1. An ion-imprinted material embedded carbon quantum dots for selective fluorometric determination of lithium ion in water samples.
- Author
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Shao, Honghong, Li, Chunyan, Ma, Changchang, Sun, Lin, Chen, Rongru, Cheng, Rujia, Liu, Yang, Yan, Yongsheng, Sun, Qingfeng, and Wu, Chunxia
- Subjects
QUANTUM dots ,FLUORIMETRY ,LITHIUM ions ,DETECTION limit ,FLUORESCENCE quenching - Abstract
An ion-imprinted fluorescent polymer (referred to as CQD@SiO@IIP) is presented for recognition of lithium ion. The material is based on the use of carbon quantum dots (CQDs) and is prepared by a surface imprinting technique using benzo-15-crown-5 (B15C5) as the complexing agent, methacrylic acid (MAA) as the functional monomer, ethylene glycol dimethacrylate (EGDMA) as the crosslinker, 2,2-azobisisobutyronitrile (AIBN) as the radical initiator, and lithium ion as the template. After optimization of the detection conditions, the relative fluorescence intensity (F/F), best measured at excitation/emission wavelength of 360 nm/460 nm, varies linearly with the Li concentration in the range between 0.5 and 50 μmol·L, with a limit of detection of 16 μmol·L. Performance was compared to the non-imprinted material, and the imprinting factor is found to be 4.5. The ion-imprinted fluorescence material was applied to the determination of Li in (spiked) water samples and obtained good recoveries ranged from 102 to 111.6%. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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