1. The localised corrosion associated with individual second phase particles in AA7075-T6: A study by SEM, EDX, AES, SKPFM and FIB-SEM.
- Author
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Mallinson, C. F., Yates, P. M., Baker, M. A., Castle, J. E., Harvey, A., and Watts, Jj F.
- Subjects
ALUMINUM-copper alloys ,ENERGY dispersive X-ray spectroscopy ,AUGER electron spectroscopy ,SCANNING electron microscopy ,CORROSION & anti-corrosives ,ALUMINUM alloys ,FOCUSED ion beams ,INTERMETALLIC compounds - Abstract
To investigate the role of intermetallic particles in the localised corrosion of AA7075-T6, three particles were monitored over 16 h immersion in 3.5 wt% KCl solution. These were examined using Auger electron spectroscopy, energy dispersive X-ray spectroscopy, scanning Kelvin probe force microscopy and focused ion beam-scanning electron microscopy. Despite similar Volta potential measurements, the corrosion microchemistry varied significantly with composition. A Al
7 Cu2 Fe intermetallic resulted in trenching while a (Al,Cu)6 (Fe,Cu) intermetallic showed crevice corrosion and sub-surface intergranular corrosion and a Al12 Fe3 Si intermetallic appeared to be galvanically inactive but showed crevice formation at the matrix interface and sub-surface intergranular corrosion. [ABSTRACT FROM AUTHOR]- Published
- 2017
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