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The presence of sertraline hydrochloride (SER) has been detected in water bodies and wastewater, which encourages the search for alternative treatments for its control and removal. Agro-industrial residues are considered efficient adsorbents and functionalization with magnetic nanoparticles improve the adsorptive properties of these materials, in addition to facilitating their separation from a fluid by an external magnetic field. Thus, this study developed and characterized a new material via the functionalization of the banana peel with iron oxide nanoparticles (BANFunc) for the adsorption of SER in batch experiments. Physicochemical and spectroscopic techniques indicated that the BANFunc functionalization method was effective and improved the adsorption capacity (0.68 and 39.96 mg g−1 for BANPure and BANFunc, respectively). The adsorption studies revealed a maximum adsorptive capacity of 142.85 mg g−1 at 240 min and 318 K. Furthermore, the process presented spontaneous and endothermic behaviour, with a better fit to the pseudo-first-order and Langmuir models for the kinetic and isothermal, respectively. The reuse of the biosorbent was effective for five cycles, and even in the 3rd cycle, the adsorbent showed more than 80% SER removal. The adsorption process can be explained by hydrogen bonds and π-interactions. In the synthetic mixture treatment, the biosorbent demonstrated a satisfactory removal rate, of 86.91%, and individual removals of 83.23%, 89.36% and 88.15% for SER, safranine orange and chloroquine, respectively. Therefore, BANFunc is a promising material for large-scale applications, considering its sustainable character and high treatment efficiency. [ABSTRACT FROM AUTHOR]

The COVID-19 pandemic increased the pollution of water resources by some contaminants, e.g., chloroquine (CQN), due to its probable benefit in the treatment of the virus. Thus, is necessary the removal of CQN from water through advanced techniques. Black soybeans have been widely used due to their benefits to human health, and as a result, there was an increase in soybean husk residue, the main by-product of the soybean processing industry. Given the current scenario and the need to develop new uses for this agricultural residue, this study aimed to establish an economical and environmental biotechnology by the CQN adsorption process onto black soybean hulls (BSH) for the first time. BSH was characterized by physicochemical and spectroscopic techniques that demonstrated porosity, organic functional groups and negative surface charges. The pH study did not affect CQN adsorption pronouncedly, indicating that π-interactions and hydrogen bonds are the main mechanisms of the adsorption process. The maximum adsorption capacity was 75.06 ± 2.24 mg g−1 with 240 min of contact time at 288 K. In order to verify the biosorbent applicability, the safranin orange dye and triclosan adsorption were also evaluated onto BSH. The absorption peaks of the contaminants used in the synthetic mixture demonstrated a removal rate of 90.81 ± 0.80% for safranin orange, 66.79 ± 1.12% for triclosan and 70.62 ± 0.67% for CQN. The satisfactory removal of other contaminants indicates that BSH is a promising, affordable and environmentally friendly biosorbent with applicability potential for alternative treatment of contaminated water. [ABSTRACT FROM AUTHOR]

The presence of micropollutants, such as caffeine (CAF), has been detected throughout the world, since conventional treatment plants are not able to properly degrade them. CAF is a widely consumed stimulant, and has been demanding the development of efficient methodologies for its removal. Aiming at the agriculture waste valorization, a new hydrochar was developed based on chemical and thermal modification of peach stones (mod-PS) for CAF removal from water and from a synthetic mixture. The morphology, functional groups and surface electrical charge of the adsorbent were characterized by SEM, FTIR and zeta potential, respectively. Regarding CAF adsorption performance, the equilibrium time was reached at 480 min and the pseudo-second-order model presented the best fit for the experimental data. The maximum adsorption capacity was 68.39 mg g-1 (298 K) and the Langmuir model exhibited a better fit for the isothermal data. The thermodynamic properties confirmed that the process was exothermic, spontaneous and reversible. The main adsorption mechanisms were hydrogen bonds and π-interactions. The global removal efficiency was satisfactory in the synthetic mixture simulating real wastewater (67%). Therefore, the proposed new hydrochar has potential application as a low-cost adsorbent for CAF removal. [ABSTRACT FROM AUTHOR]

Neutral red (NR) and safranin-O (SO) dyes are used in industrial processes, which their inappropriate disposal in surface waters causes negative impacts. Alternative techniques have been investigated for the complete removal of dyes, in which the adsorption presents itself as a feasible option, especially when low-cost adsorbents obtained from industrial waste are used, such as soybean hulls (SBH). This study proposed the use of SBH for the adsorption of NR and SO dyes. The characterization showed heterogeneous and porous morphology with predominantly negative surface charges, which favored the fixation of the cationic dyes. The comparative study of SO and NR adsorption onto SBH and commercial granular activated carbon confirmed the good performance of the biosorbent material. The maximum adsorption capacities were 287.30 and 221.74 mg g−1 for NR and SO onto SBH, respectively. The equilibrium time was reached in 90 minutes for both dyes. The experimental data was adjusted to the Langmuir and pseudo-second-order models. Thermodynamics inferred endothermic, spontaneous and reversible characteristics to adsorptive processes. The main proposed adsorption mechanisms were hydrogen bonds, π-interactions and electrostatic interactions. The regeneration study showed the possibility of reusing SBH for 6 cycles, and the effect of ionic strength found that the adsorption efficiency was not reduced. Therefore, SBH demonstrated versatility and efficiency in the removal of cationic dyes from wastewater, evidencing its industrial applicability. [ABSTRACT FROM AUTHOR]

Safranin orange (SO) is a cationic dye widely used in industrial sectors. It becomes a threat to the aquatic ecosystem once it reaches water resources, directly affecting photosynthetic activity and dissolved oxygen rate. In view of this scenario and considering the large production of agro-industrial waste, which provides significant disposal costs and environmental impacts, the agricultural by-products such as mandarin peels (MP) are being used as biosorbent materials. Thus, this work proposed the use of MP for SO adsorption. The material was characterized by SEM, zeta potential, and FTIR analysis, in which it was possible to verify heterogeneous porous morphology, predominantly negative surface, and organic functional groups that facilitate adsorption. The results were promising, wherein the maximum adsorption capacity was 464 mg g–1 (318 K), 0.4 g L–1 adsorbent concentration, 120 min equilibrium time and removal percentage of 84.75%. The experimental data showed a better fit to the Langmuir and pseudo-second order mathematical models. The thermodynamic analysis inferred spontaneous, endothermic, and reversible character for SO adsorption onto MP. The main proposed adsorptive mechanisms were hydrogen bonds, π-interactions, and electrostatic interactions. In addition, the reuse of MP showed good efficiency since the adsorption capacity was maintained above 50% after four cycles (from 77.90 to 41.55 mg g–1). Moreover, when evaluating the effect of pH and ionic strength, it verified that the adsorption efficiency was not reduced. Therefore, when compared with other materials, the versatility and potential applicability of MP as a low-cost adsorbent for wastewater treatment is notable. [ABSTRACT FROM AUTHOR]

The adsorption of dyes in water and wastewater using metallic nanoparticles stands out due to its high removal capacity and low environmental impact. The present study proposed the use of copper oxide nanoparticles (CuO_NP), synthesized with pomegranate leaves extract (Punica granatum) to remove the neutral red (NR) dye from the aqueous medium. The characterization confirmed the efficiency of the redox process and the formation of nanoparticles. The adsorption results were promising, wherein the maximum adsorption capacity was 283 mg/g (298 K), with 0.4 g/L of adsorbent concentration, equilibrium time at 120 min, and removal rate of 96%. The pseudo‐second‐order and Langmuir models had a better fit concerning the kinetic and isothermal data, respectively. Thermodynamic parameters revealed an exothermic, spontaneous, and reversible process. The mechanisms that described the adsorptive process were hydrogen bonds, π‐interactions, and electrostatic attraction. CuO_NP showed good regeneration performance up to four reuse cycles (98–52 mg/g). In addition, not pronounced changes were verified in its adsorption capacity with dissociated ions (90–102 mg/g, in relation to the adsorption with no salts 104 mg/g). This secures the material versatility and cost‐effectiveness, justifying its high potential for industrial application to remove NR from water and wastewater. [ABSTRACT FROM AUTHOR]

The development of new technologies for water and wastewater treatment is a growing need due to the occurrence of micropollutants, such as dyes, in water resources. In this sense, green-synthesized nanoparticles are being extensively studied, due to their low cost, non-toxicity, and high efficiency in adsorption processes. Thus, the present study reports the green synthesis of copper oxide nanoparticles (CuO-NP), obtained from pomegranate (Punica granatum) leaf extract, employed for the removal of Safranin-O (SO) dye. CuO-NP was characterized by physicochemical analysis. These analyzes suggested that the redox process occurred efficiently. Also, the material presented interesting elements for the removal of cationic dyes such as negative surface charge, high specific surface area, and predominance of mesopores. The kinetic data fitted the pseudo-second-order model, reaching equilibrium in 480 min. The equilibrium study resulted in a maximum adsorption capacity of 189.54 mg g−1 at 298 K and the experimental data best fitted the Langmuir model. The effect of pH and ionic strength did not present significant changes, which demonstrates an advantage of this adsorbent over other materials. The regeneration study allowed to verify the possibility of reuse CuO-NP, since after 4 cycles the adsorption capacity was 44% of the initial value. Considering the results found, CuO-NP has a high potential for applicability in the treatment of water contaminated by dyes. [ABSTRACT FROM AUTHOR]

Nowadays, the occurrence of microcontaminants in water resources has become a worldwide concern. Among them, it can be mentioned Bisphenol A, a substance widely used in the chemical composition of plastic such as manufacture of packages, bottles, toiletries, among others. Its use may cause adverse effects on human health and the environment. Thus, a treatment is necessary to remove this compound and adsorption is an interesting alternative due to its low cost, operation and high efficiency. The objective of the present study was to evaluate the adsorption capacity of bisphenol in babassu activated carbon. The obtained results were satisfactory and the best experimental conditions were at 318 K temperature, 1 g L−1 adsorbent concentration and 720 min equilibrium time, resulting in the maximum adsorptive capacity of 49.61 mg g−1. The experimental data fit best with the pseudo-second order and Langmuir models for the kinetic and equilibrium studies, respectively. Thermodynamic parameters indicated endothermic, spontaneous and reversible process. The main adsorption mechanisms were hydrogen bonds and π–π interactions. In addition, the material regeneration study allowed to verify its possibility of reuse. Therefore, it was noticed that babassu activated carbon has high potential applicability in the treatment of contaminated water. [ABSTRACT FROM AUTHOR]

[Display omitted] • Development a novel biosorbent functionalized with Fe 3 O 4 for CQN removal. • The equilibrium time for adsorption of CQN onto SBH-Fe 3 O 4 was 120 min. • SBH-Fe 3 O 4 obtained capacity maximum adsorption of 98.84 mg g−1, at 318 K. • Even after 4 cycles, more than 60% CQN removal was achieved (33.36 mg g−1). The COVID-19 pandemic has resulted in an increase in wastewater pollution, due to disposal of metabolites of several drugs (e.g., chloroquine (CQN)). Conventional wastewater treatment is not sufficient to remove these contaminants, posing a threat to the aquatic ecosystem and human health. Thus, soybean hulls residues were functionalized with iron oxide nanoparticles (SBH-Fe 3 O 4) and applied in adsorption processes to remove CQN, for the first time. The functionalization was confirmed through material characterization. The results indicated an equilibrium time of 120 min and a maximum adsorption capacity of 98.84 mg g−1 (318 K). The pseudo-first-order and Langmuir models were better fitted to the kinetic and isothermal parameters, respectively. The reuse of the biosorbent was effective for five cycles. Therefore, SBH-Fe 3 O 4 has a high potential for applicability in the treatment of water contaminated by CQN. [ABSTRACT FROM AUTHOR]

• The innovative green synthesis method of copper oxide nanoparticles was efficient. • The material used as adsorbent obtained a high methylene blue removal of 96.91%. • The adsorbent obtained a maximum adsorption capacity of 166.021 mg g−1 at 318 K. • The thermodynamic parameters indicated a spontaneous and endothermic process. The study proposed a method of obtaining copper oxide nanoparticles through green synthesis using pomegranate leaf for application in the adsorption of methylene blue. The synthesized material was characterized. The kinetic data fitted to pseudo-second-order and the intra-particle diffusion model, which showed three steps: film, intra-particle diffusion and equilibrium. The equilibrium data fitted to the Langmuir model, resulting in the maximum adsorption capacity of 166.021 mg g−1 at 318 K. Also, the thermodynamic parameters indicated a spontaneous, endothermic and reversible process. The results showed a high efficiency of the proposed adsorbent, obtaining up to 96.91% of removal. [ABSTRACT FROM AUTHOR]

• Usage of simple and innovative technique to modify the membrane surface. • Improved antifouling properties for PES membrane modified with TiO 2 and GO. • Dye removal order was YT (69.98 %) < BR (93.35 %) < SO (100 %). • The cycles for dye removal indicate possibility of membrane reusae. Membrane separation processes are an efficient method to manage the amount of wastewater improperly discharged into water due the use of dyes in industrial processes. Thus, polyethersulfone microfiltration membranes were modified with sulfuric acid, titanium dioxide (TiO 2) and graphene oxide (GO) solutions by layer-by-layer self-assembly method via electrostatic interaction through a pressure-assisted filtration system. The characterization indicated that the proposed modification was successfully accomplished. The effect of TiO 2 and GO masses deposited on the membrane surface was studied. MF TD1.0+GO2.5 membrane showed the best performance among synthesized series achieving a red bordeaux (BR) dye removal of 93.35 % and a flux recovery ratio of > 80 %. The treatment of dyes twilight yellow (TY) and safranin orange (SO) was investigated in this membrane achieving a rejection rate of 69.98 and 100 %, respectively. For dyes with high removal rates (BR and SO), other filtration cycles were performed and good results were accomplished. The proposed modification resulted in an efficient treatment of dyes with different characteristics as well as improvement of selectivity and antifouling properties of the membranes. Their reuse potential represents an additional environmental advantage of this process. [ABSTRACT FROM AUTHOR]