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8. Spatiotemporal patterns of vegetation conversion under the Grain for Green Program in southwest China.

Author

Zhao, Haiwei, Wu, Ruidong, Yang, Feiling, Hu, Jinming, Wang, Junjun, Guo, Yang, Feng, Zhixue, Zhang, Chen, Wang, Yiting, and Zhou, Jian

Subjects
*VEGETATION patterns, *FOREST canopies, *CLIMATE change, *TREND analysis, *GROUND vegetation cover
Abstract

China's Grain for Green Program (GGP) is the largest reforestation program in the world. Previous studies lacked targeted assessments regarding its effectiveness in vegetation conversion. Using the time series of Vegetation Continuous Fields in southwest China, we derived the spatiotemporal variations in total vegetation cover, short vegetation (SV) cover and tree canopy (TC) cover during the period from 2000 to 2016. By conducting residual trend analyses independently on the SV and TC cover time series, the trends in human‐induced SV cover (SVH) and TC cover (TCH) were detected. Then, we performed overlay analyses to derive the human‐induced SV–TC conversion in cropland. The study found that the SV in southwest China showed a net browning trend whereas the TC presented a net greening trend. Approximately 69.5% of the pixels with a significant browning trend in SVH showed a significant greening trend in TCH. Furthermore, 50.6% of the human‐induced SV–TC conversion in southwest China occurred in cropland, and the proportion was even larger for the eastern provinces. Our study provides a targeted evaluation of the performance of the GGP and highlights that the implementation of the GGP has caused widespread SV–TC conversion that potentially mitigates global climate change. [ABSTRACT FROM AUTHOR]

Published
2022
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18. Two Ligands Transfer from Ag to Pd: En Route to (SIPr)Pd(CF 2 H)(X) and Its Application in One-Pot C-H Borylation/Difluoromethylation.

Author

Zhao H, Herbert S, Kinzel T, Zhang W, and Shen Q

Abstract

A process for the concurrent transfer of both the NHC ligand and the difluoromethyl group from [(SIPr)Ag(CF 2 H)] to PdX 2 (X = Cl, OAc, and OPiv) for the preparation of [(SIPr)Pd(CF 2 H)X] complexes is described. These complexes were air-stable and easily underwent transmetalation with aryl pinacol boronate/reductive elimination to generate ArCF 2 H in high yields. Based on this discovery, the first one-pot C-H borylation and difluoromethylation process for the preparation of difluoromethylated (hetero)arenes was developed.

Published
2020
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