19 results on '"Kupp, Elizabeth R."'
Search Results
2. Particle size effects on yttrium aluminum garnet (YAG) phase formation by solid-state reaction
- Author
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Kupp, Elizabeth R., Kochawattana, Sujarinee, Lee, Sang-Ho, Misture, Scott, and Messing, Gary L.
- Published
- 2014
- Full Text
- View/download PDF
3. Low temperature, transient liquid phase sintering of B2O3-SiO2-doped Nd:YAG transparent ceramics
- Author
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Stevenson, Adam J., Kupp, Elizabeth R., and Messing, Gary L.
- Published
- 2011
- Full Text
- View/download PDF
4. Co-casting and optical characteristics of transparent segmented composite Er∶YAG laser ceramics
- Author
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Kupp, Elizabeth R., Messing, Gary L., Anderson, Julie M., Gopalan, Venkatraman, Dumm, John Q., Kraisinger, Charles, Nikolay, Ter-Gabrielyan, Merkle, Larry D., Dubinskii, Mark, Simonaitis-Castillo, Vida K., and Quarles, Gregory J.
- Published
- 2010
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- View/download PDF
5. Additive manufacturing of textured ceramics: A review.
- Author
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Walton, Rebecca L., Kupp, Elizabeth R., and Messing, Gary L.
- Published
- 2021
- Full Text
- View/download PDF
6. Templated grain growth of high coercive field CuO‐doped textured PYN‐PMN‐PT ceramics.
- Author
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Brova, Michael J., Watson, Beecher H., Walton, Rebecca L., Kupp, Elizabeth R., Fanton, Mark A., Meyer, Richard J., and Messing, Gary L.
- Subjects
BARIUM titanate ,CERAMICS ,GRAIN ,LIQUID phase epitaxy ,PIEZOELECTRIC materials ,CURIE temperature - Abstract
This paper explores the templated grain growth and texturing of Pb(Yb1/2Nb1/2)O3‐Pb(Mg1/3Nb2/3)O3‐PbTiO3 (PYN‐PMN‐PT) ceramics. A PbO‐CuO liquid phase was determined to substantially increase the growth of PYN‐PMN‐PT on barium titanate template particles. Texturing resulted in an 83% enhancement in strain behavior (754 pm/V) compared with random PYN‐PMN‐PT ceramics (413 pm/V). The increased Pb(Yb1/2Nb1/2)O3 (PYN) content of textured 21PYN‐41PMN‐38PT resulted in a high coercive field of 13.9 kV/cm. Residual barium titanate templates reduced the polarization from 33.7 to 26.2 µC/cm2 and slightly decreased the Curie temperature (236‐224°C). These results show that textured PYN‐PMN‐PT is a promising material for high strain and coercive field transducers. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
7. Processing and electromechanical properties of high‐coercive field ZnO‐doped PIN‐PZN‐PT ceramics.
- Author
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Brova, Michael J., Watson, Beecher H., Walton, Rebecca L., Kupp, Elizabeth R., Fanton, Mark A., Meyer, Richard J., and Messing, Gary L.
- Subjects
KIRKENDALL effect ,TRANSITION temperature ,CERAMICS ,CURIE temperature ,ZINC oxide ,PHASE transitions ,LEAD zirconate titanate ,PIEZOELECTRIC thin films - Abstract
This study explores sintering and piezoelectricity of ZnO‐doped perovskite Pb(In1/2Nb1/2)O3‐Pb(Zn1/3Nb2/3)O3‐PbTiO3 (PIN‐PZN‐PT) ceramics. The enhanced densification of ZnO‐doped PIN‐PZN‐PT is attributed to the formation of oxygen vacancies by the incorporation of Zn2+ into the perovskite B‐site and increased rate of bulk diffusion relative to undoped PIN‐PZN‐PT. Incorporation of Zn2+ into the perovskite lattice increased the tetragonal character of PIN‐PZN‐PT as demonstrated by tetragonal peak splitting and increased Curie temperature. Sintering in flowing oxygen reduced the solubility of Zn2+ in the perovskite lattice and resulted in rhombohedral PIN‐PZN‐PT. Sintering in oxygen prevented secondary phase formation which resulted in a high‐piezoelectric coefficient (d33 – 550 pC/N), high‐coercive field (Ec – 13 kV/cm), and high‐rhombohedral to tetragonal phase transition temperature (Tr‐t – 165°C). We conclude that ZnO‐doped PIN‐PZN‐PT ceramics are excellent candidates for high‐power transducer applications. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
8. Tailoring particle alignment and grain orientation during tape casting and templated grain growth.
- Author
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Walton, Rebecca L., Vaudin, Mark D., Hofer, Anna‐Katharina, Kupp, Elizabeth R., Meyer, Richard J., and Messing, Gary L.
- Subjects
GRAIN orientation (Materials) ,CASTING (Manufacturing process) ,GRAIN growth ,ALUMINUM oxide ,PIEZOELECTRIC materials - Abstract
The quality of crystallographic alignment in textured ceramics produced by tape casting and templated grain growth (TGG) has been little studied despite its demonstrated impact on magnetic, piezoelectric, and optical properties. Physical and crystallographic alignment of anisotropic template particles is shown to be directly linked to the casting rate, gap height, and casting viscosity during tape casting. These parameters are shown to affect the shape and magnitude of the shear rate profile under the doctor blade during casting which in turn causes a gradient in the torque acting on anisotropic particles. The magnitude of the torque, the time the slurry is exposed to torque during casting, and the ratio of casting height to template diameter are demonstrated to enable the particle alignment process to be tailored to produce well‐aligned template particles. Crystallographic alignment of the textured ceramic was quantified by grain misalignment angle (full width at half maximum, FWHM) and degree of orientation (r) and is directly correlated with the degree of torque during casting. High‐quality alignment (FWHM = 4.5°; r = 0.13) was demonstrated in the model TGG system consisting of submicrometer alumina and 5 vol% 11 μm diameter template platelet particles. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
9. Powder chemistry effects on the sintering of MgO‐doped specialty Al2O3.
- Author
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Frueh, Tobias, Marker, Cassie, Kupp, Elizabeth R., Compson, Charles, Atria, Joe, Gray, Jennifer L., Liu, Zi‐Kui, and Messing, Gary L.
- Subjects
POWDERS ,CHEMISTRY ,ALUMINUM oxide ,MAGNESIUM oxide ,SOIL densification - Abstract
Abstract: In this work, we investigate the effects of powder chemistry on the sintering of MgO‐doped specialty alumina. The stages at which MgO influences densification of Al
2 O3 were identified by comparing dilatometry measurements and the sintering kinetics of MgO‐free and MgO‐doped specialty alumina powders. MgO is observed to reduce the grain boundary thickness during densification using TEM. We show that MgO increases the solubility of SiO2 in alumina grains near the boundaries using EDS. First‐principles DFT calculations demonstrate that the co‐dissolution of MgO and SiO2 in alumina is thermodynamically favored over the dissolution of MgO or SiO2 individually in alumina. This study experimentally demonstrates for the first time that removal of SiO2 from the grain boundaries is a key process by which MgO enhances the sintering of alumina. [ABSTRACT FROM AUTHOR]- Published
- 2018
- Full Text
- View/download PDF
10. Texture-engineered ceramics—Property enhancements through crystallographic tailoring.
- Author
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Messing, Gary L., Poterala, Stephen, Yunfei Chang, Frueh, Tobias, Kupp, Elizabeth R., Watson III, Beecher H., Walton, Rebecca L., Brova, Michael J., Hofer, Anna-Katharina, Bermejo, Raul, and Meyer Jr., Richard J.
- Subjects
SINGLE crystals ,PIEZOELECTRIC ceramics ,CRYSTALLOGRAPHIC shear ,THERMOELECTRIC effects ,THERMOELECTRICITY - Abstract
Texture-engineered ceramics enable access to a vast array of novel texture-property relations leading to property values ranging between those of single crystals and isotropic bulk ceramics. Recently developed templated grain growth and magnetic alignment texturing methods yield high quality crystallographic texture, and thus significant advances in achievable texture-engineered properties in magnetic, piezoelectric, electronic, optical, thermoelectric, and structural ceramics. In this paper, we outline the fundamental basis for these texture-engineered properties and review recent contributions to the field of texture-engineered ceramics with an update on the properties of textured lead-free and lead-based piezoelectrics. We propose that further property improvements can be realized through development of processes that improve crystallographic alignment of the grain structure, create biaxial texture, and explore a wider array of crystallographic orientations. There is a critical need to model the physics of texture-engineered ceramics, and more comprehensively characterize texture, thus enabling testing of texture orientation-property relations and materials performance. We believe that in situ measurements of texture evolution can lead to a more fundamental and comprehensive understanding of the mechanisms of texture development. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
11. Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics.
- Author
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Guo, Jing, Guo, Hanzheng, Baker, Amanda L., Lanagan, Michael T., Kupp, Elizabeth R., Messing, Gary L., and Randall, Clive A.
- Subjects
SINTERING ,CERAMICS ,SOIL densification ,CERAMIC materials ,CRYSTAL structure ,POLYTYPIC transformations - Abstract
This paper describes a sintering technique for ceramics and ceramic-based composites, using water as a transient solvent to effect densification (i.e. sintering) at temperatures between room temperature and 200 °C. To emphasize the incredible reduction in sintering temperature relative to conventional thermal sintering this new approach is named the 'Cold Sintering Process' (CSP). Basically CSP uses a transient aqueous environment to effect densification by a mediated dissolution-precipitation process. CSP of NaCl, alkali molybdates and V
2 O5 with small concentrations of water are described in detail, but the process is extended and demonstrated for a diverse range of chemistries (oxides, carbonates, bromides, fluorides, chlorides and phosphates), multiple crystal structures, and multimaterial applications. Furthermore, the properties of selected CSP samples are demonstrated to be essentially equivalent as samples made by conventional thermal sintering. [ABSTRACT FROM AUTHOR]- Published
- 2016
- Full Text
- View/download PDF
12. The Effects of Na2O and SiO2 on Liquid Phase Sintering of Bayer Al2O3.
- Author
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Frueh, Tobias, Kupp, Elizabeth R., Compson, Charles, Atria, Joe, Messing, Gary L., and Blendell, J.
- Subjects
- *
SODIUM compounds , *SILICON oxide , *SINTERING , *ALUMINUM oxide , *CRYSTAL grain boundaries , *MAGNESIUM oxide - Abstract
To determine how grain-boundary composition affects the liquid phase sintering of MgO-free Bayer process aluminas, samples were singly or co-doped with up to 1029 ppm Na2O and 603 ppm SiO2 and heated at 1525°C up to 8 h. Na2O retards densification of samples from the onset of sintering and up to hold times of 30 min at 1525°C compared to the undoped samples, but similar to the as-received, MgO-free Al2O3, Na2O-doped samples sinter to 98% density with average grain sizes of ~3 μm after 8 h. Increasing SiO2 concentration significantly retards densification at all hold times up to 8 h. The estimated viscosities (20−400 Pa·s) of the 0.3 to 1.8 nm thick siliceous grain-boundary films in this study indicate that diffusion greatly depends on the composition of the liquid grain-boundary phase. For low Na2O/SiO2 ratios, densification of Bayer Al2O3 at 1525°C is controlled by diffusion of Al3+ through the grain-boundary liquid, whereas for high Na2O/SiO2 ratios, densification can be governed by either the interface reaction (i.e., dissolution) of Al2O3 or diffusion of Al3+. Increasing Na2O in SiO2-doped samples increases diffusion of Al3+ and Al2O3 solubility in the liquid, and thus densification increases by 1%. Based on these findings, we conclude that Bayer Al2O3 densification can be manipulated by adjusting the Na2O to SiO2 ratio. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
13. The Effects of Na2O and SiO2 on Liquid Phase Sintering of Bayer Al2O3.
- Author
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Frueh, Tobias, Kupp, Elizabeth R., Compson, Charles, Atria, Joe, Messing, Gary L., and Blendell, J.
- Subjects
SODIUM compounds ,SILICON oxide ,SINTERING ,ALUMINUM oxide ,CRYSTAL grain boundaries ,MAGNESIUM oxide - Abstract
To determine how grain-boundary composition affects the liquid phase sintering of MgO-free Bayer process aluminas, samples were singly or co-doped with up to 1029 ppm Na
2 O and 603 ppm SiO2 and heated at 1525°C up to 8 h. Na2 O retards densification of samples from the onset of sintering and up to hold times of 30 min at 1525°C compared to the undoped samples, but similar to the as-received, MgO-free Al2 O3 , Na2 O-doped samples sinter to 98% density with average grain sizes of ~3 μm after 8 h. Increasing SiO2 concentration significantly retards densification at all hold times up to 8 h. The estimated viscosities (20−400 Pa·s) of the 0.3 to 1.8 nm thick siliceous grain-boundary films in this study indicate that diffusion greatly depends on the composition of the liquid grain-boundary phase. For low Na2 O/SiO2 ratios, densification of Bayer Al2 O3 at 1525°C is controlled by diffusion of Al3+ through the grain-boundary liquid, whereas for high Na2 O/SiO2 ratios, densification can be governed by either the interface reaction (i.e., dissolution) of Al2 O3 or diffusion of Al3+. Increasing Na2 O in SiO2 -doped samples increases diffusion of Al3+ and Al2 O3 solubility in the liquid, and thus densification increases by 1%. Based on these findings, we conclude that Bayer Al2 O3 densification can be manipulated by adjusting the Na2 O to SiO2 ratio. [ABSTRACT FROM AUTHOR]- Published
- 2016
- Full Text
- View/download PDF
14. Low temperature, transient liquid phase sintering of B2O3-SiO2-doped Nd:YAG transparent ceramics.
- Author
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Stevenson, Adam J., Kupp, Elizabeth R., and Messing, Gary L.
- Subjects
SINTERING ,CERAMICS ,POLYCRYSTALS ,CRYSTALS ,METALS - Abstract
B
2 O3 -SiO2 is shown to act as a transient liquid phase sintering aid that reduces the sintering temperature of Nd:YAG ceramics to 1600 °C. 1 at.% Nd3x Y3-3x Al5 O12 (Nd:YAG) ceramics were doped with 0.34-1.35 mol% B2 O3 -SiO2 and sintered between 1100 and 1700 °C. Dilatometric measurements show that B2 O3 -SiO2 doping increases the densification rate during intermediate-stage sintering relative to SiO2 -doped samples. B3+ content is reduced to <5 ppm in samples heated to 1500 °C, as determined by mass spectrometry. For B2 O3 -SiO2 -doped samples, final stage densification and grain growth follow a more densifying sintering trajectory than SiO2 -doped 1 at.% Nd:YAG ceramics because there is less SiO2 during final-stage densification. The increased densification kinetics during intermediate-stage sintering lead to highly transparent Nd:YAG ceramics when sintered at 1600 °C in either vacuum or oxygen. Thus, transparent Nd: YAG ceramics can be sintered without the need for expensive refractory metal vacuum furnaces or pressure-assisted densification. [ABSTRACT FROM AUTHOR]- Published
- 2011
- Full Text
- View/download PDF
15. Effect of SiO.
- Author
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Stevenson, Adam J., Xin Li, Martinez, Miguel A., Anderson, Julie M., Suchy, Daniel L., Kupp, Elizabeth R., Dickey, Elizabeth C., Mueller, Karl T., and Messing, Gary L.
- Subjects
POWDER metallurgy ,SINTERING ,ELECTRON microscopy ,TRANSMISSION electron microscopy ,CRYSTAL grain boundaries ,SILICON compounds ,MAGNETIC fields - Abstract
This paper examines the influence of SiO
2 doping on densification and microstructure evolution in Nd3x Y3-3x Al5 O12 (Nd:YAG) ceramics. Nd:YAG powders were doped with 0.035-0.28 wt% SiO2 and vacuum sintered between 1484° and 1750°C.29 Si magic-angle spinning nuclear magnetic resonance showed that Si41 substitutes onto tetrahedrally coordinated Al3+ sites. High-resolution transmission electron microscopy showed no grain boundary second phases for all silica levels in samples sintered at 1600°-1750°C. Coarsening was limited by a solute drag mechanism as suggested by cubic grain growth kinetics and transmission electron microscopy energy-dispersive X-ray spectroscopy observations of increased Nd31 concentration near grain boundaries. Increasing SiO2 content increased both densification and grain growth rate and led to increasingly coarsening-dominated sintering trajectories. Fine-grained (< 3 μm), highly transparent (> 82% real in-line transmission) ceramics were produced by sintering 0.035 wt% SiO2 -doped ceramics at 1750°C for 8 h. Coarse-grained (18 μm), transparent samples were obtained with 0.28 wt%SiO2 -doped Nd:YAG when sintered at 1600°C for 8 h. [ABSTRACT FROM AUTHOR]- Published
- 2011
- Full Text
- View/download PDF
16. Hot Isostatic Pressing of Transparent Nd:YAG Ceramics.
- Author
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Sang-Ho Lee, Kupp, Elizabeth R., Stevenson, Adam J., Anderson, Julie M., Messing, Gary L., Xin Li, Dickey, Elizabeth C., Dumm, John Q., Simonaitis-Castillo, Vida K., and Quarles, Gregory J.
- Subjects
- *
ISOSTATIC pressing , *CERAMICS , *SINTER (Metallurgy) , *SILICA , *POWDER metallurgy , *METALLURGY , *POROSITY - Abstract
This paper demonstrates that fine-grained (2–3 μm), transparent Nd:YAG can be achieved at SiO2 doping levels as low as 0.02 wt% by the sinter plus hot isostatic pressing (HIP) approach. Fine grain size is assured by sintering to 98% density, in order to limit grain growth, followed by HIP. Unlike dry-pressed samples, tape-cast samples were free of large, agglomerate-related pores after sintering, and thus high transparency (i.e., >80% transmission at 1064 nm) could be achieved by HIP at <1750°C along with lower silica levels, thereby avoiding conditions shown to cause exaggerated grain growth. Grain growth was substantially limited at lower SiO2 levels because silica is soluble in the YAG lattice up to ∼0.02–0.1 wt% at 1750°C, thus allowing sintering and grain growth to occur by solid-state diffusional processes. In contrast, liquid phase enhanced densification and grain growth occur at ∼0.08–0.14 wt% SiO2, especially at higher temperatures, because the SiO2 solubility limit is exceeded. [ABSTRACT FROM AUTHOR]
- Published
- 2009
- Full Text
- View/download PDF
17. Ceramic Composites with Multilayer Interface Coatings.
- Author
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Besmann, Theodore M., Kupp, Elizabeth R., Lara-Curzio, Edgar, More, Karren L., and Naslain, R.
- Subjects
- *
FIBER-reinforced ceramics , *SURFACE coatings - Abstract
Studies ceramic composites with multilayer interface coatings. Fabrication of silicon carbide matrix composites from ceramic-grade Nicalon or Hi-Nicalon fibers; Use of chemical vapor infiltration to produce minicomposites; Tensile testing of minicomposites; Use of forced flow thermal-gradient chemical vapor infiltration in preparing multilayer interface materials.
- Published
- 2000
- Full Text
- View/download PDF
18. ChemInform Abstract: Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics.
- Author
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Guo, Jing, Guo, Hanzheng, Baker, Amanda L., Lanagan, Michael T., Kupp, Elizabeth R., Messing, Gary L., and Randall, Clive A.
- Published
- 2016
- Full Text
- View/download PDF
19. Powder chemistry effects on the sintering of MgO‐doped specialty Al2O3.
- Author
-
Frueh, Tobias, Marker, Cassie, Kupp, Elizabeth R., Compson, Charles, Atria, Joe, Gray, Jennifer L., Liu, Zi‐Kui, and Messing, Gary L.
- Subjects
- *
POWDERS , *CHEMISTRY , *ALUMINUM oxide , *MAGNESIUM oxide , *SOIL densification - Abstract
Abstract: In this work, we investigate the effects of powder chemistry on the sintering of MgO‐doped specialty alumina. The stages at which MgO influences densification of Al2O3 were identified by comparing dilatometry measurements and the sintering kinetics of MgO‐free and MgO‐doped specialty alumina powders. MgO is observed to reduce the grain boundary thickness during densification using TEM. We show that MgO increases the solubility of SiO2 in alumina grains near the boundaries using EDS. First‐principles DFT calculations demonstrate that the co‐dissolution of MgO and SiO2 in alumina is thermodynamically favored over the dissolution of MgO or SiO2 individually in alumina. This study experimentally demonstrates for the first time that removal of SiO2 from the grain boundaries is a key process by which MgO enhances the sintering of alumina. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
- View/download PDF
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