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This study presents the results of indoor and outdoor ambient gamma dose rates and radon concentration in groundwater at different locations of Koppa and Narasimharajapura taluks of Chikmagalur district, (13°40' north latitude and 75° 62' east longitudes). The total annual effective dose ranged between 0.67 mSv/y and 1.76 mSv/y with an average value of 1.16 mSv/y. The calculated total annual effective dose was found to be higher than the world average. The radon concentration in groundwater was analyzed using radon emanometry technique. The measured radon concentrations ranged from 3.96 Bq/l to 90.63 Bq/l with an average value of 35.34 Bq/l. This study reveals that 80% of drinking water samples have radon levels higher than the maximum contaminant level of 11 Bq/l recommended by the United States Environmental Protection Agency. All the recorded radon concentration values were found to be well below the action level of 100 Bq/l recommended by the World Health Organization. It is also found that the dose due to borewell water samples is higher compared to dose due to water from other sources such as hand pump, open well, and tap water. [ABSTRACT FROM AUTHOR]

Hydrogen bonding between N, N-dimethylacetamide (DMA) and alcohols has been studied in carbon tetrachloride solution by an X-band Microwave bench at 936GHz. The dielectric relaxation time (t) of the binary system are obtained by both Higasi's method and Gopalakrishna method. The most likely association complex between alcohol and DMA is 1:1 stoichiometric complex through the hydroxyl group of the alcohol and the carbonyl group of amide. The results show that the interaction between alcohols and amides is 1:1 complex through the free hydroxyl group of the alcohol and the carbonyl group of amide and the alkyl chain-length of both the alcohols and amide plays an important role in the determination of the strength of hydrogen bond (O-H: C=O) formed and suggests that the proton donating ability of alcohols is in the order: 1-propanol < 1-butanol < 1-pentanol and the accepting ability of DMA. [ABSTRACT FROM AUTHOR]

Interactions between ortho and para substituents of anilines such as chloroaniline, methylaniline and methoxyaniline with 1-octanol have been studied in carbon tetrachloride. The most likely association of complex between 1-octanol and substituents of anilines is 1:1 stoichiometric complex, through hydroxyl group of 1-octanol and amine group of ortho and para substituents of anilines. Interactions are studied on the bases of formation constant and free energy changes. Formation constant of the complex has been calculated using Nash method. The result shows that molecular interaction of 1-octanol as proton donor with methyl and chloride substitution of anilines in ortho position is smaller than the para position substitution of anilines. The results shows, the ability of acceptors is in the order p-methoxyaniline