Search

Four new hexa-nickel(II)-substituted Keggin-type tungstophosphates [Ni(μ-OH)(oeen)(HO)(B-α-PWO)]·6HO ( 1, oeen = N-(2-hydroxyethyl)enediamine), [Ni(μ-OH)(oeen)(HO)(B-α-PWO)]·13HO ( 2), [Ni(μ-OH)(oeen)(tran)(HO)(B-α-PWO)]·3HO ( 3, tran = 1,4,7-triazonane) and [Ni(μ-OH)(oeen)(tran)(HO)(B-α-PWO)]·6HO ( 4) have hydrothermally made by controlling their reaction temperatures. 1- 4 have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction, respectively. Structural analyses reveal that they consist of {Ni(μ-OH)(HO)} cores and B-α-PWO (PW) units, and further are stabilized by organic neutral oeen/tran molecules. 1- 3 are isolated clusters while 4 is the 1D chain structure. It should be noted that the tran molecules in 3 and 4 are derived from the oeen molecules in the starting materials. [ABSTRACT FROM AUTHOR]

A new heteroleptic nickel-bis-1,2-dithiolene ion-pair complex, (4-ClBz-1-APy)[Ni(dmit)(mnt)] ( 1 ) (where 4-ClBz-1-APy + = p-chloro-benzyliden-1-aminopyridinium; dmit 2− = 2-thioxo-1, 3-dithiole-4, 5-dithiolate; mnt 2− = maleonitriledithiolate) was synthesized and characterized structurally. The IR spectra, thermal analysis, magnetic and near-IR absorption properties have been investigated for 1 . Complex 1 crystallized in monoclinic system with space group P 2 1 . The anions and cations form the mixed stacked columns separated by the cation columns. The anion stacks are irregular, in which two neighboring heteroleptic [Ni(dmit)(mnt)] − anions are separated by one 4-ClBz-1-APy + cation. The neighboring anions are connected via lateral-to-lateral S…S contacts of dmit 2− ligands and short H…N, H…S and C…S contacts are observed between the cations and the anions. Magnetic susceptibility measurement shows that the magnetic data follows the S = 1 / 2 Heisenberg alternating linear-chain model in the temperature range 40–300 K and Curie-Weiss law below 40 K for 1 . Salts 1 exhibits a intense near-IR absorption in the region of 900–1400 nm, and this near-IR absorption feature makes it to be a promising optical material. [ABSTRACT FROM AUTHOR]