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The conventional way to fabricate current sub-ambient daytime radiative cooling (SDRC) systems is to maximally suppress the cooler's solar absorption and substantially improve its selective emissivity only in the atmospheric transparency window. This greatly limits the selection of materials and their practical applications. In this paper, an alternative method, which combines sunlight-triggered fluorescent cooling, particle scattering, and broadband infrared radiation, was presented for creating serial eco-friendly coatings with the SDRC effect with conventional cost-effective building materials. The presence of conventional fluorescent pigments in the coating composition increased the effective direct-normal solar reflectance via sunlight-excited fluorescent emissions to the level required for SDRC. When applied to various substrates, the serial coatings exhibited distinct SDRC effects under direct and strong sunlight in typical temperate monsoon climate regions such as Beijing. The observed sub-ambient temperature reduction of the coating with yellow–green fluorescence over an aluminium plate was 3.5 °C under a peak solar intensity of 996 W/m2, yielding a cooling power of 45.7 W/m2 under a peak solar intensity of 981 W/m2. Compared with the conventional cool white coatings, the large-scale application of the coating to urban surfaces is predicted to reduce a city's air temperature by approximately 1 °C and thereby decrease the Heat Island Intensity. Additionally, the method proposed in this paper was generic and expanded the SDRC design paradigm, thereby promoting SDRC as a viable energy-efficient technology. Image 1 • Fluorescent emissions increase the effective solar reflectance to an ideal level. • Fluorescent cooling is crucial for sub-ambient daytime radiative cooling (SDRC). • FR coatings over various substrates exhibit distinct SDRC effect. • The SDRC effect on an aluminium plate is 3.5 °C on a clear hot sunny day. • The cooling power is 45.7 W/m2 under a peak solar intensity of 981 W/m2. [ABSTRACT FROM AUTHOR]

This article has been retracted: please see Elsevier Policy on Article Withdrawal (http://www.elsevier.com/locate/withdrawalpolicy). This article has been retracted at the request of the authors and the Editor-in-Chief due to insurmountable scientific disagreements over the authorship and section 3.1. The linked second part of this article is also being retracted: "Generic method for creating waterborne coatings with sub-ambient daytime cooling–Part II: Cooling effect under real working conditions and key physical properties", Solar Energy Material and Solar Cells 204 (2019):110220. [ABSTRACT FROM AUTHOR]

This article has been retracted: please see Elsevier Policy on Article Withdrawal (http://www.elsevier.com/locate/withdrawalpolicy). This article has been retracted at the request of the authors and the Editor-in-Chief due to insurmountable scientific disagreements over the authorship and section 3.1 in the linked first part of this article, which is being also retracted: "Generic method for creating waterborne coatings with sub-ambient daytime cooling–part I: Optical properties and rooftop cooling effect measurements", Solar Energy Material and Solar Cells 204 (2019):110205 [ABSTRACT FROM AUTHOR]

This article has been retracted: please see Elsevier Policy on Article Withdrawal (http://www.elsevier.com/locate/withdrawalpolicy). This article has been retracted at the request of the authors and the Editor-in-Chief due to insurmountable scientific disagreements over the authorship and section 3.1. The linked second part of this article is also being retracted: "Generic method for creating waterborne coatings with sub-ambient daytime cooling–Part II: Cooling effect under real working conditions and key physical properties", Solar Energy Material and Solar Cells 204 (2019):110220. [ABSTRACT FROM AUTHOR]

Highlights: [•] Two waterborne cool white coatings for building energy efficiency were prepared. [•] The solar reflectance of cool coatings S1 and S2 is respective 0.879 and 0.892. [•] The predicted industrial limits for practical reflective cool white coatings are 0.91. [•] The coatings integrate multiple cooling principles and show super cooling effect. [•] Radiant heat flux may be significantly reduced by use of cool white coatings. [Copyright &y& Elsevier]