Search

Herein, a new organic cationic matrix [N(CH3)4]3MoO3F3 suitable for Mn4+ doping was constructed. Due to the large steric hindrance of N[CH3]4+ (TMA), charge compensation defects can be effectively prevented in the heterovalent Mn4+-doping process, and a high IQE (91.05%) was obtained. Through the cation co-doping strategy, Mg2+/Zn2+/Li+ cations were introduced into the Mo6+ cationic site, which improved the crystallinity of the matrix and reduced energy losses, so as to improve luminescence intensity, QE, thermal stability, water stability and other spectral properties. Meanwhile, [N(CH3)4]2TiF6:Mn4+ phosphors with the same TMA organic cation and equivalent Mn4+ doping were synthesized for comparison, and the effects of the Mg2+ cation co-doping strategy on the spectral properties of phosphors with different matrix types (fluoride/oxyfluoride) and substitution types (equivalent/non-equivalent) were analyzed. These findings provide the basis for the preparation of new luminescent materials. Furthermore, according to the optical properties exhibited by these phosphors, they are packaged into WLED devices with excellent photoelectric properties, which are suitable for indoor lighting and display fields. [ABSTRACT FROM AUTHOR]

With the increasing intelligence of automobiles, vehicle pre-ventilation can be better controlled. In summer, cars parked in the open air are directly exposed to sunlight; thus, a high-temperature environment is formed in the occupant cabin, which seriously affects the passengers and driver's riding and driving experience. Meanwhile, lowering the temperature of the passenger compartment from a very high temperature to a comfortable temperature consumes a lot of energy. Therefore, it is increasingly important to study the pre-ventilation of the cabin in order to improve the thermal comfort of the occupant cabin and reduce energy consumption. In this paper, a new theoretical model of a cabin temperature control system is proposed. To support the theoretical model, an outdoor parking temperature rise test was carried out. Environmental parameters were obtained and used as the boundary conditions of the subsequent simulation. Based on the mechanism of the cabin temperature rise, the convective heat transfer coefficient on the body surface, the equivalent heat transfer model of the cabin, the solar radiation model and the physical properties of the air, a computational simulation of the temperature rise in the occupant cabin was carried out, and a simulation of the temperature rise in the occupant cabin exposure was studied. The simulation results were compared with the experimental findings to verify the accuracy of the simulation, which provided a reference for the design of the pre-cooling function of the occupant cabin. This study revealed that the pre-ventilation model developed reduces the vehicle cabin temperature through optimal control of air supply volumes and air supply angles. Furthermore, the developed pre-ventilation model is capable of reducing energy consumption, thereby reducing greenhouse gas emissions. [ABSTRACT FROM AUTHOR]