The global shift towards electric vehicles (EVs) underscores the critical need for reliable battery performance and safety. Lithium-ion batteries, particularly Li-NMC (lithium nickel manganese cobalt oxide), are widely adopted for their balanced functional and performance characteristics. However, the advancement of batteries with higher nickel content and reduced manganese and cobalt introduces challenges, including increased susceptibility to thermal runaway and degradation, especially under abusive conditions like over-discharge. This study addresses significant research gaps by developing a machine learning (ML) algorithm for the early detection and predictive maintenance of over-discharged Li-NMC batteries. Current methods often fail to identify and mitigate the effects of continuous cycling, which can release harmful free radicals such as singlet oxygen (1 O 2 ) and superoxide ( O 2 - ) that accelerate degradation. Our ML approach utilizes supervised learning, feature engineering, and model optimization, leveraging key input features such as voltage, time, and cycle count which are derived from extensive battery life testing. To validate our model, we conducted scanning electron microscopy energy-dispersive spectroscopy (SEM–EDS), galvanostatic charge–discharge (GCD) tests, and rate capability tests. The proposed ridge regression model achieved a mean absolute error (MAE) of 0.11422%, a mean squared error (MSE) of 0.02313%, and an R-squared (R2) value of 0.99, outperforming other models such as Decision Trees (DT), Recurrent Neural Networks (RNNs), Support Vector Machines (SVMs), Gradient Boosting (GB), and Lasso Regression. Our model addresses key shortcomings of existing methods, particularly in predicting degradation in precycled batteries subjected to fault induction. The insights gained contribute to a robust control strategy for EV battery management, enabling proactive maintenance, timely battery replacement, and enhanced system reliability and safety, effectively addressing the long-term challenges in battery health management. [ABSTRACT FROM AUTHOR]