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In this work, dry carbonization (DC) and hydrothermal carbonization (HTC) of refuse-derived fuel (RDF) pellets were conducted to evaluate the physical, chemical, and fuel properties of the produced chars. In the dry carbonization tests, biomass sawdust was incorporated in different proportions on the samples to minimize agglomeration caused by the melting of the plastic fraction. The experiments were carried out in a temperature of 400 °C (DC) and 250–300 °C (HTC), in a residence time of 30 min. The respective chars and hydrochars were characterized according to their mass yield, apparent density, proximate, elemental, and mineral composition, chlorine content, high heating value, thermogravimetric profile, and surface functional groups. The results showed that the dry carbonization of RDF pellets with biomass incorporation, followed by a washing step, resulted in the production of chars with improved properties such as higher fixed carbon and higher heating value (HHV) (25–26 MJ/kg) and lower ash and chlorine content. Additionally, the HTC experiments demonstrated that hydrochars showed improved properties without the need for biomass addition and washing, however, with no significant difference in the HHV (20–21 MJ/kg). Therefore, DC of RDF pellets with 10% biomass incorporation seems to be a promising option to overcome the constraints of RDF utilization as an alternative fuel.

In this work, dry carbonization (DC) and hydrothermal carbonization (HTC) of refuse-derived fuel (RDF) pellets were conducted to evaluate the physical, chemical, and fuel properties of the produced chars. In the dry carbonization tests, biomass sawdust was incorporated in different proportions on the samples to minimize agglomeration caused by the melting of the plastic fraction. The experiments were carried out in a temperature of 400 °C (DC) and 250–300 °C (HTC), in a residence time of 30 min. The respective chars and hydrochars were characterized according to their mass yield, apparent density, proximate, elemental, and mineral composition, chlorine content, high heating value, thermogravimetric profile, and surface functional groups. The results showed that the dry carbonization of RDF pellets with biomass incorporation, followed by a washing step, resulted in the production of chars with improved properties such as higher fixed carbon and higher heating value (HHV) (25–26 MJ/kg) and lower ash and chlorine content. Additionally, the HTC experiments demonstrated that hydrochars showed improved properties without the need for biomass addition and washing, however, with no significant difference in the HHV (20–21 MJ/kg). Therefore, DC of RDF pellets with 10% biomass incorporation seems to be a promising option to overcome the constraints of RDF utilization as an alternative fuel. [ABSTRACT FROM AUTHOR]

Application of sewage sludge as fertilizer can be beneficial for sustainable agriculture as it could largely account for nitrogen and phosphorus demand for crops and has lower costs compared to other disposal routes, e.g., incineration, and sanitary landfills. This study evaluates the feasibility of pilot-scale pelletization of sewage sludge for non-food crops (e.g., ornamental plants). The co-pelletization method was designed by mixing sewage sludge and binder (tapioca starch) at a 9:1 sludge-to-starch weight ratio. The amount of nitrogen (N), phosphorus (P), and potassium (K) of the resultant pellets were determined at 5.7%, 4.9%, and 0.2%, respectively. Following Malaysian and US Standards, non-essential elements and pathogenicity of the pelletized sewage sludge were measured below the predetermined limits and hence safe for agricultural application. The planting trial using 50% inorganic fertilizer + 50% sewage sludge pellets exhibited a promising result on the growth of the flowering plant Celosia plumosa, with having better dimension and color, 20% higher in height, 4% more chlorophyll content, 54% more leaf, 43% greater stem growth, and 27% more flowers compared to control. Likewise, the planting trial on Tagetes erecta resulted in 10.5% wider leaf, 10.6% heavier leaf dry weight, and 12.5% more chlorophyll content compared to control with full usage of inorganic fertilizer. By considering liquidities to operate the production facility, the economic analysis estimated that the production cost per ton of pelletized sewage sludge produced was USD 0.98. [ABSTRACT FROM AUTHOR]

Owing to a severe shortage of natural aggregates in terms of quantity and quality, alternative aggregate resources must be utilized in civil engineering construction to meet significant increase in aggregate demand. This study focuses on manufacturing artificial aggregates for pavement applications using two waste materials- mine overburden waste from the coal mining industry and fly ash from thermal power plants. Liquid alkali activator, a mixture of sodium silicate and sodium hydroxide, is used as a binder. The centrifugal forces generated due to a rotating disc pelletizer enables mixing the said components resulting in formation of spherical-shaped pellets. The nucleated pellets are oven cured at 70°C for 7 days. Based on extensive laboratory test trials, the optimal features to produce competent aggregates in terms of angle and revolution speed of the disc pelletizer, dosage of the liquid alkali activator and the concentration of the NaOH are proposed. Finally, the manufactured aggregates are tested for properties relevant to flexible pavement applications. The aggregate impact and Los Angeles abrasion values are found to be 17% and 21.6%, indicating satisfactory resistance to impact and abrasion of aggregate particles under traffic loads. The basic material properties of these aggregates are found to conform to the Indian Roads Congress (IRC) and American Association of State Highway and Transportation Officials (AASHTO) standards for base and subbase layers. Moreover, base/subbase layers prepared with artificial aggregates and mine waste showed high California bearing ratio (CBR) of 54.3% and 80.5% for 2.5 mm and 5.0 mm penetration of the plunger, respectively, indicating high load-bearing capacity of pavement layers. [ABSTRACT FROM AUTHOR]

Calcium looping (CaL) process, as an effective way to achieve CO2 mitigation from high-temperature flue gas streams, is one of the most promising alternatives to amine scrubbing (a well-established technology for industrial post-combustion CO2 capture). CaO sorbent is considered to be an ideal CO2 adsorption material. Moreover, the development of granulation/pelletization techniques along with the mass preparation of the CaO-based sorbent is imperative for realistic large-scale applications. This work proposes two practicable moulding-crushing techniques for the scale-up granulation of CaO-based sorbents, in which the kilogram-scale produced Al-promoted CaO-based sorbent powders were first moulded and subsequently crushed into the granules of target sizes. Three types of organic acids–acetic acid, citric acid and malonic acid were employed as peptizing agents to optimize the granulation process. As a result, the anti-attrition properties and compressive strength of the synthetic sorbents were elevated owing to the introduction of an appropriate amount of acetic or malonic acid, for it expedited the disintegration of the pseudo-boehmite (served as binder agent) particles into sol particles, which allowed for tighter bonding of sorbent particles. In addition, corncob powder acted as a pore-forming agent, enhancing the porous structure of the sorbent particles due to the gases released from the thermal decomposition of organic groups during calcination. Nevertheless, the results revealed that the porous and loose structure adversely affected the mechanical strength of the granules.

This study addresses the effects of densification at varied pelletization temperatures on the novel Malaysian Khaya senegalensis wood-derived pellets biomass fuel characteristics. The lack of comprehensive understanding regarding the biomass fuel characteristics of this species prompted the research. By addressing this knowledge gap, this study explores the impact of temperature variations on key fuel properties, contributing to the optimization of sustainable biomass fuel production in manufacturing and materials processing. Khaya senegalensis wood, grown and harvested in Malaysia, was pelletized at different temperatures to analyze the calorific value, volatile matter content, ash content, fixed carbon, bulk density, and moisture contents of the pellets. The experimental data revealed a significant relationship between temperature and these fuel properties. Pelletizing at 75 °C produced the highest calorific value of 19.47 MJ/kg and the maximum fixed carbon content of 10.04%. A low ash level of 4.26% was achieved via pelletizing at 75 °C. According to the results, 75 °C produced the best thermophysical properties. These findings provide valuable understanding of how pelletization temperature influences fuel pellet thermophysical properties, a critical aspect in optimizing fuel pellet production, storage, advancing renewable energy resource utilization, and, finally, promoting a cleaner and more sustainable energy future. [ABSTRACT FROM AUTHOR]

Lignocellulosic biomass has demonstrated great potential as feedstock for pellet production, notwithstanding the fact that the industrial production of pellets is faced with some economic challenges. This study presents a technoeconomic analysis of six scenarios to develop a process model for pellet production from sawdust and oat straw that employs torrefaction and steam explosion pretreatment prior to pelletization. SuperPro Designer was used to carry out this evaluation. The pellet plants were designed to have a capacity of 9.09 t/h of sawdust and oat straw each. The pellet yield ranged from 59 kt to 72 kt/year. The scenarios analyzed included variations of steam explosion and torrefaction. In some scenarios, materials were lost in the form of liquid and gas due to the pretreatment process. The breakdown of equipment purchase cost showed that the torrefaction reactor is the most expensive unit with approximately 51% of the purchase cost. Facility-dependent and feedstock costs were the major significant contributors to the pellet production cost. The minimum selling prices of the pellets obtained from Scenarios 1–6 were $113.4/t, $118.7/t, $283.4/t, $298.7/t, $200.5/t, and $208.4/t, respectively. The profitability of pellet production as determined by the net present value (NPV), internal rate of return (IRR), and payback period was found to be sensitive to variations in feedstock cost. [ABSTRACT FROM AUTHOR]

Abstract The oral route of delivery is the most preferred route for administering most of the drugs. Pellets have gained importance since they offer numerous advantages like decreased dose dumping, improved patient compliance since dosing frequency is reduced, and ease of administering multiple chemically incompatible drugs immediately without the possibility of them interacting with each other. The critical variables related to process and equipment are identified and what impact they have on the quality of pellets formed is discussed. The position of the spray nozzle also affects the pellets and their yield. A complete guideline has been drawn which makes the process of pelletization using the Wurster method easier. The process variables affecting the pelletization process include inlet and product temperature, relative humidity, batch size; spray rate, and atomization air pressure and the equipment variables include column height, air distribution plate, a type of filter, and shaking interval. All these variables have a low, medium, or high impact on the process and they all together contribute to the quality of pellets formed. This review article focuses on critical process and equipment variables affecting the process of pelletization and the quality of pellets formed when using the Wurster equipment. The main objective is to review critical variables affecting the layering method of palletization and to sketch some basic problems encountered during pelletization and their troubleshooting.

Y-type zeolites are widely used in the carbon dioxide (CO2) adsorption applications due to their exceptional ion exchange performance and high stability. However, the pelletization of Y powder by adding binders such as kaolin often results in performance drops, which has limited its industrial application. This study employs a zeolite-kaolin blend to produce cylindrical pelletized Y zeolite, in which the kaolin is then transformed to zeolites via hydrothermal crystallization, resulting in binder-free Y pellets. The Design-Expert software and the response surface method (RSM) are employed to optimize the hydrothermal crystallization conditions for binder transformation, with the objective of attaining a maximized capacity for CO2 adsorption. Results demonstrate that optimized synthesis conditions yield cylindrical Y zeolite with a notable CO2 adsorption capacity of 5.52 mmol/g at 298 K and 1 bar, surpassing that of the initial Y powder. The average crushing strength is 110 N per particle (Diameter × Height = 3 mm × 3 mm). The IAST selectivity of CO2/N2 (15/85) is 824 at 298 K and 1 bar. The reaction mechanisms of the binder transformation are also investigated via experiments and DFT simulation. This study presents a simple and reliable method for manufacturing binder free Y zeolite, which is promising for carbon capture applications.

The employment of metal-organic frameworks in powder form is undesirable from an industrial perspective due to process and safety issues. This work is devoted to evaluating the impact of compression on the textural and structural properties of CPO-27(Ni). For this purpose, CPO-27(Ni) was synthesized under hydrosolvothermal conditions and characterized. Then, the resulting powder was compressed into binderless pellets using variable compression forces ranging from 5–90 kN (37–678 MPa) and characterized by means of nitrogen adsorption/desorption, thermogravimetric analysis and powder X-ray diffraction to evaluate textural, thermal and structural changes. Both textural and structural properties decreased with increasing compression force. Thermal stability was impacted in pellets compressed at forces over 70 kN. CPO-27(Ni) pelletized at 5, 8 and 10 kN, and retained more than 94% of its initial textural properties, while a loss of about one-third of the textural property was observed for the two most compressed samples (70 and 90 kN) compared to the starting powder. [ABSTRACT FROM AUTHOR]

The oral route of delivery is the most preferred route for administering most of the drugs. Pellets have gained importance since they offer numerous advantages like decreased dose dumping, improved patient compliance since dosing frequency is reduced, and ease of administering multiple chemically incompatible drugs immediately without the possibility of them interacting with each other. The critical variables related to process and equipment are identified and what impact they have on the quality of pellets formed is discussed. The position of the spray nozzle also affects the pellets and their yield. A complete guideline has been drawn which makes the process of pelletization using the Wurster method easier. The process variables affecting the pelletization process include inlet and product temperature, relative humidity, batch size; spray rate, and atomization air pressure and the equipment variables include column height, air distribution plate, a type of filter, and shaking interval. All these variables have a low, medium, or high impact on the process and they all together contribute to the quality of pellets formed. This review article focuses on critical process and equipment variables affecting the process of pelletization and the quality of pellets formed when using the Wurster equipment. The main objective is to review critical variables affecting the layering method of palletization and to sketch some basic problems encountered during pelletization and their troubleshooting. [ABSTRACT FROM AUTHOR]

Manufacturing artificial aggregate by utilizing waste materials has gained great importance as the aggregate occupies a high volume in concrete (60-70%). In this paper, ground-granulated blast-furnace slag (GGBFS) is utilized in aggregate manufacturing. Cold bonding and sintering methods were used as production processes. The pellets were put through a series of tests such as dry density, specific gravity, water absorption, and crushing strength. The results indicated that the density of pellets increased by increasing the GGBFS dosage while the water absorption capacity was reduced. Furthermore, the highest crushed strength was recorded at 50% addition of GGBFS. [ABSTRACT FROM AUTHOR]

Abstract The Hayabusa2 spacecraft succeeded in sampling and returning materials from the C-type, near-Earth asteroid (162173) Ryugu. As part of the Hayabusa2 Initial Analyses, chemical and isotopic compositions of volatile species were measured. The samples analyzed were grains of about 1 mm in diameter and were individually treated without exposure to Earth’s atmosphere throughout the entire analytical/experimental processes to minimize alteration and contamination effects by adsorption of Earth’s atmosphere or chemical reactions with reactive species such as oxygen and water in Earth’s atmosphere. In order to perform spectroscopic and electron-microscopic observations in advance of a series of the isotopic measurements, the sample surface needed to be smoothed. We employed a pelletization method to obtain the required flatness for the returned samples because pelletization is a less sample-consuming method compared to mechanical polishing, microtomy, or ion milling. In order to perform the subsequent analyses, the samples must undergo minimal contamination during the pelletization procedure and be easy to remove from the pelletization tools. Therefore, embedding with resins or low-melting-point metals was not employed. Under these constraints, tools and methods for sample pelletization, handling, and transportation were developed. The tools developed for pelletization and housing also contributed to easier handling of small (less than about 1 mm in diameter) samples. Here we describe the methods and the tools that enable treatment of pristine asteroidal samples under non-atmospheric exposure conditions throughout transportation, weighing, pelletization, and installation into the instruments for chemical and isotopic measurements. The methods and tools we developed can be applied to other small samples including meteorites, cosmic dust, and future returned samples. Graphical Abstract

Biomass pellets are one of the most crucial feedstocks for bioenergy production on a global scale due to their numerous advantages over raw biomass resources. Pellets provide improved energy density, bulk density, moisture content, and homogeneity thereby reducing storage, handling, and transportation costs. To produce high-quality solid fuel, it is necessary to comprehend the properties of wood fuel. This study explored the potential of Khaya senegalensis (khaya) as a dedicated energy crop (DEC) for the production of green energy. It thrives in less-than-ideal conditions and grows rapidly. The low durability of energy pellets raises the risk of dust and fire during handling and storage. In addition, the potential for fines and dust formation is strongly correlated with the mechanical strength of materials. Due to this necessity, the current study examines the effects of pelletization factors, including temperature and pressure, on pellet properties, particularly on its mechanical properties. The durability and compressive strength of pellets were determined using a sieve shaker and a universal testing machine, respectively. The highest mechanical durability was observed at 3 tons of pressure and 75 degrees Celsius, each with a value of 99.6%. The maximum axial compressive strength was measured at 57.53 MPa under 5 tons of pressure. When pelletized at 125 °C, the axial compressive strength increased by 13.8037% to 66.06 MPa compared to the strength obtained at 5 tons of pressure. Pelletizing Khaya feedstocks at 4 tons of pressure, on the other hand, produced a slightly lower diametral compressive strength of 7.08 MPa compared to 7.59 MPa at 125 °C. The experimental results revealed that the aforementioned factors significantly affect the mechanical properties of pellets. The elucidation of wood biomass, solid fuel qualities and pelletization parameters of this potential energy crop may facilitate the production of high-quality pellets from Khaya senegalensis wood to meet the increasing local and worldwide energy demands. [ABSTRACT FROM AUTHOR]

A comprehensive understanding of the mechanisms associated with the pelletization of an anaerobic digestate is necessary to optimize the pellet production process and achieve better and more sustainable management of the digestate. This work evaluated the digestate behavior during cyclic loading and unloading in a closed matrix. The results presented here are a continuation of those observed in previous work that evaluated the effect of moisture content on the behavior of the digestate under cyclic loading/unloading conditions in a closed matrix. The effect of moisture content on the distribution of permanent and elastic strain energy demonstrated in the previous study was verified in the present work under different loading conditions. A Zwick universal machine was used for the experiments. The samples were loaded with amplitudes of 8, 11, 14, 17, and 20 kN for 10 cycles. Two distinct moisture levels of the digestate—10% and 22%—were analyzed. The results of the present study confirmed that the elastic energy dissipated was independent of the moisture content of the digestate and remained relatively constant for a wide range of the applied loads. Higher values of elastic strain energy were observed for the digestate with higher moisture content only when higher loads were applied. In the range of the studied loads, characteristic differences were noted in loading/unloading curves regardless of the load magnitude. The increase in the applied load led to an increase in pellet strength, but only when the moisture content of the digestate was 10%. The results of the pellet strength reflect well the results of irreversible energy and the conclusions about the area enclosed between loading and unloading curves. [ABSTRACT FROM AUTHOR]

An agro-waste composite with a pelletized form was prepared and characterized via IR and 13C solids NMR spectroscopy. Thermal gravimetry analysis (TGA) was used to study the weight loss profiles, while SEM images provided insight on the biocomposite morphology, along with characterization of the sulfate adsorption properties under equilibrium and dynamic conditions. The sulfate monolayer adsorption capacity (qe = 23 mg/g) of the prepared agro-waste pellets was estimated from the adsorption isotherm results by employing the Langmuir model, and comparable fitting results were obtained by the Freundlich model. The dynamic adsorption properties were investigated via adsorption studies with a fixed bed column at pH 5.2. The effects of various parameters, including flow rate, bed height and initial concentrations of sulfate, were evaluated to estimate the optimal conditions for the separation of sulfate. The experimental data of the breakthrough curves were analyzed using the Thomas and Yoon–Nelson models, which provided satisfactory best-fits for the fixed bed kinetic adsorption results. The predicted adsorption capacities for all samples according to the Thomas model concur with the experimental values. The optimum conditions reported herein afford the highest dynamic adsorption capacity (30 mg/g) as follows: 1100 mg/L initial sulfate concentration, 30 cm bed height and 5 mL/min flow rate. The breakthrough time was measured to be 550 min. This study contributes to a strategy for controlled separation of sulfate using a sustainable biocomposite material that is suitable for fixed-bed column point-of-use water treatment systems. [ABSTRACT FROM AUTHOR]

This study addresses the effects of densification at varied pelletization temperatures on the novel Malaysian Khaya senegalensis wood-derived pellets biomass fuel characteristics. The lack of comprehensive understanding regarding the biomass fuel characteristics of this species prompted the research. By addressing this knowledge gap, this study explores the impact of temperature variations on key fuel properties, contributing to the optimization of sustainable biomass fuel production in manufacturing and materials processing. Khaya senegalensis wood, grown and harvested in Malaysia, was pelletized at different temperatures to analyze the calorific value, volatile matter content, ash content, fixed carbon, bulk density, and moisture contents of the pellets. The experimental data revealed a significant relationship between temperature and these fuel properties. Pelletizing at 75 °C produced the highest calorific value of 19.47 MJ/kg and the maximum fixed carbon content of 10.04%. A low ash level of 4.26% was achieved via pelletizing at 75 °C. According to the results, 75 °C produced the best thermophysical properties. These findings provide valuable understanding of how pelletization temperature influences fuel pellet thermophysical properties, a critical aspect in optimizing fuel pellet production, storage, advancing renewable energy resource utilization, and, finally, promoting a cleaner and more sustainable energy future.

The study investigates the use of artificial aggregates (AAs), specifically manufactured from ground granulated blast furnace slag (GGBFS) and ordinary Portland cement (OPC), to mitigate environmental harm caused by illegal quarrying due to the scarcity of natural aggregates (NAs). A cold-bonded pelletization technique was employed to produce five types of AAs with varying proportions of GGBFS & OPC as 82.5:17.5, 85:15, 87.5:12.5, 90:10, 95:5. The AAs with maximum OPC content exhibited a density of 1298 kg m ^−3 , water absorption of 4.8%, and crushing and impact values of 28.6% and 26.3%, respectively. The impact of these AAs on concrete properties was assessed, revealing that AAs facilitated the production of workable concrete with low-density ranges between 1700–2337 kg m ^−3 . Despite a decrease in concrete strength with higher AAs content, structural requirements were met, demonstrating AAs’ potential to effectively substitute natural coarse aggregates (NCAs). The concrete microstructure confirmed the formation of a strong interfacial transition zone (ITZ) and strength-developing cement-hydrated products. This research underscores the scientific contribution of AAs to address aggregate scarcity sustainably and recommends its application in structural elements by experimental validation.

Experimental research was carried out to produce pellets from bauxite residue for the further extraction of iron and alumina. Bauxite residue and limestone with three different mixture compositions were pelletized experimentally via agglomeration followed by drying and sintering at elevated temperatures. X-Ray diffraction (XRD) and scanning electron microscopy (SEM) were used for the phase and microstructural analysis, respectively. Tumble, abrasion, and breaking load tests were applied to determine the strength of the pellets. For measurement of porosity and surface area, mercury porosimetry and BET surface area methods were applied. It was found that at 1100 °C sintering temperature, all the three sintered pellet compositions have a moderate porosity and low strength, but the reverse result was found when 1200 °C sintering temperature was applied. Moreover, for the pellets sintered at 1150 °C high strength and proper porosities were obtained. In the sintered pellets, iron present in form of brownmillerite (Ca2Fe1.63Al0.36O5), srebrodolskite (Ca2Fe2O5), and fayalite (Fe2SiO4), while alumina present mostly in gehlenite (Ca2Al2SiO7) and little fraction in mayenite (Ca12Al14O33) and brownmillerite phases. The identified phases are the same for of the three pellets, however, with variations in their quantities. Porosity and mechanical properties of pellets are inversely related with both varying sintering temperature and composition. It was found that with more CaCO3 use in pelletizing, higher porosity is obtained. However, with increasing sintering temperature the strength of the pellets increases due to clustering of particles, while porosity decreases. [ABSTRACT FROM AUTHOR]

The Hayabusa2 spacecraft succeeded in sampling and returning materials from the C-type, near-Earth asteroid (162173) Ryugu. As part of the Hayabusa2 Initial Analyses, chemical and isotopic compositions of volatile species were measured. The samples analyzed were grains of about 1 mm in diameter and were individually treated without exposure to Earth's atmosphere throughout the entire analytical/experimental processes to minimize alteration and contamination effects by adsorption of Earth's atmosphere or chemical reactions with reactive species such as oxygen and water in Earth's atmosphere. In order to perform spectroscopic and electron-microscopic observations in advance of a series of the isotopic measurements, the sample surface needed to be smoothed. We employed a pelletization method to obtain the required flatness for the returned samples because pelletization is a less sample-consuming method compared to mechanical polishing, microtomy, or ion milling. In order to perform the subsequent analyses, the samples must undergo minimal contamination during the pelletization procedure and be easy to remove from the pelletization tools. Therefore, embedding with resins or low-melting-point metals was not employed. Under these constraints, tools and methods for sample pelletization, handling, and transportation were developed. The tools developed for pelletization and housing also contributed to easier handling of small (less than about 1 mm in diameter) samples. Here we describe the methods and the tools that enable treatment of pristine asteroidal samples under non-atmospheric exposure conditions throughout transportation, weighing, pelletization, and installation into the instruments for chemical and isotopic measurements. The methods and tools we developed can be applied to other small samples including meteorites, cosmic dust, and future returned samples. [ABSTRACT FROM AUTHOR]

Steam explosion pretreatment of sawdust and oat straw under mild, medium, and severe conditions was conducted to improve the quality of pellets generated from these feedstocks. This work examined the effects of temperature, time, and moisture content on the mechanical properties of biomass pellets. From the ANOVA conducted, the p-values of the regression models for all the response variables (dimensional stability, tensile strength, and pellet density) studied were significant (p < 0.05), except for the pellet density of steam-pretreated oat straw pellets. The interaction of these three factors did not significantly affect the response variables of oat straw pellets. In addition, the higher heating value (HHV) of treated biomass increased up to a maximum of about 9.5% and 7% as compared with the non-treated sawdust and oat straw, respectively. In addition, an increment of about 3.6-fold and 3.1-fold in pellet tensile strength of steam-pretreated sawdust and oat straw was observed, respectively. Microstructural examination of the pellets from steam-pretreated biomass revealed that the material contained particles that were more closely bonded and featured a cemented surface with fewer pores when compared to particles from untreated oat straw and sawdust. [ABSTRACT FROM AUTHOR]

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Pelletization of zeolitic materials is required to facilitate their practical industrial and commercial applications. Zeolite-NaA was synthesized from fly ash by the fusion method and shaped into spherical granules. Bentonite, kaolinite, and a combination of bentonite with kaolinite were tested as binders with different contents from 5 to 10 wt%. The pellet formation was optimized. The physicochemical properties of binders, zeolite powder, and zeolite granular were characterized by X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), nitrogen adsorption/desorption isotherm, and scanning electron microscopy (SEM) among other techniques. Deformation and breakage behavior of spherical granulates by compression was also studied. The best performance was obtained by the pellet with 10% bentonite with satisfactory mechanical strength and water resistance. The XRD and SEM results revealed NaA zeolite granular with a typical cubic shape and high crystallinity formed on the surface of bentonite. This result presents a potential use of the coal fly ash to obtain pelletized NaA zeolite following the principles of circular economy and the sustainable development goals (SDGs), particularly SDG 12. [ABSTRACT FROM AUTHOR]

The manufacturing of a granular fertilizer based on organic slurry (OS) and sorptive materials aims to enhance the circular economy. This article describes a technology that was conceived after appraising the chemistry of the anaerobic digestate and wood ash and the synergies of combining both materials. The information available in the literature about similar materials such as cattle slurry and lime was also considered to build a better understanding of the underlying science. The processes and machinery designed were optimized from the points of view of energy and material consumption, cost of storage, transportation and land application. The system was sized to process 1 tonne of OS (97% moisture) in a 10 h batch-shift, consuming 140 kg of wood pellets and 0.55 kW of electricity for the fan blowing preheated air. The results of the market research allowed us to reach the most economically viable routes for the commercialization of granular fertilizers. Based on the financial study, an initial investment of GBP 20,000 is needed to successfully implement the value proposition and business plan. The wide adoption of the composite fertilizer improves the management of the OS and reduces the contamination of air, soil, and water derived from intensive agricultural practices. [ABSTRACT FROM AUTHOR]

Raw mushroom waste has been an enormous solid waste, not only causing a huge cut on profit margin of mushroom industries but also leading to environmental pollution. Unfortunately, the current utilization methods, such as pharmaceutical extractions, are unable to keep up with the waste generation rate due to the large-scale mushroom production. Yet, the utilization of raw mushroom waste to produce biomass pellets for energetic purposes and the role of an electric composter on shortening the processing time remain unexplored. This is important because conventional composting, which takes a relatively long period (e.g., weeks to months), is less practical when it comes to commercial use of the biomass pellets. To explore this issue, an industrial composter with initial compost was utilized to process the raw mushroom waste, followed by pelletization. Extraction of the material inside the composter at different timing was carried out to determine the optimal processing time for optimal texture to form pellets. It was found that prolonged composting hour affected the pelletization process since moisture, which acts as a natural binder, reduced when the composting hour increased. The gross calorific value increased from 14.07 MJ/kg to 18.76 MJ/kg for raw mushroom waste and compost pellets at the fifth hour, respectively. This study revealed that the raw mushroom waste compost could serve as a valuable renewable energy source and that the production of energy-rich biomass compost fuel pellets without using any binder within a short composting duration is achievable with the aid of an in-vessel composter. [ABSTRACT FROM AUTHOR]

This study shows the results of the pilot-scale implementation of the use of green petroleum coke (CVP) in the manufacture of pellets from hematite iron ore in the Venezuelan steel industry, which has the main advantages: lower acquisition costs, availability in the region, greater opportunity for operational continuity and lower fuel consumption. Substituting 80 and 100% for anthracite, keeping the rest of the variables in the loading pattern fixed, such as the percentage of dolomite, iron ore and the burn profile, design the tests. Physical properties such as drum index (I.T), abrasion index (I.A) and resistance to compression (R.C) were evaluated; chemical composition and microstructural characteristics of the pellets, compared to pellets made from 100% anthracite. The physical, chemical and microstructural properties presented by the pellets manufactured on a pilot scale with CVP meet the minimum requirements required for a burned pellet, determining that coke as a solid fuel in the manufacture of pellets behaves in a similar way to anthracite with slight tendency to decrease the drum index and resistance to compression, however a tendency is also observed that favors the increase of the content of S in the burned pellets as the content of CVP is increased in the loading pattern. Microstructurally, no significant differences are observed between pellets made with anthracite or coke. [ABSTRACT FROM AUTHOR]

The sludge-based forming thermal reduction can be used to improve the resource utilization ability of sintering dust. This paper discussed the feasibility and mechanism of sewage sludge as a binder and reducing agent to facilitate iron recycling from sintering dust by mixing wet sludge to form and adding dry sludge to reduce. The results showed that a 1.4% ratio of sewage sludge significantly enhanced the strength of metallurgical pellets, and the compressive strength of wet and dry pellets reached 309.5 and 1233.5 N/P. Meanwhile, with the addition of dry sludge (S/Fe = 2.0), the metallization ratio can be up to 88.4%. Sewage sludge has a more efficient reduction potential than other carbon sources as reducing agents. Combined with XRD, XPS, TG-MS, TG-FTIR, and other characterization methods, the reduction phenomenon of iron was confirmed, and the migration and transformation of metals in sintering dust and the segmented volatilization rule of Pb, Zn, K, Na, and other elements were revealed. It is proven that sludge as the disposal route of metallurgical dust cold-pressed forming and reduction is a green and sustainable view and promising research direction. [Display omitted] • Novel sludge-based route reduces pelletized sintering dust; • Sludge replaces bentonite & CMC in cold-pressed forming; • Sludge acts as binder & carbon source in sintering dust reduction; • Thermodynamics & mechanism in carbothermic reduction are clarified. [ABSTRACT FROM AUTHOR]

Agricultural and agro-processing sector produces large stream of by-products that are either discarded or are underutilized. Lignocellulosic biomass especially crop residues’ potential to green energy development has been investigated. Material conditions as process variable was made a centerpiece of investigation in the present study since several parameters in the feedstock mixture come into interplay during pelletization. Moisture, binders, blending ratio, particle size, and principle feedstock material were the parameters of our interest in finding their effect on physical and thermochemical characteristics. It is also an endeavor to investigate low cost binder options in producing composite pellets of high quality. A Taguchi L9 orthogonal array experimental design was employed and Taguchi based Grey relational analysis was performed to determine the best combinatorial optimization of factor levels settings for producing best pellets. The optimal parameter level settings for pelletization was determined to be 3.18 mm wheat feedstock material blended with pine shavings at 60/40 ratio. An analysis of variance (ANOVA) was conducted to identify the contribution of each parameter. The magnitude of the significant impacts of parameters on performance characteristics were in the order of binder > blend ratio > grind > feedstock material. Results also showed that the physico-chemical characteristics of the pellets were concomitant with the proportion of ingredients or recipes in a blend.

Abstract Background Biomass fuel has been used to supply heat or crude materials in industry to replace the traditional fossil fuel which was one of the chief causes of climate warming. However, the large-scale utilization of biomass fuel was restricted due to the low density and high hydrophilicity of biomass, which causes the problem of transportation and storage. Therefore, pelletization of biomass was used to improve its fuel density. At present, the biomass pellet was widely used to supply heat, gas or electricity generation via gasification, which supplied clean and sustainable energy for industry. However, the energy consumption during pelletization and high hydrophilicity of pellets were still the problem for the large-scale application of biomass pellet. In this study, hydrothermal carbonization and surfactant played the role of permeation, adsorption and wetting in the solution, which was expected to improve the fuel properties and pelletization effectivity of corn stover. Results In the article, surfactant (PEG400, Span80, SDBS) was chosen to be combined with wet torrefaction to overcome the drawbacks and improve the pelletization and combustion properties of Corn stover (CS). Especially, hydrothermal carbonization (HTC) combined with surfactant improves the yield of solid products and reduces the ash content of solid product, which was beneficial for reducing the ashes of furnace during gasification. Meanwhile, surfactant promotes the formation of pseudo-lignin and the absorption for oil with low O and high C during HTC, which improves the energy density of solid product. Furthermore, the oil in solid product plays the role of lubricant and binder, which reduces the negative effect of high energy consumption, low bulk density and weak pellets strength caused by HTC during pelletization. HTC combined with surfactant improved the hydrophobicity of pellet as well as grindability due to the modification of solid product. Moreover, surfactant combined with HTC improved the combustion characteristic of solid product such as ignition and burning temperature as well as kinetic parameters due to the bio-oil absorbed and the improvement of surface and porosity. Conclusions The study supplied a new, less-energy intensive and effective method to improve the pelletization and combustion properties of corn stover via hydrothermal carbonization combined with surfactant, and provided a promising alternative fuel from corn stover .

This paper investigates the ability of insulation cellulose fiber powder (CFP) to be pelletized for its valorization as biomass fuel. CFP is a waste originating from insulation cellulose manufacturing that lacks any method of valorization because of its boron salts content. A sugar byproduct and lignosulfonate (LS) were considered as binders for the pellet manufacturing process. Physical tests were carried out to characterize the pellets' performance. Chemical and combustion tests were considered to state the pellets' potential as a green energy source. Raw CFP showed good ability in its pelletization and durability in the range of 15–30% of moisture content. The pellet's density decreased as water content increased. Binders increased the pellet's length before and after the durability test. Binders also increased the CFP pellet's water absorption, demonstrating a potential decrease in durability against environmental factors. Binders also decreased the lower heating value. Ultimate analysis showed a slight Nitrogen increase in both binder combinations that could potentially raise the pollutant NOx combustion emissions. All the combinations showed adequate combustion characteristics, but binders increased ash production. Additives decreased the CFP volatile matter content and increased the fixed carbon, which could facilitate a more stable combustion. DTA curves showed a mass loss rate decrease in the volatile stage for the binder combinations, which also could be considered as an indicator of a more stable combustion. The ashes' chemical compositions when analyzed by XPS showed boron contents oscillating between 10.03% and 16.42%, demonstrating the possibility of recovering them from the combustion ashes. [ABSTRACT FROM AUTHOR]

The disposal of industrial sewage sludge is one of the most serious environmental problems in Thailand. Moreover, the disposal expense is considered as the production cost to the manufacturer. Therefore, the concept of waste-to-energy technology (WTE) is applied to solve this problem. This study aimed to study the effect of sewage sludge and rice straw proportions on the properties of copellets. Here, the production of co-pelleted sewage sludge from the canned food industry, combined with biomass (rice straw), was performed using a lab-scale pelletization machine. The pellets consisted of sewage sludge (SS) and rice straw (RS) with sewage sludge ratios of RS100:SS0, RS50:SS50, RS35:SS65, RS25:SS75, and RS0:SS100. The co-pellets produced were characterized for physicochemical properties and calorific heating values. In addition, the benefit to cost ratio (B/C), internal rate of return (IRR), and payback period (PB) from the utilization of co-pellets were studied. The results suggest that the proportion of sewage sludge affects the properties of the copellets. The optimum sewage sludge to rice straw ratio at RS0:SS100 is considered to have good fuel combustion properties. It is suitable for the production of co-pellets because of its high volatility and low ash slagging content. [ABSTRACT FROM AUTHOR]

Pellet mixed with 5 wt% and 10 wt% of binders was tested. The pelleting process was performed using a pellet mill operated at 100 °C and at 50 MPa. The physical and chemical characteristics including hardness, high heating value and proximate analysis of pellet produces were obtained using durometer and through thermographic analysis and the results were reported in this paper. Bulk and unit density were determined according to ASABE standard. The dataset presented here are the data of palm kernel shell pellet prepared using two types of binder; (1) sago starch and (2) sodium acetate. The pelletization of palm kernel shell aimed to increase the density and strength of the palm kernel shell pellet and consequently provide better thermal degradation characteristics.

The effect of the die hole configuration in the screw extruder on the pellet quality of the fish formula feed is considered. The results of the corresponding theoretical and experimental research are presented. The surface form of the die hole that allow to produce uniform pressure of the pressable material throughout the hole length is equated. The curvilinear equation to determine the capacity under the even pressure distribution in the die hole is obtained. The pressure values along the hole length are determined experimentally, and the dependences of the hole capacity and the length on the pressures are developed. Basic requirements to the pellet quality are connected with the fish feeding specificity: durability, water resistance, crumbling, and density of pellets. The hole configuration is evaluated just according to the final quality of the mixed feed. The obtained results prove the advantages of the developed experimental die hole in comparison with the common forms. Firstly, the application of such hole in the extruder increases energy efficiency of the pressing-through process. Secondly, the pellet quality is improved.

Background: Heavy metal pollution has significant impacts on health and ecosystems; remediation technologies can reduce the cost to solve these problems. Heavy metals present a severe problem in the environment, mainly for their tendency to persist, bioaccumulate and biomagnification in the trophic chain. Removing these toxic compounds from wastewater remains a challenging task. Aim: Heavy metal removal capacity was analyzed using adsorbent pellets made with natural bentonite, kaolin, and zeolite. This study describes the equilibrium adsorption and kinetics of metal removal by using linear and nonlinear regression analysis. Adsorption mechanisms were also analyzed. Methods: The goodness of fit of the adsorption equilibrium data was tested with the four linearized forms of the Langmuir equation, as well as the Freundlich, Temkin, and Dubinin-Radushkevich models. To choose the best-fit model with greater reliability, five error functions were used: R2, X2, SSE, ABS, and ARE. For adsorption kinetics the Pseudo First Order, Pseudo Second Order and Elovich models were studied with linear and nonlinear regression analysis. Results and Discussion: Type I linearization of the Langmuir isotherm showed the best fit for the three metals, with maximum adsorption capacities for lead, copper, and cadmium of 7.27, 1.45 and 0.28 mg/L, respectively. The results show that Pseudo Second Order with linear regression best fitted for lead and copper data and Pseudo First Order model with linear regression for cadmium. Conclusions: Nonlinear regression was found better to fit adsorption equilibrium models and linear regression to fit kinetics models. The main mechanisms responsible for adsorption in the system are thought to be ion exchange between functional groups and cations and surface charge attraction related to Van der Waals forces. [ABSTRACT FROM AUTHOR]

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The effect of several pelleting process parameters on the quality of the resultant pellets was investigated by using a disk pelletizer with low- and medium-grade phosphate rock powders as the raw materials. The results showed that the optimized compressive strengths of raw and dried pellets were 12.84 N and 54.58 N, respectively, when the material fineness was -74μm with an 86.60% content. The amount of added bentonite was 2.5%, the wetting moisture was 8% and the raw pellet moisture content was 10%. The compressive strength of the finished product reached 930 N using a preheating temperature of 600 °C for 10 min, and a calcination temperature of 1200 °C for 10 min. A study on the mineral phase of the finished balls showed that the increased pellet strength after calcination was caused by a solid-state reaction within the pellets during the high-temperature calcination process. This process caused volume shrinking and a compacted structure of the pellets, and the pellet particles were sintered into a plate. [ABSTRACT FROM AUTHOR]

Inorganic binders like bentonite, used for pelletization of low-grade iron ore, generate iron ore slimes with comparatively high silica and alumina content necessitating extra steps for their removal during iron making process. This demands the usage of organic binders as full or partial replacement of bentonite for iron ore pelletization. In this work, adsorption of organic binders with saccharides skeleton and –H, –OH, –CH 2 OH and –CH 2 CH 2 OH as polar substituents, on goethite surface was studied using density functional theory, molecular dynamics and machine learning. It was observed that adsorption energy of binders on goethite surface had weak dependence on number of hydrogen bonds between them. With this favorable interaction in mind, a library containing 64 organic binders was constructed and adsorption energy of 30 of these binders was computed using molecular dynamics, followed by training of a linear regression model, which was then used to predict the adsorption energy of rest of the binders in the library. It was found that the introduction of –CH 2 CH 2 OH at R2 position resulted in statistically significant higher adsorption energy. Binder34 and Binder44 were identified as viable candidates for both goethite and hematite ore pelletization and adsorption of their n-mers on goethite and hematite surfaces was also quantified. Designing of Organic binders for Low-grade iron ore palletization using molecular dynamics simulations, quantum chemical calculations and machine learning methods. By using the quantum chemical data, the machine learning model was built and trained followed by the prediction of most probable adsorbed organic binders from a binders library. [Display omitted] • Organic polymers based on sugars used as binders for goethite ore pelletization. • A library of binders was constructed and its adsorption on Goethite was quantified. • Polar group –CH 2 CH 2 OH at R2 position resulted in higher adsorption energy. • Binder34 and Binder44 were identified as candidates for goethite ore pelletization. [ABSTRACT FROM AUTHOR]

Co-combustion of biomass and sludge is a promising method for waste treatment and power generation. In this study, additives such as ammonium dihydrogen phosphate (ADP), calcium oxide (CaO), attapulgite (AT), and their combinations were added into the co-pelletization of semi-dry sludge (with approximately 50% water content) and extraction residue from vegetable oil processing. The objective of the studies was to examine the pelletization behavior, reduce off-gas emissions during the combustion, and investigate the mechanisms influenced by these additives through the thermogravimetric analysis and the tube furnace combustion experiment. The results of the analysis of variance (ANOVA) indicated an increase in pellet density due to the addition of additives. During the combustion, the addition of AT and compound additives generated more complex compounds with high melting temperatures, thereby mitigating the high slagging tendency. Meanwhile, additives facilitated the conversion of ultrafine particles (PM 0.1) to fine particles, leading to a reduction in PM 0.1 emissions by 15.60–42.40%. The additives exhibited efficacy in reducing SO 2 emissions, with a reduction range of 5.00–23.20%. However, the addition of ADP additives resulted in a 12.00% increase in NO emissions. Consequently, adding additives to pellets could address the slagging issue and reduce the emission of air pollutants during combustion. [Display omitted] • The additives enhanced the density of the pellets. • The AT and compound additives showed a low slagging tendency. • The additives reduced the combustion stability of the pellets. • The additives decreased the PM 0.1 emission by 15.62–45.48%. • The compound additives showed better reduction of SO 2 emission. [ABSTRACT FROM AUTHOR]

This study was first conducted to comprehensively investigate the potential of yak manure as a raw material to prepare fuel pellets. The effect of different parameters such as binder, pressure, and moisture content on pellet density and diametric compressing strength was investigated using a laboratory single pelleting press unit. Results showed that increasing the pressure can help to obtain high-quality fuel pellets. The pellet properties (density and diametric compressing strength) initially increased and then decreased with moisture content increase. By contrast, binder was not identified to promote density and diametric compressing strength. The parameters were optimized using the response surface method with central composite design to obtain high-quality pellets. In conclusion, the use of yak manure as a raw material to make fuels can be considered a sustainable approach and can effectively be used to fulfill the energy and heating requirements of rural areas.

The manufacturing of a granular fertilizer based on organic slurry (OS) and sorptive materials aims to enhance the circular economy. This article describes a technology that was conceived after appraising the chemistry of the anaerobic digestate and wood ash and the synergies of combining both materials. The information available in the literature about similar materials such as cattle slurry and lime was also considered to build a better understanding of the underlying science. The processes and machinery designed were optimized from the points of view of energy and material consumption, cost of storage, transportation and land application. The system was sized to process 1 tonne of OS (97% moisture) in a 10 h batch-shift, consuming 140 kg of wood pellets and 0.55 kW of electricity for the fan blowing preheated air. The results of the market research allowed us to reach the most economically viable routes for the commercialization of granular fertilizers. Based on the financial study, an initial investment of GBP 20,000 is needed to successfully implement the value proposition and business plan. The wide adoption of the composite fertilizer improves the management of the OS and reduces the contamination of air, soil, and water derived from intensive agricultural practices.

The localization and intensification of the poultry industry over the past 50 years have incidentally created a largely ignored environmental management crisis. As a result of these changes in poultry production, concentrated animal feeding operations (CAFOs) produce far more waste than can be managed by land disposal within the regions where it is produced. As a result, alternative waste management practices are currently being implemented, including incineration and pelletization of waste. However, organic arsenicals used in poultry feed are converted to inorganic arsenicals in poultry waste, limiting the feasibility of waste management alternatives. The presence of inorganic arsenic in incinerator ash and pelletized waste sold as fertilizer creates opportunities for population exposures that did not previously exist. The removal of arsenic from animal feed is a critical step toward safe poultry waste management.

Fungal pretreatment of switchgrass using Phanerochaete chrysosporium (PC), Trametes versicolor 52J (TV52J), and the Trametes versicolor mutant strain (m4D) under solid-state fermentation was conducted to improve its pellet quality. For all three fungal strains, the fermentation temperature had a significant effect (p < 0.05) on pellet unit density and tensile strength. The p-values of the quadratic models for all the response variables showed highly significant regression models (p < 0.01) except for dimensional stability. In addition, 3.1-fold and 2.8-fold increase in pellet tensile strength were obtained from P. chrysosporium- and T. versicolor 52J-treated materials, respectively. Microstructural examination showed that fungal pretreatment reduced pores in the pellets and enhanced pellet particle bonding. Among the fungal strains, PC had the shortest optimum fermentation time (21 d) and most positive impact on the pellet tensile strength and hydrophobicity. Therefore, switchgrass pretreatment using PC has the potential for resolving the challenges of switchgrass pellet transportation and storage and reducing the overall pelletization cost. However, a detailed comparative technoeconomic analysis would be required to make definitive cost comparisons.

Manures can be treated by solid–liquid separation and more sophisticated, subsequent approaches. These processes generate fertilizers, which may differ in composition and N2O release potential. The aim of the study was to investigate the influence of processing-related changes in digestate composition on soil-derived N2O emissions after application to soil. For that purpose, N2O emissions within the first 7 weeks after fertilization with two raw and eight processed digestates (derived from solid–liquid separation, drying and pelletizing of separated solid, and vacuum evaporation of separated liquid) were measured in the field in 2015 and 2016. Additionally, an incubation experiment was run for 51 days to further investigate the effect of subsequent solid and liquid processing on soil-derived N2O release. The results showed that, only in 2016, the separation of digestate into solid and liquid fractions led to a decrease in N2O emissions in the following order: raw digestate > separated liquid > separated solid. N removal during subsequent processing of separated solid and liquid did not significantly influence the N2O emissions after fertilization. In contrast, the concentrated application of the final products led to contradictory results. Within the solid processing chain, utilization of pellets considerably increased the N2O emissions by factors of 2.7 (field, 2015), 3.5 (field, 2016), and 7.3 (incubation) compared to separated solid. Fertilization with N-rich ammonium sulfate solution led to the lowest emissions within the liquid processing chain. It can be concluded that the input of less recalcitrant organic C into the soil plays a greater role in N2O release after fertilization than the input of ammoniacal N. Digestate processing did not generally reduce emissions but apparently has the potential to mitigate N2O emissions substantially if managed properly.