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The icy moons of the outer Solar System display evidence of subsurface liquid water and, therefore, potential habitability for life. Flybys of Saturn's moon Enceladus by the Cassini spacecraft have provided measurements of material from plumes that suggest hydrothermal activity and the presence of organic matter. Jupiter's moon Europa may have similar plumes and is the target for the forthcoming Europa Clipper mission that carries a high mass resolution and high sensitivity mass spectrometer, called the MAss Spectrometer for Planetary EXploration (MASPEX), with the capability for providing detailed characterization of any organic materials encountered. We have performed a series of experiments using pyrolysis-gas chromatography-mass spectrometry to characterize the mass spectrometric fingerprints of microbial life. A range of extremophile Archaea and Bacteria have been analyzed and the laboratory data converted to MASPEX-type signals. Molecular characteristics of protein, carbohydrate, and lipid structures were detected, and the characteristic fragmentation patterns corresponding to these different biological structures were identified. Protein pyrolysis fragments included phenols, nitrogen heterocycles, and cyclic dipeptides. Oxygen heterocycles, such as furans, were detected from carbohydrates. Our data reveal how mass spectrometry on Europa Clipper can aid in the identification of the presence of life, by looking for characteristic bacterial fingerprints that are similar to those from simple Earthly organisms.

Improved methods are presented for the separation of platinum from iron meteorites and subsequent analyses of both mass-independent and mass-dependent Pt isotope compositions of iron meteorites by multiple collector ICP-MS. The procedures are optimised for sample throughput and feature improvements in yield and the reduction of constituents that produce spectral interferences and matrix effects. The performance of the methods is demonstrated by replicate analyses of terrestrial reference materials and eight iron meteorites from the IC and IVB groups. The pilot iron meteorite analyses confirm previous work, which demonstrates that the Pt isotope compositions of iron meteorites are particularly sensitive to alteration by neutron capture reactions induced by exposure to galactic cosmic rays (GCR). It is shown that the mass-independent Pt isotope data obtained with the new methods are suitable for accurate correction of correlated cosmogenic isotope effects for other isotope systems in the same sample aliquots. The methods for the measurement of mass-dependent Pt isotope compositions (δ198Pt) employ a robust double spike approach. The accurate determination of δ198Pt values for iron meteorites requires, however, that possible cosmogenic isotope effects from GCR exposure are monitored and appropriately corrected on a sample aliquot specific basis. A robust approach for such corrections using the mass-independent Pt isotope data collected with the new methods is shown to provide accurate results for iron meteorites with variable compositions and GCR exposure histories. Initial results obtained for eight IC and IVB iron meteorites reveal both within- and between-group variations in δ198Pt values, which indicate that such analyses may provide novel constraints for studies of planetary processes.

Cyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High-resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well-suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408-U1410 are highly complex with several hiatuses. Here, we built a two-site composite and constructed a conservative age-depth model to provide a reliable chronology for this rhythmic, highly resolved (

Meteorites are excavated fragments from asteroid surfaces and planets, and determining their thermophysical properties is important since they contain valuable information about internal structures of their parent bodies. We investigated thermophysical properties of the Saricicek meteorite by differential scanning calorimetry (DSC), measuring phase transition temperatures, enthalpy changes and specific heat capacities of samples and thermogravimetric analysis (TGA), investigating weight change in a sample as a function of temperature or time. DSC results indicate that troilite alpha/beta and beta/gamma phase transition temperatures of the interior part of the meteorite were at 421.98 +/- 0.02 and 581.74 +/- 1.71 K, and troilite content of interior and crust parts of the meteorite were 0.28 and 0.02 wt%, respectively. Relict temperatures were calculated as 453 +/- 10, 465 +/- 17, and 588 +/- 55 K; specific heat capacities were measured as 779, 745, and 663 J kg(-1) K-1 at 300 K; and predicted as 568, 537, and 480 J kg(-1) K-1 at 200 K, for interior, edge, and crust, respectively. TGA results revealed that Saricicek's weight loss was 0.98% at 1170 degrees C, and water content and hydrogen abundance at 200-800 degrees C were 0.34% and 0.04%, respectively. Obtained results shed light on a thermal history of Saricicek's parent body and provide further knowledge on thermal alteration of 4 Vesta., Ege University Scientific Research Projects Coordination Unit [17-FEN-050]; Scientific and Technological Research Council of Turkey (TUBITAK) [MFAG/113F035], This work was supported by Ege University Scientific Research Projects Coordination Unit (project number 17-FEN-050). Ozan Unsalan acknowledges the Scientific and Technological Research Council of Turkey (TUBITAK) that supported meteoritic studies in Turkey (project number MFAG/113F035). The authors gratefully thank Professor Akira Yamaguchi and Professor Guy Consolmagno for very detailed and constructive reviews. We are also indebted to Professor Dr. A. J. Timothy Jull for instructive insights and extensive editorial suggestions.

A full-mission analysis has been conducted of Cl-bearing species in the coma of comet 67P/Churyumov–Gerasimenko as detected by the Double Focusing Mass Spectrometer (DFMS) of Rosetta's ROSINA instrument. The isotope ratio of the two stable chlorine isotopes 37Cl/35Cl is found to be 0.336 ± 0.017, to be compared with the standard mean ocean chloride value of 0.320. The isotope ratio does not change appreciably throughout the mission. The Cl-bearing species fingerprint in DFMS indicates that there is at least one additional chlorine-bearing species in the coma next to HCl, CH3Cl, and NH4Cl. The identity of this volatile or semivolatile species is unknown at this time.

Accretion disks surrounding compact objects, and other environmental factors, deviate satellites from geodetic motion. Unfortunately, setting up the equations of motion for such relativistic trajectories is not as simple as in Newtonian mechanics. The principle of general (or Lorentz) covariance and the mass-shell constraint make it difficult to parametrize physically adequate 4-forces. Here, we propose a solution to this old problem. We apply our framework to several conservative and dissipative forces. In particular, we propose covariant formulations for Hooke's law and the constant force, and compute the drag due to gravitational and hard-sphere collisions in dust, gas and radiation media. We recover and covariantly extend known forces such as Epstein drag, Chandrasekhar's dynamical friction and Poynting-Robertson drag. Variable-mass effects are also considered, namely Hoyle-Lyttleton accretion and the variable-mass rocket. We conclude with two applications: 1. The free-falling spring. We find that Hooke's law corrects the deviation equation by an effective Anti-de Sitter tidal force; 2. Black hole infall with drag. We numerically compute some trajectories on a Schwarzschild background supporting a dust-like accretion disk., Comment: 21 pages + appendices; v2: revised introduction, added conclusion. Accepted in PRD

Meteorites contain organic matter that may have contributed to the origin of life on Earth. Carbonyl compounds such as aldehydes and carboxylic acids, which occur in meteorites, may be precursors of biologically necessary organic materials in the solar system. Therefore, such organic matter is of astrobiological importance and their detection and characterization can contribute to the understanding of the early solar system as well as the origin of life. Most organic matter is typically sub-micrometer in size, and organic nanoglobules are even smaller (50-300 nm). Novel analytical techniques with nanoscale spatial resolution are required to detect and characterize organic matter within extraterrestrial materials. Most techniques require powdered samples, consume the material, and lose petrographic context of organics. Here, we report the detection of nanoglobular aldehyde and carboxylic acids in a highly primitive carbonaceous chondrite (DOM 08006) with similar to 20 nm spatial resolution using nano-FTIR spectroscopy. Such organic matter is found within the matrix of DOM 08006 and is typically 50-300 nm in size. We also show petrographic context and nanoscale morphologic/topographic features of the organic matter. Our results indicate that prebiotic carbonyl nanoglobules can form in a less aqueous and relatively elevated temperature-environment (220-230 degrees C) in a carbonaceous parent body. RISE2 node of NASA's Solar System Exploration Research Virtual Institute (SSERVI) We thank the associate editor and the reviewers for their constructive comments, which significantly improved this manuscript. We thank NASA-JSC for providing the meteorite samples. This work was also supported in part by the RISE2 node of NASA's Solar System Exploration Research Virtual Institute (SSERVI; PI: T.D. Glotch).

International audience; Carbonaceous chondrites are often considered potential contributors of water and other volatiles to terrestrial planets as most of them contain significant amounts of hydrous mineral phases. As such, carbonaceous chondrites are candidate building blocks for Earth, and elucidating their thermal histories is of direct importance for understanding the volatile element history of Earth and the terrestrial planets. A significant fraction of CM type carbonaceous chondrites are thermally metamorphosed or "heated" and have lost part of their water content. The origin and the timing of such heating events are still debated, as they could have occurred either in the first Myrs of the Solar System via short-lived radioactive heating, or later by impact induced heating and/or solar radiation. Since Rb is more volatile than Sr, and some heated CM chondrites are highly depleted in Rb, a dating system based on the radioactive decay of Rb-87 to( 87)Sr(lambda(87) Rb = 1.393 x 10(-11) yr(-1)) could be used to date the heating event relating to the fractionation of Rb and Sr. Here, we have leveraged the Rb-87/Sr-87 system to date the heating of five CM chondrites (PCA 02012, PCA 02010, PCA 91008, QUE 93005 and MIL 07675). We find that the heating events of all five meteorites occurred at least 3 Ga after the formation of the Solar System. Such timing excludes short-lived radioactive heating as the origin of thermal metamorphism in these meteorites, and relates such heating events to ages of collisional families of C-type asteroids.

The presence of an unseen ‘Planet 9’ on the outskirts of the Solar system has been invoked to explain the unexpected clustering of the orbits of several Edgeworth–Kuiper Belt Objects. We use N-body simulations to investigate the probability that Planet 9 was a free-floating planet (FFLOP) that was captured by the Sun in its birth star formation environment. We find that only 1–6 per cent of FFLOPs are ensnared by stars, even with the most optimal initial conditions for capture in star-forming regions (one FFLOP per star, and highly correlated stellar velocities to facilitate capture). Depending on the initial conditions of the star-forming regions, only 5–10 of 10 000 planets are captured on to orbits that lie within the constraints for Planet 9. When we apply an additional environmental constraint for Solar system formation – namely the injection of short-lived radioisotopes into the Sun’s protoplanetary disc from supernovae – we find the probability for the capture of Planet 9 to be almost zero., Monthly Notices of the Royal Astronomical Society. Letters, 472 (1), ISSN:1745-3933, ISSN:1745-3925

The atmospheric entry heating of micrometeorites (MMs) can significantly alter their pre-existing mineralogy, texture and organic material. The degree of heating depends predominantly on the gravity and atmospheric density of the planet on which they fall. For particles falling on Earth the alteration can be significant, leading to the destruction of much of the pre-entry organics, however, the weaker gravity and thinner atmosphere of Mars enhances the survival of MMs and increases the fraction of particles that preserve organic material. This paper investigates the entry heating of MMs on the Earth and Mars in order to examine the micrometeorite population on each planet and give insights into the survival of extraterrestrial organic material. The results show that particles reaching the surface of Mars experience a lower peak temperature compared to Earth and, therefore, experience less evaporative mass loss. Of the particles which reach the surface, 68.2% remain unmelted on Mars compared to only 22.8% on Earth. Due to evaporative mass loss, unmelted particles that reach the surface of Earth are restricted to sizes 475 µm survive unmelted on Mars. Approximately 10% of particles experience temperatures below ~800 K, i.e. the sublimation temperature of refractory organics found in MMs. On Earth this fraction is significantly lower with less than 1% expected to remain below this temperature. Lower peak temperatures coupled with the larger sizes of particles surviving without significant heating on Mars suggests a much higher fraction of organic material surviving to the martian surface.

Advancing technology in near-infrared instrumentation and dedicated planetary telescope facilities have enabled nearly two decades of reconnoitering the spectral properties for near-Earth objects (NEOs). We report measured spectral properties for more than 1000 NEOs, representing >5% of the currently discovered population. Thermal flux detected below 2.5 µm allows us to make albedo estimates for nearly 50 objects, including two comets. Additional spectral data are reported for more than 350 Mars-crossing asteroids. Most of these measurements were achieved through a collaboration between researchers at the Massachusetts Institute of Technology and the University of Hawaii, with full cooperation of the NASA Infrared Telescope Facility (IRTF) on Mauna Kea. We call this project the MIT-Hawaii Near-Earth Object Spectroscopic Survey (MITHNEOS; myth-neos). While MITHNEOS has continuously released all spectral data for immediate use by the scientific community, our objectives for this paper are to: (1) detail the methods and limits of the survey data, (2) formally present a compilation of results including their taxonomic classification within a single internally consistent framework, (3) perform a preliminary analysis on the overall population characteristics with a concentration toward deducing key physical processes and identifying their source region for escaping the main belt. Augmenting our newly published measurements are the previously published results from the broad NEO community, including many results graciously shared by colleagues prior to formal publication. With this collective data set, we find the near-Earth population matches the diversity of the main-belt, with all main-belt taxonomic classes represented in our sample. Potentially hazardous asteroids (PHAs) as well as the subset of mission accessible asteroids (ΔV ≤ 7 km/s) both appear to be a representative mix of the overall NEO population, consistent with strong dynamical mixing for the population that interacts most closely with Earth. Mars crossers, however, are less diverse and appear to more closely match the inner belt population from where they have more recently diffused. The fractional distributions of major taxonomic classes (60% S, 20% C, 20% other) appear remarkably constant over two orders of magnitude in size (10 km to 100 m), which is eight orders of magnitude in mass, though we note unaccounted bias effects enter into our statistics below about 500 m. Given the range of surface ages, including possible refreshment by planetary encounters, we are able to identify a very specific space weathering vector tracing the transition from Q- to Sq- to S-types that follows the natural dispersion for asteroid spectra mapped into principal component space. We also are able to interpret a shock darkening vector that may account for some objects having featureless spectra. Space weathering effects for C-types are complex; these results are described separately by Lantz, Binzel, DeMeo. (2018, Icarus 302, 10–17). Independent correlation of dynamical models with taxonomic classes map the escape zones for NEOs to main-belt regions consistent with well established heliocentric compositional gradients. We push beyond taxonomy to interpret our visible plus near-infrared spectra in terms of the olivine and pyroxene mineralogy consistent with the H, L, and LL classes of ordinary chondrites meteorites. Correlating meteorite interpretations with dynamical escape region models shows a preference for LL chondrites to arrive from the ν6 resonance and H chondrites to have a preferential signature from the mid-belt region (3:1 resonance). L chondrites show some preference toward the outer belt, but not at a significant level. We define a Space Weathering Parameter as a continuous variable and find evidence for step-wise changes in space weathering properties across different planet crossing zones in the inner solar system. Overall we hypothesize the relative roles of planetary encounters, YORP spin-up, and thermal cycling across the inner solar system.

Micrometeorites (MMs) provide constraints on the flux and sources of extraterrestrial dust falling on Earth as well as recording the processes occurring during atmospheric entry. Collections of micrometeorites have been recovered from a wide variety of environments including Antarctic moraine, rock traps, ice and snow and on roof tops in urban areas. Studies of the mineralogy and composition of MMs suggest that most particles (>98%) >50 ​μm in diameter have asteroidal sources, whilst ~50% of particles smaller than 50 ​μm are likely to be derived from comets. The relative abundance of S(IV)-type asteroid materials, similar to ordinary chondrites increases with size, although C-type asteroidal materials, similar to carbonaceous chondrites dominate over all. Although MMs provide excellent evidence on the nature and abundance of extraterrestrial dust at the Earth’s orbit they are not without bias and uncertainty. Mineralogical and compositional change during atmospheric entry makes the exact nature of their precursors uncertain complicating evaluation of source beyond basic classes of material. This is particularly true at larger sizes when complete melting to form cosmic spherules occurs, however, unmelted MMs >50 ​μm in size are also often thermally altered. Mixing with atmospheric oxygen and mass fractionation by evaporation furthermore complicates the use of oxygen isotope compositions in identifying parent bodies. All MM collections are suggested to exhibit biases owing to: (1) collection method, (2) terrestrial weathering, (3) terrestrial contamination, and (4) erosion and deposition by terrestrial surface processes. Even in the least biased collections, those collected by dedicated melting of Antarctic snow, erosive loss of material is suggested here to make fluxes uncertain by factors of up to ~2. The abundance of asteroid-derived MMs observed in collections contradicts models of the orbital evolution of interplanetary dust to Earth, which suggests >70% should be provided by comets.

CASTAway is a mission concept to explore our Solar System's main asteroid belt. Asteroids and comets provide a window into the formation and evolution of our Solar System and the composition of these objects can be inferred from space-based remote sensing using spectroscopic techniques. Variations in composition across the asteroid populations provide a tracer for the dynamical evolution of the Solar System. The mission combines a long-range (point source) telescopic survey of over 10,000 objects, targeted close encounters with 10 to 20 asteroids and serendipitous searches to constrain the distribution of smaller (e.g. 10 m) size objects into a single concept. With a carefully targeted trajectory that loops through the asteroid belt, CASTAway would provide a comprehensive survey of the main belt at multiple scales. The scientific payload comprises a 50 cm diameter telescope that includes an integrated low-resolution (R = 30 to 100) spectrometer and visible context imager, a thermal (e.g. 6 to 16 microns) imager for use during the flybys, and modified star tracker cameras to detect small (approx. 10 m) asteroids. The CASTAway spacecraft and payload have high levels of technology readiness and are designed to fit within the programmatic and cost caps for a European Space Agency medium class mission, whilst delivering a significant increase in knowledge of our Solar System., 40 pages, accepted by Advances in Space Research October 2017

The debiased absolute-magnitude and orbit distributions as well as source regions for near-Earth objects (NEOs) provide a fundamental frame of reference for studies of individual NEOs and more complex population-level questions. We present a new four-dimensional model of the NEO population that describes debiased steady-state distributions of semimajor axis, eccentricity, inclination, and absolute magnitude $H$ in the range $17, Comment: 33 pages, 28 figures, accepted for publication in Icarus

The Outer Solar System Origins Survey (OSSOS), a wide-field imaging program in 2013-2017 with the Canada-France-Hawaii Telescope, surveyed 155 deg$^{2}$ of sky to depths of $m_r = 24.1$-25.2. We present 838 outer Solar System discoveries that are entirely free of ephemeris bias. This increases the inventory of trans-Neptunian objects (TNOs) with accurately known orbits by nearly 50%. Each minor planet has 20-60 Gaia/Pan-STARRS-calibrated astrometric measurements made over 2-5 oppositions, which allows accurate classification of their orbits within the trans-Neptunian dynamical populations. The populations orbiting in mean-motion resonance with Neptune are key to understanding Neptune's early migration. Our 313 resonant TNOs, including 132 plutinos, triple the available characterized sample and include new occupancy of distant resonances out to semi-major axis $a \sim 130$ au. OSSOS doubles the known population of the non-resonant Kuiper belt, providing 436 TNOs in this region, all with exceptionally high-quality orbits of $a$ uncertainty $\sigma_{a} \leq 0.1\%$; they show the belt exists from $a \gtrsim 37$ au, with a lower perihelion bound of $35$ au. We confirm the presence of a concentrated low-inclination $a\simeq 44$ au "kernel" population and a dynamically cold population extending beyond the 2:1 resonance. We finely quantify the survey's observational biases. Our survey simulator provides a straightforward way to impose these biases on models of the trans-Neptunian orbit distributions, allowing statistical comparison to the discoveries. The OSSOS TNOs, unprecedented in their orbital precision for the size of the sample, are ideal for testing concepts of the history of giant planet migration in the Solar System., Comment: Invited paper, special issue Data: Insights and Challenges in a Time of Abundance. Data tables and example survey simulator are in the supplementary materials (see arXiv source under Downloads > Other formats)

The X-ray luminosities of T Tauri stars are about two to four orders of magnitude higher than the luminosity of the contemporary Sun. As these stars are born in clusters, their disks are not only irradiated by their parent star but also by an X-ray background field produced by the cluster members. We aim to quantify the impact of X-ray background fields produced by young embedded clusters on the chemical structure of disks. Further, we want to investigate the importance of the dust for X-ray radiative transfer in disks. We present a new X-ray radiative transfer module for the radiation thermo-chemical disk code ProDiMo, which includes X-ray scattering and absorption by both the gas and dust component. For the X-ray radiative transfer, we consider irradiation by the star and by X-ray background fields. To study the impact of X-rays on the chemical structure of disks we use the well-established disk ionization tracers N2H+ and HCO+. For evolved dust populations, X-ray opacities are mostly dominated by the gas; only for photon energies $E\gtrsim5-10\,$keV, dust opacities become relevant. Consequently, the local disk X-ray radiation field is only affected in dense regions close to the disk midplane. X-ray background fields can dominate the local X-ray disk ionization rate for disk radii $r\gtrsim20\,$au. However, the N2H+ and HCO+ column densities are only significantly affected in case of low cosmic-ray ionization rates, or if the background flux is at least a factor of ten higher than the flux level expected for clusters typical for the solar vicinity. Observable signatures of X-ray background fields in low-mass star-formation regions, like Taurus, are only expected for cluster members experiencing a strong X-ray background field. For the majority of the cluster members, the X-ray background field has only little impact on the disk chemical structure., 16 pages, 12 figures, accepted for publication in A&A

The short-lived $^{182}$Hf-$^{182}$W decay system is a powerful chronometer for constraining the timing of metal-silicate separation and core formation in planetesimals and planets. Neutron capture effects on W isotopes, however, significantly hamper the application of this tool. In order to correct for neutron capture effects, Pt isotopes have emerged as a reliable in-situ neutron dosimeter. This study applies this method to IAB iron meteorites, in order to constrain the timing of metal segregation on the IAB parent body. The $\epsilon^{182}$W values obtained for the IAB iron meteorites range from -3.61 $\pm$ 0.10 to -2.73 $\pm$ 0.09. Correlating $\epsilon^{\mathrm{i}}$Pt with $^{182}$W data yields a pre-neutron capture $^{182}$W of -2.90 $\pm$ 0.06. This corresponds to a metal-silicate separation age of 6.0 $\pm$ 0.8 Ma after CAI for the IAB parent body, and is interpreted to represent a body-wide melting event. Later, between 10 and 14 Ma after CAI, an impact led to a catastrophic break-up and subsequent reassembly of the parent body. Thermal models of the interior evolution that are consistent with these estimates suggest that the IAB parent body underwent metal-silicate separation as a result of internal heating by short-lived radionuclides and accreted at around 1.4 $\pm$ 0.1 Ma after CAIs with a radius of greater than 60 km., Comment: 11 pages, 8 figures, 2 tables; open access article under the CC BY-NC-ND license (see http://creativecommons.org/licenses/by-nc-nd/4.0/)

In the past years the observational evidence that s-process elements from Sr to Pb are produced by stars ascending the socalled Asymptotic Giant Branch (or AGB) could not be explained by self-consistent models, forcing researchers to extensive parameterizations. The crucial point is to understand how protons can be injected from the envelope into the He-rich layers, yielding the formation of 13C and then the activation of the 13C(a,n)16O reaction. Only recently, attempts to solve this problem started to consider quantitatively physically-based mixing mechanisms. Among them, MHD processes in the plasma were suggested to yield mass transport through magnetic buoyancy. In this framework, we compare results of nucleosynthesis models for Low Mass AGB Stars (M, 16 page, 10 figures

The winonaites are primitive achondrites which are associated with the IAB iron meteorites. Textural evidence implies heating to at least the Fe, Ni–FeS cotectic, but previous geochemical studies are ambiguous about the extent of silicate melting in these samples. Oxygen isotope evidence indicates that the precursor material may be related to the carbonaceous chondrites. Here we analysed a suite of winonaites for modal mineralogy and bulk major- and trace-element chemistry in order to assess the extent of thermal processing as well as constrain the precursor composition of the winonaite-IAB parent asteroid.\ud \ud Modal mineralogy and geochemical data are presented for eight winonaites. Textural analysis reveals that, for our sub-set of samples, all except the most primitive winonaite (Northwest Africa 1463) reached the Fe, Ni–FeS cotectic. However, only one (Tierra Blanca) shows geochemical evidence for silicate melting processes. Tierra Blanca is interpreted as a residue of small-degree silicate melting. Our sample of Winona shows geochemical evidence for extensive terrestrial weathering. All other winonaites studied here (Fortuna, Queen Alexander Range 94535, Hammadah al Hamra 193, Pontlyfni and NWA 1463) have chondritic major-element ratios and flat CI-normalised bulk rare-earth element patterns, suggesting that most of the winonaites did not reach the silicate melting temperature. The majority of winonaites were therefore heated to a narrow temperature range of between ∼1220 (the Fe, Ni–FeS cotectic temperature) and ∼1370 K (the basaltic partial melting temperature). Silicate inclusions in the IAB irons demonstrate partial melting did occur in some parts of the parent body (Ruzicka and Hutson, 2010), thereby implying heterogeneous heat distribution within this asteroid. Together, this indicates that melting was the result of internal heating by short-lived radionuclides. The brecciated nature of the winonaites suggests that the parent body was later disrupted by a catastrophic impact, which allowed the preservation of the largely unmelted winonaites.\ud \ud Despite major-element similarities to both ordinary and enstatite chondrites, trace-element analysis suggests the winonaite parent body had a carbonaceous chondrite-like precursor composition. The parent body of the winonaites was volatile-depleted relative to CI, but enriched compared to the other carbonaceous classes. The closest match are the CM chondrites; however, the specific precursor is not sampled in current meteorite collections.

International audience; Recent models involving the Moon-forming giant impact hypothesis have managed to reproduce the striking isotopic similarity between the two bodies, albeit using two extreme models: one involves a high-energy small impactor that makes the Moon out of Earth's proto-mantle; the other supposes a gigantic collision between two half-Earths creating the Earth-Moon system from both bodies. Here we modeled the geochemical influence of the giant impact on Earth's mantle and found that impactors larger than 15% of Earth mass result in mantles always violating the present-day concentrations of four refractory moderately siderophile trace elements (Ni, Co, Cr, and V). In the aftermath of the impact, our models cannot further discriminate between a fully and a partially molten bulk silicate Earth. Then, the preservation of primordial geochemical reservoirs predating the Moon remains the sole argument against a fully molten mantle after the Moon-forming impact.

During the planet formation process, billions of comets are created and ejected into interstellar space. The detection and characterization of such interstellar comets (also known as extra-solar planetesimals or extra-solar comets) would give us in situ information about the efficiency and properties of planet formation throughout the galaxy. However, no interstellar comets have ever been detected, despite the fact that their hyperbolic orbits would make them readily identifiable as unrelated to the solar system. Moro-Mart\'in et al. 2009 have made a detailed and reasonable estimate of the properties of the interstellar comet population. We extend their estimates of detectability with a numerical model that allows us to consider "close" interstellar comets, e.g., those that come within the orbit of Jupiter. We include several constraints on a "detectable" object that allow for realistic estimates of the frequency of detections expected from the Large Synoptic Survey Telescope (LSST) and other surveys. The influence of several of the assumed model parameters on the frequency of detections is explored in detail. Based on the expectation from Moro-Mart\'in et al. 2009, we expect that LSST will detect 0.001-10 interstellar comets during its nominal 10-year lifetime, with most of the uncertainty from the unknown number density of small (nuclei of $\sim$0.1-1 km) interstellar comets. Using simulated LSST-like astrometric data, we study the problem of orbit determination for these bodies, finding that LSST could identify their orbits as hyperbolic and determine an ephemeris sufficiently accurate for follow-up in about 4-7 days. We give the hyperbolic orbital parameters of the most detectable interstellar comets. Taking the results into consideration, we give recommendations to future searches for interstellar comets., Comment: Published in Astrophysical Journal, 18 pages, 5 figures

Organics are observed to be a significant component of cosmic dust in nearly all environments were dust is observed. In many cases only remote telescope observations of these materials are obtainable and our knowledge of the nature of these materials is very basic. However, it is possible to obtain actual samples of extraterrestrial dust in the Earth’s stratosphere, in Antarctic ice and snow, in near-Earth orbit, and via spacecraft missions to asteroids and comets. It is clear that cosmic dust contains a diverse population of organic materials that owe their origins to a variety of chemical processes occurring in many different environments. The presence of isotopic enrichments of D and 15N suggests that many of these organic materials have an interstellar/protosolar heritage. The study of these samples is of considerable importance since they are the best preserved materials of the early Solar System available.

International audience; Atmospheric transport and suspension of dust frequently brings electrification, which may be substantial. Electric fields of 10 kV m−1 to 100 kV m−1 have been observed at the surface beneath suspended dust in the terrestrial atmosphere, and some electrification has been observed to persist in dust at levels to 5 km, as well as in volcanic plumes. The interaction between individual particles which causes the electrification is incompletely understood, and multiple processes are thought to be acting. A variation in particle charge with particle size, and the effect of gravitational separation explains to, some extent, the charge structures observed in terrestrial dust storms. More extensive flow-based modelling demonstrates that bulk electric fields in excess of 10 kV m−1 can be obtained rapidly (in less than 10 s) from rotating dust systems (dust devils) and that terrestrial breakdown fields can be obtained. Modelled profiles of electrical conductivity in the Martian atmosphere suggest the possibility of dust electrification, and dust devils have been suggested as a mechanism of charge separation able to maintain current flow between one region of the atmosphere and another, through a global circuit. Fundamental new understanding of Martian atmospheric electricity will result from the ExoMars mission, which carries the DREAMS (Dust characterization, Risk Assessment, and Environment Analyser on the Martian Surface)—MicroARES (Atmospheric Radiation and Electricity Sensor) instrumentation to Mars in 2016 for the first in situ electrical measurements.

International audience; Isotopic ratios in comets provide keys for the understanding of the origin of cometary material, and the physical and chemical conditions in the early Solar Nebula. We review here measurements acquired on the D/H, N-14/N-15, O-16/O-18, C-12/C-13, and S-32/S-34 ratios in cometary grains and gases, and discuss their cosmogonic implications. The review includes analyses of potential cometary material available in collections on Earth, recent measurements achieved with the Herschel Space Observatory, large optical telescopes, and Rosetta, as well as recent results obtained from models of chemical-dynamical deuterium fractionation in the early solar nebula. Prospects for future measurements are presented.

Context: The $^{15}$N fractionation has been observed to show large variations among astrophysical sources, depending both on the type of target and on the molecular tracer used. These variations cannot be reproduced by the current chemical models. Aims: Until now, the $^{14}$N/$^{15}$N ratio in N$_2$H$^+$ has been accurately measured in only one prestellar source, L1544, where strong levels of fractionation, with depletion in $^{15}$N, are found ($^{14}$N/$^{15}$N$\: \approx 1000$). In this paper we extend the sample to three more bona fide prestellar cores, in order to understand if the antifractionation in N$_2$H$^+$ is a common feature of this kind of sources. Methods: We observed N$_2$H$^+$,N$^{15}$NH$^+$ and $^{15}$NNH$^+$ in L183, L429 and L694-2 with the IRAM 30m telescope. We modeled the emission with a non-local radiative transfer code in order to obtain accurate estimates of the molecular column densities, including the one for the optically thick N$_2$H$^+$. We used the most recent collisional rate coefficients available, and with these we also re-analysed the L1544 spectra previously published. Results: The obtained isotopic ratios are in the range $630-770$ and significantly differ with the value, predicted by the most recent chemical models, of $\approx 440$, close to the protosolar value. Our prestellar core sample shows high level of depletion of $^{15}$N in diazenylium, as previously found in L1544. A revision of the N chemical networks is needed in order to explain these results., Comment: Accepted for publication in A&A

The origin of Earth oceans is controversial. Earth could have acquired its water either from hydrated silicates (wet Earth scenario) or from comets (dry Earth scenario). [HDO]/[H2O] ratios are used to discriminate between the scenarios. High [HDO]/[H2O] ratios are found in Earth oceans. These high ratios are often attributed to the release of deuterium enriched cometary water ice, which was formed at low gas and dust temperatures. Observations do not show high [HDO]/[H2O] in interstellar ices. We investigate the possible formation of high [HDO]/[H2O] ratios in dense (n(H) > 106 cm-3) and warm gas (T = 100-1000 K) by gas-phase photochemistry in the absence of grain surface chemistry. We derive analytical solutions, taking into account the major neutral-neutral reactions for gases at T > 100 K. The chemical network is dominated by photodissociation and neutral-neutral reactions. Despite the high gas temperature, deuterium fractionation occurs because of the difference in activation energy between deuteration enrichment and the back reactions. The analytical solutions were confirmed by the time-dependent chemical results in a 10-3 M-circle dot disc around a typical T Tauri star using the photochemical code ProDiMo. The ProDiMo code includes frequency-dependent 2D dust-continuum radiative transfer, detailed non-local thermodynamic equilibrium gas heating and cooling and hydrostatic calculation of the disc structure. Both analytical and time-dependent models predict high [HDO]/[H2O] ratios in the terrestrial planet-forming region (

The debris disk around $\beta$~Pictoris is known to contain gas. Previous ALMA observations revealed a CO belt at $\sim$85 au with a distinct clump, interpreted as a location of enhanced gas production. Photodissociation converts CO into C and O within $\sim$50 years. We resolve CI emission at 492 GHz using ALMA and study its spatial distribution. CI shows the same clump as seen for CO. This is surprising, as C is expected to quickly spread in azimuth. We derive a low C mass (between $5\times10^{-4}$ and $3.1\times10^{-3}$ M$_\oplus$), indicating that gas production started only recently (within $\sim$5000 years). No evidence is seen for an atomic accretion disk inwards of the CO belt, perhaps because the gas did not yet have time to spread radially. The fact that C and CO share the same asymmetry argues against a previously proposed scenario where the clump is due to an outward migrating planet trapping planetesimals in an resonance; nor can the observations be explained by an eccentric planetesimal belt secularly forced by a planet. Instead, we suggest that the dust and gas disks should be eccentric. Such a configuration, we further speculate, might be produced by a recent tidal disruption event. Assuming that the disrupted body has had a CO mass fraction of 10%, its total mass would be $\gtrsim$3 $M_\mathrm{Moon}$., Comment: 30 pages, 15 figures, accepted by ApJ

We review our knowledge of the icy moons of Saturn prior to the Cassini orbital mission, describe the discoveries made by the instrumentation onboard the Cassini spacecraft.

We present a model that describes stellar infrared excesses due to heating of the interstellar (IS) dust by a hot star passing through a diffuse IS cloud. This model is applied to six lambda Bootis stars with infrared excesses. Plausible values for the IS medium (ISM) density and relative velocity between the cloud and the star yield fits to the excess emission. This result is consistent with the diffusion/accretion hypothesis that lambda Bootis stars (A- to F-type stars with large underabundances of Fe-peak elements) owe their characteristics to interactions with the ISM. This proposal invokes radiation pressure from the star to repel the IS dust and excavate a paraboloidal dust cavity in the IS cloud, while the metal-poor gas is accreted onto the stellar photosphere. However, the measurements of the infrared excesses can also be fit by planetary debris disk models. A more detailed consideration of the conditions to produce lambda Bootis characteristics indicates that the majority of infrared-excess stars within the Local Bubble probably have debris disks. Nevertheless, more distant stars may often have excesses due to heating of interstellar material such as in our model., 10 pages, 5 figures, 4 tables, accepted by ApJ, emulateapj

The Optical, Spectroscopic, and Infrared Remote Imaging System OSIRIS is the scientific camera system onboard the Rosetta spacecraft (Figure 1). The advanced high performance imaging system will be pivotal for the success of the Rosetta mission. OSIRIS will detect 67P/Churyumov-Gerasimenko from a distance of more than 106 km, characterise the comet shape and volume, its rotational state and find a suitable landing spot for Philae, the Rosetta lander. OSIRIS will observe the nucleus, its activity and surroundings down to a scale of ~2 cm px−1. The observations will begin well before the onset of cometary activity and will extend over months until the comet reaches perihelion. During the rendezvous episode of the Rosetta mission, OSIRIS will provide key information about the nature of cometary nuclei and reveal the physics of cometary activity that leads to the gas and dust coma. OSIRIS comprises a high resolution Narrow Angle Camera (NAC) unit and a Wide Angle Camera (WAC) unit accompanied by three electronics boxes. The NAC is designed to obtain high resolution images of the surface of comet 67P/Churyumov-Gerasimenko through 12 discrete filters over the wavelength range 250–1000 nm at an angular resolution of 18.6 μrad px−1. The WAC is optimised to provide images of the near-nucleus environment in 14 discrete filters at an angular resolution of 101 μrad px−1. The two units use identical shutter, filter wheel, front door, and detector systems. They are operated by a common Data Processing Unit. The OSIRIS instrument has a total mass of 35 kg and is provided by institutes from six European countries. The support of the national funding agencies of Germany (DLR), France (CNES), Italy (ASI), Sweden (SNSB), and Spain (MEC) is gratefully acknowledged. Substantial support for the development of the Data Processing Unit was provided by the ESA Technical Directorate through the Technical Research Programme. In addition to the formal co-authors of this paper (comprising lead scientists, Co-Is, project managers, and lead engineers ), the project was supported by an enormous number of scientists, engineers, and technicians involved in the day-to-day development of the hardware. These include J. C. Blanc, D. Pouliquen, M. Saisse (France), A. Alvarez, A. L. Arteaga, A. Carretero, M. Fernández, H. Guerrero, P. Gutiérrez, J. L. Lizondo, V. Luengo, J. A. Martín, M. A. Martín, J. Meseguer, J. M. Mi, L. Moreno, J. Navarro, A. Núñez, E. Ragel, D. Rodríguez, G. Rosa, A. Sanchez, J. C. Sanmartín, G. Tonellotto (Spain), W. Boogaerts, W. Engelhardt, K. Eulig, B. Fiethe, A. Fischer, M. Gartner, K. Grabig, K. Kellner, A. Kiihn. W. Kiihn. J. Knollenberg, W. Neumann, J. Nitsch, P. Rüffer, H. Schüddekopf, U. Schiihlc. I. Sebastian, S. Stelzer, U. Strohmeyer, T. Tzscheetzsch, M. Wassermeyer (Germany), B. Johlander (ESTEC), M. Baessato, P. F. Brunello, S. Casotto, F. Don-, M. Lazzarin, E. Marchetti, F. Marzari, P. G. Nicolosi, F. Perón, F. Rampazzi, B. Saggin, G. Tondello, S. Verani, P. Zambolin ' (Italy), J. Lagerros, and B. Davidsson (Sweden). Peerreview

We have analyzed the 9.7 and "18'' mu m interstellar silicate absorption features along the line of sight toward four heavily extincted galactic WC-type Wolf-Rayet (WR) stars. We construct two interstellar extinction curves from 1.25 to 25 mu m using near-IR extinction measurements from the literature, along with the silicate profiles of WR 98a ( representing the local ISM) and GCS3 ( representing the Galactic center). We have investigated the mineralogy of the interstellar silicates by comparing extinction profiles for amorphous silicates with olivine and pyroxene stoichiometry to the 9.7 and "18'' mu m absorption features in the WR 98a spectrum. In this analysis, we have considered solid and porous spheres and a continuous distribution of ellipsoids. While it is not possible to simultaneously provide a perfect match to both profiles, we find that the best match requires a mixture of these two types of compounds. We also consider iron oxides, aluminosilicates, and silicate carbide (SiC) as grain components. Iron oxides cannot be accommodated in the observed spectrum, while the amount of Si in SiC is limited to

Electron-stimulated oxidation of CO in layered H2O/CO/H2O ices was investigated with infrared reflectionabsorption spectroscopy (IRAS) as a function of the distance of the CO layer from the water/vacuum interface. The results show that while both oxidation and reduction reactions occur within the irradiated water films, there are distinct regions where either oxidation or reduction reactions are dominant. At depths less than similar to 15 ML from the vacuum interface, CO oxidation to CO2 dominates over the sequential hydrogenation of CO to methanol (CH3OH), consistent with previous observations. At its highest yield, CO2 accounts for similar to 45% of all the reacted CO. Another oxidation product is identified as the formate anion (HCO2). In contrast, for CO buried more than similar to 35 ML below the water/vacuum interface, the CO-to-methanol conversion efficiency is close to 100%. Production of CO2 and formate is not observed for the more deeply buried CO layers, where hydrogenation dominates. Experiments with CO dosed on preirradiated ASW samples suggest that OH radicals are primarily responsible for the oxidation reactions. Possible mechanisms of CO oxidation, involving primary and secondary processes of water radiolysis at low temperature, are discussed. The observed distance-dependent radiation chemistry results from the higher mobility of hydrogen atoms that are created by the interaction of the 100 eV electrons with the water films. These hydrogen atoms, which are primarily created at or near the water/vacuum interface, can desorb from or diffuse into the water films, while the less-mobile OH radicals remain in the near-surface zone, resulting in preferential oxidation reactions there. The diffusing hydrogen atoms are responsible for the hydrogenation reactions that are dominant for the more deeply buried CO layers.

In the present study, a range of igneous rocks with weight percentage of silica ranging from 45% to 70% were used to generate reflectance spectra in the VIS-NIR region. The laboratory generated reflectance spectra of these rocks were used to study the effect of chemical composition and mineralogy on the spectral properties. The characteristic spectral features were evaluated based on the mineralogical and chemical characteristics of the rocks. The main spectral features in the VIS-NIR region are the 0.7 mu m absorption band due to the inter valance charge transfer between Fe2+ and Fe3+ termed as Band F, the 1 mu m broad absorption band from Fe2+ at the octahedral sites in pyroxene termed as Band I, the 1.9 mu m and 2.3 mu m narrow absorption bands due to H2O or OH functional group in hydrated minerals. The 2 mu m absorption feature (Band II; Cloutis and Gaffey, 1991) is observed as a weak feature in all the mafic rocks. The analysis of Band I with the bulk chemistry and mineralogy, we observed a positive correlation to the bulk Ca abundance. Rocks with high bulk calcic content exemplify Band I as a prominent spectral feature towards longer wavelength. Consequently, basalt, gabbro and anorthositic rocks show Band I as a strong feature. However, rocks with low bulk Calcic content show Band I as weak absorption feature observed towards shorter wavelength. Thus, igneous rocks of alkaline affinity have subdued Band I feature that appears towards shorter wavelength. The analysis of Band F with the bulk chemistry and mineralogy showed a positive correlation to the bulk Fe abundance. The results of the present study have implications towards remote compositional mapping and lithological discrimination for Planetary Studies. (c) 2014 Elsevier B.V. All rights reserved.

The Planck satellite provides a set of all-sky maps at nine frequencies from 30GHz to 857GHz. Planets, minor bodies, and diffuse interplanetary dust emission (IPD) are all observed. The IPD can be separated from Galactic and other emissions because Planck views a given point on the celestial sphere multiple times, through different columns of IPD. We use the Planck data to investigate the behaviour of zodiacal emission over the whole sky at sub-millimetre and millimetre wavelengths. We fit the Planck data to find the emissivities of the various components of the COBE zodiacal model-a diffuse cloud, three asteroidal dust bands, a circumsolar ring, and an Earth-trailing feature. The emissivity of the diffuse cloud decreases with increasing wavelength, as expected from earlier analyses. The emissivities of the dust bands, however, decrease less rapidly, indicating that the properties of the grains in the bands are different from those in the diffuse cloud. We fit the small amount of Galactic emission seen through the telescope's far sidelobes, and place limits on possible contamination of the cosmic microwave background (CMB) results from both zodiacal and far-sidelobe emission. When necessary, the results are used in the Planck pipeline to make maps with zodiacal emission and far sidelobes removed. We show that the zodiacal correction to the CMB maps is small compared to the Planck CMB temperature power spectrum and give a list of flux densities for small solar system bodies., The development of Planck has been supported by: ESA; CNES and CNRS/INSU-IN2P3-INP (France); ASI, CNR, and INAF (Italy); NASA and DoE (USA); STFC and UKSA (UK); CSIC, MICINN and JA (Spain); Tekes, AoF and CSC (Finland); DLR and MPG (Germany); CSA (Canada); DTU Space (Denmark); SER/SSO (Switzerland); RCN (Norway); SFI (Ireland); FCT/MCTES (Portugal); and PRACE (EU).

The purpose of this work is to report the measurement of a time-shift in the OPERA set-up in a totally independent way from Time Of Flight (TOF) measurements of CNGS neutrino events. The LVD and OPERA experiments are both installed in the same laboratory: LNGS. The relative position of the two detectors, separated by an average distance of ~ 160 m, allows the use of very high energy horizontal muons to cross-calibrate the timing systems of the two detectors, using a TOF technique which is totally independent from TOF of CNGS neutrino events. Indeed, the OPERA-LVD direction lies along the so-called "Teramo anomaly", a region in the Gran Sasso massif where LVD has established, many years ago, the existence of an anomaly in the mountain structure, which exhibits a low m. w. e. thickness for horizontal directions. The "abundant" high-energy horizontal muons (nearly 100 per year) going through LVD and OPERA exist because of this anomaly in the mountain orography. The total live time of the data in coincidence correspond to 1200 days from mid 2007 until March 2012. The time coincidence study of LVD and OPERA detectors is based on 306 cosmic horizontal muon events and shows the existence of a negative time shift in the OPERA set-up of the order of deltaT(AB) = - (73 \pm 9) ns when two calendar periods, A and B, are compared. This result shows a systematic effect in the OPERA timing system from August 2008 until December 2011. The size of the effect is comparable with the neutrino velocity excess recently measured by OPERA. It is probably interesting not to forget that with the MRPC technology developed by the ALICE Bologna group the TOF world record accuracy of 20 ps was reached. That technology can be implemented at LNGS for a high precision determination of TOF with the CNGS neutrino beams of an order of magnitude smaller than the value of the OPERA systematic effect. The purpose of this work is to report the measurement of a time-shift in the OPERA set-up in a totally independent way from Time Of Flight (TOF) measurements of CNGS neutrino events. The LVD and OPERA experiments are both installed in the same laboratory: LNGS. The relative position of the two detectors, separated by an average distance of ~ 160 m, allows the use of very high energy horizontal muons to cross-calibrate the timing systems of the two detectors, using a TOF technique which is totally independent from TOF of CNGS neutrino events. Indeed, the OPERA-LVD direction lies along the so-called 'Teramo anomaly', a region in the Gran Sasso massif where LVD has established, many years ago, the existence of an anomaly in the mountain structure, which exhibits a low m. w. e. thickness for horizontal directions. The 'abundant' high-energy horizontal muons (nearly 100 per year) going through LVD and OPERA exist because of this anomaly in the mountain orography. The total live time of the data in coincidence correspond to 1200 days from mid 2007 until March 2012. The time coincidence study of LVD and OPERA detectors is based on 306 cosmic horizontal muon events and shows the existence of a negative time shift in the OPERA set-up of the order of deltaT(AB) = - (73 \pm 9) ns when two calendar periods, A and B, are compared. This result shows a systematic effect in the OPERA timing system from August 2008 until December 2011. The size of the effect is comparable with the neutrino velocity excess recently measured by OPERA. It is probably interesting not to forget that with the MRPC technology developed by the ALICE Bologna group the TOF world record accuracy of 20 ps was reached. That technology can be implemented at LNGS for a high precision determination of TOF with the CNGS neutrino beams of an order of magnitude smaller than the value of the OPERA systematic effect.

International audience; The howardite-eucrite-diogenite (HED) clan is a group of meteorites that probably originate from the asteroid Vesta. Some of them are complex breccias that contain impact glasses whose compositions mirror that of their source regions. Some K-rich impact glasses (up to 2 wt% K2O) suggest that in addition to basalts and ultramafic cumulates, K-rich rocks are exposed on Vesta's surface. One K-rich glass (up to 6 wt% K2O), with a felsic composition, provides the first evidence of highly differentiated K-rich rocks on a large asteroid. They can be compared to the rare lunar granites and suggest that magmas generated in a large asteroid are more diverse than previously thought.

We have analyzed the 9.7 and "18'' mu m interstellar silicate absorption features along the line of sight toward four heavily extincted galactic WC-type Wolf-Rayet (WR) stars. We construct two interstellar extinction curves from 1.25 to 25 mu m using near-IR extinction measurements from the literature, along with the silicate profiles of WR 98a ( representing the local ISM) and GCS3 ( representing the Galactic center). We have investigated the mineralogy of the interstellar silicates by comparing extinction profiles for amorphous silicates with olivine and pyroxene stoichiometry to the 9.7 and "18'' mu m absorption features in the WR 98a spectrum. In this analysis, we have considered solid and porous spheres and a continuous distribution of ellipsoids. While it is not possible to simultaneously provide a perfect match to both profiles, we find that the best match requires a mixture of these two types of compounds. We also consider iron oxides, aluminosilicates, and silicate carbide (SiC) as grain components. Iron oxides cannot be accommodated in the observed spectrum, while the amount of Si in SiC is limited to

A newly discovered sedimentary accumulation of micrometeorites in the Sør Rondane Mountains of East Antarctica, close to the Widerøefjellet summit at ∼2750 m above sea level, is characterized in this work. The focus here lies on 2099 melted cosmic spherules larger than 200 μm, extracted from 3.2 kg of sampled sediment. Although the Widerøefjellet deposit shares similarities to the micrometeorite traps encountered in the Transantarctic Mountains, both subtle and more distinct differences in the physicochemical properties of the retrieved extraterrestrial particles and sedimentary host deposits are discernable (e.g. types of bedrock, degree of wind exposure, abundance of metal-rich particles). Unlike the Frontier Mountain and Miller Butte sedimentary traps, the size fraction below 240 μm indicates some degree of sorting at Widerøefjellet, potentially through the redistribution by wind, preferential alteration of smaller particles, or processing biases. However, the cosmic spherules larger than 300 μm appear largely unbiased following their size distribution, frequency by textural type, and bulk chemical compositions. Based on the available bedrock exposure ages for the Sør Rondane Mountains, extraterrestrial dust is estimated to have accumulated over a time span of ∼1–3 Ma at Widerøefjellet. Consequently, the Widerøefjellet collection reflects a substantial reservoir to sample the micrometeorite influx over this time interval. Petrographic observations and 3D microscopic CT imaging are combined with chemical and triple-oxygen isotopic analyses of silicate-rich cosmic spherules larger than 325 μm. The major element composition of 49 cosmic spherules confirms their principally chondritic parentage. For 18 glassy, 15 barred olivine, and 11 cryptocrystalline cosmic spherules, trace element concentrations are also reported on. Based on comparison with evaporation experiments reported in literature and accounting for siderophile and chalcophile element losses during high-density phase segregation and ejection, the observed compositional sequence largely reflects progressive heating and evaporation during atmospheric passage accompanied by significant redox shifts, although the influence of (refractory) chondrite mineral constituents and terrestrial alteration cannot be excluded in all cases. Twenty-eight cosmic spherules larger than 325 μm analyzed for triple-oxygen isotope ratios confirm inheritance from mostly carbonaceous chondritic precursor materials (∼55% of the particles). Yet, ∼30% of the measured cosmic spherules and ∼50% of all glassy cosmic spherules are characterized by oxygen isotope ratios above the terrestrial fractionation line, implying genetic links to ordinary chondrites and parent bodies currently unsampled by meteorites. The structural, textural, chemical, and isotopic characteristics of the cosmic spherules from the Sør Rondane Mountains, and particularly the high proportion of Mg-rich glass particles contained therein, imply a well-preserved and representative new sedimentary micrometeorite collection from a previously unstudied region in East Antarctica characterized by distinct geological and exposure histories., SCOPUS: ar.j, info:eu-repo/semantics/published

Insoluble organic matter (IOM) in primitive carbonaceous meteorites has preserved its chemical composition and isotopic heterogeneity since the solar system formed similar to 4.567 billion years ago. We have identified the carrier moieties of isotopically anomalous hydrogen in IOM isolated from the Orgueil carbonaceous chondrite. Data from high spatial resolution, quantitative isotopic NanoSIMS mapping of Orgueil IOM combined with data from electron paramagnetic resonance spectroscopy reveals that organic radicals hold all the deuterium excess (relative to the bulk IOM) in distinct, micrometer-sized, D-rich hotspots. Taken together with previous work, the results indicate that an isotopic exchange reaction took place between pre-existing organic compounds characterized by low D/H ratios and D-rich gaseous molecules, such as H2D+ or HD2+. This exchange reaction most likely took place in the diffuse outer regions of the proto-planetary disk around the young Sun, offering a model that reconciles meteoritic and cometary isotopic compositions of organic molecules.