Search

Introduction: 316L stainless steel (316L SS) has poor wear and corrosion resistance compared to that of the Cp-Ti and Ti-6Al-4V implants [when studied under a physiological environment using phosphate-buffered saline (PBS)]. However, 316L SS implants are cost-effective. Their wear and corrosion properties can be improved by depositing biocompatible coatings. Method: In this research work, a polymer coating of polyetheretherketone (PEEK) and polytetrafluoroethylene (PTFE) was deposited at optimized parameters (20 V for 3 min) on 316L SS via electrophoretic deposition (EPD). We compared the performance between of the PEEK coating and hybrid PEEK/PTFE coatings for biomedical applications. The PEEK/PTFE coating was sintered at 350°C for 30 min. Results and Discussion: Scanning electron microscopy (SEM) analysis revealed that the PEEK/PTFE coating showed a uniform coating with a uniform thickness of ∼80 µm. Fourier transform infrared (FTIR) spectroscopy analysis confirmed the presence of bonds attributed to the PEEK and PTFE coatings. The PEEK/PTFE coating exhibited adequate average surface roughness (Ra) of 2.1 ± 0.2 µm with a high value of contact angle of 132.71 ± 3, indicating the hydrophobic nature of the PEEK/PTFE coating. Scratch tests evaluated that the PEEK/PTFE coating demonstrated a 7 N load, which indicated the good adhesion between the coating and 316L SS. Furthermore, the PEEK/PTFE coating demonstrated good wear resistance, capable of withstanding a 7 N load under dry conditions, and showed a specific wear rate of ∼0.0114 mm3/Nm. Electrochemical analysis conducted using the phosphate-buffered saline (PBS) solution demonstrated that the corrosion rate of 316L SS was reduced from 0.9431 mpy to 0.0147 mpy by depositing the PEEK/PTFE coating. Thus, the developed coatings present suitable wear and corrosion resistance and are thus considered for potential orthopedic applications. [ABSTRACT FROM AUTHOR]

Polymer coatings have gained a lot of attention in the recent past because of their ability to be easily coated on complex shapes, their low cost, and their ability to reduce friction as compared to other materials. Polyether ether ketone (PEEK) is one such high-performance polymer that has gained significant attention in recent years due to its exceptional mechanical properties, chemical resistance, and thermal stability making it a prominent candidate for applications in industries. However, PEEK in its pristine form exhibits poor wear resistance with a moderate coefficient of friction (0.30–0.38). Many attempts have been made by several researchers to improve its wear resistance and lower the COF by developing composite coatings. Hence, in this review, we aim to summarize and present in detail the tribological evaluation of pristine PEEK and PEEK composite coatings by discussing the various methods adopted by the researchers to improve the properties of PEEK, the different types of reinforcements and various dispersion techniques used to develop PEEK composite coatings. By consolidating and analyzing the existing body of knowledge, we also aim to offer valuable insights into the development of more durable, high-performance PEEK nanocomposite coatings for a broad range of tribological applications. [ABSTRACT FROM AUTHOR]

Objective: Smoke inhalation lung injury (SILI) is a common complication in fires and wars, characterized by acute onset and severe condition. Pirfenidone (PFD), a new small‐molecule drug, has been shown to improve lung function and inhibit pulmonary fibrosis and inflammation. This study aimed to elucidate the effect and underlying mechanism of PFD on SILI in rats. Materials and Methods: SILI rats were constructed using a homemade smoking device, which was then treated with PFD. The blood was collected from the abdominal aorta, and the arterial blood gas was detected. The productions of oxidative stress markers and inflammatory cytokines in plasma were measured by enzyme linked immunosorbent assay assay. Moreover, the alveolar surface area, wet:dry weight ratio of the lung tissues, and bronchoalveolar lavage fluid (BALF) were determined as well. The pulmonary histopathology, cell apoptosis, and the related proteins of nuclear factor kappa B (NF‐κB) pathway were determined by hematoxylin‐eosin staining, TdT‐mediated dUTP‐biotin nick end labeling, and western blot assays, respectively. Results: PFD had a significant protective effect on SILI via inhibiting oxidative stress, inflammation, and apoptosis. Mechanistically, PFD inhibited the activation of NF‐κB pathway in vivo. Moreover, activation of NF‐κB pathway attenuated the PFD‐mediated protective effect against SILI. Conclusions: These data demonstrate that PFD alleviates SILI of rats via the NF‐κB signaling pathway, which provides an attractive therapeutic option for SILI treatment. [ABSTRACT FROM AUTHOR]

The Ganjiahu Saxoul National Nature Reserve in Xinjiang, China, is situated in a typical oasis-desert transition zone. Clearly identifying the main vegetation types and their distribution within the reserve is essential for biodiversity protection and restoration. Based on remote sensing images from 2022, a field survey was conducted in August 2023. Vegetation samples from the Ganjiahu Saxoul National Nature Reserve were classified using the two-way indicator species analysis (TWINSPAN) method. Alpha diversity indices of each vegetation type were calculated, followed by the development of a random forest model to evaluate and visualize the clustering results of vegetation quadrats. The results are as follows: (1) In the Ganjiahu Saxoul National Nature Reserve, the dominant herbaceous plants are primarily Salsola spp., while the principal shrubs include Haloxylon ammodendron, Suaeda spp., Reaumuria songarica, and Ceratocarpus arenarius. (2) Sixty-two vegetation sample plots were categorized into 14 types in TWINSPAN. Among these, the Ass. Salsola spp.+Suaeda spp. (G5) covered the largest area and exhibited the highest vegetation diversity. The Ass. Salsola spp. + Ceratocarpus arenarius (G7) showed both high species diversity and extensive coverage. The G14 type represented a single vegetation community with the lowest Shannon-Wiener and Simpson's diversity indices and had a Pielou's evenness index of 1, predominantly comprising farmland and highly saline bare land in the Ganjiahu Saxoul National Nature Reserve. (3) The random forest model achieved an overall accuracy of 87.10%, with a Kappa coefficient of 0.8553, and demonstrated relatively low commission and omission errors. (4) H. ammodendron and H. persicum are mainly distributed in the core area in the northwest and the buffer zone extending from the central to southern parts of the Ganjiahu Saxoul National Nature Reserve. These findings provide a foundation for future precise management of the Ganjiahu Saxoul National Nature Reserve. [ABSTRACT FROM AUTHOR]

Nanomaterials are an emerging class of compounds with potential to advance technology for wastewater treatment. There are many toxic substances in industrial wastewater that are dangerous to the aquatic ecosystem and public health. These pollutants require the development of novel techniques to remove them from the environment. Iron oxide nanoparticles are being studied and develop as new technology to address the problem of environmental pollution due to their unique properties and effectiveness against different kind of pollutants. A variety of modified iron oxide nanoparticles have been developed through extensive research that mitigates the shortcomings of aggregation or oxidation and enhances their efficiency as novel remediator against environmental pollutants. In this review, we present synthetic approaches used for the preparation of iron oxide nanoparticles and their corresponding nanocomposites, along with the processes in which the materials are used as adsorbent/photocatalysts for environmental remediation. Applications explored includes adsorption of dyes, photocatalytic degradation of dyes, and adsorption of heavy metal ions. The use of iron oxides nanocomposite in real wastewater samples and recyclability of adsorbents and photocatalysts were also explored. [ABSTRACT FROM AUTHOR]

In biomaterials research, using one or two components to prepare materials is common. However, there is a growing interest in developing materials composed of three components, as these can offer enhanced physicochemical properties compared to those consisting of one or two components. The introduction of a third component can significantly improve the mechanical strength, biocompatibility, and functionality of the resulting materials. Cross-linking is often employed to further enhance these properties, with chemical cross-linking agents being the most widely used method. This article provides an overview of the chemical agents utilized in the cross-linking of three-component biomaterials. The literature review focused on cases where the material was composed of three components and a chemical substance was employed as the cross-linking agent. The most commonly used cross-linking agents identified in the literature include glyoxal, glutaraldehyde, dialdehyde starch, dialdehyde chitosan, and the EDC/NHS mixture. Additionally, the review briefly discusses materials cross-linked with the MES/EDC mixture, caffeic acid, tannic acid, and genipin. Through a critical analysis of current research, this work aims to guide the development of more effective and safer biopolymeric materials tailored for biomedical applications, highlighting potential areas for further investigation and optimization. [ABSTRACT FROM AUTHOR]

Two new species of Russula subsect. Cyanoxanthinae, collected from tropical and subtropical regions of China, are proposed based on morphological and multi-gene phylogenetic data. Russula icterina is characterized by its green pileus, lamellae with frequent furcations but without lamellulae, basidiospores ornamented with isolated warts with indistinct and inamyloid suprahilar spots, widely dispersed hymenial cystidia rarely with appendages, terminal cells with attenuated or constricted apexes in the pileipellis, one-celled and fusiform pileocystidia without apices that turn grayish black in sulfovanillin, and presence in low-altitude broad-leaved forests dominated by Castanopsis sclerophylla and Quercus acutissima. Russula purpureobrunnea is characterized by its purplish pink to purplish brown pileus, lamellae mixed with lamellulae some with furcations, basidiospores ornamented with isolated warts, clavate or lageniform hymenial cystidia with capitate or mucronate appendages, metachromatic pileipellis with apically attenuated or constricted terminal cells, one-celled pileocystidia that turn grayish black in sulfovanillin, and presence in Pinus yunnanensis, Keteleeria fortunei, Lithocarpus dealbatus, and Quercus spp. mixed forests. Comprehensive morphological descriptions, illustrations, and comparisons with morphologically and phylogenetically related species are provided. [ABSTRACT FROM AUTHOR]

Background and aims: Forest management practices affect soil carbon dynamics, particularly by changing the diversity of aboveground plant functional groups. However, we have a limited understanding of the underlying mechanisms for how plant management affects soil respiration in planted forest ecosystems. Methods: We conducted a 3-year manipulation experiment of plant functional groups that included understory removal, tree root trenching, and fertilization treatments in 2-year-old and 6-year-old Eucalyptus plantations in the subtropical region, to explore the responses of soil carbon emission and microbial community composition. Results: Soil respiration was significantly suppressed by understory removal (-38%), tree root trenching (-41%), and their interactions (-54%), but fertilization alone and in interactions had no significant effect. Soil bacterial and fungal diversity was negatively affected by understory removal and tree root trenching, respectively. Soil respiration and microbial diversity were lower in younger plantations. Reductions in soil carbon emissions were associated with losses of plant functional groups and soil microbial diversity, while increases in soil respiration were associated with soil physicochemical factors, soil temperature, and plantation age. Conclusions: The results indicated that understory removal and tree root trenching strongly affected soil respiration, while the power effects were regulated by soil microbial community and soil properties in contrast plantation ages. Our findings highlight that plant management is of great significance to the soil carbon emission processes in afforested plantations. [ABSTRACT FROM AUTHOR]

TiZrTaAg alloy is a remarkable material with exceptional properties, making it a unique choice among various industrial applications. In the present study, two types of bioactive coatings using MAPLE were obtained on a TiZrTaAg substrate. The base coating consisted in a mixture of chitosan and bioglass in which zinc oxide and graphene oxide were added. The samples were characterized in-depth through a varied choice of methods to provide a more complete picture of the two types of bioactive coating. The analysis included Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), ellipsometry, and micro-Raman. The Vickers hardness test was used to determine the hardness of the films and the penetration depth. Film adhesion forces were determined using atomic force microscopy (AFM). The corrosion rate was highlighted by polarization curves and by using electrochemical impedance spectroscopy (EIS). The performed tests revealed that the composite coatings improve the properties of the TiZrTaAg alloy, making them feasible for future use as scaffold materials or in implantology. [ABSTRACT FROM AUTHOR]

Forests worldwide are experiencing fragmentation, with especially important consequences for ecosystems bordering urbanized areas. Urban forests are exposed to local warming due to the urban heat island which affects their biodiversity and ecosystem functioning. A key ecosystem function affecting carbon and nutrient cycling in forests is litter decomposition, a process driven by the local microclimate. Thus, our aim was to clarify the impact of the urban heat island on litter decomposition in urban forests. We studied soil microclimate and litter decomposition in six urban forests across Europe and along local gradients from the urban forest edge to the interior. To quantify decomposition independent from local forest composition and litter quality, we used standardized green tea and rooibos tea litterbags. We determined the role of the soil microclimate and other environmental drivers for litter decomposition. Secondly, we assessed effects of edge proximity and landscape context on the soil microclimate. Soil characteristics were only driving green tea and not rooibos tea decomposition. On the contrary, higher soil temperatures resulted in faster rates of litter decomposition for both green and rooibos tea and were related to the proximity to the forest edge and the proportion of built-up area in the landscape. Via structural equation modelling we detected cascading effects of the urban heat island on litter decomposition. Such changes in litter decomposition have the potential to alter the soil food web, nutrient cycling and carbon drawdown in urban forests, and could result in significant interactions between urbanisation and ongoing climate change. [ABSTRACT FROM AUTHOR]

The aim of the work is to compare the properties of nanohydroxyapatite coatings obtained using the electrophoretic deposition method (EDP) at 10 V, 20 V, and 30 V, and with deposit times of 2 and 5 min. The primary sedimentation was used to minimize the risk of the formation of particle agglomerates on the sample surface. Evaluation of the coating was performed by using a Scanning Electron Microscope (SEM), Energy-Dispersive Spectroscopy (EDS), Atomic Force Microscopy (AFM), optical profilometer, drop shape analyzer, and a nanoscratch tester. All of the coatings are homogeneous without any agglomerates. When low voltage (10 V) was used, the coatings were uniform and continuous regardless of the deposition time. The increase in voltage resulted in the formation of cracks in the coatings. The wettability test shows the hydrophilic behavior of the coatings and the mean contact angle values are in the range of 20–37 ° . The coatings showed excellent adhesion to the substrate. The application of a maximum force of 400 mN did not cause delamination in most coatings. It is concluded that the optimal coating for orthopedic implants (such as hip joint implants, knee joint implants or facial elements) is obtained at 10 V and 5 min because of its homogeneity, and a contact angle that promotes osseointegration and great adhesion to the substrate. [ABSTRACT FROM AUTHOR]

Approaches for remote sensing can be used to estimate the influence of changes in environmental conditions on terrestrial plants, providing timely protection of their growth, development, and productivity. Different optical methods, including the informative multispectral and hyperspectral imaging of reflected light, can be used for plant remote sensing; however, multispectral and hyperspectral cameras are technically complex and have a high cost. RGB imaging based on the analysis of color images of plants is definitely simpler and more accessible, but using this tool for remote sensing plant characteristics under changeable environmental conditions requires the development of methods to increase its informativity. Our review focused on using RGB imaging for remote sensing the characteristics of terrestrial plants. In this review, we considered different color models, methods of exclusion of background in color images of plant canopies, and various color indices and their relations to characteristics of plants, using regression models, texture analysis, and machine learning for the estimation of these characteristics based on color images, and some approaches to provide transformation of simple color images to hyperspectral and multispectral images. As a whole, our review shows that RGB imaging can be an effective tool for estimating plant characteristics; however, further development of methods to analyze color images of plants is necessary. [ABSTRACT FROM AUTHOR]

Acceptability analyses of place–based innovations provide crucial in-depth knowledge (e.g., perceptions and values on landscapes) for the social–ecological transformation of landscapes. However, previous acceptability analyses often neglected complex and ongoing processes. We argue that, for the design of a sustainability-oriented transformation and to address spatial and temporal dynamics in landscapes, an operational heuristic is needed; one that integrates acceptability analyses into an adaptive landscape co-design and management approach. Therefore, this conceptual–empirical paper introduces the concept of the 'acceptability and landscape design cycle' (ALDC), which is based on findings from various transdisciplinary innovation processes in the Spreewald region (Germany). It is composed of four iterative phases: (1) defining the preconditions for acceptability analysis, (2) conducting the acceptability analysis, (3) integrating the results into the landscape development strategy, and (4) re-designing and refining it. We illustrate the application of these phases using a case study of the cultural landscape in Spreewald. The paper provides practical implementation guidelines of the ALDC and contributes to a better understanding of the dynamics of acceptability decisions regarding the transformation processes of landscapes. Furthermore, it can advance the understanding of how co-evolution of socio-ecological systems occurs. [ABSTRACT FROM AUTHOR]

The aim of this research was the modification of fish collagen films with various amounts of dialdehyde starch (DAS). Film properties were examined before and after the cross-linking process by DAS. Prepared biopolymer materials were characterized by Fourier Transform Infrared Spectroscopy and Atomic Force Microscopy. Moreover, the mechanical, thermal and swelling properties of the films were evaluated and the contact angle was measured. Research has shown that dialdehyde starch applied as a cross-linking agent influences collagen film properties. Mechanical testing indicated a decrease in Young's Modulus and an increase in breaking force, elongation at break, and tensile strength parameters. Results for contact angle were significantly higher for collagen films cross-linked with DAS; thus, the hydrophilicity of samples decreased. Modified samples presented a lower swelling degree in PBS than native collagen films. However, the highest values for the degree of swelling among the modified specimens were obtained from the 1% DAS samples, which were 717% and 702% for 1% and 2% collagen, respectively. Based on AFM images and roughness values, it was noticed that DAS influenced collagen film surface morphology. The lowest value of Rq was observed for 2%Coll_2%DAS and was approximately 10 nm. Analyzing thermograms for collagen samples, it was observed that pure collagen samples were less thermally stable than cross-linked ones. Dialdehyde starch is a promising cross-linking agent for collagen extracted from fish skin and may increase its applicability. [ABSTRACT FROM AUTHOR]

Traditionally, calcareous beech forests were classified and differentiated according to vascular plants. Bryophytes were often omitted or not all substrates were sampled in relevés, and therefore, the role of bryophytes in plant community differentiation remained unclear. In this paper, we studied bryophyte species richness, composition and functional patterns in vegetation units differentiated by vascular plants. We analysed 45 phytosociological relevés from 400 m2 plots in Fagus sylvatica-dominated forests on dolomite bedrock in Central Slovakia. The most frequent among 59 moss and 8 liverwort species was Tortella tortuosa, followed by Hypnum cupressiforme, Brachytheciastrum velutinum and Ctenidium molluscum. Average richness of bryophytes was 8.1 compared to 38.7 species of vascular plants. Seven bryophyte species were significantly linked to a particular vegetation unit. One-way ANOVA showed no noticeable differences in bryophyte species richness between vegetation units. However, it was negatively affected by xericity and positively by cover of rocks on soil surface. CCA revealed that species composition was affected significantly by xericity, cover of bare rocks and cover of tree layer. Mat and turf life forms prevailed, and both long-lived taxa/perennials and short-lived colonists formed the bryophyte layer. Observed bryophyte species grew mostly on rock, living and dead wood, and only minority of them on soil. Therefore, available substrates greatly contributed to the species richness of bryophytes and total plant diversity of the forest community. A complete investigation of substrates is necessary to assess the drivers of bryophyte species distribution and diversity, and their role in classification of calcareous beech forests. [ABSTRACT FROM AUTHOR]

The spread of neophytes (non-native plant species) challenges the conservation status and ecological integrity of forests, especially in lowland areas. Long-term resurvey studies are needed to evaluate the temporal dynamics of neophytes in forests; however, such data are scarce. In 2023, we resampled a set of 45 permanent vegetation plots (established in 1992/93) in two forest vegetation types: oak–hornbeam forests dominated by Quercus robur and colline oak–beech forests dominated by Q. petraea. Over the last 30 years, oak forests have experienced extensive oak tree mortality, with the degree of habitat degradation being greater in Q. robur forests. In the early 1990s, only three neophytes with low abundance were recorded across all plots. In the 2023 resurvey, the total number of neophytes increased to 22 species (15 herbaceous and 7 woody species), comprising 6.9% of the total species pool in the understory layer. The increase in the plot-level number and cover of neophytes was significant in plots dominated by Q. robur but not in those with Q. petraea. The most frequent neophytes were Impatiens parviflora (present in 31% of plots), Solidago gigantea (27%), Erigeron annuus (16%) and Erechtites hieraciifolia (16%). The richness and cover of neophytes were significantly affected by the tree layer cover (negative correlation) and the degree of soil disturbance (positive correlation). All neophytes established in disturbed patches, whereas the occurrence of I. parviflora was exceptional as it was able to colonize less degraded, shaded understory environments. Habitat degradation (the mortality-induced loss of stand-forming oak trees resulting in extensive tree layer cover decrease) emerged as a key driver promoting neophyte proliferation, coupled with the impact of management-induced disturbances affecting overstory and soil conditions. The spread is expected to continue or even intensify in the future because novel light regimes and disturbances make forest habitats less resistant to neophyte proliferation. [ABSTRACT FROM AUTHOR]

Lung cancer has the lowest survival rate due to its late-stage diagnosis, poor prognosis, and intra-tumoral heterogeneity. These factors decrease the effectiveness of treatment. They release chemokines and cytokines from the tumor microenvironment (TME). To improve the effectiveness of treatment, researchers emphasize personalized adjuvant therapies along with conventional ones. Targeted chemotherapeutic drug delivery systems and specific pathway-blocking agents using nanocarriers are a few of them. This study explored the nanocarrier roles and strategies to improve the treatment profile's effectiveness by striving for TME. A biofunctionalized nanocarrier stimulates biosystem interaction, cellular uptake, immune system escape, and vascular changes for penetration into the TME. Inorganic metal compounds scavenge reactive oxygen species (ROS) through their photothermal effect. Stroma, hypoxia, pH, and immunity-modulating agents conjugated or modified nanocarriers co-administered with pathway-blocking or condition-modulating agents can regulate extracellular matrix (ECM), Cancer-associated fibroblasts (CAF),Tyro3, Axl, and Mertk receptors (TAM) regulation, regulatory T-cell (Treg) inhibition, and myeloid-derived suppressor cells (MDSC) inhibition. Again, biomimetic conjugation or the surface modification of nanocarriers using ligands can enhance active targeting efficacy by bypassing the TME. A carrier system with biofunctionalized inorganic metal compounds and organic compound complex-loaded drugs is convenient for NSCLC-targeted therapy. [ABSTRACT FROM AUTHOR]

The Devonian outcrops of the Azrou-Khenifra Basin are located in the eastern band of the Moroccan Central Massif. They are characterized by a high geodiversity since they show sedimentary, stratigraphic, paleontological, tectonic and geomorphological aspects. Those outcrops allow the understanding of the evolution and geodynamic of the area during the Devonian. This proves their relevant in term of scientific value. In addition, they also have educational and touristic interests. The objectives of this work are making the inventory and quantitative assessment as well as the mapping of nine Devonian geosites. To approach the topic, the method proposed by Brilha (2016) have been used which based on qualitative and quantitative criteria. The results show that the geosite Famennian zebra griottes limestones of Ziyar has the highest scientific value (345) while the others are characterized by scientific, educational and tourist values ranging from moderate to high. Regarding the degradation risk, the geosites have a low value. This work could be considered as the base of any geoconservation strategy and geotourism action plan in the area since it focused on the two first steps of it. This may help improve the sustainable development through the establishment of geopark consequently and enhance economical level of people living the Azrou-Khenifra area. [ABSTRACT FROM AUTHOR]

The respiratory barrier, a thin epithelial barrier that separates the interior of the human body from the environment, is easily damaged by toxicants, and chronic respiratory diseases are common. It also allows the permeation of drugs for topical treatment. Animal experimentation is used to train medical technicians, evaluate toxicants, and develop inhaled formulations. Species differences in the architecture of the respiratory tract explain why some species are better at predicting human toxicity than others. Some species are useful as disease models. This review describes the anatomical differences between the human and mammalian lungs and lists the characteristics of currently used mammalian models for the most relevant chronic respiratory diseases (asthma, chronic obstructive pulmonary disease, cystic fibrosis, pulmonary hypertension, pulmonary fibrosis, and tuberculosis). The generation of animal models is not easy because they do not develop these diseases spontaneously. Mouse models are common, but other species are more appropriate for some diseases. Zebrafish and fruit flies can help study immunological aspects. It is expected that combinations of in silico, in vitro, and in vivo (mammalian and invertebrate) models will be used in the future for drug development. [ABSTRACT FROM AUTHOR]

Background: Considering the growing demand for plant trait data and taking into account the lack of trait data from Eastern Europe, especially from its steppic region, we launched a new Ukrainian Plant Trait Database (UkrTrait v. 1.0) aiming at collecting all the available plant trait data from Ukraine. To facilitate further use of this database, we linked the trait terminology to the TRY Plant Trait Database, Thesaurus of Plant Characteristics (TOP) and Plant Trait Ontology (TO). For taxa names, we provide the crosswalks between the Ukrainian checklist and international sources, i.e. GBIF Backbone Taxonomy, World Checklist of Vascular Plants (World Checklist of Vascular Plants (World Checklist of Vascular Plants (WCVP), World Flora Online (WFO) and Euro+Med PlantBase. We aim to integrate our data into the relevant global (TRY Plant Trait Database) and pan-European (FloraVeg.EU) databases. The current version of the database is freely available at the Zenodo repository and will be updated in the future. New information: Until now, plant traits for the Ukrainian flora were scattered across literature, often focusing on single species and written mainly in Ukrainian. Additionally, many traits were in grey literature or remained non-digitised, which rendered them inaccessible to the global scientific community. Addressing this gap, our Ukrainian Plant Trait Database (UkrTrait v. 1.0) represents a significant step forward. We compiled and digitised plant traits from local Ukrainian literature sources. Furthermore, we performed our own field and laboratory measurements of various plant traits that were not previously available in literature. In the current version of the UkrTrait, we focus on vascular plant species that are absent from the other European trait databases, with emphasis on species that are representative for the steppe vegetation. Traits assembled from literature include life span (annuals, biennials, perennials), plant height, flowering period (flowering months), life form (by Raunkiaer), plant growth form and others. Our own measured traits include seed mass, seed shape, leaf area, leaf nitrogen concentration and leaf phosphorus concentration. The current version, i.e. UkrTrait v. 1.0, comprises digitised literature data of 287,948 records of 75 traits for 6,198 taxa and our own trait measurements of 2,390 records of 12 traits for 388 taxa. [ABSTRACT FROM AUTHOR]

Geoparks are territorial organizations, whose primary aim is to foster sustainable local development through the promotion of geoheritage, geotourism and geoeducation. Sites of significant interest from the perspective of geosciences (geosites), as well as the overall geodiversity of the territory, are the fundamental resources for geopark activities. The distribution of these resources in the geographical space of geoparks may, however, be uneven. We first review four cases of UNESCO Global Geoparks from different European countries (Czechia, Germany, Hungary, Portugal) where such a situation occurs, with consequences on tourism development. Then, we place particular focus on an aspiring geopark of the Land of Extinct Volcanoes in SW Poland, providing evidence of its geoheritage and geodiversity values. The aspiring geopark integrates a mountainous–upland terrain and a lowland part, the latter with much fewer sites of interest and, apparently, fewer opportunities to successfully develop geotourism. Recognizing the challenges emerging from the non-uniform distribution of resources and learning from established geoparks, we highlight various opportunities to encourage (geo)tourism in the less diverse sections of the geoparks. Implementation of the ABC (abiotic–biotic–cultural) concept could be particularly helpful, as could be various events organized in these areas. [ABSTRACT FROM AUTHOR]

Climate data matching the scales at which organisms experience climatic conditions are often missing. Yet, such data on microclimatic conditions are required to better understand climate change impacts on biodiversity and ecosystem functioning. Here we combine a network of microclimate temperature measurements across different habitats and vertical heights with a novel radiative transfer model to map daily temperatures during the vegetation period at 10 m spatial resolution across Switzerland. Our results reveal strong horizontal and vertical variability in microclimate temperature, particularly for maximum temperatures at 5 cm above the ground and within the topsoil. Compared to macroclimate conditions as measured by weather stations outside forests, diurnal air and topsoil temperature ranges inside forests were reduced by up to 3.0 and 7.8 ∘ C, respectively, while below trees outside forests, e.g. in hedges and below solitary trees, this buffering effect was 1.8 and 7.2 ∘ C, respectively. We also found that, in open grasslands, maximum temperatures at 5 cm above ground are, on average, 3.4 ∘ C warmer than those of the macroclimate, suggesting that, in such habitats, heat exposure close to the ground is often underestimated when using macroclimatic data. Spatial interpolation was achieved by using a hybrid approach based on linear mixed-effect models with input from detailed radiation estimates from radiative transfer models that account for topographic and vegetation shading, as well as other predictor variables related to the macroclimate, topography, and vegetation height. After accounting for macroclimate effects, microclimate patterns were primarily driven by radiation, with particularly strong effects on maximum temperatures. Results from spatial block cross-validation revealed predictive accuracies as measured by root mean squared errors ranging from 1.18 to 3.43 ∘ C, with minimum temperatures being predicted more accurately overall than maximum temperatures. The microclimate-mapping methodology presented here enables a biologically relevant perspective when analysing climate–species interactions, which is expected to lead to a better understanding of biotic and ecosystem responses to climate and land use change. [ABSTRACT FROM AUTHOR]

This document provides a comprehensive overview of research on sustainable rural development and the challenges faced by rural areas worldwide. It explores topics such as citizen participation, social innovation, tourism, infrastructure development, and agricultural practices. The research aims to propose strategies to reduce depopulation in rural areas and make them more economically viable. The document covers various regions and countries, highlighting the importance of social dynamism, the role of social agents and partnerships, and the need for new approaches to rural development. [Extracted from the article]

One of the important ways to promote geoheritage values is to use geosites in school education. Particularly useful for this are nature reserves that include interesting geological and geomorphological sites. The area of Świętokrzyskie Province is one of the most interesting geological regions of Poland. In 2021, the Holy Cross Mountains UNESCO Global Geopark was established. The main objective of this study was to determine the school students' knowledge of geoheritage sites and their use in geotourism and education. The province's nature reserves are well accessible by transportation from school. Diverse geoheritage sites were selected for the assessment of their geotourism values. An assessment of their geotourism values was made. The problem of knowledge and perception of geoheritage was studied using a questionnaire survey among students of high schools located in the city of Starachowice. The results showed that despite the presence of sites of high value, unique in the country and Europe, they are rarely visited by students and even less frequently used in formal education (field classes). On the other hand, students declare that geoheritage assets can be treated as important tourism attractions. Researchers in the field of geoeducation and geotourism should place greater emphasis on disseminating this knowledge among teachers and the public. An opportunity for the development of geoeducation will certainly be the establishment of a geopark. [ABSTRACT FROM AUTHOR]

This study describes the development and characterization of novel composite scaffolds, made of an alginate‐chitosan hydrogel matrix containing eggshell (ES) particles, for bone tissue engineering applications. Scaffolds with ES particles, either untreated or treated with phosphoric acid to create a nanotextured particle surface, were compared to scaffolds without particles. Results indicate that the nanotexturing process exposed occluded ES proteins orthologous to those in human bone extracellular matrix. Scaffolds with ES or nanotextured ES (NTES) particles had a higher porosity (81 ± 4% and 89 ± 5%, respectively) than scaffolds without particles (59 ± 5%) (p =.002 and p <.001, respectively). Scaffolds with NTES particles had a larger median pore size (113 μm [interquartile range [IQ]: 88–140 μm]) than scaffolds with ES particles (94 μm [IQ: 75–112 μm]) and scaffolds without particles (99 μm [IQ: 74–135 μm]) (p <.001 and p =.011, respectively). The compressive modulus of the scaffolds with ES or NTES particles remained low (3.69 ± 0.70 and 3.14 ± 0.62 kPa, respectively), but these scaffolds were more resistant to deformation following maximum compression than those without particles. Finally, scaffolds with ES or NTES particles allowed better retention of human mesenchymal stem cells during seeding (53 ± 12% and 57 ± 8%, respectively, vs. 17 ± 5% for scaffolds without particles; p <.001 in both cases), as well as higher cell viability up to 21 days of culture (67 ± 17% and 61 ± 11%, respectively, vs. 15 ± 7% for scaffolds without particles; p <.001 in both cases). In addition, alkaline phosphatase (ALP) activity increased up to 558 ± 164% on day 21 in the scaffolds with ES particles, and up to 567 ± 217% on day 14 in the scaffolds with NTES particles (p =.006 and p =.002, respectively, relative to day 0). Overall, this study shows that the physicochemical properties of the alginate‐chitosan hydrogel scaffolds with ES or NTES particles are similar to those of cancellous bone. In addition, scaffolds with particles supported early osteogenic differentiation and therefore represent a promising new bone substitute, especially for non‐load bearing applications. [ABSTRACT FROM AUTHOR]

The treatment of beryllium wastewater has become a major problem in industry. In this paper, CaCO3 is creatively proposed to treat beryllium-containing wastewater. Calcite was modified by an omnidirectional planetary ball mill by a mechanical−chemical method. The results show that the maximum adsorption capacity of CaCO3 for beryllium is up to 45 mg/g. The optimum treatment conditions were pH = 7 and the amount of adsorbent was 1 g/L, and the best removal rate was 99%. The concentration of beryllium in the CaCO3-treated solution is less than 5 μg/L, which meets the international emission standard. The results show that the surface co-precipitation reaction between CaCO3 and Be (II) mainly occurs. Two different precipitates are generated on the used-CaCO3 surface; one is the tightly connected Be (OH)2 precipitation, and the other is the loose Be2(OH)2CO3 precipitation. When the pH of the solution exceeds 5.5, Be2+ in the solution is first precipitated by Be (OH)2. After CaCO3 is added, CO32- will further react with Be3(OH)33+ to form Be2(OH)2CO3 precipitation. CaCO3 can be considered as an adsorbent with great potential to remove beryllium from industrial wastewater. [ABSTRACT FROM AUTHOR]

The study of the semiochemicals produced by the flowers of Impatiens spp. is an important topic that may explain the reason for the rapid expansion of some species in this genus. Impatiens L. belongs to the Balsaminaceae family, which includes several species considered to be invasive plants in Europe. This study aimed to characterize the phytochemistry of four naturally occurring plant species in Poland, including three invasive alien taxa (Impatiens parviflora, I. glandulifera, and I. capensis) and one native species (I. noli-tangere). Gas chromatographic techniques were used to assess phytochemical profiles of chemical attractant cues in their pollination biology. We detected differences in the scent profiles of the investigated species. All the examined Impatiens species produce various alcohols, i.e., heptacosanol, octacosanol, aldehydes (e.g., octadecanal, eicosanal, etc.), and fatty acids, as well as long-chain hydrocarbons such as dodecane, tricosane, petacosane, hexacosane, and farnesene. Impatiens parviflora, I. glandulifera, and I. capensis produce geraniol and linalool, which attract members of the Apidae family, including bumblebees and honeybees. Impatiens parviflora also produces linalool-derived monoterpenes (linalool oxide and 8-hydroxylinalool), which are a strong attractant for Diptera; this may clarify why the species is mainly visited and pollinated by syrphid flies. A list of insect visitors to the Impatiens species under study can be found in the article. [ABSTRACT FROM AUTHOR]

The characteristics of shaded chasmophytic habitats on calcareous rocks in forest conditions are described, where the forest canopy primarily acts as a shading factor that determines microclimate, humidity and light levels. These communities can be found in deciduous forests of the Carpinion betuli, Fagion sylvaticae and Tilio-Acerion alliances, where they are confined to steep calcareous rock faces and cliffs. Syntaxonomically, these communities belong to the Polypodietea class (Ctenidio-Polypodietalia vulgaris order, Ctenidio-Polypodion vulgaris alliance) and to four informal communities: Isothecium alopecuroides-Polystichum braunii, Porella platyphylla-Asplenium ruta-muraria, Pseudanomodon attenuatus-Chrysosplenium alternifolium and Pedinophyllum interruptum-Polystichum aculeatum. We evaluated indices of environmental parameters according to the synphytoindication method using Didukh's scales. An assessment of the threat impacts and indicators of sociological significance shows that the habitat belongs to a rare type (II class), and therefore requires specific conservation measures. [ABSTRACT FROM AUTHOR]

Context: The Mediterranean mountains have witnessed the revegetation of former pasture and cultivated fields since the mid-20th century. The process started when the mountains joined a dynamic and competitive market, which led to depopulation, abandoning cultivated fields, and a reduction in extensive livestock farming. Objectives: We investigate changes in land use and land cover (LULC) and landscape structure in a valley of the Central Pyrenees in 1956, 1981 and 2017, and we discuss the implications for land management within a multidisciplinary context. Methods: Aerial photographs are used to map the LULC in 1956, 1981 and 2017, followed by landscape ecology metrics and indices to analyse the structure of the landscape. Results: The results show: (i) a reduction in cultivated area (-42%) and pastures (-63%) in the montane belt between 1956 and 2017, while forests doubled in area; (ii) changes in LULC are more significant in the montane belt than in subalpine and alpine areas; (iii) based on the Kappa index, it was found that the 29% of the area had undergone changes in LULC between 1956 and 2017, with the changes being greater in the first period (1956–1981) than in the second (1981–2017); (iv) the structure and heterogeneity of the landscape shows an increase between 1956 and 1981, and a change in trend from 1981 to 2017, so that the landscape is more homogeneous in 2017 than in 1956. Conclusion: The discussion suggests the need to maintain and recover mosaic landscapes, since their structure is akin to traditional cultural ones, to increase biodiversity and sustainability, and provide ecosystem services to the population. [ABSTRACT FROM AUTHOR]

The rise of antimicrobial resistance caused by inappropriate use of these agents in various settings has become a global health threat. Nanotechnology offers the potential for the synthesis of nanoparticles (NPs) with antimicrobial activity, such as iron oxide nanoparticles (IONPs). The use of IONPs is a promising way to overcome antimicrobial resistance or pathogenicity because of their ability to interact with several biological molecules and to inhibit microbial growth. In this review, we outline the pivotal findings over the past decade concerning methods for the green synthesis of IONPs using bacteria, fungi, plants, and organic waste. Subsequently, we delve into the primary challenges encountered in green synthesis utilizing diverse organisms and organic materials. Furthermore, we compile the most common methods employed for the characterization of these IONPs. To conclude, we highlight the applications of these IONPs as promising antibacterial, antifungal, antiparasitic, and antiviral agents. [ABSTRACT FROM AUTHOR]

Depopulation often leads to the abandonment of agricultural land and the resulting process of afforestation and reforestation. In this paper, we study the land use changes between 2000 and 2018 in two Spanish provinces, Soria and Teruel. The provinces chosen as case studies are of particular interest because they have some of the lowest population densities in Europe and continue to suffer depopulation processes that have been ongoing since the mid-20th century. The reasons for this are not immediately clear given that unlike other European regions with similar population density values, for example in Northern Scandinavia, they are not exposed to extreme climatic conditions, nor are they located in isolated mountain regions. Using the CORINE Land Cover database, we observed that in both provinces, there has been an expansion in shrub and forest land uses and a decline in agriculture due largely to the fact that certain areas have been abandoned by their inhabitants, although in other parts of these provinces, the amount of land used for agriculture has increased. Urban growth over this period has been minimal. In the coming years, it seems likely that the population of these areas will continue to fall, given that the policies carried out over decades to try to revert this trend have not been successful. [ABSTRACT FROM AUTHOR]

Autologous adipose tissue is commonly used for tissue engraftment for the purposes of soft tissue reconstruction due to its relative abundance in the human body and ease of acquisition using liposuction methods. This has led to the adoption of autologous adipose engraftment procedures that allow for the injection of adipose tissues to be used as a "filler" for correcting cosmetic defects and deformities in soft tissues. However, the clinical use of such methods has several limitations, including high resorption rates and poor cell survivability, which lead to low graft volume retention and inconsistent outcomes. Here, we describe a novel application of milled electrospun poly(lactic‐co‐glycolic acid) (PLGA) fibers, which can be co‐injected with adipose tissue to improve engraftment outcomes. These PLGA fibers had no significant negative impact on the viability of adipocytes in vitro and did not elicit long‐term proinflammatory responses in vivo. Furthermore, co‐delivery of human adipose tissue with pulverized electrospun PLGA fibers led to significant improvements in reperfusion, vascularity, and retention of graft volume compared to injections of adipose tissue alone. Taken together, the use of milled electrospun fibers to enhance autologous adipose engraftment techniques represents a novel approach for improving upon the shortcomings of such methods. [ABSTRACT FROM AUTHOR]

Question: Soil properties can play a crucial role in influencing the abundance and distribution of plant species. Fire regimes can also have substantial impacts on plant community composition. However, few studies have examined the effects of both fire regimes and soil properties on the occurrence of rare plant species. Here, we asked if rare species have specific soil and fire regime associations relative to common species, and if soil properties may explain potential fire effects. Location: Booderee National Park, southeastern Australia. Methods: We collected soil cores and completed vegetation surveys on 42 sites in Sydney Coastal Dry Sclerophyll Forest vegetation. We tested for associations between the number of rare species and common species present in relation to three soil chemical properties (available phosphorus, ammonium and organic carbon), fire frequency, and time since fire. Results: We found that rare and common species were not associated with any of the examined soil properties. However, rare species were associated with sites with a high fire frequency, while common species were negatively associated with time since fire. Conclusions: Our results indicate that rare species' occurrence patterns may be influenced by the direct effects of fire or mediated by multiple factors, rather than shaped solely by soil properties in our study area. Future work to understand the factors that underpin rare species' occurrence patterns in response to fire is critical to develop fire management protocols that effectively conserve rare species in dry sclerophyll forests. [ABSTRACT FROM AUTHOR]

In recent years, there has been growing interest in public valuation for forest ecosystem services in policymaking. This paper investigates the public's perception of the Czech forest ecosystem services, i.e., provisioning, regulating and cultural services, with associated factors (changes in forest cover, production, and respondents' characteristics). The performance perception of forest ecosystem services was gathered from a nationwide survey in 2020. The Coordination of Information on the Environment Land Cover information in 2000 and 2018 was used for observation of forest cover changes. Coniferous and non-coniferous (broadleaved) roundwood, mushroom, and bilberry production data from the observed years were acquired from the Czech Statistical Office and the Ministry of Agriculture's annual nationwide surveys. The Bohemia vs. Moravia study areas were also statistically compared. Predictor analysis of the high score of performance perception from individual and cluster forest ecosystems was also performed to answer the research objectives. The group of forest provisioning services received high scores in public evaluation (from 3.9 to 4.2), followed by regulating services (mean range: 3.7–4.1). The highest score was found in forest as a natural habitat for wild animals and plants (mean: 4.6). However, the lowest value was the esthetic value (mean: 2.3). Both are categorized as forest cultural services. The broadleaved and mixed forest areas in 2018 were significantly higher than in 2000, especially in Bohemia. Meanwhile, the total coniferous forested region in 2018 declined substantially compared to 2000 (p = 0.030), especially in Moravian areas. A significantly higher total production of the coniferous and broadleaved roundwood removals in 2018 than in 2000 was reported, in contrast to a marked decrease in collected mushrooms and bilberries. The high score of performance perception of forests as the wood provisioning service was positively and significantly associated with the changes in broadleaved roundwood removals. Older-age and female respondents were the primary predictors of the studied cluster and individual forest ecosystem services. The findings indicate that the social value of the individual forest provisioning services supports the implementation of multi-species and multi-purpose forests; hence, it encourages the implementation of the current Czech forest policy. [ABSTRACT FROM AUTHOR]

Silk fibroin (SF) holds promise for the preparation of matrices for tissue engineering and regenerative medicine or for the development of drug delivery systems. Regenerated fibroin from Bombyx mori cocoons is water-soluble and can be processed into scaffolds of various forms, such as fibrous matrices, using the electrospinning method. In the current study, we studied the correlation between concentrations of fibroin aqueous solutions and their properties, in order to obtain electrospun mats for tissue engineering. Two methods were used to prevent solubility in fibroin-based matrices: The conversion of fibroin to the β-conformation via treatment with an ethanol solution and chemical cross-linking with genipin (Gp). The interaction of Gp with SF led to the appearance of a characteristic blue color but did not lead to the gelation of solutions. To speed up the cross-linking reaction with Gp, we propose using chitosan-containing systems and modifying fibrous materials via treatment with a solution of Gp in 80% ethanol. It was shown that the composition of fibroin with chitosan contributes to an improved water resistance, reduces defective material, and leads to a decrease in the diameter of the fibers. The electrospun fiber matrices based on regenerated fibroin modified by cross-linking with genipin in water–alcohol solutions were shown to promote cell adhesion, spreading, and growth and, therefore, could hold promise for tissue engineering. [ABSTRACT FROM AUTHOR]

Invasive fungal pathogens are an increasing problem globally and can cause strong effects on forest ecosystems. In this study, we contrast vegetation surveys in eutrophic elm (Ulmus glabra) and ash (Fraxinus excelsior) forests in southern Sweden, conducted just prior to the arrival of Dutch elm disease (DED) in 1989, and then again in 2021, several years after ash dieback (ADB) began. At the sample plot scale, species richness (α–diversity) of the upper tree layer strongly decreased from 1989 to 2021, and the mean cover of elm decreased from 27 to 1% and of ash from 29 to 13%. In the lower tree and shrub layers, elm and ash were replaced by other, mainly shade-tolerant, tree species. The cover and richness of the shrub layer increased in previously elm-dominated stands but not in ash-dominated stands. The extensive loss of canopy cover in elm stands caused a larger change in upper tree layer species composition and increased compositional variability (β-diversity) between plots when compared to the ash stands. The direction of the changes in tree layer composition between the surveys varied with soil moisture and nutrient availability. While beech increased in less eutrophic plots, more nutrient-rich plots changed toward hornbeam or small-leaved lime, and wetter plots turned toward alder and bird cherry. Hence, our results indicate increased compositional diversity and alternative successional pathways for community reorganization following DED and ADB. Future research will reveal if these pathways will later merge or further split. [ABSTRACT FROM AUTHOR]

Inflammation is closely related to the pathogenesis of chronic illnesses. Secondary metabolites of marine seaweeds are recognized as reliable sources of bioactive compounds due to their health benefits besides their nutritional value. The objective of this study was to determine the potential anti-inflammatory effect of phloroglucinol (Phl) in RAW264.7 murine macrophages after lipopolysaccharides (LPS) stimulation. MTT, nitric oxide (NO), and DCFH-DA assays were conducted to determine cell viability, NO production, and reactive oxygen species (ROS) generation respectively. Pro-inflammatory cytokines and prostaglandin E2 (PGE2) levels were measured using ELISA assay kits. Protein expression levels were determined by western blot analysis. Phl treatment showed a promising anti-inflammatory effect by reducing NO production, secretion of pro-inflammatory cytokines (TNF-α, IL-1β, and IL-6), PGE2 production, protein expression levels of inducible nitric oxide synthase (iNOS), and cyclooxygenase-2 (COX-2), and ROS generation in LPS-stimulated RAW264.7 murine macrophages. Phl treatment upregulated heme oxygenase-1 (HO-1) expression by inducing nuclear translocation of nuclear factor erythroid 2-related factor 2 (Nrf2) and activating AMPK. However, Zinc protoporphyrin (ZnPP), an inhibitor of HO-1, partially reversed these effects, including NO production, pro-inflammatory cytokine secretion, iNOS, COX-2 and HO-1 expression, and ROS generation. Phl has potential anti-inflammatory activities by regulating AMPK/Nrf2/HO-1 pathway in LPS-stimulated RAW264.7 murine macrophages. [ABSTRACT FROM AUTHOR]

Graphene is a two-dimensional nanomaterial composed of carbon atoms with sp2 hybrid orbitals. Both graphene and graphene-based composite have gained broad interest among researchers because of their outstanding physiochemical, mechanical, and biological properties. Graphene production techniques are divided into top-down and bottom-up synthesis methods, of which chemical vapor deposition (CVD) is the most popular. The biomedical applications of graphene and its composite include its use in sensors, implantology, and gene and drug delivery. They can be used for tissue engineering, anticancer therapies, and as antimicrobial agents in implant application. The biocompatibility of graphene-based nanomaterials enables their use in the field of biomedicine. This article reviews the properties of graphene, the methods used to produce it, the challenges associated with its use, and the potential applications of this material in biomedicine, regenerative medicine, and drug delivery systems. [ABSTRACT FROM AUTHOR]

Introduction. In the Iberian Peninsula, Schistostega pennata is a rare, acidophilic, Holarctic moss with a characteristic glowing protonema when illuminated by sunlight. It is typically found in dark and humid habitats and is categorised as Threatened or Near Threatened on the Iberian Red Lists. The main aim of this study was to improve knowledge of the distribution, ecology and conservation of S. pennata on the Iberian Peninsula. Methods. All data that were available to us for Schistostega pennata on the Iberian Peninsula (relating to distribution, ecology, phenology) were compiled from the literature, citizen science platforms, and our own observations. Species distribution models were created in Maxent to provide the first approximation to its potential Iberian distribution. Key results. Twenty-six new populations of Schistostega pennata were located, making a total of 73 records for the Iberian Peninsula, mostly from natural and artificial caves, cavities, mines and crevices, and essentially on siliceous substrates. All observations corresponded to areas with abundant rainfall, mild temperatures, and at least some oceanic influence. Species distribution models predicted an expanded potential climatic range in the Iberian temperate region and several montane Mediterranean areas. Conclusions. There remains very little information on Schistostega pennata on the Iberian Peninsula. Existing data coincide with the ecology of the species, although other niches are exploited in other parts of the world that do not seem to occur in this area. It is important to promote its conservation, given the fragmentation of its populations and habitat requirements. Monitoring and initiation of exhaustive sampling campaigns involving citizen science could be a good way to approach this. [ABSTRACT FROM AUTHOR]

This paper presents the results of an analysis of the effects of Poland's forest management evolution over the last 75 years on forest biodiversity at the ecosystem level. Forest biodiversity changes in the two politically and economically different eras (socialism and democracy) are interpreted based on four indicators used in assessments of forest stands (naturalness; habitat diversity; forest management system; forest stand age structure). In the era of socialism (1945–1989), there were dynamic increases in the area of semi-natural forests as well as in the proportion of the most fertile habitats, whilst the proportion of the poorest habitats decreased quite dynamically. Then, the clearcutting management system was regularly implemented, with adverse impacts on forest spatial structure diversity. The proportion of old/mature tree stands and the stand average age increased at relatively slow rates. In the era of democracy (1990–2020), there were comparatively more dynamic increases observed in the area of forests undisturbed by man, as well as in the proportions of mixed broadleaved and wetland forest habitats. At the same time, the proportion of old/mature stands and stand average age kept increasing at relatively fast rates. The area of forests managed with the use of the shelterwood system increased and the area of forest plantations substantially decreased. On the other hand, irrespective of the era under study, there occurred a noticeable not-so-favourable decreasing trend in the proportion of the youngest forest stands. All in all, during the analysed period of more than seven decades, the evolution of forest management practice implemented in Poland's forests by State Forests National Forest Holding led to the restoration of/an increase in biodiversity at the ecosystem level. Yet, there have remained unsolved issues, as regards the following aspects: organisational (the assurance of further reconstruction of forest stands, and the restoration of water profiles), political (a lack of up-to-date national forest policy), and financial (the costs of protecting/restoring biodiversity vs. State Forests' self-financing), as well as conceptual (old-growth stands in managed forests, and controversy over clearcutting) and natural/anthropogenic (climate change, and the eutrophication of forest habitats) issues. The solutions may require measures outside the limits of Poland's forestry, if not far beyond national borders. [ABSTRACT FROM AUTHOR]

While crowdsourcing applications that can support decision-making are increasing in volume, citizen science practice in Greece is in its early stages. The article presents the design of a BioBlitz that took place in the Ioannina Castle and aims to complement the natural and cultural heritage assessment of the specific site through the participation of 116 citizens and university students. The iNaturalist mobile application and online social network were used as basic tools for recording biodiversity and assisting in the identification process. Before the activity, participants received basic training through an open course in Science Education offered by the School of Early Childhood Education at the University of Ioannina. Additionally, participants completed prequestionnaire of the Connectedness to Nature Scale (CNS). The results revealed that more than 26% of almost 1,000 observations received a ResearchGrade, while 207 species were recorded, engaging 191 identifiers. The analysis of both the pre-questionnaires and the post-questionnaires that were collected a week after the BioBlitz, showing a statistically significant positive shift in the levels of CNS. However, low intensity and small scale of the activity should be considered, and multiple interventions or long-time programs could supply more robust findings. [ABSTRACT FROM AUTHOR]

Membranes produced by crosslinking chitosan with magnesium phytate were prepared using highly deacetylated chitosan and its N-carboxymethyl, O-carboxymethyl and N,O-carboxymethyl derivatives. The conditions of the membrane production were described. IR, Raman, electron absorption and emission spectra were measured and analyzed for all the substrates. It was found that O-carboxymethyl chitosan derivative is the most effectively crosslinked by magnesium phytate, and the films formed on this substrate exhibit good mechanical parameters of strength, resistance and stability. Strong O–H···O hydrogen bonds proved to be responsible for an effective crosslinking process. Newly discovered membrane types produced from chitosan and magnesium phytate were characterized as morphologically homogenous and uniform by scanning electron microscopy (SEM) and IR measurements. Due to their good covering properties, they do not have pores or channels and are proposed as packaging materials. [ABSTRACT FROM AUTHOR]

The healing of bone defects after a fracture remains a key issue to be addressed. Globally, more than 20 million patients experience bone defects annually. Among all artificial bone repair materials that can aid healing, implantable scaffolds made from a mineralized collagen (MC) base have the strongest bionic properties. The MC/PLGA scaffold, created by adding Poly (lactic-co-glycolic acid) copolymer (PLGA) and magnesium metal to the MC substrate, plays a powerful role in promoting fracture healing because, on the one hand, it has good biocompatibility similar to that of MC; on the other hand, the addition of PLGA provides the scaffold with an interconnected porous structure, and the addition of magnesium allows the scaffold to perform anti-inflammatory, osteogenic, and angiogenic activities. Using the latest 3D printing technology for scaffold fabrication, it is possible to model the scaffold in advance according to the requirement and produce a therapeutic scaffold suitable for various bone-defect shapes with less time and effort, which can promote bone tissue healing and regeneration to the maximum extent. This study reviews the material selection and technical preparation of MC/PLGA scaffolds, and the progress of their research on bone defect treatment. [ABSTRACT FROM AUTHOR]

Collagen with a multi-hierarchical architecture exhibits powerful biological performance, thus being developed in biomedical applications as a processing building block. The isolated collagen after extraction from biological tissues can be processed into various forms such as fibrils, scaffolds, membranes, microspheres, hydrogels, and sponges for further use in specific applications. This review briefly discusses the multi-hierarchical structure, powerful biological performances, extraction, and processing approaches of collagen as a natural biomaterial. The processing of collagen including dissolution, self-assembly, cross-linking, and electrospinning, is discussed to show more feasibility for specific applications of collagen composite biomaterials. Further emphasis is directed towards the biomedical applications of drug and gene delivery, as well as tissue repair involving bone, cartilage, vascular, and corneal, along with wound healing. Additionally, there is a focus on the development of flexible sensors and electronic skins (e-skins). Furthermore, the potential challenges and perspectives for the development of collagen-based biomaterials are proposed. In short, collagen-based biomaterials are expected to facilitate sustainable development and the next generation of advanced biomaterial applications. [ABSTRACT FROM AUTHOR]

Critical‐sized bone damage resulting from traumas, fractures, and tumors, impairs the bone tissues' inherent capacity for self‐repair. Conventional therapies could be associated with infection and pain besides demanding additional surgery while being costly. These limitations highlight the paucity of potential unique treatment strategies such as bone tissue engineering. In this study, strontium‐doped mesoporous silica nanoparticles (Sr‐MSN) were successfully synthesized and incorporated into the chitosan/alginate scaffolds which were then freeze‐dried and cross‐linked using CaCl2. The physicochemical characteristics of the fabricated scaffolds containing various Sr‐MSN contents were investigated using Fourier‐transform infrared spectroscopy (FTIR), Scanning Electron Microscopy (SEM), and Energy Dispersive Spectroscopy (EDS). The hydrolytic degradation of the scaffolds was decreased with the increase in the Sr‐MSN content while maintaining their water uptake capacity. All fabricated scaffolds showed biocompatibility and Sr‐MSN‐containing scaffolds showed significantly increased Bone marrow mesenchymal stem cells (BMSCs) cell viability compared to chitosan/alginate scaffold after 72 h. The osteogenic differentiation potential investigations via mineralization assay and alkaline phosphatase enzyme activity indicated that the chitosan/alginate scaffold containing 20% Sr‐MSN showed the highest osteogenic differentiation capacity. Overall, bionanocomposite Cs/Alg/Sr‐MSN scaffolds integrated with desired physicochemical characteristics, biocompatibility, osteogenic differentiation capacity, and drug delivery potential show promising properties for attaining ideal results for bone repair and regeneration applications. [ABSTRACT FROM AUTHOR]

In this study, multilayered Cu/HA/ZnS + PEEK coatings were fabricated using hybrid technology on Zr–2.5Nb alloy substrates. The use of electrophoretic deposition (EPD) and heat treatment allowed the 1st base composite ZnS + PEEK layer and the 2nd hydroxyapatite (HA) top layer to be obtained. The EPD kinetics of both layers was studied. Heating at a temperature of 450 °C and slow cooling resulted in densification and sulfonation of PEEK. It also led to an increase in the adhesion of HA particles on the surface of the PEEK + ZnS layer and to the settlement of HA particles deep into the 1st layer. The effect of substrate preparation on the adhesion strength of coatings was investigated. The ZnS + PEEK layer exhibited high adhesion to the chemically treated zirconium alloy. Furthermore, the first layer was characterized by a high scratch resistance. The selective distribution of Cu on the top of the coating was obtained by shadow-masked pulsed laser deposition (PLD). The multilayered coatings exhibited high roughness and mild hydrophobicity. This study showed the possibility of obtaining a multilayered coating system with a controlled distribution of bioactive components (HA) and antimicrobial components (Cu) on its surface using a hybrid method that combined EPD, heat treatment, and PLD. [ABSTRACT FROM AUTHOR]

We report the first record of Russula granulata in Japan, based on morphological characteristics and phylogenetic positions of the specimens collected in mixed subalpine forests in Nagano Prefecture. The species was characterized by a medium-sized fruiting body that is grayish orange to reddish-brown, a strongly viscid pileus with yellowish-red to reddish-brown centers, and a whitish stipe that exhibits light brown discoloration on the lower half. Phylogenetic analyses showed that the Russula specimens from Japan placed within a clade comprising R. granulata from North America and Eurasia. [ABSTRACT FROM AUTHOR]

Copyright of Economics & Environment / Ekonomia i Środowisko is the property of Fundacja Ekonomistow Srodowiska i Zasobow Naturalnych and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)