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We define and study the properties of baric algebras defined by ω-polynomial identities, called ω-PI algebras. We show that every finite dimensional baric algebra is ω-PI. Next we introduce the study of ω-PI algebras of degree 4 with one indeterminate. By gametization we reduce their study to four types. We study the first type corresponding to algebras that are neither barycentric nor invariant by gametization. We show that the variety of these algebras is partitioned into only two subvarieties admiting an unique ponderation, an idempotent, and verifying ω-monomial identities of degrees > 4. [ABSTRACT FROM AUTHOR]