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Based on the structural characteristics of pervious concrete, an improved mix design method for pervious concrete was developed based on permeability, compressive strength and slurry layer thickness relationships. The results of validation experiments showed that when the slurry layer thickness of the pervious concrete is about 0.35–0.55 mm, the effective porosity is about 22–36%, the permeability coefficient is about 4.88–8.90 mm/s and the compressive strength is about 5.9–18.5 MPa. With an increase in the slurry layer thickness of the pervious concrete, the compressive strength increased, but the effective porosity and permeability coefficient decreased, and vice versa. The results of this study proved that pervious concrete can be formulated to satisfy permeability and compressive strength requirements by using the improved mix design method.

The self-compacting concrete (SCC) filling layer is a key structural component of the China railway track system type III ballastless track structure. The quality of the filling layer directly affects the durability, comfort and safety of the track system. Based on job site practice in the construction of the Zhengzhou–Fuyang high-speed railway, the distribution characteristics of the dynamic elastic modulus and homogenisation index of the SCC used as the filling layer with different workability parameters (slump flow, T500 and filling time) were obtained by sampling the SCC core from the filling layer. Image analysis software was employed to analyse the size and distribution characteristics of the surface defects statistically. The filling layer quality was evaluated according to the homogenisation index and the surface defect ratio. The results showed that the dynamic elastic modulus of the SCC in the filling layer tended to decrease from the intermediate filling hole to the four outlets. The order of influence of workability parameters on the filling layer quality was found to be T500, slump flow and filling time.

Phase change materials (PCMs) are widely used in solar energy utilization, industrial waste heat recovery and building temperature regulation. However, there have been few studies on the application of PCMs in the field of biomedicine. In recent years, some scholars have carried out research in the biomedicine field using the characteristics of PCMs. It was observed that the excellent properties of PCMs enhance the quality of a variety of biomedical applications with many advantages over existing applications, which provide new methods for the treatment of disease. PCMs have broad application prospects in the field of biomedicine. Therefore, a timely review of relevant research progress is of great significance for the continuous development of new methods. Innovatively, from the unique perspective of the biomedical field, this paper systematically reviews the application and related research progress of PCMs from four aspects: cold chains for vaccines and medicines, drug delivery systems, thermotherapy/cold compress therapy and medical dressings. In addition, we summarize and discuss the general principles of the design and construction of PCMs in the biomedical field. Finally, existing problems, solutions and future research directions are also put forward in order to provide a basis for guidance and promote the future applications of phase change materials in the biomedicine field.

As a high-output industrial byproduct, fly ash can partially replace Portland cement in concrete, which is one of the important treatment methods to improve its utilization. However, the low activi...

High-speed railways with high load capacity and long-term performance have been developed by the aid of high-performance construction materials for foundation treatments. The mechanical properties and durability of new cement-soil mixture reinforced by local sourced waste coal gangue aggregate were investigated in this study. Extensive experiments were carried out to analyse the effects of coal gangue on compressive strength, elastic modulus, stress-strain curve and anti-corrosion of cement-soil mixture. The results show that incorporation of coal gangue significantly improve the strength, stiffness and anti-corrosion ability of cement-soil mixture. Strength improvements up to 81.8% was achieved, but the ductile failure model shited to brittle failure with more than 42% coal gangue reinforcements. Except for the declining segment of the stress-strain curve, the ascending segment of the stress-strain curve can be fitted by the existing models. From the microstructural characterization, coal gangue can reduce acid solution permeation compared to the soil. For the cemented soil with coal gangue, the mass-loss rates only reach 4–7% after 140 days acid solution immersion. Therefore, this new clean production of high-performance cement-soil mixture through waste coal gangue reinforcement has great potential for railway foundation treatments.

Filling layer self-compacting concrete (FLSCC) is a key construction material in China Rail Track System (CRTS) III slab ballastless track and its resistance to impact loading is of great importance to the service security of high-speed train. In this paper, the dynamic mechanical characteristics of FLSCC under impact loading were investigated with a split Hopkinson pressure bar (SHPB) at strain rates ranging from 101 s−1 to 102 s−1. Results show that the compressive strength, peak strain, elastic modulus and toughness ratio of FLSCC all increase with strain rate. The increase factors of compressive strength (DIFc) and strain (DIFe) of FLSCC increase linearly with decimal logarithm of strain rate. The elastic modulus (Ed) and toughness ratio (TR) increase linearly with strain rate. Self-compacting concrete (SCC) shows greater strain rate effect than normal concrete (NC). However, FLSCC presents lower strain rate effect but better toughness performance than normal SCC. The incorporation of large content of SP and VMA provides FLSCC with higher porosity, which makes it possess excellent dynamic mechanical performance.

Filling layer self-compacting concrete (FLSCC) is a key material in newly-built China Rail Track System (CRTS), which is commonly subjected to cyclic dynamic load from high-speed train and various ambient temperature during service. In this paper, a series of indoor simulating experiments was conducted to investigate the impact resistance of FLSCC suffering from cyclic flexural load and different temperature conditions with a Φ75 mm split Hopkinson pressure bar (SHPB). The dynamic increase factors were introduced to evaluate the strain rate effect on various mechanical properties of FLSCC and the corresponding mechanisms were explained. Results show that the dynamic increase factor of compressive strength (DIFc) and peak strain (DIFe) of FLSCC increase linearly with logarithm of strain rate, while specific energy absorption increases exponentially with strain rate. The impact resistance of FLSCC is greatly influenced by cyclic flexural load and low temperature. The strain rate sensitivity of compressive strength of FLSCC at minus temperature (−20°C) is weaker than that at normal temperature (20°C) and after freeze-cyclic load coupling action the sensitivity decreases further. Similar tendencies were also observed in peak strain and specific energy absorption.

As one of the core components, high quality self-compacting concrete filling layer is of great importance to the long-term safe service of CRTS III type slab ballastless track. The present paper designed a freeze and flexural-loading coupling action testing system to investigate the mechanical characteristics of self-compacting concrete applied in filling layer (FLSCC), aiming at understanding the service behavior of filling layer under severe environment condition. The effects of temperature, cycle number and stress level on mechanical properties including flexural strength, dynamic elastic modulus and damping ratio of FLSCC were discussed. Results show that the freeze and cyclic load coupling action aggravates the deterioration of concrete compared to single cyclic load condition. FLSCC exhibits better resistance to freeze and cyclic load action than other three investigated concretes in term of flexural strength, dynamic elastic modulus and damping ratio. The flexural strength of FLSCC decreases with increasing cycle number stress level at low temperature (−20 °C) and the damage variable of FLSCC increases exponentially with cycle number. The outstanding resistance of FLSCC to freeze and cyclic load coupling action results from the excellent microstructure which can maintain its good deformation capacity and delay the damage propagation.

In order to study the synergistic effects of organic and inorganic thickening agents on the rheological properties of cement paste, the rheological parameters, thixotropy cement-paste containing limestone powder (LP), re-dispersible polymer powder (RPP), and hydroxypropyl methylcellulose ether (HPMC) were investigated using the Anton Paar MCR 102 rheometer at different resting times. The early-age hydration process, hydration products, and microstructure were also analyzed with scanning electron microscopy (SEM) and thermogravimetry analyses (TGA). The results showed that the addition of LP, RPP, and HPMC affected the rheological properties of cement paste, but the thickening mechanism between organic and inorganic thickening agents was different. The small amount of LP increased the plastic viscosity but decreased the yield stress of cement paste due to its dense filling effect. Adding 1% of RPP improved the thixotropic property of cement paste by 50%; prolonging the standing time could improve the thixotropic performance by as much as two times. Only 0.035% HPMC added to the cement paste increased the plastic viscosity by 20%, while the yield stress increased nearly twice. The more HPMC added, the more significant effect it showed. Cement paste compounds with LP, RPP, and HPMC balanced the yield stress and plastic viscosity and improved the thixotropy. The C-L6-R1.0-H0.035 paste presented as a pseudoplastic, its rheological indexes were close to one, and it was hardly affected by the resting time. The composite superposition effect of organic and inorganic thickening agents reduced the impact of resting time for all pastes. As the organic thickening component inhibited the hydration more than the LP promoted the hydration of the cement paste, indicating that the C-L6-R1.0-H0.035 paste remained in the particle fusion stage after curing for three days, as shown by the SEM images.

Based on the relations between slump flow (SF), coarse aggregate average diameter (dav,i) and volume of coarse aggregate (Vg,i) used in self-compacting concrete (SCC), it was found that the preferable SF was that coarse aggregate could flow into a compact single layer status when SF testing was taken. Therefore, an improved mix design method of SCC was proposed according to relations among SF, dav,i and Vg,i. In the same Vg,i condition, large dav,i is suitable for small SF, but small dav,i should match large SF. When nominal size of coarse aggregate was 5–20 mm, proper SF for SCC should be 570 mm–720 mm. Results from the validated experiment show that properties of SCC including workability and compressive strength can satisfy the requirements. This improved mix design method helps to further develop SCC and cuts cost in real engineering projects.

In this study, isothermal calorimetry and the boundary nucleation and growth model (BNG model) were adopted to investigate the influence of fly ash (FA) and slag (SL) on the nucleation and growth of cement hydrates at early-stage. Afterwards, the mechanism was discussed by analyses of instantaneous activation energy and microtopography. The results show that the hinderance of FA on the early hydration at 20℃ is possibly contributed by the inhibition of nucleation, while SL promotes nucleation at both 20℃ and 60℃. Moreover, it is found that the paste containing FA has the lowest activation energy at early-stage, while the paste containing SL has the highest activation energy, which further indicate that the nucleation of the paste containing FA is more difficult. Besides, the surface microtopography analysis of particles confirm that SL has higher reactivity than FA in paste to generates more additional C-S-H gel to provide stronger seeding effect for producing C-S-H.

Rheological behaviors are the essential workability characteristics of fresh concrete. Generally speaking, paste volume in self-compacting concrete (SCC) are no less than 340 L/m3. Therefore, rheology of paste could be mainly responsible for rheology of SCC. Mineral admixtures are important for modern concrete, taking great influence on concrete rheology. In this paper, an experiment was designed to investigate the shear thickening behaviors of cement paste replaced by fly ash (FA), slag (SL) and limestone powder (LP), respectively. Results show that plastic viscosity of paste discussed in this paper prominently decrease first and then increase with the shear rate increasing. Therefore, there exist critical shear rate (γcrit), critical shear stress (τcrit) and minimum plastic viscosity (ηmin) in rheological curves at the beginning of shear thickening taking place. The addition of FA, SL and LP into cement paste not only decrease the γcrit, τcrit and ηmin, resulting in cement paste easy to exhibit shear thickening, but also increase the rheological index (n), leading to shear thickening intensity augmenting. γcrit of cement paste with addition 30% SL drops to10 s−1, displaying shear thickening response taking place easily compared to cement paste with the same FA and LP contents. Rheological index (n) of cement paste with SL is also larger than cement paste with FA and LP at the same mineral admixtures contents. The shear thickening intensity sequence of cement paste under the effects of mineral admixtures are SL, FA and LP, respectively.

Sealed-space-filling self-compacting concrete (SSFSCC) is used in China Rail Track System (CRTS) III ballastless slab track of high-speed rail, which has been originally developed in China recently. In this track system, SSFSCC needs to be grouted into a flat, narrow, and sealed space (90 mm × 2500 mm × 5600 mm) which is enclosed by above prefabricated slab and bottom base plate. Good bonding between SSFSCC filling layer and above prefabricated slab has to be secured since these two layers are required to work as a composite plate. SSFSCC presents some special characteristics in comparison with normal SCC. This paper elaborated the property requirements of SSFSCC and the structural characteristics of SSFSCC layer of CRTS III ballastless slab track of high-speed rail. The compositions and mix proportioning of SSFSCC as well as construction technology were briefly introduced. The challenges of the application of this special SCC were also addressed.

The influences of four nanoparticles of nanosilica (SiO2), nano-calcium carbonate (CaCO3), nano-aluminium oxide (Al2O3) and nano-iron oxide (Fe2O3) on workability, hydration, pore structure and mechanical strength of reactive powder concrete (RPC) are investigated by macro/microscopic methods. The aim of this study is to provide an essential basis for exploiting new-generation cementitious materials with ultra-high strength and super-long service life by employing modern nano-modification technology. The results indicate that addition of low-dosage nanoparticles to RPC shows a remarkable influence on the mechanical strength, hydration and pore structure compared to the ordinary cement system with a relatively high water/cement ratio. The compactness and mechanical strength of RPC can be greatly improved by incorporating nanoparticles. The promotive ratio of flexural and compressive strength of RPC is up to 30%. The elevated temperature further promotes the effect of nanoparticles on the strength of RPC. The seeding effect of nanoparticles on hydration of cement and the nano-size filling role are strengthened in the RPC system.

The dynamic mechanical property of concrete is one of the key parameters, which greatly influences durability of infrastructures subjected to continuous heavy loading, such as girder and track slab of high-speed railway foundation structure. This paper reports serials of experiments designed to investigate the deterioration of dynamic mechanical properties of different concretes under fatigue loading condition. Four parameters including relative dynamic elastic modulus (RDEM), relative dynamic shear modulus (RDSM), relative compressive strength (RCS) and water absorption (WA) of concrete were evaluated to assess the dynamic properties and microstructures of concretes. Results show that the fatigue stress levels and fatigue cycle durations significantly influence the dynamic mechanical properties of concrete including dynamic elastic modulus and dynamic shear modulus. Addition of proper mineral admixture can improve the dynamic mechanical characteristics of concrete and increase its resistance against the fatigue loading effect. Keeping the amount of mineral admixture in concrete constant, its dynamic mechanical property with fly ash is lower than that with fly ash and silica fume. The water absorption in concrete, which is an indirect parameter reflecting capillary porosity, increases evidently after bearing fatigue-loading. There is a close correlation between the deterioration of dynamic mechanical property and the increasing of water absorption of concrete. This indicates that the damage of microstructure of concrete subjected to fatigue loading is the indispensable reason for the decay of its dynamic mechanical performance.

Steam-cured concrete is widely used to manufacture prefabricated units of high-speed railway foundation structure such as girder and track slab. The dynamic mechanical property of steam-cured concrete is one of the key properties affecting service performance of high-speed railway foundation structure. In the present paper, serial macro/micro-experiments were carried out to investigate the dynamic elastic modulus, shear modulus, damping ratio, and microstructure of steam-cured concrete. The relationships between compositions, curing regime, microstructure, and dynamic properties of steam-cured concrete as well as the corresponding mechanisms were discussed. The results indicate that steam-cured concrete in early age has a larger dynamic elastic modulus and shear modulus as well as a smaller damping ratio compared with standard-cured concrete. On the contrary, at a later age a slightly smaller dynamic elastic modulus and a larger damping ratio of steam-cured concrete are observed. Addition of mineral admixture results in a bit lower dynamic elastic modulus and damping ratio of concrete than that of the control specimen without mineral admixtures. The achievements can provide some fundamental suggestions for materials parameters selection during structural design of steam-cured concrete precast element.

Rheological curves of cement&ndash, fly ash (C&ndash, FA) paste incorporating nanomaterials including nano-SiO2 (NS), nano-CaCO3 (NC) and nano-Al2O3 (NA) at different resting times (hydration time of 5 min, 60 min, and 120 min) were tested with a rheometer. The rheological behaviors were described by the Herschel&ndash, Bulkley (H&ndash, B) model, and the influences of these nanomaterials on rheological properties of C&ndash, FA paste were compared. Results show that the types, content of nanomaterials and resting time have great influences on the rheological properties of C&ndash, FA paste. Incorporating NS and NA increases yield stress and plastic viscosity, and decreases the rheological index of C&ndash, FA paste. When the content of NS and NA were 2 wt%, the rheological index of C&ndash, FA paste was less than 1, indicating rheological behavior changes from shear thickening to shear thinning. Meanwhile, with rising resting time, yield stress and plastic viscosity increased significantly, but the rheological index decreased evidently, showing paste takes on shear thinning due to the rise of resting time. However, incorporating 3 wt% NC and the rising of resting time did not change the rheological properties of C&ndash, FA paste. These differences are mainly that the specific surface area (SSA) of NS (150 m2/g) and NA (120 m2/g) are much larger than that of NC (40 m2/g). The huge SSA of NS and NA consume lots of free water and these tiny particles accelerate the hydration process during resting time.