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99Tc primarily exists high mobility in the natural aqueous environment due to its extremely high solubility and non-complexing features, which can easily cause radioactive pollution. We herein report a general strategy for constructing a novel resin (SiPAN-PEI) with multiple positive charges nitrogen, exhibiting ultrafast adsorption kinetics (< 3 min), superior adsorption capacities (463.96 mg g−1), and excellent selectivity in the presence of excess competitive anions, which exceed those of most commercial resins. Moreover, based on impressive structure stability in extreme conditions, SiPAN-PEI can still maintain superior adsorption abilities after suffering irradiation, calcination, and immersion in strong acid. In addition, the separation performance kept excellently after five loading-washing-eluting cycles and the total adsorption ratio can still reach 97 %. Outstandingly, SiPAN-PEI can remove most of ReO 4 - from simulated nuclear wastewater through a sequential injection automatic separation system and can reduce the concentration of ReO 4 - to the maximum concentration standard set by the World Health Organization (WHO) in a short time. Leveraging density functional theory calculations and other characteristics clearly elucidated adsorption mechanism of anion-exchange between Cl- and TcO 4 -/ReO 4 -. In terms of superior adsorption property, SiPAN-PEI is demonstrated to be a pretty candidate for 99Tc elimination from wastewater. [Display omitted] • A novel resin SiPAN-PEI was successfully synthesized for selective capture of 99Tc. • SiPAN-PEI exhibited excellent adsorption ability of 99Tc in harsh conditions. • Multiple positive charge nitrogen plays a critical role in capture of 99Tc. • SiPAN-PEI demonstrated efficiency capture of 99Tc in simulated wastewater. [ABSTRACT FROM AUTHOR]

[Display omitted] • A novel adsorbent FeOOH@SiO 2 was successfully prepared and used for removal of Se(IV) and Se(VI). • FeOOH@SiO 2 shows powerful adsorption abilities for Se(IV) and Se(VI) in 3 mol/L HNO 3 system. • FeOOH@SiO 2 has excellent acid resistance, γ-irradiation and thermal stability. • Surface complexing process was proposed for Se(IV) and Se(VI) adsorption. Due to its high solubility, radioactivity and toxicity, the separation of selenium from spent fuel reprocessing waste and industrial wastewater has attracted much attention. In this study, a novel adsorbent FeOOH@SiO 2 with particle size of ∼100 μm was successfully prepared by loading FeOOH on micron-sized silica with emulsion methods. FeOOH@SiO 2 with good acid resistance, γ-irradiation and thermal stability exhibits excellent adsorption abilities for Se(IV) and Se(VI) including fast adsorption kinetics, great adsorption capacities (11.0 mg/g for Se(IV) and 6.04 mg/g for Se(VI)) and preferable adsorption selectivity. It is worth noting that FeOOH@SiO 2 can still remove nearly 90 % of Se(IV) and 80 % of Se(VI) even in 3 mol/L HNO 3 system. Combined with the observations from X-ray photoelectron spectroscopic characterization and surface potential measurement, the adsorption mechanism caused with electrostatic attraction and the formation of inner complexes for Se(IV), and reduction reaction and partial formation of outer complexes for Se(VI) can be deduced. After 4 adsorption–desorption cycles, FeOOH@SiO 2 still exhibits satisfactory reusability. Dynamic column experiments also demonstrated that FeOOH@SiO 2 exhibited excellent removal capabilities towards Se(IV) and Se(VI) from real water samples. The present work demonstrates that FeOOH@SiO 2 has great potential application for 79Se removal in highly acidic nuclear waste. [ABSTRACT FROM AUTHOR]