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The structure of the centrosymmetric title complex, [Cu(C5H9O2)2(C6H7NO)2], has the CuII atom on a centre of inversion. The CuII atom is six-coordinate with a distorted octahedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two carboxylate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by intermolecular C—H...O and intramolecular O—H...O hydrogen-bond interactions.