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Abstract Hydrogeological perturbations in response to earthquakes are widely described worldwide. In carbonate aquifers, a post-seismic discharge increase is often attributed to an increase of bulk permeability due to co-seismic fracturing and the attention on the role of faults to explain the diversion of groundwater is increasing. We focus on the reaction of carbonate hydrogeological basins to extensional seismicity, taking as an example the effects of the Central Italy 2016–2017 seismic sequence, on the Basal aquifer of the Sibillini Mountains area. Geo-structural, seismological and ground deformation data were collected and merged with artificial tracer tests results and with a 4-years discharge and geochemical monitoring campaign. The main NNW-directed groundwater flow was diverted to the west and a discharge deficit was observed at the foot-wall of the activated fault system with a relevant discharge increase, accompanied by geochemical variations, at the fault system hanging-wall. The observed variations are consistent with the combined action of a permeability increase along the activated fault systems, which modified the predominant pre-seismic along-strike regional flow, and with hydraulic conductivity increase due to fracturing, determining a fast aquifers emptying. We show that the prevailing mechanism depends on the aquifer systems position with respect to the activated faults.

The importance of considering groundwater (GW) and surface water (SW) as a single resource of two interconnected components has rapidly increased during the last decades. To investigate GW-SW interaction in an aquifer system exploited by several pumping wells, an integrated continuous monitoring of the hydrological conditions was carried out. The sub-catchment (14 km2), located in the Aspio basin near Ancona (Central Italy), is drained by a small stream named Betelico, and it is characterised by the presence of an unconfined alluvial aquifer and a semi-confined limestone aquifer. The aim of this study is to evaluate the drivers of stream drying up occurred during the last couple of years. This has been achieved by applying a trend analysis on rainfall, air temperatures, piezometric and stream level, and well pumping rates. Precipitation trends were analysed over a 30-years period through the calculation of the Standard Precipitation Index (SPI) and through heavy rainfall events frequency plots, while the correlation between piezometric stream levels and pumping rate was analysed during the last six years. The groundwater level was compared with the stream baseflow level, highlighting the interconnection between GW-SW over the years. The analysis on the water surplus (WS) trend, together with the rainfall events characterisation, supports the hypothesis of the decrease in recharge rate as the main driver of the stream drying up. This case study stresses the importance of studying GW-SW interactions in a continuously changing climatic context characterised by a decreasing precipitation trend, coupling both the advantages of a robust method like trend analysis on time series and the field continuous monitoring.

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The stability of a rock slope is strongly influenced by the pattern of groundwater flow through the fracture system, which may lead to an increase in the water pressure in partly open joints and the consequent decrease in the rock wall strength. The comprehension of the fracture pattern is a challenging but vital aspect in engineering geology since the fractures’ spatial distribution, connectivity, and aperture guide both the water movement and flow quantity within the rock volume. In the literature, the most accepted methods to hydraulically characterise fractured rocks in situ are the single borehole packer test, the high-resolution flow meters for fractures, and the artificial tracer tests performed in boreholes. However, due to the high cost a borehole requires and the general absence of wells along coastal cliffs, these methods may not be appropriate in rockfall-prone areas. In this study, an unsaturated rocky cliff, strongly affected by rockfalls, was investigated by combining kinematic analysis, Discrete Fracture Network (DFN) modelling, and artificial tracer tests. The DFN model and potential rock block failure mechanisms were derived from high-resolution 3D virtual outcrop models via the Structure from Motion (SfM) photogrammetry technique. An artificial tracer was injected using a double ring infiltrometer atop the recharge zone of the slope to determine the infiltration rate and validate the DFN results. The DFN and tracer test methods are frequently used at different spatial scales and for different disciplines. However, the integration of digital photogrammetry, DFN, and tracer tests may represent a new step in rockfall and landslide studies. This approach made possible the identification of groundwater flow patterns within the fracture system and revealed about a 10-day tracer transit time from the injection area and the monitored slope, with similar conductivity values gathered from both the DFN and tracer test. Planar and wedge failures with volumes ranging from 0.1 and 1 m3 are the most probable failure mechanisms in the areas. The results were consistent with the delay between the intense rainfall and the slope failures previously documented in the study area and with their mechanisms.

Carbonate aquifers are characterised by strong heterogeneities and their modelling is often a challenging aspect in hydrological studies. Understanding carbonate aquifers can be more complicated in the case of strong seismic events which have been widely demonstrated to influence groundwater flow over wide areas or on a local scale. The 2016–2017 seismic sequence of Central Italy is a paradigmatic example of how earthquakes play an important role in groundwater and surface water modifications. The Campiano catchment, which experienced significant discharge modifications immediately after the mainshocks of the 2016–2017 seismic sequence (Mmax = 6.5) has been analysed in this study. The study area is within an Italian national park (Sibillini Mts.) and thus has importance from a naturalistic and socio-economic standpoint. The research strategy coupled long-period artificial tracer tests (conducted both before and after the main earthquakes), geochemical and discharge analyses and isotope hydrology with hydrogeological cross-sections. This study highlights how the seismic sequence temporarily changed the behaviour of the normal faults which act predominantly as barriers to flow in the inter-seismic period, with water flow being normally favoured along the fault strikes. On the contrary, during earthquakes, groundwater flow can be significantly diverted perpendicularly to fault-strikes due to co-seismic fracturing and a consequent permeability increase. The interaction between groundwater and surface water is not only important from the point of view of scientific research but also has significant implications at an economic and social level.

This study wants to give a contribution to the semi-automatic evaluation of rock mass discontinuities, orientation and spacing, as important parameters used in Engineering. In complex and inaccessible study areas, a traditional geological survey is hard to conduct, therefore, remote sensing techniques have proven to be a very useful tool for discontinuity analysis. However, critical expert judgment is necessary to make reliable analyses. For this reason, the open-source Python tool named DCS (Discontinuities Classification and Spacing) was developed to manage point cloud data. The tool is written in Python and is based on semi-supervised clustering. By this approach the users can: (a) estimate the number of discontinuity sets (here referred to as “clusters”) using the Error Sum of Squares (SSE) method and the K-means algorithm; (b) evaluate step by step the quality of the classification visualizing the stereonet and the scatterplot of dip vs. dip direction from the clustering; (c) supervise the clustering procedure through a manual initialization of centroids; (d) calculate the normal spacing. In contrast to other algorithms available in the literature, the DCS method does not require complex parameters as inputs for the classification and permits the users to supervise the procedure at each step. The DCS approach was tested on the steep coastal cliff of Ancona town (Italy), called the Cardeto–Passetto cliff, which is characterized by a complex fracturing and is largely affected by rockfall phenomena. The results of discontinuity orientation were validated with the field survey and compared with the ones of the FACETS plug-in of CloudCompare. In addition, the algorithm was tested and validated on regular surfaces of an anthropic wall located at the bottom of the cliff. Eventually, a kinematic analysis of rock slope stability was performed, discussing the advantages and limitations of the methods considered and making fundamental considerations on their use.

The dynamic of groundwater systems feeding several springs of the Sibillini Mountains was deeply affected by nine Mw 5.0÷6.5 seismic events occurred in central Italy starting from August 2016. The strongest shock occurred on October 30th 2016 about 5 km NNE of Norcia Town, 9 km below the surface, as a result of upper crust normal faulting on the nearly 30 km-long Mt Vettore - Mt Bove fault system, a NW-SE trending, SW-dipping fault system outcropping on the western slope of Mt Vettore, the highest peak of Sibillini Mountains. Soon after this event, a general increase of springs and rivers discharge and groundwater levels was observed both in the Visso and Norcia areas, west of the Sibillini Mountains. In the Visso area the hydrogeological changes due to the seismic sequence exhausted in the 2019, while nowadays both discharges and groundwater levels are still higher than before in the Norcia area. Discharge data of the main springs located east, south-east of the Sibillini Mountains were analysed to verify whether the general increase observed on the western side was associated to a decrease on the eastern and southern-east area. The results show that the springs located on the eastern side and southern-east side of Mt Vettore experienced a significant long-term discharge decrease. In this preliminary work, the analysis of the historical discharge series of the Pescara di Arquata spring (SE of Mt Vettore), and its relationship with the Standard Precipitation Index (SPI) shows that the very low discharge values recorded during the post-seismic period are not associated with SPI as low as documented in the past for similar discharges. Moreover, the stable isotopic composition of Pescara di Arquata water during the post-earthquake period is slightly different from that measured before the seismic events; this suggests that a lower amount of water having more enriched isotopic δ18O content reaches the spring after the seismic sequence. These aspects seem to indicate that groundwater circulation in the southern-east area of Sibillini Mountains has been affected by the 2016-2017 seismic sequence.

Environmental isotopes are essential in hydrogeological studies, thanks to their contribution to the understanding of aquifers dynamics, vulnerability, water resources assessment, and management issues. The environmental isotopic approach plays a vital role in tracing the hydrological cycle and identifying various sources of contamination in the environment and gives independent information concerning what can be determined by a traditional hydrogeological study. Even in the framework of COP-26, isotopes have been indicated as fingerprints of climate change and therefore suitable for the evaluation of water balance and assessment of processes involved therein; in pollution studies they are used as fundamental support of traditional geochemical measures. Tritium, in particular, has been used since the 1960s to identify potential leaks in the containment walls of waste disposal sites, since its presence in the leachate (at very high levels in some cases) depends on the incorrect waste disposal of some peculiar items. Its use as a tracer of pollution by landfills is highlighted and emphasized by the very low concentrations of tritium in the natural environment. By comparing tritium content of leachate to that of water downflow from the waste disposal site, it is therefore possible to establish with a good success rate whether leachate have migrated or not out of the landfill, in the surrounding environment. An additional potential of tritium is to give a prompt indication of pollution risk in the environment indicating leaching even before the chemical indicator of pollution can be detected. This article wants to provide a contribution to the scientific community, collecting all the existing research in this field and providing data and benchmarks about this method, in particular stressing the role of tritium as an indicator of leachate transfer out of waste disposal sites.

We compared five regression approaches, namely, ordinary least squares, major axis, reduced major axis, robust, and Prais–Winsten to estimate δ18O–δ2H relationships in four water types (precipitation, surface water, groundwater collected in wells from lowlands, and groundwater from low-yield springs) from the northern Italian Apennines. Differences in terms of slopes and intercepts of the different regressions were quantified and investigated by means of univariate, bivariate, and multivariate statistical analyses. We found that magnitudes of such differences were significant for water types surface water and groundwater (both in the case of wells and springs), and were related to robustness of regressions (i.e., standard deviations of the estimates and sensitiveness to outliers). With reference to surface water, we found the young water fraction was significant in inducing changes of slopes and intercepts, leading us to suppose a certain role of kinetic fractionation processes as well (i.e., modification of former water isotopes from both snow cover in the upper part of the catchments and precipitation linked to pre-infiltrative evaporation and evapotranspiration processes). As final remarks, due to the usefulness of δ18O–δ2H relationships in hydrological and hydrogeological studies, we provide some recommendations that should be followed when assessing the abovementioned water types from the northern Italian Apennines.

Groundwater management of alluvial aquifers facing the northern Italian Apennines is an important issue that is becoming more complicated due to ongoing climate changes and increased water demands. The large groundwater withdrawals, coupled with an overall worsening of the water quality, require detailed knowledge of the recharge mechanisms of these aquifers that can be useful for further adaptation measures. We have focused our attention on a selected alluvial fan in which 49 slug injections of hyperconcentrated solutions of NaCl allowed river discharges to be estimated in seven different hydraulic sections. Consequently, losses from the streambed were assessed for the six river reaches along with the corresponding uncertainties in the estimates. The study confirms the suitability of such tests for identifying sectors in which streambed losses are promoted and for quantifying the total recharge conveyed to underlying aquifers. In addition, it has been demonstrated that the total streambed losses can be further linked to river discharges in any gauge upstream of the alluvial fan thanks to linear regression. Once obtained, the latter makes monitoring groundwater recharge by stream losses in real time possible if a permanent measurement device (such as the common telemetry used for river discharge monitoring) is available.

Nowadays, the balance between incoming precipitation and stream or spring discharge is a challenging aspect in many scientific disciplines related to water management. In this regard, although advances in the methodologies for water balance calculation concerning each component of the water cycle have been achieved, the Thornthwaite–Mather method remains one of the most used, especially for hydrogeological purposes. In fact, in contrast to physical-based models, which require many input parameters, the Thornthwaite–Mather method is a simple, empirical, data-driven procedure in which the error associated with its use is smaller than that associated with the measurement of input data. The disadvantage of this method is that elaboration times can be excessively long if a classical MS Excel file is used for a large amount of data. Although many authors have attempted to automatize the procedure using simple algorithms or graphical user interfaces, some bugs have been detected. For these reasons, we propose a WebApp for monthly water balance calculation, called WaterbalANce. WaterbalANce was written in Python and is driven by a serverless computing approach. Two respective European watersheds are selected and presented to demonstrate the application of this method.

As the rise in pore water pressure is one of the main factors in triggering landslides, the understanding of groundwater processes taking place at the hillslope scale is a crucial issue in slope stability analysis. However, identifying flow-paths travelled by water molecules from their infiltration is still a complex task. Hydrochemistry is recognized as a powerful tool that can help to gain useful hydrogeological information and has gradually become increasingly used in addition to conventional study methods. This manuscript presents a comprehensive geochemical investigation consisting of leaching tests and quantitative mineralogical analyses on soil samples, chemical analyses on groundwater samples and modelling. Our results highlighted the usefulness of coupling, even in hydrogeological studies focusing on landslides, geochemical surveys on both water and the soil matrix to constrain the interactions between host-rocks and groundwater. Moreover, it demonstrated that kinetic-based geochemical models, if properly calibrated on leaching tests, can provide valuable information on groundwater dynamics, allowing us to elucidate water-mixing processes beneath the soil surface.

The investigated area, located in the inner part of the Marche region (central Italy) and belonging to the carbonate Umbria- Marche ridges in the central Apennines, is characterised by very complex geo-structural setting and widespread karst phenomena that make difficult the definition of the relation among the aquifers basing only on the hydrogeological survey. Hence, the presence of different flowpaths among aquifers of the Umbria-Marche hydrostratigraphic sequence and of tectonic contacts among the different structures is verified using tracer tests. In particular, the tests showed that the Calcare Massiccio and the Maiolica aquifers are connected under certain tectonic conditions. A new tracer given by a single stranded DNA molecule and traditional fluorescent dyes have been injected into the Montelago sinkhole in different periods (during the recharge and during the discharge) and recovered in several points along the expected hydrogeological basin, using either manual and automatic sampling. Fluorescent traps were positioned in creeks, rivers and springs. The DNA molecule is useful to trace surface water and groundwater, is detectable even at very low concentrations, no significant change in water density and viscosity can be observed and its use is not dangerous for the environment. The results stress the suitability of DNA as hydrogeological tracer, capable to identify connections among aquifers and study different flowpaths even in high flow conditions when traditional tracers are more and more diluted. Moreover, fluorescein tracer allowed for the transport parameter determination, giving mean velocities ranging from 100 to 3000 m/day and mean residence time from some tens to hundreds of hours, and determining the aquifer volumes.

Tracers techniques are a good tool to investigate groundwater dynamics; they are essential to perform measurement of hydrogeological parameters of aquifers. This study was aimed at characterizing adsorption, effective porosity and pore water velocity in soil samples collected in a hydrographic basin of Marche Region (Italy). This basin has the typical geologic and hydrogeological features of many basins in Central Italy. Therefore. the principal aim is to evaluate the best tracer to be used for hydrogeological purpose (i.e. groundwater tracer test and aquifer parameter estimation). Adsorption has been investigated by means of laboratory batch tests using different tracers and involving different soils. In literature some application of tracers both to laboratory scale and to field scale can be found. Column tests have been performed also to test the effectiveness of different test equipment and to investigate the influence of some test parameters on the calculation of effective porosity and pore water velocity. These considerations and test results are very useful to advise the choice of the best tracer to be used in tracer field tests.