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Laser site-selective spectroscopy and high-resolution absorption measurements have been used to determine 51 crystal-field energy levels for one of the Ho$^{3+}$ centres in Y$_{2}$SiO$_{5}$. This centre is denoted as Site 2 and has been tentatively assigned as the seven-fold coordinated centre. High resolution absorption measurements reveal complex hyperfine patterns that obey and approximate selection rule. The application of a magnetic field along the three optical axes reveals the presence of avoided crossings below 0.5 Tesla, in both the ground and excited states.

Many powerful tests of the Standard Model of particle physics and searches for new physics with precision atomic spectroscopy are plagued by our lack of knowledge of nuclear properties. Ideally, such properties may be derived from precise measurements of the most sensitive and theoretically best-understood observables, often found in hydrogen-like systems. While these measurements are abundant for the electric properties of nuclei, they are scarce for the magnetic properties, and precise experimental results are limited to the lightest of nuclei. Here, we focus on $^9$Be which offers the unique possibility to utilize comparisons between different charge states available for high-precision spectroscopy in Penning traps to test theoretical calculations typically obscured by nuclear structure. In particular, we perform the first high-precision spectroscopy of the $1s$ hyperfine and Zeeman structure in hydrogen-like $^9$Be$^{3+}$. We determine its effective Zemach radius with an uncertainty of $500$ ppm, and its bare nuclear magnetic moment with an uncertainty of $0.6$ parts-per-billion (ppb) - uncertainties unmatched beyond hydrogen. Moreover, we compare to measurements conducted on the three-electron charge state $^9$Be$^{+}$, which, for the first time, enables testing the calculation of multi-electron diamagnetic shielding effects of the nuclear magnetic moment at the ppb level. In addition, we test quantum electrodynamics (QED) methods used for the calculation of the hyperfine splitting. Our results serve as a crucial benchmark essential for transferring high-precision results of nuclear magnetic properties across different electronic configurations.

Modern physics experiments are frequently very complex, relying on multiple simultaneous events to happen in order to obtain the desired result. The experiment control system plays a central role in orchestrating the measurement setup: However, its development is often treated as secondary with respect to the hardware, its importance becoming evident only during the operational phase. Therefore, the AEgIS (Antimatter Experiment: Gravity, Interferometry, Spectroscopy) collaboration has created a framework for easily coding control systems, specifically targeting atomic, quantum, and antimatter experiments. This framework, called Total Automation of LabVIEW Operations for Science (TALOS), unifies all the machines of the experiment in a single entity, thus enabling complex high-level decisions to be taken, and it is constituted by separate modules, called MicroServices, that run concurrently and asynchronously. This enhances the stability and reproducibility of the system while allowing for continuous integration and testing while the control system is running. The system demonstrated high stability and reproducibility, running completely unsupervised during the night and weekends of the data-taking campaigns. The results demonstrate the suitability of TALOS to manage an entire physics experiment in full autonomy: being open-source, experiments other than the AEgIS experiment can benefit from it.

This paper advocates for an innovative approach designed for estimating optoelectronic properties of quantum structures utilizing Tight-Binding (TB) theory. Predicated on the comparative analysis between estimated and actual properties, the study strives to validate the efficacy of this proposed technique; focusing notably on the computation of bandgap energy. It is observed that preceding methodologies offered a restricted accuracy when predicting complex structures like super-lattices and quantum wells. To address this gap, we propose a methodology involving three distinct phases using orbital interaction parameters (OIPs) and the TB theory. The research employed Aluminium Arsenide (AlAs) and Gallium Arsenide (GaAs) as the primary bulk materials. Our novel approach introduces a computation framework that first focuses on bulk computation, subsequently expanding to super-lattice structures. The findings of this research demonstrate promising results regarding the accuracy of predicated optoelectronic properties, particularly the cut-off wavelength. This study paves the way for future research, potentially enhancing the precision of the proposed methodology and its application scope within the field of quantum optoelectronics., Comment: This paper is published in the journal of Micro and Nanostructures

The Aharonov-Bohm effect is a quantum mechanical phenomenon that demonstrates how potentials can have observable effects even when the classical fields associated with those potentials are absent. Initially proposed for electromagnetic interactions, this effect has been experimentally confirmed and extensively studied over the years. More recently, the effect has been observed in the context of gravitational interactions using atom interferometry. Additionally, recent predictions suggest that temporal variations in the phase of an electron wave function will induce modulation sidebands in the energy levels of an atomic clock, solely driven by a time-varying scalar gravitational potential [1]. In this study, we consider the atomic clock as a two-level system undergoing continuous Rabi oscillations between the electron's ground and excited state. We assume the photons driving the transition are precisely frequency-stabilized to match the transition, enabling accurate clock comparisons. Our analysis takes into account, that when an atom transitions from its ground state to an excited state, it absorbs energy, increasing its mass according to the mass-energy equivalence principle. Due to the mass difference between the two energy levels, we predict that an atomic clock in an eccentric orbit will exhibit a constant frequency shift relative to a ground clock corresponding to the orbit's average gravitational redshift, with additional modulation sidebands due to the time-varying gravitational potential.

We present results from a pilot study, using a laser-produced plasma, to identify new lines in the 350 to 1000 nm spectral region for the r-process element gold (Au), of relevance to studies of neutron star mergers. This was achieved via optical-IR spectroscopy of a laser-produced Au plasma, with an Au target of high purity (99.95 %) and a low vacuum pressure to remove any air contamination from the experimental spectra. Our data were recorded with a spectrometer of 750 mm focal length and 1200 lines mm-1 grating, yielding a resolution of 0.04 nm. We find 54 lines not previously identified and which are not due to the impurities (principally copper (Cu) and silver (Ag)) in our Au sample. Of these 54 lines, we provisionally match 21 strong transitions to theoretical results from collisional-radiative models that include energy levels derived from atomic structure calculations up to the 6s level. Some of the remaining 33 unidentified lines in our spectra are also strong and may be due to transitions involving energy levels which are higher-lying than those in our plasma models. Nevertheless, our experiments demonstrate that laser-produced plasmas are well suited to the identification of transitions in r-process elements, with the method applicable to spectra ranging from UV to IR wavelengths.

The experimental comparison of two thulium optical lattice clocks in a time interval of up to one hour has been carried out. The synchronous comparison of a clock transition in two independent atomic ensembles using a single ultrastable laser has allowed us to eliminate fluctuations of the laser frequency from the measured frequency difference and to reach a relative measurement error of $10^{-16}$ after 500-s averaging, which corresponds to a relative instability of $2\times10^{-15}/\sqrt{\tau}$. The successful demonstration of the long-term operation of two systems using the synchronous comparison of clock transitions opens the possibility of studying systematic shifts in thulium optical clocks with an uncertainty of $10^{-17}$., Comment: 6 pages, 3 figures

Strongly interacting systems appear in several areas of physics and are characterized by attractive interactions that can almost, or just barely, loosely bind two particles. Although this definition is made at the two-body level, this gives rise to fascinating effects in larger systems, including the so-called Efimov physics. In this context, the zero-range theory aims to describe low-energy properties based only on the scattering length. However, for a broad range of physical applications, the finite range of the interactions plays an important role. In this work, I discuss some aspects of finite-range effects in strongly interacting systems. I present the zero-range and shapeless universalities in two-body systems with applications in atomic and nuclear physics. I derived an analytical expression for the $s$-wave bound-state spectrum of the modified P\"oschl-Teller potential for two particles in three dimensions, which is compared with the approximations to illustrate their usefulness. Concerning three identical bosons, I presented a trimer energy scaling function that explicitly includes the effective range. The implications for larger systems are briefly discussed., Comment: 22 pages, 5 figures

The spectra of singly ionised Strontium and Yttrium (Sr {\sc ii} and Y {\sc ii}) have been proposed as identifications of certain spectral features in the AT2017gfo spectrum. With the growing demand for NLTE simulations of Kilonovae, there is a increasing need for atomic data for these and other $r$-process elements. Our goal is to expand upon the current set of atomic data for $r$-process elements, by presenting transition probabilities and Maxwellian-averaged effective collision strengths for Sr {\sc ii} and Y {\sc ii}. The Breit-Pauli and DARC $R$-matrix codes are employed to calculate the appropriate collision strengths, which are thermally averaged according to a Maxwellian distribution to calculate excitation and de-excitation rates. The {\sc tardis} and {\sc ColRadPy} packages are subsequently used to perform LTE and NLTE modelling respectively. A complete set of transition probabilities and effective collision strengths involving levels for Sr {\sc ii} and Y {\sc ii} have been calculated for temperature ranges compatible with kilonova plasma conditions. Forbidden transitions were found to disagree heavily with the Axelrod approximation, an approximation which is currently employed by other models within the literature. Theoretically important spectral lines are identified with both LTE and NLTE modelling codes. LTE simulations in {\sc tardis} reveal no new significant changes to the full synthetic spectra. NLTE simulations in {\sc ColRadPy} provide indications of which features are expected to be strong for a range of regimes, and we include luminosity estimates. Synthetic emission spectra over KNe densities and temperatures reveal potentially interesting spectral lines in the NIR.

Sensing based on Nitrogen-Vacancy (NV) centers in nanodiamonds (NDs) offers significant potential across various applications. However, optimizing their quantum-optical properties remains challenging. This study focuses on enhancing and controlling the optical properties of NV centers in NDs through surface chemistry tuning and proton beam irradiation. Systematic thermal oxidations were performed to investigate the evolution of surface chemical groups using IR spectroscopy and their influence on optical properties using photoluminescence spectroscopy and PL decay measurements. Proton irradiation was explored over a wide range of fluences (10^14 to 10^17 cm^-2) to precisely control the NV center concentration, identifying conditions that maximize creation and emission intensity. Furthermore, NV center charge state control was achieved by analyzing the NV-/NV0 ratio with varying surface terminations and NV center concentrations. A novel predictive mathematical model was developed to evaluate the efficiencies of forming NV- and NV0. Although tested specifically with proton-irradiated NDs, this model has broad applicability, representing a significant advancement in predicting the outcomes of ion-beam-based color center generation in diamond.

The design of single chip current source based on a common power operational amplifier is presented and demonstrated for the purpose of controlling applied magnetic fields using bias/shim electromagnets in cold atom experiments. The efficacy of the design is realized via application to red-detuned polarization-gradient cooling of $^{87}$Rb down to 3 $\mu$K. Further, we demonstrate Raman spectroscopy using these devices to apply current and so generate a precise, accurate, and reproducible magnetic field. This work is intended as a short tutorial for new graduate students and postdocs of laser cooling and trapping., Comment: 7 pages, 3 figures, tutorial for newcomers

Optical atomic clocks$^{1,2}$ use electronic energy levels to precisely keep track of time. A clock based on nuclear energy levels promises a next-generation platform for precision metrology and fundamental physics studies. Thorium-229 nuclei exhibit a uniquely low energy nuclear transition within reach of state-of-the-art vacuum ultraviolet (VUV) laser light sources and have therefore been proposed for construction of the first nuclear clock$^{3,4}$. However, quantum state-resolved spectroscopy of the $^{229m}$Th isomer to determine the underlying nuclear structure and establish a direct frequency connection with existing atomic clocks has yet to be performed. Here, we use a VUV frequency comb to directly excite the narrow $^{229}$Th nuclear clock transition in a solid-state CaF$_2$ host material and determine the absolute transition frequency. We stabilize the fundamental frequency comb to the JILA $^{87}$Sr clock$^2$ and coherently upconvert the fundamental to its 7th harmonic in the VUV range using a femtosecond enhancement cavity. This VUV comb establishes a frequency link between nuclear and electronic energy levels and allows us to directly measure the frequency ratio of the $^{229}$Th nuclear clock transition and the $^{87}$Sr atomic clock. We also precisely measure the nuclear quadrupole splittings and extract intrinsic properties of the isomer. These results mark the start of nuclear-based solid-state optical clock and demonstrate the first comparison of nuclear and atomic clocks for fundamental physics studies. This work represents a confluence of precision metrology, ultrafast strong field physics, nuclear physics, and fundamental physics., Comment: 22 pages, 5 figures, 1 extended data figure

Performance of nano- and micro-scale heat engines can be improved with a help from quantum mechanical phenomena. Recently, heat reservoirs with quantum coherence have been proposed to enhance engine performance beyond the Carnot limit even with a single reservoir. However, no physical realizations have been achieved so far. Here, we report the first proof-of-principle experimental demonstration of a photonic quantum engine driven by superradiance employing a single heat reservoir composed of atoms and photonic vacuum. Reservoir atoms prepared in a quantum coherent superposition state underwent superradiance while traversing the cavity. This led to about 40-fold increase of the effective engine temperature, resulting in a near-unity engine efficiency. Moreover, the observed engine output power grew quadratically with respect to the atomic injection rate. Our work can be utilized in quantum mechanical heat transfer as well as in boosting engine powers, opening a pathway to development of photomechanical devices that run on quantum coherence embedded in heat baths., Comment: 8 pages, 3 figures, 1 extended data figure

We demonstrate chip-scale sub-Doppler spectroscopy in an integrated and fiber-coupled photonic-metasurface device. The device is a stack of three planar components: a photonic mode expanding grating emitter circuit with a monolithically integrated tilt compensating dielectric metasurface, a microfabricated atomic vapor cell and a mirror. The metasurface photonic circuit efficiently emits a 130 micrometer-wide $1/e^2$ diameter) collimated surface-normal beam with only -6.3 dB loss and couples the reflected beam back into the connecting fiber, requiring no alignment between the stacked components. We develop a simple model based on light propagation through the photonic device to interpret the atomic spectroscopy signals and explain spectral features covering the full Rb hyperfine state manifold.

Multiple-RF (MRF) dressing allows trapping of ultracold atoms in novel spatial geometries, such as highly controllable bilayer structures for 2D ultracold gases, providing unique opportunities for the investigation of 2D quantum systems both in and out of equilibrium. Here, we give an overview of the recent developments of MRF-dressed atom experiments, illustrated by the detailed studies of universal relaxation dynamics across the Berezinskii-Kosterlitz-Thouless critical point enabled by coherent splitting quench protocols and detection of correlations via spatially selective matter-wave interferometry.

Multichannel quantum defect theory is applied in the treatment of the dissociative recombination and vibrational excitation processes for the BeD$^+$ ion in the twenty four vibrational levels of its ground electronic state ($\textrm{X}\,{^{1}\Sigma^{+}},v_{i}^{+}=0\ldots 23$). Three electronic symmetries of BeD$^{**}$ states (\ensuremath{^{2}\Pi}, \ensuremath{^{2}\Sigma^{+}}, and \ensuremath{^{2}\Delta}), are considered in the calculation of cross sections and the corresponding rate coefficients. The incident electron energy range is $10^{-5}$--2.7 eV and the electron temperature range is 100--5000~K. The vibrational dependence of these collisional processes is highlighted. The resulting data are useful in magnetic confinement fusion edge plasma modelling and spectroscopy, in devices with beryllium based main chamber materials, such as ITER and JET, and operating with the deuterium-tritium fuel mix. An extensive rate coefficients database is presented in graphical form and also by analytic fit functions whose parameters are tabulated in the supplementary material., Comment: 7 pages, 5 figures, 3 tables

The intriguing law of anomalous numbers, also named Benford's law, states that the significant digits of data follow a logarithmic distribution favoring the smallest values. In this work, we test the compliance with this law of the atomic databases developed at the National Institute of Standards and Technology (NIST) focusing on line energies, oscillator strengths, Einstein coefficients and radiative opacities. The considered databases are the Atomic Spectra Database (ASD) and the NIST-LANL (Los Alamos National Laboratory) Lanthanide/Actinide Opacity Database. The present study is not limited to the first digit and the case of multipole lines is also considered. The fact that the law is verified with a high accuracy means that the occurrence of digits reflects the constraints induced, in a given angular-momentum coupling, by the selection rules for atomic processes. As a consequence, Benford's law may be of great interest to detect inconsistencies in atomic databases., Comment: submitted to "Journal of Quantitative Spectroscopy and Radiative Transfer"

We present Einstein coefficient spectra and a detailed-balance derivation of generalized Einstein relations between them that is based on the connection between spontaneous and stimulated emission. If two broadened levels or bands overlap in energy, transitions between them need not be purely absorptive or emissive. Consequently, spontaneous emission can occur in both transition directions, and four Einstein coefficient spectra replace the three Einstein coefficients for a line. At equilibrium, the four different spectra obey five pairwise relationships and one lineshape generates all four. These relationships are independent of molecular quantum statistics and predict the Stokes' shift between forward and reverse transitions required by equilibrium with blackbody radiation. For Boltzmann statistics, the relative strengths of forward and reverse transitions depend on the formal chemical potential difference between the initial and final bands, which becomes the standard chemical potential difference for ideal solutes. The formal chemical potential of a band replaces both the energy and degeneracy of a quantum level. Like the energies of quantum levels, the formal chemical potentials of bands obey the Rydberg-Ritz combination principle. Each stimulated Einstein coefficient spectrum gives a frequency-dependent transition cross section. Transition cross sections obey causality and a detailed-balance condition with spontaneous emission, but do not directly obey generalized Einstein relations. Even with an energetic width much less than the photon energy, an absorptive forward transition with an energetic width much greater than the thermal energy can have such an extreme Stokes' shift that its reverse transition cross section becomes predominantly absorptive rather than emissive., Comment: 15 pages, 4 figures; changed "Bose statistics" to "Bose photon number distribution" and corrected equation in note 38; corrected derivatives to partial derivatives in group velocity and added missing acknowledgment section

Calculations are performed for electron collision with the methylene molecular ion CH$_2^+$ in its bent equilibrium geometry, with the goal to obtain cross sections for electron impact excitation and dissociation. The polyatomic version of the UK molecular R-matrix codes was used to perform an initial configuration-interaction calculation on the doublet and quartet states of the CH$_2^+$ ion. Subsequently, scattering calculations are performed to obtain electron impact electronic excitation and dissociation cross sections and, additionally, the bound states of the CH$_2$ molecule and Feshbach resonances in the $e$-CH$_2^+$ system., Comment: 6 pages, 6 figures and 3 tables

Absolute measurements were conducted to study the bremsstrahlung emission from ~5-25 keV electrons incident on three thick solid conductive compounds of MoSi$_2$, TiB$_2$ and ZrB$_2$. The additivity approximation was applied in the Monte Carlo PENELOPE simulations for compounds and mixtures. The results showed that in general the experimental bremsstrahlung spectra were in good agreement with the Monte Carlo simulation results, suggesting the feasibility of the additivity approximation in Monte Carlo simulations for the studied cases even in the absolute measurements and that the significant differences between experiments and Monte Carlo simulations near the Duane-Hunt limit for insulating targets in previous studies do not appear in the present studies.

The latest molecular data - potential energy curves and Rydberg$/$valence interactions - characterizing the super-excited electronic states of CO are reviewed, in order to provide inputs for the study of their fragmentation dynamics. Starting from this input, the main paths and mechanisms for CO$^+$ dissociative recombination are analyzed; its cross sections are computed using a method based on Multichannel Quantum Defect Theory. Convoluted cross sections, giving both isotropic and anisotropic Maxwellian rate-coefficients, are compared with merged-beam and storage-ring experimental results. The calculated cross sections underestimate the measured ones by a factor of $2$, but display a very similar resonant shape. These facts confirm the quality of our approach for the dynamics, and call for more accurate and more extensive molecular structure calculations., Comment: 12 pages, 8 figures 5 tables

The latest molecular data - potential energy curves and Rydberg-valence interactions - characterising the super-excited electronic states of BF are reviewed in order to provide the input for the study of their fragmentation dynamics. Starting from this input, the main paths and mechanisms of BF$^+$ dissociative recombination and vibrational excitation are analysed. Their cross sections are computed for the first time using a method based on the multichannel quantum defect theory (MQDT), and Maxwellian rate-coefficients are calculated and displayed in ready-to-be-used format for low temperature plasma kinetics simulations., Comment: 8 pages, 4 figures, 4 tables

Cross-sections for dissociative recombination and electron-impact vibrational excitation of the BF$^+_2$ molecular ion are computed using a theoretical approach that combines the normal modes approximation for the vibrational states of the target ion and use of the UK R-matrix code to evaluate electron-ion scattering matrices for fixed geometries of the ion. Thermally-averaged rate coefficients are obtained from the cross-sections for temperatures in the 10-3000 K range., Comment: 6 pages, 5 figures, 2 tables

The reactive collisions of the CH$^+$ molecular ion with electrons is studied in the framework of the multichannel quantum defect theory, taking into account the contribution of the core-excited Rydberg states. In addition to the $X^1\Sigma^+$ ground state of the ion, we also consider the contribution to the dynamics of the $a^3\Pi$ and $A^1\Pi$ excited states of CH$^+$. Our results - in the case of the dissociative recombination in good agreement with the storage ring measurements - rely on decisive improvements - complete account of the ionisation channels and accurate evaluation of the reaction matrix - of a previously used model., Comment: 8 pages, 8 figures

Polar molecules confined in an optical lattice are a versatile platform to explore spin-motion dynamics based on strong, long-range dipolar interactions. The precise tunability of Ising and spin-exchange interactions with both microwave and dc electric fields makes the molecular system particularly suitable for engineering complex many-body dynamics. Here, we used Floquet engineering to realize interesting quantum many-body systems of polar molecules. Using a spin encoded in the two lowest rotational states of ultracold KRb molecules, we mutually validated XXZ spin models tuned by a Floquet microwave pulse sequence against those tuned by a dc electric field through observations of Ramsey contrast dynamics, setting the stage for the realization of Hamiltonians inaccessible with static fields. In particular, we observed two-axis twisting mean-field dynamics, generated by a Floquet-engineered XYZ model using itinerant molecules in 2D layers. In the future, Floquet-engineered Hamiltonians could generate entangled states for molecule-based precision measurement or could take advantage of the rich molecular structure for quantum simulation of multi-level systems., Comment: 20 pages, 4 figures + 4 extended data figures

What time does a clock tell after quantum tunneling? Predictions and indirect measurements range from superluminal or instantaneous tunneling to finite durations, depending on the specific experiment and the precise definition of the elapsed time. Proposals and implementations utilize the atomic motion to define this delay, even though the inherent quantum nature of atoms implies a delocalization and is in sharp contrast to classical trajectories. Here, we rely on an operational approach: we prepare atoms in a coherent superposition of internal states and study the time read off via a Ramsey sequence after the tunneling process without the notion of classical trajectories or velocities. Our operational framework (a) unifies definitions of tunneling delay within one approach; (b) connects the time to a frequency standard given by a conventional atomic clock which can be boosted by differential light shifts; and (c) highlights that there exists no superluminal or instantaneous tunneling., Comment: 9 pages, 5 figures

Predicting the charged particle transport properties of warm dense matter / hot dense plasma mixtures is a challenge for analytical models. High accuracy ab initio methods are more computationally expensive, but can provide critical insight by explicitly simulating mixtures. In this work, we investigate the transport properties and optical response of warm dense carbon-hydrogen mixtures at varying concentrations under either conserved electronic pressure or mass density at a constant temperature. We compare options for mixing the calculated pure species properties to estimate the results of the mixtures. We find that a combination of the Drude model with the Matthiessen's rule works well for DC electron transport and low frequency optical response. This breaks down at higher frequencies, where a volumetric mix of pure-species AC conductivities works better., Comment: Special Collection: Charged-Particle Transport in High Energy Density Plasmas

Recent advances in attosecond science have made it increasingly important to develop stable, reliable and accurate algorithms and methods to model the time evolution of atoms and molecules in intense laser fields. A key process in attosecond science is high-harmonic generation, which is challenging to model with fixed Gaussian basis sets, as it produces high-energy electrons, with a resulting rapidly varying and highly oscillatory wave function that extends over dozens of {\aa}ngstr\"om. Recently, Rothe's method, where time evolution is rephrased as an optimization problem, has been applied to the one-dimensional Schr\"odinger equation. Here, we apply Rothe's method to the hydrogen wave function and demonstrate that complex-valued Gaussian wave packets with time-dependent width, center, and momentum parameters are able to reproduce spectra obtained from essentially exact grid calculations for high-harmonic generation with only 50-181 Gaussians for field strengths up to $5\times 10^{14}$W/cm$^2$. This paves the way for the inclusion of continuum contributions into real-time, time-dependent electronic-structure theory with Gaussian basis sets for strong fields, and eventually accurate simulations of the time evolution of molecules without the Born-Oppenheimer approximation., Comment: 20 pages, 10 figures

Similar to the optical diffraction of light passing through a material grating, the Kapitza-Dirac effect occurs when an electron is diffracted by a standing light wave. In its original description the effect is time-independent. In the present work, we extend the Kapitza-Dirac concept to the time domain. By tracking the spatiotemporal evolution of a pulsed electron wave packet diffracted by a femtosecond (10 15 second) standing wave pulse in a pump-probe scheme, we observe so far unseen time-dependent diffraction patterns. The fringe spacing in the observed pattern differs from that generated by the conventional Kapitza-Dirac effect, moreover it decreases as the pump-probe delay time increases. By exploiting this time-resolved diffraction scheme, we gather access to the time evolution of the previously inaccessible phase properties of a free electron.

We demonstrate that phase-matched frequency upconversion of ultrafast laser light can be extended to shorter wavelengths by using longer driving laser wavelengths. Experimentally, we show that the phase-matching cutoff for harmonic generation in argon increases from 45 to 100 eV when the driving laser wavelength is increased from 0.8 to 1.3 micrometers. Phase matching is also obtained at higher pressures using a longer-wavelength driving laser, mitigating the unfavorable scaling of the single-atom response. Theoretical calculations suggest that phase-matched high harmonic frequency upconversion driven by mid-infrared pulses could be extended to extremely high photon energies., Comment: 10 pages, 3 figures

High-harmonic generation is one of the most extreme nonlinear-optical processes observed to date. By focusing an intense laser pulse into a gas, the light-atom interaction that occurs during the process of ionising the atoms results in the generation of harmonics of the driving laser frequency, that extend up to order ~300 (corresponding to photon energies from 4 to >500eV). Because this technique is simple to implement and generates coherent, laser-like, soft-x-ray beams, it is currently being developed for applications in science and technology including probing of dynamics in chemical and materials systems and for imaging. In this work we demonstrate that by carefully controlling the shape of intense light pulses of 6-8 optical cycles, we can control the interaction of light with an atom as it is being ionised, in a way that improves the efficiency of x-ray generation by an order of magnitude. Furthermore, we demonstrate that it is possible to control the spectral characteristics of the emitted radiation and to channel the interaction between different-order nonlinear processes. The result is an increased utility of harmonic generation as a light source, as well as the first demonstration of optical pulse-shaping techniques to control high-order nonlinear processes., Comment: 16 pages, 3 figures

We present spatial coherence measurements of extreme-ultraviolet light generated using the process of high-harmonic upconversion of a femtosecond laser. Using a phase-matched hollow-fiber geometry, the generated beam is found to exhibit essentially full spatial coherence. The coherence of this laser-like EUV source is demonstrated by recording Gabor holograms of small objects. This work demonstrates the capability to do EUV holography using a tabletop experimental setup. Such an EUV source, with low divergence and high spatial coherence, can be used for experiments such as high-precision metrology, inspection of optical components for EUV lithography (1), and for microscopy and holography (2) with nanometer resolution. Furthermore, the short time duration of the EUV radiation (a few femtoseconds) will enable EUV microscopy and holography to be performed with ultrahigh time resolution., Comment: 16 pages, 4 figures

Phase-matched harmonic conversion of visible laser light into soft x-rays was demonstrated. The recently developed technique of guided-wave frequency conversion was used to upshift light from 800 nanometers to the range from 17 to 32 nanometers. This process increased the coherent x-ray output by factors of 10^2 to 10^3 compared to the non-phase-matched case. This source uses a small-scale (sub-millijoule) high repetition-rate laser and will enable a wide variety of new experimental investigations in linear and nonlinear x-ray science., Comment: 9 pages, 4 figures

High harmonic generation traditionally combines ~100 near-infrared laser photons, to generate bright, phase matched, extreme ultraviolet beams when the emission from many atoms adds constructively. Here we show that by guiding a mid-infrared femtosecond laser in a high pressure gas, ultrahigh harmonics can be generated up to orders > 5000, that emerge as a bright supercontinuum that spans the entire electromagnetic spectrum from the ultraviolet to > 1.6 keV, allowing in-principle the generation of pulses as short as 2.5 attoseconds. The multi-atmosphere gas pressures required for bright, phase matched emission also supports laser beam self-confinement, further enhancing the x-ray yield. Finally, the x-ray beam exhibits high spatial coherence, even though at high gas density, the recolliding electrons responsible for high harmonic generation encounter other atoms during the emission process., Comment: 32 pages, 9 figures (4 in main text, 5 in supplemental materials)

Iron-based molybdenum disulfide (Fe-MoS$_2$) has emerged as a Fenton-like catalyst for the highly efficient degradation of antibiotics, but the structure-activity relationship remains elusive. Herein, garland-like MIL-101(Fe)/MoS$_2$ nanosheets (MMS) with dual metal active sites (Fe and Mo) and rich sulfur vacancies were fabricated to directly activate peroxymonosulfate (PMS) for fast degradation of different organic pollutants (phenols, dyes and drugs), even in real water bodies. The MMS exhibited extremely fast catalytic rate constant of 0.289 min$^{-1}$ in the degradation of sulfamethoxazole (SMX), which was about 36 and 29 times that of single MoS$_2$ (0.008 min$^{-1}$) and MIL-101(Fe) (0.01 min$^{-1}$). Moreover, MMS with good stability and reusability could reach 92% degradation of SMX after 5 cycles. Quenching experiments and electron spin resonance (ESR) tests revealed that hydroxyl radicals (.OH) and singlet oxygen ($^1$O$_2$) were the dominant reactive oxygen species (ROS) for SMX degradation. The integration of experimental works, characterization techniques and density functional theory (DFT) calculations unraveled that the formation of sulfur vacancies in MMS catalyst could expose more Mo sites, improve the charge density and boost the electron transfer, which was conducive to accelerating the Fe$^{3+}$/Fe$^{2+}$ cycle for enhancing the activation of PMS. Finally, the C-N, N-O, S-N, C-O and C-S bonds of SMX were easily attacked by ROS to generate the nontoxic intermediates in the MMS/PMS/SMX system. This study offers a new approach to designing high-performance Fe-MoS$_2$ catalysts for the removal of organic pollutants.

The investigation of the fluctuations in interacting quantum systems at finite temperatures showcases the ongoing challenges in understanding complex quantum systems. Recently, atom number fluctuations in weakly interacting Bose-Einstein condensates were observed, motivating an investigation of the thermal component of partially condensed Bose gases. Here, we present a combined analysis of both components, revealing the presence of fluctuations in the thermal component. This analysis includes a comprehensive statistical evaluation of uncertainties in the preparation and parameter estimation of partially condensed Bose gases. Using Monte Carlo simulations of optical density profiles, we estimate the noise contributions to the atom number and temperature estimation of the condensed and thermal cloud, which is generally applicable in the field of ultracold atoms. Furthermore, we investigate the specific noise contributions in the analysis of atom number fluctuations and show that preparation noise in the total atom number leads to an important technical noise contribution. Subtracting all known noise contributions from the variance of the atom number in the BEC and thermal component allows us to improve the estimate of the fundamental peak fluctuations.

The article gives the motivations for the measurement of the hyperfine splitting (hfs) in the ground state of muonic hydrogen to explore the properties of the proton at low momentum transfer. It summarizes these proposed measurement methods and finally describes the FAMU experiment in more detail.

The hydrogen deuteride (HD) molecule is an important deuterium tracer in astrophysical studies. The atmospheres of gas giants are dominated by molecular hydrogen, and simultaneous observation of H$_2$ and HD lines provides reliable information on the D/H ratios on these planets. The reference spectroscopic parameters play a crucial role in such studies. Under thermodynamic conditions encountered in these atmospheres, the spectroscopic studies of HD require not only the knowledge of line intensities and positions but also accurate reference data on pressure-induced line shapes and shifts. Our aim is to provide accurate collision-induced line-shape parameters for HD lines that cover any thermodynamic conditions relevant to the atmospheres of giant planets, i.e., any relevant temperature, pressure, and perturbing gas (the H$_2$/He mixture) composition. We perform quantum-scattering calculations on a new highly accurate ab initio potential energy surface, and we use scattering S-matrices obtained this way to determine the collision-induced line-shape parameters. We use the cavity ring-down spectroscopy for validation of our theoretical methodology. We report accurate collision-induced line-shape parameters for the pure rotational R(0), R(1), and R(2) lines, the most relevant HD lines for the investigations of atmospheres of the giant planets. Besides the basic Voigt-profile collisional parameters (i.e. the broadening and shift parameters), we also report their speed dependences and the complex Dicke parameter, which can influence the effective width and height of the HD lines up to almost a factor of 2 for giant planet conditions. The sub-percent-level accuracy, reached in this work, considerably improves the previously available data. All the reported parameters are consistent with the HITRAN database format, hence allowing for the use of HAPI for generating the beyond-Voigt spectra of HD.

Miniaturizing and integrating atomic vapor cells is widely investigated for the purposes of fundamental measurements and technological applications such as quantum sensing. Extending such platforms to the realm of molecular physics is a fascinating prospect that paves the way for compact frequency metrology as well as for exploring light-matter interactions with complex quantum objects. Here, we perform molecular rovibrational spectroscopy in a thin-cell of micrometric thickness, comparable to excitation wavelengths. We operate the cell in two distinct regions of the electromagnetic spectrum, probing $\nu_1$+$\nu_3$ resonances of acetylene at 1.530$\mu$m, within the telecommunications wavelength range, as well as the $\nu_3$ and $\nu_2$ resonances of $SF_6$ and $NH_3$ respectively, in the mid-infrared fingerprint region around 10.55$\mu$m. Thin-cell confinement allows linear sub-Doppler transmission spectroscopy due to the coherent Dicke narrowing effect, here demonstrated for molecular rovibrations. Our experiment can find applications extending to the fields of compact molecular frequency references, atmospheric physics or fundamental precision measurements., Comment: published in Nature Communications

We present new experimental and theoretical cross sections for electron-impact single ionization of Xe$^{12+}$ and Xe$^{13+}$ ions, and double ionization of Xe$^{12+}$, Xe$^{13+}$ and Xe$^{14+}$ ions for collision energies from the respective ionization thresholds up to 3500 eV. The calculations use the fully relativistic subconfiguration-averaged distorted-wave (SCADW) approach and, partly, the more detailed level-to-level distorted wave (LLDW) method. We find that, unlike in previous work, our theoretical cross sections agree with our experimental ones within the experimental uncertainties, except for the near-threshold double-ionization cross sections. We attribute this remaining discrepancy to the neglect of direct-double ionization in the present theoretical treatment., Comment: 12 pages, 9 figures, 1 table

Continuously and widely tunable lasers actively stabilized on a frequency reference are broadly employed in atomic, molecular and optical (AMO) physics. The frequency-stabilized optical frequency comb (OFC) provides a novel optical frequency reference with a broadband spectrum that meets the requirement of laser frequency stabilization. Therefore, we demonstrate a frequency-stabilized and precisely tunable laser system based on it. In this scheme, the laser frequency locked to the OFC is driven to jump over the ambiguity zones, which blocks the wide tuning of the locked laser, and tuned until the mode hopping happens with the always-activated feedback loop. Meanwhile, we compensate the gap of the frequency jump with a synchronized acoustic optical modulator to ensure the continuity. This scheme is applied to an external cavity diode laser (ECDL) and we achieve tuning at a rate of about 7 GHz/s with some readily available commercial electronics. Furthermore, we tune the frequency-stabilized laser only with the feedback of diode current and its average tuning speed can exceed 100 GHz/s. Due to the resource-efficient configuration and the simplicity of completion, this scheme can be referenced and find wide applications in AMO experiments.

This manuscript explores how a seemingly straightforward inquiry, emerging from the widely accepted semiclassical description of laser-matter interaction, concretely from a well-known adiabatic technique as Coherent Population Return (CPR), can pose a challenge to our comprehension of a fundamental principle in Physics like energy conservation. Throughout our investigation to resolve this apparent paradox, we have delved into fundamental concepts, thereby deepening our understanding of the aspects inherent to the formalism of Quantum Mechanics. We emphasize that the significance of attaining a conclusive answer extends beyond the answer itself, encompassing the illuminating journey undertaken to reach it. Consequently, our work holds educational value as it aims to foster a deeper understanding of the phenomenon by elucidating the process employed. This approach not only aids students in grasping the subject matter but also enhances our own understanding of laser-matter interaction and the counterintuitive phenomena that continuously defied our understanding of Quantum Mechanics.

We present the design and characterization of individual addressing optics based on a multi-channel acousto-optic modulator (AOM) for trapped ytterbium-171 ions. The design parameters of the individual addressing system were determined based on the tradeoff between the expected crosstalk and the required numerical aperture of the projection objective lens. The target beam diameter and separation were 1.90 $\mu$m and 4.28 $\mu$m, respectively. The individual beams shaped by the projection optics were characterized by an imaging sensor and a field probe ion. The resulting effective beam diameters and separations were approximately 2.34--2.36 $\mu$m and 4.31 $\mu$m, respectively, owing to residual aberration., Comment: 14 pages, 5 figures

Quantum technologies are advancing from fundamental research in specialized laboratories to practical applications in the field, driving the demand for robust, scalable, and reproducible system integration techniques. Ceramic components can be pivotal thanks to high stiffness, low thermal expansion, and excellent dimensional stability under thermal stress. We explore lithography-based additive manufacturing of technical ceramics especially for miniaturized physics packages and electro-optical systems. This approach enables functional systems with precisely manufactured, intricate structures and high mechanical stability while minimizing size and weight. It facilitates rapid prototyping, simplifies fabrication and leads to highly integrated, reliable devices. As an electrical insulator with low outgassing and high temperature stability, printed technical ceramics such as Al2O3 and AlN bridge a technology gap in quantum technology and offer advantages over other printable materials. We demonstrate this potential with CerAMRef, a micro-integrated rubidium D2 line optical frequency reference on a printed Al2O3 micro-optical bench and housing. The frequency instability of the reference is comparable to laboratory setups while the volume of the integrated spectroscopy setup is only 6 ml. We identify potential for future applications in compact atomic magnetometers, miniaturized optical atom traps, and vacuum system integration.

The accurate determination of atom numbers is an ubiquitous problem in the field of ultracold atoms. For modest atom numbers, absolute calibration techniques are available, however, for large numbers and high densities, the available techniques neglect many-body scattering processes. Here, a spatial calibration technique for time-of-flight absorption images of ultracold atomic clouds is presented. The calibration is obtained from radially averaged absorption images and we provide a practical guide to the calibration process. It is shown that the calibration coefficient scales linearly with optical density and depends on the absorbed photon number for the experimental conditions explored here. This allows for the direct inclusion of a spatially dependent calibration in the image analysis. For typical ultracold atom clouds the spatial calibration technique leads to corrections in the detected atom number up to $\approx\! 12\,\%$ and temperature up to $\approx \!14\,\%$ in comparison to previous calibration techniques. The technique presented here addresses a major difficulty in absorption imaging of ultracold atomic clouds and prompts further theoretical work to understand the scattering processes in ultracold dense clouds of atoms for accurate atom number calibration.

A powerful and robust control system is a crucial, often neglected, pillar of any modern, complex physics experiment that requires the management of a multitude of different devices and their precise time synchronisation. The AEgIS collaboration presents CIRCUS, a novel, autonomous control system optimised for time-critical experiments such as those at CERN's Antiproton Decelerator and, more broadly, in atomic and quantum physics research. Its setup is based on Sinara/ARTIQ and TALOS, integrating the ALPACA analysis pipeline, the last two developed entirely in AEgIS. It is suitable for strict synchronicity requirements and repeatable, automated operation of experiments, culminating in autonomous parameter optimisation via feedback from real-time data analysis. CIRCUS has been successfully deployed and tested in AEgIS; being experiment-agnostic and released open-source, other experiments can leverage its capabilities.

We present a three-photon based fluorescence readout method where the strength of the fluorescence scales with the strength of the radio-frequency (RF) field being applied. We compare this method to conventional three-photon electromagnetically-induced transparency (EIT) and electromagnetically-induced absorption (EIA). Our demonstrated EIA/EIT sensitivity in the collinear three-photon Cesium system is the best reported to date at roughly 30 uVm^{-1}Hz^{-1/2}. The fluorescence is nearly 4 fold better in sensitivity compared to EIA/EIT readout., Comment: 9 figure, quantum optics, rydberg electrometry

Experimental implementations of quantum simulation must balance the controllability of the quantum system under test with decoherence typically introduced through interaction with external control fields. The ratio of coherent interaction strength to decoherence induced by stimulated emission in atomic systems is typically determined by hardware constraints, limiting the flexibility needed to explore different operating regimes. Here, we present an optomechanical system for in-situ tuning of the coherent spin-motion and spin-spin interaction strength in two-dimensional ion crystals confined in a Penning trap. The system introduces active optical positioners into the tightly constrained space of the bore of a superconducting magnet, allowing adjustability of the key hardware parameter which determines the ratio of coherent to incoherent light-matter interaction for fixed optical power. Using precision closed-loop piezo-actuated positioners, the system permits in-situ tuning of the angle-of-incidence of laser beams incident on the ion crystal up to $\theta_{\text{ODF}}\approx 28^\circ$. We characterize the system using measurements of the induced mean-field spin precession under the application of an optical dipole force in ion crystals cooled below the Doppler limit through electromagnetically induced transparency cooling. These experiments show approximately a $\times2$ variation in the ratio of the coherent to incoherent interaction strength with changing $\theta_{\text{ODF}}$, consistent with theoretical predictions. We characterize system stability over 6000 seconds; rigid mounting of optomechanics to the ion trap structure reduces differential laser movements to approximately $2\times 10^{-3}$ degrees per hour, enabling long-duration experiments. These technical developments will be crucial in future quantum simulations and sensing applications.

This work investigates the electronic stopping power for protons of a tungsten plasma at various electron densities and temperatures. The study employs a dielectric formalism to model the stopping power due to free and bound electrons, considering relativistic and non-relativistic effects. The bound electron stopping power is modeled using the shellwise local plasma approximation (SLPA) introduced by Montanari and Miraglia. The ionization state of the plasma is also examined, revealing its impact on the bound electron contribution. We compare our results with the T-Matrix approach and the Li-Petrasso model for free electrons in combination with SLPA calculations for the bound electron ones. Results demonstrate the significance of bound electron stopping power, particularly for plasma with high-Z ions. This investigation contributes valuable insights into plasma physics and fusion energy research, providing essential data for future experiments and simulations.

The 5S$\to$6P transition in Rubidium (Rb) at 420 nm offers the advantage of a narrower linewidth and diverse applications in quantum technologies. However, the direct spectroscopy at this transition is challenging due to its weak transition strength. In this paper, we have discussed the saturated absorption spectroscopy (SAS) of Rb using the narrow-line transition at 420 nm. We have studied the effect of the temperature of the Rb cell, pump power and the beam size on the SAS dip heights and their linewidths. Additionally, our study offers a comprehensive examination, encompassing all eight error signals of Rb for the 5S$\to$6P transition at 420 nm and 421 nm. These findings contribute valuable insights to the field of laser frequency stabilization of Rb at blue transition and can be useful in quantum technologies based on this transition., Comment: 8 pages, 6 figures