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Three mononuclear compounds formulated as {M[(2-1H-tetrazol-5-yl)pyridine]2(H2O)2} (M = FeII (1), CoII (2), CuII (3)) were reported and synthesized. Their space group is monoclinic, P21/c, revealed by single-crystal X-ray diffraction. Antiferromagnetic interactions exist in Compounds 1, 2 and 3, as evidenced by magnetic and low-temperature heat capacity measurements. In addition, their thermodynamic functions were determined by a relaxation calorimeter, indicating that Compound 1 exhibits a Schottky anomaly in low-temperature heat capacity. This work can provide an important fundamental basis for the research of the thermophysical properties of molecular-based magnetic materials. [ABSTRACT FROM AUTHOR]

The objective of this study was to investigate the feasibility of using modified biochars to enhance removal of ammonium from aqueous solution. The pristine, NaOH-modified, ball-milled, and NaOH-modified ball-milled biochars were prepared from wheat straw at 500 °C. The surface morphology and characteristics of biochar were obviously changed after modification. The NaOH-modification elevated the pH value and ash content of biochar, and the ball-milling treatment promoted the formation of oxygen-containing functional groups. The specific surface area of biochar (20.9 m2/g) increased to 51.4 m2/g and 145.6 m2/g after NaOH-modification and ball-milling treatment, respectively. The modified biochars showed considerable ammonium sorption capacity in a wide pH range (3–7), and the optimal pH of ammonium sorption was around 6. Both NaOH-modification and ball-milling treatment improved ammonium sorption on the biochars. Ammonium sorption of the biochars could be well fitted by the Langmuir and pseudo-second-order model, and the NaOH-modified ball-milled biochar showed the highest ammonium sorption capacity of 8.93 mg g−1. The surface complexation with oxygen-containing functional groups and cation exchange were the dominant mechanisms of ammonium sorption on the biochars. These results indicate that NaOH-modified/ball-milled biochar has a good potential to be used for the ammonium removal from polluted water. [ABSTRACT FROM AUTHOR]

Thermoelectric materials, which can directly convert thermal energy into electricity, play an important role in waste heat recovery. Sb2Si2Te6 is a promising medium-temperature thermoelectric material for power generation. However, its application is restricted by the relatively low power factor (PF) and the decompostion at high temperature. Herein, we successfully improved the power factor of Sb2Si2Te6 by doping with germanium (Ge). Benefiting from the optimized carrier concentration, the power factor of Sb2Si1−xGexTe6 remains higher than 1100 μW m−1 K−2 from 473 K to 773 K and the highest zT value reaches 1.0 at 773 K. Furthermore, the power generation performance of a single-pair thermoelectric module, consisting of Sb2Si1.94Ge0.06Te6 and Mg3.2Sb1.5Bi0.49Te0.01, is evaluated by three-dimensional numerical simulation. The simulated conversion efficiency is as high as 13% at a temperature difference of 500 K, and the power density can reach up to 3 W cm−2. Our results demonstrate that Ge doping can effectively modify the thermoelectric properties of Sb2Si2Te6 and improve its power generation performance, paving the way for realistic applications in the medium-temperature region. [ABSTRACT FROM AUTHOR]

Chelate-assisted phytoextraction is an attractive strategy to remove toxic metals from soil. However, there is lack of an effective and sustainable chelating agent. In this study, 11 kinds of fruit residue were extracted and selected to combine with N, N-bis (carboxymethyl) glutamic acid (GLDA) (0.7%) and tea saponin (4%) for the compounded activation agent (CAA), and its enhancement on Pb phytoextraction by Sedum alfredii was further evaluated by pot experiment. Among 11 fruit residue extracts, lemon residue showed the highest ability (34.7%) to extract Pb from soil. Through combining with GLDA (0.7%) and tea saponin (4%) at the optimal volume ratio of 15:2.5:2.5, the CAA removed Pb most effectively (57.1%) from soil and increased the solubility of three Pb mineral (PbS, PbCO3 and PbSO4) by 8.7–56.4 times. In pot experiment, the addition of high dosage (15 mL) CAA increased the biomass of S. alfredii by 52% and doubled the Pb accumulation. In addition, CAA-assisted phytoextraction also increased both water-soluble and acid-soluble Pb in soil, while reduced the proportion of the immobile Pb (oxidizable and residual). Generally, the compounded activation agent derived from lemon residue could be considered as-a promising enhancer for Pb phytoextraction. [ABSTRACT FROM AUTHOR]

Abscisic acid (ABA) is a key phytohormone underlying plant resistance to toxic metals. However, regulatory effects of ABA on apoplastic transport in roots and consequences for uptake of metal ions are poorly understood. Here, we demonstrate how ABA regulates development of apoplastic barriers in roots of two ecotypes of Sedum alfredii and assess effects on cadmium (Cd) uptake. Under Cd treatment, increased endogenous ABA level was detected in roots of nonhyperaccumulating ecotype (NHE) due to up‐regulated expressions of ABA biosynthesis genes (SaABA2, SaNCED), but no change was observed in hyperaccumulating ecotype (HE). Simultaneously, endodermal Casparian strips (CSs) and suberin lamellae (SL) were deposited closer to root tips of NHE compared with HE. Interestingly, the vessel‐to‐CSs overlap was identified as an ABA‐driven anatomical trait. Results of correlation analyses and exogenous applications of ABA/Abamine indicate that ABA regulates development of both types of apoplastic barriers through promoting activities of phenylalanine ammonialyase, peroxidase, and expressions of suberin‐related genes (SaCYP86A1, SaGPAT5, and SaKCS20). Using scanning ion‐selected electrode technique and PTS tracer confirmed that ABA‐promoted deposition of CSs and SL significantly reduced Cd entrance into root stele. Therefore, maintenance of low ABA levels in HE minimized deposition of apoplastic barriers and allowed maximization of Cd uptake via apoplastic pathway. Abscisic acid regulated the development of endodermal Casparian strips (CSs) and suberin lamellae (SL) in roots of S. alfredii exposed to Cd. Maintenance of low ABA levels in hyperaccumulating ecotype minimized deposition of CSs/SL and allowed maximization of Cd uptake via apoplastic pathway. [ABSTRACT FROM AUTHOR]