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2. Ribbon-Type Boron-Doped Polycyclic Aromatic Hydrocarbons: Conformations, Dynamic Complexation and Electronic Properties

Author

Wenting Sun, Jiaxiang Guo, Zengming Fan, Liuzhong Yuan, Kaiqi Ye, Chuandong Dou, and Yue Wang

Subjects
General Medicine, General Chemistry, Catalysis
Abstract

Molecular ribbons (MRs), one-dimentional topological polycyclic aromatic hydrocarbons (PAHs), are of importance for synthetic chemistry and material sciences. Herein, we disclose an effective strategy to develop boron-doped MRs, i.e. photochemical cyclization on conjugated organoboranes for rapid π-extension. A series of ribbon-type boron-doped PAHs that own multiple cove edges were synthesized using Mallory photoreaction in solution. Two of them feature isomeric C

Published
2022

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