantly among sites. Moreover, we found that the WFPS level at peak net methanotroph activity was strongly correlated with the mean annual precipitation of the site. These results suggest that the local precipitation regime determines unique sensitivity of CH4 uptake rates to soil moisture. Our findings indicate that grassland CH4 uptake may be predicted using local soil water conditions. More variable soil moisture, potentially induced through predicted future extremes of rainfall and drought, could reduce grassland CH4 sink capacity in the future. [ABSTRACT FROM AUTHOR]

All humans are exposed to radon, the primary source of natural radiation, which can harm people due to natural processes rather than human activity. Thus, it is of significant importance to determine the levels of radon in indoor, soil gas, water, and outdoors. Radon concentration (CRn) was measured in Kiraz district, İzmir, and the correlation between the indoor and soil gas CRn values was investigated. The indoor CRn values measured in 40 randomly selected dwellings in Kiraz exhibited a wide range from 19.50 ± 2.50 to 204.70 ± 8.00 Bq m−3 with an average value of 61.11 ± 4.23 Bq m−3. The measured indoor CRn values were compared to the reference levels in the world to help control radon in the dwellings. Indoor CRn values were lower than the ICRP reference level of 300 Bq m−3 in all of the dwellings studied. Furthermore, in 34 dwellings (representing 85% of the total number of dwellings studied), indoor CRn values were lower than the WHO reference level of 100 Bq m−3. Health hazard indices, namely annual effective dose (AED) and excess lifetime cancer risk (ELCR), were also calculated for each dwelling and compared with internationally acceptable levels to estimate the risk to human health. The AED values varied from 0.49 ± 0.06 to 5.16 ± 0.20 mSv y−1 with an average value of 1.54 ± 0.11 mSv y−1, which exceeds the world average of 1.15 mSv y−1 as reported by UNSCEAR. The ELCR values ranged from 2.05 ± 0.26 × 10−3 to 21.55 ± 0.84 × 10−3 with an average value of 6.43 ± 0.44 × 10−3, exceeding the world average of 0.29 × 10−3 as reported by UNSCEAR. The soil gas CRn values measured exhibited a wide variation ranging from 129.25 ± 6.38 Bq m−3 to 6172.64 ± 44.06 Bq m−3 with an average value of 1291.79 ± 18.70 Bq m−3. The soil gas CRn values were less than 10,000 Bq m−3; hence, the research area is categorized as "low radon risk areas" according to Sweden Criteria, and so no special constructions are required in the studied area. When soil gas CRn values were compared to indoor CRn values, no linear relationship was found between the CRn values. However, a strong positive linear correlation was found between indoor and soil gas CRn values less than 200 Bq m−3 and 2500 Bq m−3, respectively. [ABSTRACT FROM AUTHOR]

Appropriate mechanized straw returning and tillage sowing techniques were effective means to optimize soil physical properties and enhance agricultural productivity, as well as important measures for the conservation and restoration of mollisols region in Northeast China. Under the condition of full-scale maize straw returning, four mechanized tillage and sowing modes were set, including plough tillage and sowing (PTS), combined tillage and sowing (CTS), no-tillage and sowing (NTS), and no-tillage and sowing with straw mulching (NTSM). In 2020 and 2021, the study investigated the effects of different mechanized tillage and sowing modes on soil physical properties, soybean yield and economic benefits. The results showed that during the pod-setting and pod-filling period of soybean, the NTS and NTSM treatments exhibited better effects on deep soil insulation and shallow soil moisture retention, the soil physical structure of PTS and CTS treatments were relatively ideal. Compared with PTS and CTS treatments, NTS and NTSM treatments significantly increased soil gravimetric water content (SWC) by 2.35% to 7.98% in the 5-15 cm soil layer and increased soil temperature (ST) by 3.94% to 10.42% in the 2535 cm soil layer (p<0.05), significantly increased soil bulk density (SBD) by 2.98% to 6.72% and significantly reduced soil total porosity (STP) by 3.88% to 6.53% in the 5-25 cm soil layer, and significantly reduced soil gas phase ratio by 8.26% to 6.27% at the 15-25 cm soil layers, which caused soil three-phase ratio (STPR) of PTS and CTS treatment in 15-25 cm soil layer were relatively ideal. The soybean yield of NTSM treatment in 2020 was not significantly different from PTS and CTS treatment (p>0.05), the soybean yield of NTSM treatment in 2021 significantly increased by 7.30% and 5.84% over PTS and CTS treatments, respectively. And the average annual profit per unit area of NTSM treatment increased by 12.84%, 12.41% and 8.57% compared with PTS, CTS and NTS treatments, respectively. Therefore, it was recommended to combine NTSM technique with PTS or CTS technique in a maize-soybean rotation system in mollisols region. The research results provided reference for the selection of appropriate mechanized tillage and sowing techniques in Northeast China's mollisols region and had important guiding significance and practical value for the construction of rational plow layers and the implementation of conservation tillage. [ABSTRACT FROM AUTHOR]

Various anomalies occurring before earthquakes are currently being studied to predict seismic events, with one of them being the radioactive element radon (222Rn). Radon concentrations in the soil, water, and atmosphere fluctuate in response to crustal movement. Recent research has statistically detected anomalies by analyzing the fluctuations in radon concentrations before earthquakes and conducting quantitative evaluations of radon. However, the method used to determine the parameters in the analysis was problematic. Therefore, in this study, we compared observed atmospheric radon concentration data with predicted values based on typical annual patterns using Random Forest analysis. We conducted a more objective analysis by employing this method and statistically determining anomalies using thresholds. This analysis was conducted using atmospheric radon concentration observation data obtained at Kobe Pharmaceutical University (KPU) before the 1995 Kobe Earthquake, and ionization currents emitted when radon decays were obtained at Fukushima Medical University (FMU) before the 2011 Tohoku-oki Earthquake. Consequently, before the major earthquakes occurred at both locations, the difference between the predicted and observed values exceeded the standard deviation by a factor of three. These results indicate the potential of Random Forest analysis to identify anomalies in atmospheric radon concentrations before earthquakes occur. [ABSTRACT FROM AUTHOR]

From autumn 2021 through summer 2023, scientists from the National Oceanic and Atmospheric Administration (NOAA) and partners conducted the Study of Precipitation, the Lower Atmosphere, and Surface for Hydrometeorology (SPLASH) campaign in the East River Watershed of Colorado. One objective of SPLASH was to observe the transfer of energy between the atmosphere and the surface, which was done at several locations. Two remote sites were chosen that did not have access to power utilities. These were along the valley floor near the East River in the vicinity of the unincorporated town of Gothic, Colorado. Energy balance measurements were made at these locations using autonomous, single-level flux towers referred to as Atmospheric Surface Flux Stations (ASFS). The ASFS were deployed on 28 September 2021 at the "Kettle Ponds Annex" site and on 12 October 2021 at the "Avery Picnic" site and operated until 19 July and 21 June 2023, respectively. Measurements included basic meteorology; upward and downward longwave and shortwave radiative fluxes, and subsurface conductive flux, each at 1-minute resolution; 3-d winds from a sonic anemometer and H2O/CO2 from an open-path gas analyser, both at 20 Hz from which sensible, latent heat, and CO2 fluxes were derived; and profiles of soil properties in the upper 0.5 m (both sites) and temperature profiles through the snow (at Avery Picnic), each reported between 10 min and 6 hours. For most measurements, uptime was 96 % (Kettle Ponds) and 89 % (Avery Picnic), and collectively 1,184 days of data were obtained between the stations. The purpose of this manuscript is to document the ASFS deployment at SPLASH, the data acquisition and post-processing of measurements, and to serve as a guide for interested users of the data sets, which are archived under the Creative Commons 4.0 Public Domain licensing at Zenodo. [ABSTRACT FROM AUTHOR]

In this work, a full characterization of the new user-friendly version of the Atmospheric Radon MONitor (ARMON), used to measure very low activity concentrations of the radioactive radon gas in the outdoor atmosphere, is carried out. The ARMON is based on the electrostatic collection of 218 Po + particles on a semiconductor detector surface. A main advantage of this instrument is that it offers high-resolution alpha-energy spectra, which will allow us to separate radon progeny (210 Po, 218 Po, and 214 Po). The monitor feature may also allow measurements of thoron (220 Rn) by collection of 216 Po + , although the instrument is not calibrated for this gas. In the paper, the physical principle; the hardware configuration; and the software development of the automatic and remotely controlled ARMON, conceived and constructed within the MAR 2 EA and the traceRadon projects, are described. The monitor efficiency and its linearity over a wide span of radon concentration activities have been evaluated and tested here using theoretical and experimental approaches. Finally, a complete budget analysis of the total uncertainty of the monitor was also achieved. Results from the application of a simplified theoretical approach show a detection efficiency for 218 Po + of about 0.0075 (Bq m -3) -1 s -1. The experimental approach, consisting of exposing the ARMON at controlled radon concentrations between a few hundreds to a few thousands of becquerels per cubic metre (Bq m -3), gives a detection efficiency for 218 Po + of 0.0057 ± 0.0002 (Bq m -3) s -1. This last value and its independence from the radon levels were also confirmed thanks to a new calibration method which allows us, using low-emanation sources, to obtain controlled radon levels of a few tens of becquerels per cubic metre (Bq m -3). The total uncertainty of the ARMON detection efficiency obtained for hourly radon concentrations above 5 Bq m -3 was lower than 10 % (k= 1). The characteristic limits of the ARMON – being those dependent on the presence of thoron in the sampled air – were also calculated. A detection limit of 0.132 Bq m -3 was estimated in the absence of thoron. At a typical thoron concentration at atmospheric sites of 0.017 min -1 , the detection limit was calculated to be 0.3 Bq m -3 , but this can be reduced if using a delay volume, obtaining a decision threshold of 0.0045 Bq m -3. Current results may allow us to confirm that the ARMON is suitable to measure low-level radon activity concentrations (1–100 Bq m -3) and to be used as a transfer standard to calibrate secondary atmospheric radon monitors. [ABSTRACT FROM AUTHOR]

Gas hydrates deposits in the Andaman forearc basin are inferred from seismic data and confirmed by drilling/coring during the NGHP-01 expedition. We present new evidence of gas flares in the Andaman forearc basin, detected through water column image (WCI), subbottom profiling, and high-resolution seismic data acquired onboard RV Sindhu Sadhana (SSD-085) in November- December 2021. The gas flares are located over an elongated sedimentary ridge, featuring two prominent mounds (M1 and M2) with distinct geological features. Compressional tectonics induced by the Diligent fault (DLF) formed the ridge with varying slopes and elevations. Gas flares observed above the mound M1 in WCI and sub-bottom profiler data. Seafloor samples reveal carbonate rocks with visible pores, indicating gas/fluid migration or burrows. The regional seismic profile delineates three sedimentary sequences: folded and faulted strata, mass transport deposits, and horizontal-to-sub-horizontal sedimentary layers. Additionally, we observed a bottom simulating reflector (BSR), indicating potential subsurface gas hydrate deposits. Detailed high-resolution seismic data revealed complex fault systems near bathymetry mounds (M1 and M2), which may serve as pathways for vertical fluid/gas migration. [ABSTRACT FROM AUTHOR]

At many dormant volcanoes, magmatic gases are not channeled through preferential degassing routes as fumaroles and only percolate through the flanks of the volcano in a diffuse way. This type of volcanic gas emission provides valuable information, even though the soil matrix contains an important atmospheric component. This study aimed to demonstrate that chemical ratios such as He/CO2 in soil gases provide excellent information on the evolution of volcanic unrest episodes and help forecast the volcanic eruption onset. Before and during the occurrence of the October 2011–March 2012 submarine of El Hierro, Canary Islands, more than 8500 soil He analyses and diffuse CO2 emission measurements were performed. The results show that the soil He/CO2 emission ratio began increasing drastically one month before eruption onset, reaching the maximum value 10 days before. During the eruptive period, this ratio also showed a maximum value several days before the period with the highest magma emission rate. The He/CO2 ratio was also helpful in forecasting the eruption onset. We demonstrate that this tool can be applied in real-time during volcanic emergencies. Our results also encourage a reevaluation of the global He emission from the subaerial volcanism. [ABSTRACT FROM AUTHOR]

The geochemical monitoring of volcanic activity today relies largely on remote sensing, but the combination of this approach together with soil gas monitoring, using the appropriate parameters, is still not widely used. The main purpose of this study was to correlate data from crater gas emissions with flank emissions of soil gases at Mt. Etna volcano from June 2006 to December 2020. Crater SO2 fluxes were measured from fixed stations around the volcano using the DOAS technique and applying a modeled clear-sky spectrum. The SO2/HCl ratio in the crater plume was measured with the OP-FTIR technique from a transportable instrument, using the sun as an IR source. Soil CO2 efflux coupled with the 220Rn/222Rn activity ratio in soil gases (named SGDI) were measured at a fixed monitoring site on the east flank of Etna. All signals acquired were subject both to spectral analysis and to filtering of the periodic signals discovered. All filtered signals revealed changes that were nicely correlated both with other geophysical signals and with volcanic eruptions during the study period. Time lags between parameters were explained in terms of different modes of magma migration and storage inside the volcano before eruptions. A comprehensive dynamic degassing model is presented that allows for a better understanding of magma dynamics in an open-conduit volcano. [ABSTRACT FROM AUTHOR]

Indoor radon surveying and remediation were implemented in a single-family home affected by high levels of indoor radon in the Celleno municipality (central Italy) with the aim of identifying the contribution of radon sources, evaluating the factors affecting radon entry into the building, and reducing radon risk. Average radon levels were relatively low at the ground floor (286 ± 202 Bq m−3) and first floor (167 ± 84 Bq m−3) in autumn when the temperature was still warm and the windows were open, but increased up to 2776 ± 1768 Bq m−3 and 970 ± 202 Bq m−3 in the first half of December, when the heating system was on and the windows were closed. The inner walls of the pilot room at the ground floor, semi buried on one side, were then treated with a waterproof product (a silane terminated polymer) and the average radon was halved (1475 ± 1092 Bq m−3) in the following month, which was still characterised by winter conditions. Radon entry in the room was identified and sealed with the same product, and a radon accumulation space behind a NE-SW oriented wall was naturally ventilated, reducing radon below the reference level in April with northerly winds conditions. [ABSTRACT FROM AUTHOR]

When optimizing irrigation methods, much consideration is given to crop growth indicators while less attention has been paid to soil's gaseous carbon (C) and nitrogen (N) emission indicators. Therefore, adopting an irrigation practice that can reduce emissions while maintaining crop yield and quality is of great interest. Thus, open-field experiments were conducted from September 2020 to January 2022 using a single-factor randomized block design with three replications. The lettuce plants ("Feiqiao Lettuce No.1") were grown using four different irrigation methods established by setting the lower limit of drip irrigation to 75%, 65%, and 55% of soil water content at field capacity corresponding to DR1, DR2, and DR3, respectively. Furrow irrigation (FI) was used as a control. Crop growth indicators and soil gas emissions were observed. Results showed that the mean lettuce yield under DR1 (64,500 kg/ha) was the highest, and it was lower under DR3 and FI. The lettuces under DR3 showed greater concentrations of crude fiber, vitamin C, and soluble sugar, and a greater nitrate concentration. Compared with FI, the DR treatments were more conducive to improving the comprehensive quality of lettuce, including the measured appearance and nutritional quality. Among all the irrigation methods, FI had the maximum cracking rate of lettuce, reaching 25.3%, 24.6%, and 22.7%, respectively, for the three continuous seasons. The stem cracking rates under DR2 were the lowest—only 10.1%, 14.4%, and 8.2%, respectively, which were decreased to nearly half compared with FI. The entropy model detected that the weight coefficient evaluation value of DR2 was the greatest, reaching 0.93, indicating that the DR2 method has the optimal benefits under comprehensive consideration of water saving, yield increase, quality improvement, and emission reduction. [ABSTRACT FROM AUTHOR]

This study uses CR-39 radon detectors to examine radon distributions, seasonal indoor radon variations, correction factors, and the influence of building materials and characteristics on indoor radon concentration in 120 dwellings. The study also determines the spatial distribution of radon levels using the ArcGIS geostatistical method. Radon detectors were exposed in bedrooms from April to July (RS), August to November (DS); December to March (HS), and January-December (YS) from 2021 to 2022. The result for the radon levels during the weather seasons were; 32.3 to 190.1 Bqm-3 (80.9 ± 3.2 Bq/m3) for (RS), 30.8 to 151.4 Bqm-3 (68.5 ± 2.7 Bqm-3) for HS and 24.8 to 112.9 Bqm-3(61.7 ± 2.1 Bqm-3) for DS, and 25.2 to 145.2 Bq/m3 (69.4 ± 2.7 Bqm-3). The arithmetic mean for April to July season was greater than August to November. The correction factors associated with this study ranged from 0.9 to 1.2. The annual effective dose (AE) associated with radon data was varied from 0.6 to 4.04 mSv/y (1.8 ± 0.1 mSv/y). The April to July period which was characterized by rains recorded the highest correlation coefficient and indoor radon concentration. Distribution and radon mapping revealed radon that the exposure to the occupant is non-uniformly spread across the studied dwellings. 15.4% of the studied data exceeded WHO reference values of 100 Bq/m3. The seasonal variation, dwelling age, and building materials were observed to have a substantial impact on the levels of radon concentration within the buildings. [ABSTRACT FROM AUTHOR]

The Jiangmen Underground Neutrino Observatory is constructing the world's largest liquid scintillator detector, with a 20 kt target mass and approximately 700 m of overburden. The total underground space of civil construction is around 300,000 m 3 , with the main hall comprising about 120,000 m 3 , making it the largest experimental hall in the world. Maintaining a low radon concentration in the underground air is crucial for both human health and the accuracy of experiments involving rare decay detection, such as neutrino and dark matter experiments. To ensure human health and the integrity of neutrino physics experiments, the nominal radon concentration in the main hall must be kept below 200 Bq/m 3 with a maximum value below 400 Bq/m 3 . Introduction of fresh air from above ground can significantly lower radon concentration. A benchmark experiment conducted in the refuge room near the main hall revealed that the radon emanating from underground water is a significant source of radon in the underground air. The total underground ventilation rate is approximately 160,000 m 3 /h of fresh air with about 30 Bq/m 3 222 Rn from the bottom of the vertical tunnel after the installation of powerful fans. Of this, 55,000 m 3 /h is used for ventilation in the main hall. As a result of these measures, the radon concentration inside the main hall has decreased from 1600 Bq/m 3 to below 200 Bq/m 3 under stable working conditions, with exceptions during rare adverse weather events or fan failures. The employed strategies to control radon concentration in the underground air are described in this paper. [ABSTRACT FROM AUTHOR]

Boreal forests nowadays act as a sink for atmospheric carbon dioxide; however, their sequestration capacity is highly sensitive to weather conditions and, specifically to ongoing climate warming. Extreme weather events such as heavy rainfalls or, conversely, heat waves during the growing season might perturb the ecosystem carbon balance and convert them to an additional CO2 source. Thus, there is an urgent need to revise ecosystem carbon fluxes in vast Siberian taiga ecosystems as influenced by extreme weather events. In this study, we focused on the soil CO2 pulses appearing after the rainfall events and quantification of their input to the seasonal cumulative CO2 efflux in the boreal forests in Central Siberia. Seasonal measurements of soil CO2 fluxes (both soil respiration and net soil exchange) were conducted during three consecutive frost-free seasons using the dynamic chamber method. Seasonal dynamics of net soil exchange fluxes demonstrated positive values, reflecting that soil respiration rates exceeded CO2 uptake in the forest floor vegetation layer. Moreover, the heavy rains caused a rapid pulse of soil emissions and, as a consequence, the release of additional amounts of CO2 from the soil into the atmosphere. A single rain event may cause a 5–11-fold increase of the NSE flux compared to the pre-rainfall values. The input of CO2 pulses to the seasonal cumulative efflux varied from near zero to 39% depending on precipitation patterns of a particular season. These findings emphasize the critical need for more frequent measurements of soil CO2 fluxes throughout the growing season which capture the CO2 pulses induced by rain events. This approach has inevitable importance for the accurate assessment of seasonal CO2 soil emissions and adequate predictions of response of boreal pine forests to climatic changes. [ABSTRACT FROM AUTHOR]

How convective boundary‐layer (CBL) processes modify fluxes of sensible (SH) and latent (LH) heat and CO2 (Fc) in the atmospheric surface layer (ASL) remains a recalcitrant problem. Here, large eddy simulations for the CBL show that while SH in the ASL decreases linearly with height regardless of soil moisture conditions, LH and Fc decrease linearly with height over wet soils but increase with height over dry soils. This varying flux divergence/convergence is regulated by changes in asymmetric flux transport between top‐down and bottom‐up processes. Such flux divergence and convergence indicate that turbulent fluxes measured in the ASL underestimate and overestimate the "true" surface interfacial fluxes, respectively. While the non‐closure of the surface energy balance persists across all soil moisture states, it improves over drier soils due to overestimated LH. The non‐closure does not imply that Fc is always underestimated; Fc can be overestimated over dry soils despite the non‐closure issue. Plain Language Summary: Large swirling motions, called large turbulent eddies, efficiently transport water vapor, carbon dioxide, and heat up and down throughout the convective boundary layer (CBL). To what extent scalar fluxes in the atmospheric surface layer (ASL) are modulated by large turbulent eddies from the top of the CBL (i.e., top‐down eddies) remains a recalcitrant problem in many fields spanning atmospheric sciences, hydrology, ecology, and climate change. Here, high‐resolution computational simulations of the CBL show that scalar fluxes in the ASL linearly change with height across soil wetness conditions largely due to changes in the interactions of top‐down processes and bottom‐up surface exchange. Such linear height‐dependence of the fluxes indicates that reported fluxes from direct turbulent measurements in the ASL are not identical to their sought surface values. As a result, the non‐closure of the surface energy balance occurs across all soil moisture conditions but improves as soil becomes dry. CO2 measured fluxes are underestimated over wet soils and overestimated over dry soils, which has its implication when interpreting CO2 exchanges from global flux measuring networks utilizing turbulence theories. Height dependence of fluxes, which confirms that the constant flux layer assumption is not routinely satisfied, is a fundamental reason for the non‐closure. Key Points: Asymmetric flux transport by bottom‐up and top‐down processes leads to varying flux divergence/convergence (FDC) in the surface layerLatent heat and CO2 fluxes are underestimated when soil is wet and overestimated when dry, but sensible heat flux is always underestimatedNon‐closure of the surface energy balance is regulated by varying FDC and improves for dry soils due to overestimated latent heat flux [ABSTRACT FROM AUTHOR]

Atmospheric radon measurements assist in many aspects of climate and meteorological research, notably as an airmass tracer and for modelling boundary layer development, mixing heights and stability. Daughter products from radon decay are sometimes incorporated into the particle pollution measurements of commercially available beta-attenuation monitors (BAM). BAMs incorporating radon measurements are used in air quality monitoring networks and can supplement traditional radon measurements. Here we compare in-situ radon measurements from Thermo Fisher Scientific (Franklin, MA, USA) BAM instruments (Thermo Scientific 5014i, Thermo Scientific 5030 SHARP, Thermo Anderson FH62C14) at two air quality monitoring stations in New South Wales, Australia. Between systems we find strong correlations for hourly measurements (r = 0.97–0.99); daily means (r = 0.97–0.99); hour of the day (r = 0.84–0.98); and month (r = 0.82–0.98). The regression analysis for radon measurements between systems showed strong linear responses, although there are some variations in the slopes of the regressions. This implies that with correction BAM measurements can be comparable to standard measurement techniques, for example, from the Australian Nuclear Science and Technology Organisation (ANSTO) dual flow loop monitors. Our findings imply that BAM derived radon measurements are precise, although their accuracy varies. BAM radon measurements can support studies on boundary layer development or where radon is used as an atmospheric transport tracer. [ABSTRACT FROM AUTHOR]

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The occurrence of sinkhole phenomena in Italy is a prevalent and very uncertain class of geological hazards that pose a significant threat to human infrastructure and individuals. These events are characterized by their unpredictability and the challenges associated with their accurate forecasting. Both natural and anthropic factors influence the occurrence of these events; therefore, accurate identification of the above factors is critical for effective proactive and predictive efforts. The work presented in this paper refers to a collapse that occurred in a volcanic region in northern Latium (central Italy) on 31 January 2023. The area has been monitored using drones since the early stages of the sinkhole's formation and has continued to date. Then, the collapse and the neighboring area were examined via geophysical and geochemical investigations to identify potential underlying factors. Geophysical and geochemical data were combined to provide a preliminary hypothesis on the collapse's genesis. The obtained data indicate that the structural collapse can be attributable to the fluctuation in groundwater levels as well as the development of instabilities along its banks, leading to a growth in its dimensions. [ABSTRACT FROM AUTHOR]

Radon and its progenies found in water indicate the existence of seismically active faults in the region. However, exposure to high levels of radon can also result in radiation-related health risks. This study focuses on radon-based active tectonic studies along the Muzaffarabad Fault in the core of the Hazara-Kashmir Syntaxis (HKS), NW Himalayas, Pakistan. In this study, spring water samples were collected along roadside of Jhelum Valley and in close proximity to the Muzaffarabad Fault in Pakistan using Radon Thoron Monitor (RTM1688-2). The results of the study showed that the radon concentrations in the water samples ranged from 1.895 to 17.097 Bq/l. The study found that the highest radon concentration was observed in the samples collected closest to the fault, while the lowest concentration was observed in the samples collected further away. The statistical analysis between the radon concentration and the distance from the fault showed a strong inverse relationship (R2=0.73). The study also found that 68% of the sampling sites had radon concentrations that exceeded the maximum contamination level (MCL) set by the US Environmental Protection Agency (EPA). The higher radon concentrations in the springs water suggest the probability of earthquake, which in turn poses potential health risks for the local population. The findings suggest that the measurement of radon concentration in water can be used as a tool for identifying seismically active faults in the region. [ABSTRACT FROM AUTHOR]

In the frame of a collaboration between the Italian National Research Council (CNR) and Mares s.r.l., a study, about the possibility of determining radon vertical distribution at different soil depths in order to trace light non-aqueous phase liquid (LNAPL) contaminations, was developed. The radon deficit technique, based on the preferential solubility of soil gas radon into non-polar fluids, such as refined hydrocarbons, has been investigated by various theoretical and applied research so far. According to international scientific literature, radon deficit can be used both for geochemical prospection of the spatial irregular NAPL dispersion and for monitoring of remediation activities. Even though it is well known that this type of pollutants can be distributed along the vertical soil profile—firstly due to their density in comparison to water density, and secondly due to fluctuations of shallow aquifers, soil pore size, aging of contamination, and so on—the vertical localization of the plume still represents a scientific challenge. In this article, a method to determine the radon vertical profile is tested and applied to assess the potential use of the radon deficit technique in the vertical detection of pollutant presence for the first time in a fuelling station. Two LNAPL-contaminated sites were selected for a pilot test. Experimental findings seem to support the use of vertical radon geochemical prospection to delimit the depth range of a LNAPL pollution directly. Systematic data collection and modeling may lead to a 3D reconstruction of the dispersion of contaminant in different soil levels. [ABSTRACT FROM AUTHOR]

Most marine gas hydrate systems follow a vertical pattern with hydrate overlying free gas. Here we document the discovery of a gas to hydrate system in a horizontal sand layer in the Qiongdongnan Basin of the South China Sea. Eight wells were drilled by the Guangzhou Marine Geological Survey in 2021–2022 to investigate the occurrence and mechanisms responsible for the formation of the system. We describe a free gas‐bearing sand reservoir at the center of the system sustained by advecting hot fluids and gas; away from the advecting zone, the cooler, surrounding sand reservoir is filled with hydrate. Observations at this site show that advective heat has a large control on hydrate formation in sands and may be a key mechanism which allows gas migration within the hydrate stability zone and the formation of high‐saturation hydrate in sand layers. Plain Language Summary: Natural gas hydrate, an ice‐like substance composed of water and gas, is commonly found in sediments under the ocean. Most marine hydrate systems follow a vertical pattern where hydrate‐bearing sediments overlie free gas‐bearing sediments; in addition, most hydrate is hosted in marine muds at low concentration. Here we document a horizontal system that transitions from high concentrations of free gas to high concentrations of hydrate in a horizontal sand layer in the northern South China Sea. Two recent drilling expeditions are conducted to explore this unique system. Seismic and logging data suggests that multiple processes including focused fluid flow, capillary sealing and heat transfer control the formation of the system. Key Points: We discover a gas hydrate system where gas transitions to hydrate in a flat‐lying sand layer in the northern South China SeaCapillary sealing occurs at the sand‐clay interface, preventing upward fluid advection and causes fluids to migrate laterallyAdvecting warm fluids and gas are the primary control on the hydrate and free gas system in this sand layer [ABSTRACT FROM AUTHOR]

Hundreds of thousands of unconventional natural gas wells recently constructed across North America have transformed the global energy landscape and generated widespread concern relating to fugitive methane leakage. To date, no studies have evaluated the integrity of unconventional wells post‐abandonment. Here, we evaluated emissions at nine decommissioned unconventional wells within the Montney region of British Columbia, Canada and found two exhibited co‐emission of CH4 and CO2 from surrounding soils indicating integrity failure, releasing up to ∼2,000 kg of CO2‐eq/yr into the atmosphere. A further three wells exhibited statistically significant anomalous CO2 fluxes of ∼500 kg/year from surficial soils around the well, likely associated with minor integrity failure and derived from near total soil‐based aerobic oxidation of fugitive CH4. These findings suggest that more than half of decommissioned unconventional wells may generate emissions, however only relatively small contributions to GHG emissions result that are significantly mitigated through natural soils‐based CH4 oxidation. Plain Language Summary: We examined the integrity of decommissioned unconventional wells hosted in the Montney Play of British Columbia, Canada, with a view to constraining emission incidence rates and quantifying potential fugitive emissions to atmosphere. Through monitoring of soil gas fluxes, climatic factors and characterizing gas molecular signatures and surficial sediments, we show that out of nine unconventional wells examined two were co‐emitting small excess amounts of CH4 and CO2 while a further three were emitting excess CO2 from soils around the wellhead indicative of leakage. We conclude that while emissions from some decommissioned unconventional wells may occur, natural soils‐based oxidation may fully convert released CH4 to CO2 and significantly mitigate greenhouse gas emissions from such sources. Key Points: First evaluation of leakage of methane from nine decommissioned unconventional gas wellsAt least five wells (56% of those examined) potentially suffering integrity loss resulting in minimal emissionsMethane emissions observed are considerably mitigated through natural soils‐based oxidation [ABSTRACT FROM AUTHOR]

The mid-eastern segment of the Qilianshan fault zone (QLF) on the northeastern margin of the Qinghai–Tibet Plateau is considered one of the key seismic hazard areas. The Zhangye Ms5.0 earthquake and Menyuan Ms6.9 earthquake are the two Ms ≥ 5.0 earthquakes in recent years. The spatio-temporal evolution of Rn across the fault before the two Ms ≥ 5.0 earthquakes were explored by combining a solid seismogenic model and numerical simulation results in this study. The results demonstrates the spatial distribution of Rn concentration intensity varies over time, indicating the evolving characteristics of fracture zone activity. The time-series variation characteristics are closely related the Zhangye Ms5.0 earthquake and Menyuan Ms6.9 earthquake. Overall, in the seismic source area and surrounding medium area of Zhangye Ms5.0 earthquake, the soil gas Rn anomaly across faults characterized by a turning upward trend after continuous decline. The closer to the source area, the more obvious the upward trend. For Menyuan Ms6.9 earthquake, the survey line (HT1) located in the main fracture zone of the earthquake and the survey line (HT7,30km from the epicenter) closer to the epicenter also showed a similar trend, while the other measurement lines in far-field exhibit declining trend before the Menyuan Ms6.9 earthquake. Therefore, the continuous decline trend of soil gas may be crucial information for medium-term earthquake preparation in the seismogenic zone, and the trend of turning upward after continuous decline is a significant signal of short-term seismogenic event in far-field. This research could improve the understanding of the anomalous features of soil gas precursors and tracking the active sections of the fault. According to the model, the earthquake area canseismic source area, the surrounding medium area be divided into three sections: the seismic source area, the surrounding medium area, and the fracture fragmentation area. [ABSTRACT FROM AUTHOR]

Multivariate classification and regression analysis of multiple meteorological variables and indoor radon activity concentration in Ground Level Laboratory in the Institute of Physics Belgrade, was performed and discussed. Meteorological variables used in this analysis were from radon active device, nearby meteorological station and finally from Global Data Assimilation System. Single variate analysis has identified variables with greatest value of Pearson's correlation coefficient with radon activity concentration and also, variables with greatest separation of events with increased radon activity concentration of over 200 Bqm-3 and of events with radon level below this value. This initial analysis is showing the expected behavior of radon concentration with meteorological variables, with emphasis on data periods with or without air conditioning and with emphasis on indoor water vapor pressure, which was, in our previous research, identified as important variable in analysis of radon variability. This single variate analysis, including all data, proved that Global Data Assimilation System data could be used as a good enough approximate replacement for meteorological data from nearby meteorological station for multivariate analysis. Variable importance of Boosted Decision Trees with Gradient boosting multivariate analysis method are shown for all three periods and most important variables were discussed. Multivariate regression analysis gave good results, and can be useful to better tune the multivariate analysis methods. [ABSTRACT FROM AUTHOR]

Indoor radon, thoron and thoron progeny concentrations, along with the equilibrium factor for thoron progeny and soil gas radon concentrations, have been measured to assess radiological risks in the centre and south regions of Cameroon. Indoor radon and thoron concentrations were estimated using radon–thoron discriminative detectors (RADUET), while thoron progeny monitors measured the equilibrium equivalent thoron concentration (EETC). Radon concentrations in the soil were determined using a MARKUS 10 detector. It was found that radon, thoron and thoron progeny concentrations range between 19 and 62 Bq m−3, 10 and 394 Bq m−3 and 0.05 and 21.8 Bq m−3, with geometric means of 32 Bq m−3, 98 Bq m−3 and 4.9 Bq m−3, respectively. The thoron equilibrium factor ranges between 0.007 and 0.24, with an arithmetic mean of 0.06 ± 0.03; this is higher than the world average value of 0.02 provided by the United Nations Scientific Commission on the Effects of Atomic Radiation(UNSCEAR, New York, USA). The level of the soil radon concentration ranges from 4.8 to 57.3 kBq m−3, with a geometric mean of 12.1 kBq m−3 at a depth of 0.7 m. Of the sampling points, 66% fall within normal radon risk areas, and 3% of the sampling areas are high radon risk areas exceeding 50 kBq m−3. The annual effective dose was found to be 0.03 ± 0.01 mSv for radon, 0.08 ± 0.05 mSv for thoron, 0.63 ± 0.12 mSv for radon progeny and 1.40 ± 0.84 mSv for thoron progeny. The total dose is estimated to be 2.14 mSv y−1. The mean estimated indoor excess lifetime cancer risk values due to radon, thoron, radon progeny and thoron progeny are 0.12 × 10−3, 0.31 × 10−3, 2.51 × 10−3 and 5.58 × 10−3, respectively. Thoron progeny contributed 60% to the effective dose. Thus, thoron progeny cannot be neglected in dose assessments, in order to avoid biased results in radio-epidemiological studies. [ABSTRACT FROM AUTHOR]

The potential risks of vapor intrusion (VI) can arise from low bulk soil contaminant concentration existing in shallow soils beneath a building foundation. To assess VI risks for such a contamination scenario, a comprehensive study was conducted on a factory building located at a trichloroethylene (TCE)-contaminated site. This study involved the integration of various types of field data, including groundwater, bulk soil, soil gas and indoor air data, along with the utilization of the Vapor Intrusion Screening Level (VISL) calculator. Previously observed high TCE concentrations in soil gas are attributed to accumulation of TCE vapor within the unsaturated soil beneath the building floor, since ground surface is extensively paved at this site. These soil gas data do not directly correlate with the magnitudes of bulk soil and/or groundwater TCE concentration with the linear adsorption model. Soil gas TCE concentration exceeding 107 μg/m³ (or bulk soil concentration exceeding 18.9 mg/kg) observed in shallow soils (at a depth of less than 1 m) may pose health risk to the workers inside the building due to VI, as we have detected TCE vapor concentrations exceeding indoor air screening level several times in the past. This bulk soil TCE concentration, however, falls below soil pollution control standards for TCE, i.e., 60 mg/kg, in Taiwan. As a result, soil remediation is not considered at this site. Soil gas TCE concentrations have reduced to less than 106 μg/m³ after two years of groundwater remediation work at this site. However, we have observed significantly higher soil gas TCE levels at a depth of 0.5 m compared to other depths. This discrepancy raises suspicions that an amount of TCE may still be trapped within the shallow soils that are not reached by groundwater table. [ABSTRACT FROM AUTHOR]

The exploration of natural H2 or white hydrogen has started in various geological settings. Ophiolitic nappes are already recognized as one of the promising contexts. In South America, the only data available so far concerns the Archean iron-rich rocks of the Mina Gerais in Brazil or the subduction context of Bolivia. In Colombia, despite government efforts to promote white hydrogen, data remain limited. This article introduces the initial dataset obtained through soil gas sampling within the Cauca-Patia Valley and Western Cordillera, where the underlying geology comprises accreted oceanic lithosphere. In this valley, promising areas with H2 potential were identified using remote sensing tools, in particular vegetation anomalies. The Atmospherically Resistant Vegetation Index (ARVI) appears to be well adapted for this context and the field data collection confirmed the presence of H2 in the soil in all pre-selected structures. The valley undergoes extensive cultivation, mainly for sugar cane production. While H2 emissions lead to alterations in vegetation, unlike reports from other countries, they do not result in its complete disappearance. Soil gas measurements along the thrusts bordering the Cauca Valley also show high H2 content in the fault zones. In the valley, the presence of sedimentary cover above the ophiolites which are presumably the H2 generating rocks, which addresses the possible presence of reservoirs and seals to define potential plays. Drawing parallels with the Malian case, it could be that the intrusive element could serve as seals. [ABSTRACT FROM AUTHOR]

Expansive soils change volume due to changes in moisture content, which results in ground movement. Lightweight shallow-depth structures such as pavements, residential footings, and pipelines can suffer distress as they face additional stresses from the moving ground. The soil reactivity (the ability of soil to expand or contract due to change in moisture content) and the interactions at the soil-atmosphere-vegetation boundary are two of the major contributing factors to the ground movement. The current methodology used in design to account for ground movement is based on limited field and laboratory observations. Aiming at a better understanding of the interaction at the soil-atmosphere-vegetation boundary and its correlation with ground movement, this paper presents results from a field study. The research site was located in a semi-arid climate area and consisted of moderately to highly reactive clay soils. Part of the site was vegetated with mature trees, and part was occupied by grass. The order of 10 s of mm difference was observed in the magnitude of movement across the site owing to site soil variability as well as differences in vegetation. The areas with large trees showed relatively lower ground movement over the study period compared to the area occupied by grass, which was attributed to the microclimate created by the tree canopy and the already established deeper drying of the soil near the trees. [ABSTRACT FROM AUTHOR]

Background: Changes in soil greenhouse gas (GHG) fluxes caused by nitrogen (N) addition are considered as the key factors contributing to global climate change (global warming and altered precipitation regimes), which in turn alters the feedback between N addition and soil GHG fluxes. However, the effects of N addition on soil GHG emissions under climate change are highly variable and context-dependent, so that further syntheses are required. Here, a meta-analysis of the interactive effects of N addition and climate change (warming and altered precipitation) on the fluxes of three main soil GHGs [carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O)] was conducted by synthesizing 2103 observations retrieved from 57 peer-reviewed articles on multiple terrestrial ecosystems globally. Results: The interactive effects of N addition and climate change on GHG fluxes were generally additive. The combination of N addition and warming or altered precipitation increased N2O emissions significantly while it had minimal effects on CO2 emissions and CH4 uptake, and the effects on CH4 emissions could not be evaluated. Moreover, the magnitude of the combined effects did not differ significantly from the effects of N addition alone. Apparently, the combined effects on CO2 and CH4 varied among ecosystem types due to differences in soil moisture, which was in contrast to the soil N2O emission responses. The soil GHG flux responses to combined N addition and climate change also varied among different climatic conditions and experimental methods. Conclusion: Overall, our findings indicate that the effects of N addition and climate change on soil GHG fluxes were relatively independent, i.e. combined effects of N addition and climate change were equal to or not significantly different from the sum of their respective individual effects. The effects of N addition on soil GHG fluxes influence the feedbacks between climate change and soil GHG fluxes. [ABSTRACT FROM AUTHOR]

In the outdoor environment of Qena city, located in southern Egypt, 222Rn concentrations were continuously measured from January 2015 to December 2015 using Alpha-Guard radon monitor, PQ 2000 PRO. Meteorological parameters (air temperature AT, relative humidity RH, and evaporation rate EV) and gaseous pollutants [ozone O3, nitrogen oxide NOx, and particulate matter that has a diameter of less than 10 µm (PM10)] data for the same period were collected from the meteorological station. This work aims to study the potential relationships between 222Rn and each of the meteorological parameters and gaseous pollutants. According to observational data, the yearly average concentrations of 222Rn were 19.35 ± 1.58 Bq/m3, 31.68 ± 1.97 µg/m3 for O3, 9.97 ± 2.27 µg/m3 for NOx, and 109.95 ± 6.48 µg/m3 for PM10. The concentration of 222Rn is positively correlated with relative humidity, nitrogen oxide, and particulate matter, whereas it is negatively correlated with air temperature, evaporation rate, and ozone. Descriptive statistical analysis revealed various distribution patterns for 222Rn, meteorological parameters, and gaseous pollutants. [ABSTRACT FROM AUTHOR]

OpenToolFlux 1.0 is an open-source software designed to estimate soil gas fluxes from gas concentration time-series data generated by automatic chamber systems. This paper describes the physical equipment used as well as the software design and workflow. The software is a command-line application that imports tabular time-series data from the analyzer following the instructions specified in a configuration file by the user, performs configurable data-cleaning operations, and outputs a data file with volumetric flux estimates as well as diagnostic plots. The software can be configured according to the specifics of the physical equipment and experimental setups, and it is, therefore, applicable to a wide range of studies. [ABSTRACT FROM AUTHOR]

The processes of heat and moisture transfer in mole plowed undersoil are modeled taking into account the phase transitions of water and steam. The annual and daily temperature fluctuations over the depth of the soil layer and ground have been studied. Estimates of moisture condensation onto the inner surface of the soil and mole passage are proposed. The velocities of atmospheric air movement in mole passages and its flow rates in laminar and turbulent modes of flow are determined. Moisture condensation from the soil air into the root layer at night and in the morning was found. It has been established that under natural conditions the mass of the condensate fallen in mole passages is insufficient to significantly increase the moisture content of soil, but the presence of mole passages in the soil has a positive effect on its productivity. It is shown that the use of such passages in semideserts improves the feeding of saigas and other wild animals. [ABSTRACT FROM AUTHOR]

Gas permeability (ka) and gas diffusion coefficient (Dp) are vital for controlling gas transport through earthen landfill cover overlying municipal solid wastes or acid mine tailings. Soil clods generated during the construction of landfill cover can result in various soil microstructures. However, the effects of soil microstructure on Dp and ka are unclear. This study aimed to investigate and compare effects of soil microstructure on measured ka and Dp of compacted manufactured sand tailings (MST)-bentonite mixtures, considering the effects of specimen preparation method, compaction water content (wcomp), and wetting path. The related pore size distributions (PSDs) were measured by mercury intrusion porosimetry. The measurements show that the average ka of as-compacted specimens increased and then decreased as wcomp increased (i.e., a lower soil air content ε —gas-filled volume per unit soil volume), while Dp reduced monotonically. It was because the compacted MST-bentonite mixtures exhibited a multimodal PSD, in which macropores significantly increased the average advective flow velocity of gas. However, the average diffusive flow velocity of gas was independent of pore size, according to the kinetic theory of gas molecules. Conversely, ka and Dp both decreased as ε decreased when the water content of the as-compacted specimen was increased along the wetting path by spraying water, due to the wetting-induced collapse of macropores. These illustrated that Dp was mainly controlled by the ε and tortuosity of gas-filled pores, while ka was dominated by well-connected gas-filled macropores. Moreover, the PSD of specimens was affected by the specimen preparation method, bentonite content, and sieving treatment, thus affecting ka and Dp. [ABSTRACT FROM AUTHOR]

The development of geochemical exploration technologies unaffected by marsh microorganisms is necessary to improve the prediction of wells and explore for natural gas hydrates in mid-latitude permafrost areas. Here, we examine the potential of inert gas as a new tool for the investigation of gas hydrates in permafrost areas. The study area, 150 km2 in size, is situated in the alpine wetland landscape of the Qilian Mountains. The sampling density and depth were 2 points/km2 and 60 cm, respectively. In total, 300 soil and headspace gas samples were collected. The chromatographic backflush technique was used to analyze the inert gases helium (He) and neon (Ne) in the headspace gas samples. A comprehensive interpretation was conducted based on geological and geochemical survey results. We propose a geogas migration mechanism of inert gases in the soil above the natural gas hydrate deposits. The inert gas anomalies near the ground surface of the Muli coalfield in the Qilian Mountains, derived from the deep hydrate deposits and fault structure, are not affected by marsh microorganisms. Thus, inert gas anomalies are practical tools for natural gas hydrate exploration in permafrost areas. [ABSTRACT FROM AUTHOR]

Soil greenhouse gas (GHG) fluxes relate to soil carbon and nitrogen budgets and have a significant impact on climate change. Nevertheless, the temporal variation and magnitude of the fluxes of all three major GHGs (CO2, CH4 and N2O) and their influencing factors have not been elucidated clearly in primary forests on the eastern Qinghai-Tibetan Plateau. Herein, field chamber GHG fluxes from May to November, soil microbial community and enzyme activity were analyzed in a fir-dominated (Abies fargesii var. faxoniana) primary forest. The emission rates of CO2 and N2O ranged between 64.69–243.22 mg CO2 m−2 h−1 and 1.69–5.46 ug N2O m−2 h−1, exhibiting a temporally unimodal pattern with a peak in July. The soil acted as a CH4 sink, and the uptake rate varied between 52.96 and 84.67 μg CH4 m−2 h−1 with the higher uptake rates in June and November. The temporal variation in the CO2 flux was significantly correlated with the geometric mean of enzyme activities, suggesting that the soil CO2 flux was determined by microbial activity rather than soil microbial biomass. The soil N2O flux was positively related to nitrate concentration with marginal significance, probably because N2O was a byproduct of nitrification and denitrification processes. The soil CH4 uptake was closely associated with methanotrophic biomass (18:1ω7c). The results highlight divergent temporal dynamics of GHG fluxes owing to different driving mechanisms and an important CH4 sink in the primary forest soil, helping to evaluate the carbon and nitrogen budgets of primary forests on the eastern Qinghai-Tibetan Plateau. [ABSTRACT FROM AUTHOR]

Land-surface models represent exchange processes between soil and atmosphere via the surface by coupling water, energy and carbon fluxes. As it strongly mediates the link between these cycles and, vegetation is an important component of land-surface models. In doing so, some of these models include modules for vegetation dynamics which allow adaptation of vegetation biomass, especially leaf area index, to environmental conditions. Here, we conducted a model-data comparison to investigate whether and how vegetation dynamics in the models improves the representation of vegetation processes and related surface fluxes in two specific models ECLand and Noah-MP in contrast to using prescribed values from look-up tables or satellite-based products. We compare model results with stations from the FLUXNET 2015 dataset covering a range in climate and vegetation types, the MODIS leaf area product, and use more detailed information from the TERENO site "Hohes Holz". With the current implementation, switching vegetation dynamics on did not enhance representativeness of e.g. leaf area index and net ecosystem exchange in ECLand, while Noah-MP improved it only for some sites. The representation of energy fluxes and soil moisture was almost unaffected for both models. Interestingly, for both models, the performance regarding vegetation- and hydrology-related variables was unrelated, such that the weak performance regarding e.g. leaf area index did not detoriate the performance regarding e.g. latent heat flux. One reason, we showed here, might be that implemented ecosystem processes diverge from the observations in their seasonal patterns and variability. Noah-MP includes a seasonal hysteresis of the relationship between leaf area index and gross primary production that cannot be found in observations. The same relationship is represented by a strong linear response in ECLand which substantially underestimates the variability seen in observations. For both, water and carbon fluxes, the current implemented modules for vegetation dynamics in these two models yielded no better model performance compared to runs with static vegetation and prescribed leaf-area climatology. [ABSTRACT FROM AUTHOR]

Plant leaf temperature and its environmental parameters provide valuable information on plant growth. This paper presents the development of a plant monitoring system using an IoT-based SCADA (Supervisory Control and Data Acquisition). The developed SCADA system monitors the leaf temperature and the air parameters of temperature and humidity, as well as the soil parameters of temperature, moisture, pH, electrical conductivity, nitrogen, phosphorous, and potassium. A novel method is proposed for measuring the leaf temperature using a low-cost 8 × 8 array thermal camera. The sensor systems in the field are developed to wirelessly communicate with the Hawell IoT Cloud HMI via a Modbus TCP protocol. To visualize the thermal image on the HMI dashboard, a novel approach is proposed wherein the data are transferred using the Modbus TCP protocol. The HMI is connected to a cloud server and can be accessed by the users using the web browser or mobile application on a smartphone. The experimental results show that the proposed hardware, software, and communication protocol are reliable for real-time and continuous plant monitoring. Further, the evaluation of sensor data shows that the data from the thermal camera and air parameters sensor can be independently interpreted. However, the data from the soil sensor should be interpreted in consideration of the other parameters. [ABSTRACT FROM AUTHOR]

Radon is a major source of naturally occurring radioactivity, and its measurement is considered extremely important in radiation protection, given its association with lung cancer. This pilot study aimed to estimate the annual effective dose received by students and staff based on monitoring data on the concentration of radon in the buildings of al-Farabi Kazakh National University (Almaty, Republic of Kazakhstan), based on the distance to the tectonic fault. The measurements were recorded daily from February 2021 to September 2022 using a RAMON-02 radiometer (SOLO LLP, Almaty, Kazakhstan). All measurements were taken from the basement to the top floor under normal conditions of use. The average accumulated concentrations of radon in the studied buildings ranged from 16.34 to 78.33 Bq/m3, which is below the maximum level of 100 Bq/m3 established by the World Health Organization (WHO) and the legislation of the Republic of Kazakhstan (200 Bq/m3). Relatively high values were recorded in the basement of the Faculty of Physics and Technology building (282.0 Bq/m3 in winter, 1742.0 Bq/m3 in spring, 547.7 Bq/m3 in summer, and 550.7 Bq/m3 in autumn), which is located closest to the tectonic fault and poorly ventilated. In almost all rooms (94%), radon levels were within the WHO-recommended reference level. The averaged results show the influence of the distance to the fault on the average indoor radon levels. The annual effective dose of radon for university students and staff ranged from 1.09 mSv/year to 1.53 mSv/year. The excess lifetime risk of developing cancer ranged from 0.44% to 0.61%. [ABSTRACT FROM AUTHOR]

Urumqi City, located in the northwest of China, is a city with a high indoor radon concentration in a nationwide indoor radon survey in China. This study focuses on the assessment of the indoor radon level and its distribution in this city. Indoor radon measurement using RAD7 and solid nuclear track detector (SSNTD), soil gas radon measured by RAD7, and the determination of the specific activity of uranium and radium in soil samples by a high pure germanium spectrometer were performed from 2021 to 2023. The results reveal a wide range of indoor radon concentrations in Urumqi, with anomalies above 400 Bq/m3 in some dwellings. The arithmetical and geometric mean values of indoor radon concentration are 80 ± 77 Bq/m3 and 58 Bq/m3, respectively. The geometric mean value of radon measured by SSNTD is 101 Bq/m3. The distribution of areas with a high indoor radon concentration is spatially consistent with deep and large active faults or overlapping and intersection zones of multiple groups of faults. It is recommended to conduct a more comprehensive investigation and research into the elevated radon potential and radioactivity associated with building materials. [ABSTRACT FROM AUTHOR]

With increasing global temperatures, it remains unclear, how seedling emergence and survival will be affected in highly dynamic ecosystems like salt marshes. Our study combines passive and active warming treatments with the natural inundation dynamics of salt marshes. We studied the effects of active soil and passive air warming (ambient temperature, + 1.5°C and + 3.0°C) on seedling numbers of different species in three salt marsh zones (pioneer zone, low marsh, and high marsh) and on seedling survival (lifespan), seedling diversity and species richness in two salt marsh zones (low marsh and high marsh) in situ. We found a significant influence of warming on Shannon diversity at two dates, but we found no significant effects of warming on seedling number and survival. However, we found trends, which differed between zones. In the pioneer zone, seedling numbers were slightly higher in the warming treatments than in the ambient treatment from April to June. Whereas, in the high marsh, seedling numbers decreased more in the warming treatments during the same period. The median lifespan was slightly reduced under warming treatments. We conclude warming might have increased drought stress for seedlings in the high marsh, which led to the trend of lower seedling numbers and shorter survival times. Seedling number decreased with elevation, which could be attributed to both species‐specific strategies and differences in available space. Median survival differed significantly between species, which we assume is due to differing life‐history traits like seed size and if the species are annual or perennial. [ABSTRACT FROM AUTHOR]

BTEX (benzene, toluene, ethylbenzene, and xylene), as characteristic pollutants in chemical plant sites, are widely present in the environment and pose a serious threat to the health and safety of nearby residents. Studying the spatial distribution characteristics and transport fluxes of BTEX in soil and air at contaminated sites and the health risks they pose to humans is of great significance for fine pollution control and environmental management. This study took a typical decommissioned steel plant as a case study. A total of 23 soil and air samples were collected from different locations to investigate the spatial distribution characteristics of BTEX in soil and air. The transport and fate of BTEX in soil and air were evaluated using the fugacity model, and finally, a human health risk assessment was conducted. The results indicate a relatively severe level of benzene pollution in both soil and air. The maximum exceedance factor of benzene in soil samples is 31.5, with the concentration exceedance depth at 1.5 m. The maximum concentration of benzene in air samples is 4.98 μg·m−3. Benzene, at 5.9% of the site, shows a low flux with negative values, while other components at various locations all exhibit a trend of transport from the soil phase to the atmospheric phase. Benzene is the pollutant that contributes the most to the transport flux from soil to air within the site. The coking area and sewage treatment area are key areas within the steel mill where BTEX accumulate easily in the soil. The non-carcinogenic risk values of the individual components of BTEX in the soil are below the acceptable risk level. However, the carcinogenic risk value of benzene in the children's exposure scenario exceeds the carcinogenic risk level of 10−6. The carcinogenic risk range of various components of BTEX in the air is 2.63 × 10−6~3.88 × 10−5, with 28.6% of the locations exceeding the threshold of 10−6. The range of the total HI (hazard index) is 2.08 × 10−4~1.81 × 10−1, all of which is below the safety threshold of 1. The results of this study will provide scientific support for the fine pollution control and environmental management of industrial contaminated sites with BTEX as their typical pollutants. [ABSTRACT FROM AUTHOR]

Featured Application: Soil gas permeability in various fields. The measurement of soil gas permeability is influenced by the temperature and pressure fluctuation in the low gas pressure region. In order to investigate these influences, a soil temperature-controlled apparatus connected to a low-gas-pressure supply equipment is proposed in this study. The low constant gas pressure is supplied by two Mariotte bottles, by which the airflow rate is measured. Meanwhile, the soil specimen is controlled by a temperature-controlled apparatus. During the test, the negative pore water pressure and volume change of the soil specimen are measured. Through the temperature-controlled apparatus, it is observed that as the temperature increases from 25 °C to 60 °C, there is a corresponding increase in soil sample porosity by 5.4%, while the negative pressure of pore water decreases by 11.1%. This can be attributed to the reduction in the surface tension of contractile skin caused by elevated temperatures. Furthermore, due to variations in gas viscosity with temperature, there was a significant decrease in the gas flow rate by 50.5%. And, the relationship between permeability and volumetric gas content at different temperatures in low-pressure regions well confirms the existing power-law model. In addition, the existence of a temperature-independent critical negative pore water pressure is observed, beyond which the intrinsic permeability remains constant. At 36 kPa of negative pore water pressure, the intrinsic permeability at 60 °C exhibits an 81.8% reduction compared to that at 25 °C. This decline in intrinsic permeability can be attributed to a diminished pore connectivity, resulting from elevated temperatures. [ABSTRACT FROM AUTHOR]