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While magnetic flow applications have become a topic of great interest for decades, the coupling between fluid flow and electromagnetic forces is not straightforward. Therefore, the necessity of a robust guideline to simulate these types of problems has become apparent. Moreover, the heat transfer capabilities and the interaction between electromagnetic forces such as Lorentz and Kelvin require further investigation.In this regard, two objectives are pursued to address the noted issues. First, a robust and flexible solution framework using User-Defined-Functions (UDF)s is presented so that magnetic flow applications can be investigated without software limitations such as discretization scheme, solution setup, and simultaneous use of other advanced modules. Next, the impact of electromagnetic forces on streamlines and isotherms has been studied, and the forces’ area of influence is carefully investigated.Based on the results, the introduced framework has successfully predicted consistent results for three previous studies. Next, by considering a wide range of Rayleigh (Ra), Hartmann (Ha), and Magnetic (Mn) numbers, valuable revelations regarding the force interactions, thermofluidic properties, and force area of influence were revealed. Finally, the situations in which the Kelvin and Lorentz forces are influential are identified based on dimensional analysis.

Abstract Production and utilization of grey and blue hydrogen is responsible for emission of millions of tons of carbon dioxide (CO2) across the globe. This increased emission of CO2 has severe repercussions on the planet earth and in particular on climate change. Here in, we explored advance bimetallic (BM) CuO/Ag and trimetallic (TM) CuO/Ag/NiO based nanoporous materials supported with silica nanoparticles (SiNPs) via sol–gel route. The explored nanocatalysts were characterized by Powder X-ray diffraction (P-XRD), scanning electron microscopy (SEM), transmittance electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDX), and Raman spectroscopic techniques. These advance nanocatalysts were evaluated for the green hydrogen production through electrocatalysis and photocatalysis. The catalysts exhibited an exceptional catalytic performance, the onset potential for hydrogen evolution reaction (HER) was determined to be − 0.9 V BMSiNPs-GCE and − 0.7 V (vs Ag/AgCl) for TMSiNPs-GCE, whereas η@10 for BMSiNPs-GCE and TMSiNPs-GCE is − 1.26 and − 1.00 V respectively. Significantly, the TMSiNPs composite and the BMSiNPs composite exhibited superior photochemical H2 evolution rates of 1970.72 mmol h−1 g−1 and 1513.97 mmol h−1 g−1, respectively. The TMSiNPs catalyst presents a highly promising material for HER. This study reveals a cost-effective approach to develop sustainable and resourceful electrocatalysts for HER.

Hydrogen energy has the potential to be a cost-effective and strong technology for brighter development. Hydrogen fuel production by water electrolyzers has attracted attention. 2D nanocomposites with distinctive properties have been extensively explored for various applications from hydrogen evolution reactions to improving the efficiency of water electrolyzer, which is the most eco-friendly, and high-performance for hydrogen production. Recently, typical 2D nanocomposites such as Metal-Free 2D, TMDs, Mxene, LDH, organic composites, and Heterostructure have recently been thoroughly researched for use in the HER. We discuss effective ways for increasing the HER efficiency of 2D catalysts in this paper, And the unique advantages and mechanisms for specific applications are highlighted. Several essential regulating strategies for developing 2D nanocomposite-based HER electrocatalysts are included such as interface engineering, defect engineering, heteroatom doping, strain & phase engineering, and hybridizing which improve HER kinetics, the electrical conductivity, accessibility to catalytic active sites, and reaction energy barrier can be optimized. Finally, the future prospects for 2D nanocomposites in HER are discussed, as well as a thorough overview of a variety of methodologies for designing 2D nanocomposites as HER electrocatalysts with excellent catalytic performance. We expect that this review will provide a thorough overview of 2D nanocatalysts for hydrogen production.

By taking socio-economic, terrain, and meteorological impacts into account, an eco-friendly methodology to sort the potential locations for installation of renewable energy infrastructure has been proposed, which is also able to address the most important challenge in the field, i.e., determination of the best contribution of the renewable energy sources. For this purpose, three advanced approaches, namely, remote sensing by geographic information system (GIS), optimization, and weighted decision-making are employed. Moreover, a sensitivity analysis is conducted to evaluate the influence of land prices, nominal capacity, and relative importance of technical and economic indicators in decision-making. Iran is chosen as the case study because it has significant solar and wind energy potential and also has serious energy, economic, and environmental issues. The findings indicate an optimal land price of $200 per m2, a hub nominal capacity of 50 MW, and an equal weighting of objective functions for the case study. The average energy generation, levelized cost of energy (LCOE), PV ratio, and land utilization are projected to reach 288.5 GWh.year−1, 0.3260 $.(kWh)-1, 4.15 %, and 2362334 m2, respectively when the optimal procedure is applied. The sensitivity study also shows that relative to PV, the contribution of wind turbines increases with plant size.

Abstract One of the best methods of extracting Vitamin A, as a helper of the immune body system and vision, was measured in supercritical carbon dioxide (SC-CO2); Mole fractions were gained at practical conditions in which the temperature was in the range of 303–323 K and the pressure range was 90–235 bar, respectively. Moreover, four Equation of States [Soave–Redlich–Kwong, Peng–Robinson, Stryjek–Vera and Dashtizadeh–Pazuki–Taghikhani–Ghotbi (DPTG)] were compared with the experimental data. Also, the mixing rules of Van der Waals (vdW1 and vdW2) selected to correlate the solubility data of vitamin A. The outcomes indicate that each of EOSs coupled with vdW2, as a method of estimating the physicochemical and critical properties, were correlated with the solubility data of vitamin A in SC-CO2 with more accuracy, in comparison with vdW1. Among the cubic EOSs, the DPTG model with vdW2 generated the most suitable correlation with the percentage average absolute relative deviation (Average Absolute Relative Deviation%) of 6.

A novel photocatalytic continuous system has been proposed for the treatment of tannery waste water, which has high levels of environmental pollutants. The purification process was performed by passing wastewater on a titanium dioxide (TiO2)-coated surface, which is continuously activated by irradiation of ultraviolet light. To improve the yield of the process, ferric chloride (FeCl3) was used as a coagulation agent. The organic and inorganic compounds, as well as the microorganisms in the tannery wastewater media, were degraded through a photocatalytic process. The results revealed that total dissolved solids and total suspended solids contents were significantly decreased from 8,450 and 8,990 mg·L−1 to 4,032 and 4,127 mg·L−1, respectively. Furthermore, the chemical oxygen demand content of the sample was reduced from 370 to 50 mg·L−1 after the addition of 100 mL of FeCl3 and 4 h of treatment. The same results were observed for the elimination of sulfate and chromium ions, which led to a decline in electrical conductivity. This suggests that introducing 100 mL of FeCl3 as the coagulation agent and continuous treatment with photocatalityc set-up could be considered as an effective method for the purification of tannery wastewaters. HIGHLIGHTS Continuous set-up fabricated for tannery wastewater treatment using photocatalytic reactions.; TiO2 photocatalyst activated by UV light for improvement of purification yield.; FeCl3, as coagulation agent, facilitated treatment by removing total dissolved solids.; Toxic ions and microorganisms were eliminated in this method.;

Abstract More than five decades have been invested in understanding glucose biosensors. Yet, this immensely versatile field has continued to gain attention from the scientific world to better understand and diagnose diabetes. However, such extensive work done to improve glucose sensing devices has still not yielded desirable results. Drawbacks like the necessity of the invasive finger‐pricking step and the lack of optimization of diagnostic interventions still need to be considered to improve the testing process of diabetic patients. To upgrade the glucose‐sensing devices and reduce the number of intermediary steps during glucose measurement, fourth‐generation glucose sensors (FGGS) have been introduced. These sensors, made using robust electrocatalytic copper nanostructures, improve diagnostic efficiency and cost‐effectiveness. This review aims to present the essential scientific progress in copper nanostructure‐based FGGS in the past 10 years (2010 to present). After a short introduction, we presented the working principles of these sensors. We then highlighted the importance of copper nanostructures as advanced electrode materials to develop reliable real‐time FGGS. Finally, we cover the advantages, shortcomings, and prospects for developing highly sensitive, stable, and specific FGGS.

Developing new methods and technologies for CO2 removal with a variety of applications, such as purification of synthesis gas, natural gas sweetening, and greenhouse gas sequestration are nowadays carried out in research works involving polymeric membranes. By employing suitable reactive carriers into themembrane matrix, the solubility and absorption rate of the reactive gas (i.e., CO2) are enhanced. In facilitated transport membrane, the selective transport through the membrane occurs owing to a reversible reaction between the reactive carriers and the target gas, while in contrast the solution-diffusion is the dominant mechanism for permeation of inert gases such as CH4, N2 and H2. In this work, the cross-linking of diethanolamine (DEA)-impregnated polyvinyl alcohol (PVA) by glutaraldehyde (GA) with different blend compositions (GA/PVA: 0.5, 1, 3, 5, 7 ratio%) were performed in the absence of an acid catalyst and organic solvents in order to avoid any interference in CO2 facilitation reaction with DEA. The fabricated membranes were characterized by differential scanning calorimetry, Fourier transform infrared (FTIR) and scanningelectron microscopy. Furthermore, the effects of cross-linking agent content and feed pressure on CO2/CH4 transport properties were investigated in pure gas experiments. Finally, the cross-linked membranes showed reasonable CO2/CH4 permselectivity indexes in comparison to uncross-linked membranes. The best-yield in CO2-selective membranes (DEA-PVA/GA (1 wt%)/PTFE) represented the best CO2/CH4 selectivityof 91.13 for pure gas experiments.