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A review of the present status of the global warming science is presented in this paper. The term global warming is now popularly used to refer to the recent reported increase in the mean surface temperature of the earth; this increase being attributed to increasing human activity and in particular to the increased concentration of greenhouse gases (carbon dioxide, methane and nitrous oxide) in the atmosphere. Since the mid to late 1980s there has been an intense and often emotional debate on this topic. The various climate change reports (1996, 2001) prepared by the IPCC (Intergovernmental Panel on Climate Change), have provided the scientific framework that ultimately led to the Kyoto protocol on the reduction of greenhouse gas emissions (particularly carbon dioxide) due to the burning of fossil fuels. Numerous peer-reviewed studies reported in recent literature have attempted to verify several of the projections on climate change that have been detailed by the IPCC reports. The global warming debate as presented by the media usually focuses on the increasing mean temperature of the earth, associated extreme weather events and future climate projections of increasing frequency of extreme weather events worldwide. In reality, the climate change issue is considerably more complex than an increase in the earth’s mean temperature and in extreme weather events. Several recent studies have questioned many of the projections of climate change made by the IPCC reports and at present there is an emerging dissenting view of the global warming science which is at odds with the IPCC view of the cause and consequence of global warming. Our review suggests that the dissenting view offered by the skeptics or opponents of global warming appears substantially more credible than the supporting view put forth by the proponents of global warming. Further, the projections of future climate change over the next fifty to one hundred years is based on insufficiently verified climate models and are therefore not considered reliable at this point in time. [ABSTRACT FROM AUTHOR]

The economic benefits of a multi-gas approach to climate change mitigation are clear. However, there is still a debate on how to make the trade-off between different greenhouse gases (GHGs). The trade-off debate has mainly centered on the use of Global Warming Potentials (GWPs), governing the trade-off under the Kyoto Protocol, with results showing that the cost-effective valuation of short-lived GHGs, like methane (CH4), should be lower than its current GWP value if the ultimate aim is to stabilize the anthropogenic temperature change. However, contrary to this, there have also been proposals that early mitigation mainly should be targeted on short-lived GHGs. In this paper we analyze the cost-effective trade-off between a short-lived GHG, CH4, and a long-lived GHG, carbon dioxide (CO2), when a temperature target is to be met, taking into consideration the current uncertainty of the climate sensitivity as well as the likelihood that this will be reduced in the future. The analysis is carried out using an integrated climate and economic model (MiMiC) and the results from this model are explored and explained using a simplified analytical economic model. The main finding is that the introduction of uncertainty and learning about the climate sensitivity increases the near-term cost-effective valuation of CH4 relative to CO2. The larger the uncertainty span, the higher the valuation of the shortlived gas. For an uncertainty span of ±1°C around an expected climate sensitivity of 3°C, CH4 is cost-effectively valued 6.8 times as high as CO2 in year 2005. This is almost twice as high as the valuation in a deterministic case, but still significantly lower than its GWP100 value. [ABSTRACT FROM AUTHOR]

This paper examines different concepts of a 'warming commitment' which is often used in various ways to describe or imply that a certain level of warming is irrevocably committed to over time frames such as the next 50 to 100 years, or longer. We review and quantify four different concepts, namely (1) a 'constant emission warming commitment', (2) a 'present forcing warming commitment', (3) a 'zero emission (geophysical) warming commitment' and (4) a 'feasible scenario warming commitment'. While a 'feasible scenario warming commitment' is probably the most relevant one for policy making, it depends centrally on key assumptions as to the technical, economic and political feasibility of future greenhouse gas emission reductions. This issue is of direct policy relevance when one considers that the 2002 global mean temperatures were 0.8 ± 0.2°C above the pre-industrial (1861-1890) mean and the European Union has a stated goal of limiting warming to 2°C above the pre-industrial mean: What is the risk that we are committed to overshoot 2°C? Using a simple climate model (MAGICC) for probabilistic computations based on the conventional IPCC uncertainty range for climate sensitivity (1.5 to 4.5 °C), we found that (1) a constant emission scenario is virtually certain to overshoot 2°C with a central estimate of 2.0°C by 2100 (4.2°C by 2400). (2) For the present radiative forcing levels it seems unlikely that 2°C are overshoot. (central warming estimate 1.1 °C by 2100 and 1.2°C by 2400 with ∼10% probability of overshooting 2°C). However, the risk of overshooting is increasing rapidly if radiative forcing is stabilized much above 400 ppm CO2 equivalence (1.95 W/m²) in the long-term. (3) From a geophysical point of view, if all human-induced emissions were ceased tomorrow, it seems 'exceptionally unlikely' that 2°C will be overshoot (central estimate: 0.7°C by 2100; 0.4°C by 2400). (4) Assuming future emissions according to the lower end of published mitigation scenarios (350 ppm CO2eq to 450 ppm CO2eq) provides the central temperature projections are 1.5 to 2.1 °C by 2100 (1.5 to 2.0°C by 2400) with a risk of overshooting 2°C between 10 and 50% by 2100 and 1-32% in equilibrium. Furthermore, we quantify the 'avoidable warming' to be 0.16-0.26°C for every 100 GtC of avoided CO2 emissions - based on a range of published mitigation scenarios. [ABSTRACT FROM AUTHOR]

• Comprehensive exploration and critique of aerogels as promising CO 2 -capture materials. • Perspectives on aerogels' tunable surface chemistry and proper textural properties. • Focus on characterisation, process economics and performance. • Detailed outlook towards prospects for future CO 2 -capture deployment. Recently, greenhouse gases - especially CO 2 – have been released into the atmosphere in ever-increasing quantities through activities such as industrial emission and combustion. Owing to their high absorption capacities, they appear to be implicated causatively in observed increases in surface temperature and global climate changes. Between porous solid sorbents, aerogels have recently been considered as promising adsorbents for CO 2 capture due to their tunable surface chemistry and proper textural properties. Currently, a variety of different aerogels are being developed at laboratory scale, and some of them have been taken to pilot production. In order to explore the commercialisation-feasibility of aerogels as CO 2 capture adsorbents, more research needs to be done on low-cost materials and production processes, with low or controlled sorption of water as well as a good thermal regeneration capacity. In this review paper, different aspects of scientific investigations on CO 2 -sorption applications of aerogels have been studied. The review contains seven main sections: preparation, characterisation, modification of aerogels, literature studies on CO 2 -sorption performances, kinetic and thermodynamic models on CO 2 adsorption, important factors on CO 2 capture and outlook for future perspectives. [ABSTRACT FROM AUTHOR]

Palaeoclimate reconstructions of periods with warm climates and high atmospheric CO.sub.2 concentrations are crucial for developing better projections of future climate change. Deep-ocean.sup.1,2 and high-latitude.sup.3 palaeotemperature proxies demonstrate that the Eocene epoch (56 to 34 million years ago) encompasses the warmest interval of the past 66 million years, followed by cooling towards the eventual establishment of ice caps on Antarctica. Eocene polar warmth is well established, so the main obstacle in quantifying the evolution of key climate parameters, such as global average temperature change and its polar amplification, is the lack of continuous high-quality tropical temperature reconstructions. Here we present a continuous Eocene equatorial sea surface temperature record, based on biomarker palaeothermometry applied on Atlantic Ocean sediments. We combine this record with the sparse existing data.sup.4-6 to construct a 26-million-year multi-proxy, multi-site stack of Eocene tropical climate evolution. We find that tropical and deep-ocean temperatures changed in parallel, under the influence of both long-term climate trends and short-lived events. This is consistent with the hypothesis that greenhouse gas forcing.sup.7,8, rather than changes in ocean circulation.sup.9,10, was the main driver of Eocene climate. Moreover, we observe a strong linear relationship between tropical and deep-ocean temperatures, which implies a constant polar amplification factor throughout the generally ice-free Eocene. Quantitative comparison with fully coupled climate model simulations indicates that global average temperatures were about 29, 26, 23 and 19 degrees Celsius in the early, early middle, late middle and late Eocene, respectively, compared to the preindustrial temperature of 14.4 degrees Celsius. Finally, combining proxy- and model-based temperature estimates with available CO.sub.2 reconstructions.sup.8 yields estimates of an Eocene Earth system sensitivity of 0.9 to 2.3 kelvin per watt per square metre at 68 per cent probability, consistent with the high end of previous estimates.sup.11.A 26-million-year record of equatorial sea surface temperatures reveals synchronous changes of tropical and polar temperatures during the Eocene epoch forced by variations in concentrations of atmospheric carbon dioxide, with a constant degree of polar amplification., Author(s): Margot J. Cramwinckel [sup.1] , Matthew Huber [sup.2] , Ilja J. Kocken [sup.1] , Claudia Agnini [sup.3] , Peter K. Bijl [sup.1] , Steven M. Bohaty [sup.4] , Joost [...]

The article offers information on the research conducted by palaeoclimatologists on the implication of concentrations of stable isotopes and trace elements to climatic changes in Antarctica. Researchers believed that such factors infer changes in climate long before they themselves were on the scene. Members of the European Project for Ice Coring in Antarctica (EPICA) collaborated and gathered valuable information including atmospheric gases trapped and preserved in ice cores extracted from the Earth's polar regions. Such information provides scientists with an overview of the cycling of greenhouse gases such as carbon dioxide and methane. Discussed are the details of the experiment undertaken by palaeoclimatologists.

So far, climate change mitigation pathways focus mostly on CO2 and a limited number of climate targets. Comprehensive studies of emission implications have been hindered by the absence of a flexible method to generate multi-gas emissions pathways, user-definable in shape and the climate target. The presented method 'Equal Quantile Walk' (EQW) is intended to fill this gap, building upon and complementing existing multi-gas emission scenarios. The EQW method generates new mitigation pathways by 'walking along equal quantile paths' of the emission distributions derived from existing multi-gas IPCC baseline and stabilization scenarios. Considered emissions include those of CO2 and all other major radiative forcing agents (greenhouse gases, ozone precursors and sulphur aerosols). Sample EQW pathways are derived for stabilization at 350 ppm to 750 ppm CO2 concentrations and compared to WRE profiles. Furthermore, the ability of the method to analyze emission implications in a probabilistic multi-gas framework is demonstrated. The probability of overshooting a 2°C climate target is derived by using different sets of EQW radiative forcing peaking pathways. If the probability shall not be increased above 30%, it seems necessary to peak CO2 equivalence concentrations around 475 ppm and return to lower levels after peaking (below 400 ppm). EQW emissions pathways can be applied in studies relating to Article 2 of the UNFCCC, for the analysis of climate impacts, adaptation and emission control implications associated with certain climate targets. See www.simcap.org for EQW-software and data. [ABSTRACT FROM AUTHOR]