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The self‐assembled hole transporting molecules (SAHTMs) bearing anchoring groups have been established as the hole transporting layers (HTLs) for highly efficient p–i–n perovskite solar cells (PSCs), yet their stability and engineering at the molecular level remain challenging. A topological design of highly anisotropic aligned SAHTM‐based HTLs for operationally stable PSCs that exhibit exceptional solar‐to‐electric power conversion efficiencies (PCEs) is demonstrated. The judiciously designed multifunctional self‐assembled molecules comprise the donor–acceptor subunit for hole transporting and the phosphonic acid group for anchoring, realizing face‐on π‐stacking parallel to the transparent conductive oxide substrate. The high affinity of SAHTMs to the multi‐crystalline perovskite thin film benefits passivating the perovskite buried interface, strengthening interfacial contact while facilitating interfacial hole transfer. Consequently, highly efficient p–i–n PSC devices are obtained with a champion PCE of 23.24% and outstanding operational stability toward various environmental factors including long‐term full sunlight soaking at evaluated temperatures. Perovskite solar modules with a champion efficiency approaching 20% are also fabricated for an active device area above 17 cm2. [ABSTRACT FROM AUTHOR]

Despite being a critical communication skill, grasping humor is challenging—a successful use of humor requires a mixture of both engaging content build-up and an appropriate vocal delivery (e.g., pause). Prior studies on computational humor emphasize the textual and audio features immediately next to the punchline, yet overlooking longer-term context setup. Moreover, the theories are usually too abstract for understanding each concrete humor snippet. To fill in the gap, we develop DeHumor, a visual analytical system for analyzing humorous behaviors in public speaking. To intuitively reveal the building blocks of each concrete example, DeHumor decomposes each humorous video into multimodal features and provides inline annotations of them on the video script. In particular, to better capture the build-ups, we introduce content repetition as a complement to features introduced in theories of computational humor and visualize them in a context linking graph. To help users locate the punchlines that have the desired features to learn, we summarize the content (with keywords) and humor feature statistics on an augmented time matrix. With case studies on stand-up comedy shows and TED talks, we show that DeHumor is able to highlight various building blocks of humor examples. In addition, expert interviews with communication coaches and humor researchers demonstrate the effectiveness of DeHumor for multimodal humor analysis of speech content and vocal delivery. [ABSTRACT FROM AUTHOR]

Long‐term stability has become the major obstacle for the successful large‐scale application of perovskites devices. Owing to the ionic nature of metal‐halide perovskites, the interfacial ion diffusion can induce irreversible degradation under operational conditions, which presents a great challenge to realize stable perovskite solar modules. Here, a diphenylphosphine oxide compound, ethane‐1,2‐diylbis(diphenylphosphine oxide) (DPPO) is introduced to coordinate with lead iodide and form a cross‐linked 1D Pb3I6‐DPPO (1D‐PbI2) complex. These judiciously designed cross‐linked nonionic low‐dimensional lead halide/organic adducts can passivate the defects of perovskite while acting as a robust ion diffusion barrier, thus significantly improving the electronic quality and intrinsic stability of perovskite films. As a result, high‐performance inverted (p‐i‐n) solar modules with a champion efficiency approaching 19% (a certified stabilized efficiency of 17.8%) for active device areas above 17 cm2 without the use of antisolvents, accompanied by outstanding operational stability under heat stress and continuous illumination are achieved. [ABSTRACT FROM AUTHOR]

Analyzing students’ emotions from classroom videos can help both teachers and parents quickly know the engagement of students in class. The availability of high-definition cameras creates opportunities to record class scenes. However, watching videos is time-consuming, and it is challenging to gain a quick overview of the emotion distribution and find abnormal emotions. In this article, we propose EmotionCues, a visual analytics system to easily analyze classroom videos from the perspective of emotion summary and detailed analysis, which integrates emotion recognition algorithms with visualizations. It consists of three coordinated views: a summary view depicting the overall emotions and their dynamic evolution, a character view presenting the detailed emotion status of an individual, and a video view enhancing the video analysis with further details. Considering the possible inaccuracy of emotion recognition, we also explore several factors affecting the emotion analysis, such as face size and occlusion. They provide hints for inferring the possible inaccuracy and the corresponding reasons. Two use cases and interviews with end users and domain experts are conducted to show that the proposed system could be useful and effective for analyzing emotions in the classroom videos. [ABSTRACT FROM AUTHOR]

Emotions play a key role in human communication and public presentations. Human emotions are usually expressed through multiple modalities. Therefore, exploring multimodal emotions and their coherence is of great value for understanding emotional expressions in presentations and improving presentation skills. However, manually watching and studying presentation videos is often tedious and time-consuming. There is a lack of tool support to help conduct an efficient and in-depth multi-level analysis. Thus, in this paper, we introduce EmoCo, an interactive visual analytics system to facilitate efficient analysis of emotion coherence across facial, text, and audio modalities in presentation videos. Our visualization system features a channel coherence view and a sentence clustering view that together enable users to obtain a quick overview of emotion coherence and its temporal evolution. In addition, a detail view and word view enable detailed exploration and comparison from the sentence level and word level, respectively. We thoroughly evaluate the proposed system and visualization techniques through two usage scenarios based on TED Talk videos and interviews with two domain experts. The results demonstrate the effectiveness of our system in gaining insights into emotion coherence in presentations. [ABSTRACT FROM AUTHOR]

Ether‐based electrolytes are commonly used in Li–O2 batteries (LOBs) because of their relatively high stability. But they are still prone to be attacked by superoxides or singlet oxygen via hydrogen abstract reactions, which leads to performance decaying during long‐term operation. Herein we propose a methylated cyclic ether, 2,2,4,4,5,5‐hexamethyl‐1,3‐dioxolane (HMD), as a stable electrolyte solvent for LOBs. Such a compound does not contain any hydrogen atoms on the alpha‐carbon of the ether, and thus avoids hydrogen abstraction reactions. As the result, this solvent exhibits excellent stability with the presence of superoxide or singlet oxygen. In addition the CO2 evolution during charge process is prohibited. The LOB with HMD‐based electrolyte was able to run up to 157 cycles, 4 times more than with 1,3‐dioxolane (DOL) or 1,2‐dimethoxyethane (DME) based electrolytes. [ABSTRACT FROM AUTHOR]

A metal‐free and oxidant‐free method for the one‐pot preparation of quinazolin‐4(3H)‐ones enabled by electrochemical oxidation is described. Together with 2‐aminobenzamides, a variety of aldehydes were successfully applied to an acid‐catalyzed annulation and direct anodic oxidation cascade, affording structurally diverse quinazoline‐4(3H)‐ones in good to excellent yields. Additionally, certain alcohols can be directly applied instead of the corresponding aldehydes to achieve the same final products with the assistance of an electrolysis mediator (TEMPO). The reaction mechanism was carefully examined and the results strongly suggest that the direct and indirect oxidation go through different pathways. As an efficient and environmentally friendly access to a broad range of quinazolin‐4(3H)‐ones, the synthetic utility of this method was demonstrated by gram‐scale operation, as well as the preparation of bioactive mackinazolinone and truncated erlotinib. [ABSTRACT FROM AUTHOR]

The radical-initiated C-H bond functionalization of cyclic ethers with imines represents an efficient way to form C-C bonds and construct 1,2-amino ethers. Despite being a net redox-neutral process, most examples require excess amounts of radical reagents or oxidants to continuously generate the radical species. Herein, we report an atom-economic protocol for the radical addition of cyclic ethers to imines without the need for any oxidant, metal salt, delicate catalyst, or UV irradiation. In the presence of small amounts of AIBN (2 mol-%), tetrahydrofuran smoothly undergoes the reaction with a variety of imines to afford 1,2-amino ethers in moderate to good yields. Preliminary mechanistic studies suggest that this transformation likely proceeds through a radical chain process with the hydrogen atom abstraction as the rate-determining step. [ABSTRACT FROM AUTHOR]

Understanding co-occurrence in urban human mobility (i.e. people from two regions visit an urban place during the same time span) is of great value in a variety of applications, such as urban planning, business intelligence, social behavior analysis, as well as containing contagious diseases. In recent years, the widespread use of mobile phones brings an unprecedented opportunity to capture large-scale and fine-grained data to study co-occurrence in human mobility. However, due to the lack of systematic and efficient methods, it is challenging for analysts to carry out in-depth analyses and extract valuable information. In this paper, we present TelCoVis, an interactive visual analytics system, which helps analysts leverage their domain knowledge to gain insight into the co-occurrence in urban human mobility based on telco data. Our system integrates visualization techniques with new designs and combines them in a novel way to enhance analysts' perception for a comprehensive exploration. In addition, we propose to study the correlations in co-occurrence (i.e. people from multiple regions visit different places during the same time span) by means of biclustering techniques that allow analysts to better explore coordinated relationships among different regions and identify interesting patterns. The case studies based on a real-world dataset and interviews with domain experts have demonstrated the effectiveness of our system in gaining insights into co-occurrence and facilitating various analytical tasks. [ABSTRACT FROM AUTHOR]