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Soils irrigated with raw wastewater for many years accumulate trace metals, especially in the surface horizon. We do not know, however, to what extent the metals migrate down the profile and whether they accumulate in deeper horizons. We assessed the migration of trace metals in the suburbs of Paris where market gardens had been irrigated with wastewater for more than 100 years. Within a soil series, we compared metals in the polluted soils with those of a reference soil of the same kind. We sampled by horizons three representative Luvisol profiles in the irrigated area and a fourth profile selected as a reference just outside the irrigated area. Large quantities of Zn, Pb, Cd and Cu appeared to have accumulated in the topsoil, at the base of which concentrations diminished markedly. There appeared to be appreciable migration into the subsoil only at the most intensely irrigated site. By relating the total trace metal contents to the total iron contents we could detect anomalous values and identify migration into the subsurface horizons more sensitively. This approach was tested first with the endogenous metal Cr, then with metal pollutants. We showed that Zn, Pb, Cd and Cu migrated downwards in all three irrigated soils. [ABSTRACT FROM AUTHOR]

Massive volumes of raw wastewater have been spread on sandy Luvisols in the Paris region since 1899, causing major soil contamination with metallic trace elements (MTE). To identify the factors influencing the vertical and horizontal redistribution of MTE at the plot scale, a study was carried out of the three-dimensional distribution of zinc. The background and exogenous fractions of zinc in the contaminated soil were discriminated using correlations between zinc and iron defined from unpolluted soils of the area. At the surface, the spatial distribution of zinc is determined by the geometry of the irrigation system and the terrain topography. The highest concentrations are observed near the irrigation outlets and in areas of very slight slope. The exogenous zinc has migrated down to the base of the studied solums (1 m depth), and its subsurface distribution depends upon the physico-chemical properties of the horizons. In the E horizon, the trapping of exogenous zinc is governed by the number of available reactive sites, whereas in the Bt horizon it is a function of the vertical and lateral behaviour of the drainage. Moreover, lateral transfer of exogenous zinc occurs in the C horizon. In the case of soil contaminated with raw wastewater, the organization of water flow on the surface and in the subsurface is a determining factor in the redistribution of zinc within a plot. [ABSTRACT FROM AUTHOR]