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Impurity scattering in a superconductor may serve as an important probe for the nature of superconducting pairing state. Here we report the impurity effect on superconducting transition temperature $T_\mathrm{c}$ in the newly discovered Cr-based superconductor K$_2$Cr$_3$As$_3$. The resistivity measurements show that the crystals prepared using high-purity Cr metal ($\geq$99.99\%) have an electron mean free path much larger than the superconducting coherence length. For the crystals prepared using impure Cr that contains various \emph{nonmagnetic} impurities, however, the $T_\mathrm{c}$ decreases significantly, in accordance with the generalized Abrikosov-Gor'kov pair-breaking theory. This finding supports a non-$s$-wave superconductivity in K$_2$Cr$_3$As$_3$., Comment: 5 pages, 3 figures, accepted for publication in SCIENCE CHINA Physics, Mechanics & Astronomy

The newly discovered superconductors A2Cr3As3 (A = K, Rb, Cs), with a quasi-one-dimensional crystal structure have attracted considerable interest. The crystal structure consists of double-walled tubes of [Cr3As3]^(2-) that extend along the c-axis. Previously we reported measurements of the change in London penetration depth of polycrystalline samples of K2Cr3As3 using a tunnel diode oscillator based technique, which show a linear temperature dependence at low temperatures, giving evidence for line nodes in the superconducting gap. Here we report similar measurements of the penetration depth for polycrystalline Rb2Cr3As3 and several single crystals of K2Cr3As3, prepared by two different research groups. The single crystal measurements show similar behavior to polycrystalline samples down to 0.9-1.2 K, where a downturn is observed in the frequency shift for all single crystal samples. These results give further evidence for nodal superconductivity in K2Cr3As3, which indicates that the superconducting pairing state is unconventional. The different low temperature behavior observed in samples which have deteriorated after being exposed to air, emphasises that it is necessary to properly handle the samples prior to being measured because the A2Cr3As3 compounds are extremely air sensitive and evidence for nodal superconductivity from penetration depth measurements is only observed in the samples which display a sharp superconducting transition. Therefore further work is required to improve the quality of single crystals and to identify the origin of the downturn., Comment: 9 pages, 3 Figures

We report $^{75}$As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) studies on the superconductor Rb$_{2}$Cr$_{3}$As$_{3}$ with a quasi one-dimensional crystal structure. Below $T\sim$ 100 K, the spin-lattice relaxation rate (1/$T_{1}$) divided by temperature, 1/$T_{1}T$, increases upon cooling down to $T_{\rm c}$ = 4.8 K, showing a Curie-Weiss-like temperature dependence. The Knight shift also increases with decreasing temperature. These results suggest ferromagnetic spin fluctuation. In the superconducting state, 1/$T_{1}$ decreases rapidly below $T_{\text{c}}$ without a Hebel-Slichter peak, and follows a $T^5$ variation below $T\sim$ 3 K, which point to unconventional superconductivity with point nodes in the gap function., Comment: submitted for publication on June 22, 2015