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In today's electric power network, fast changes are the norm, and auxiliary services such as automatic generation control (AGC) play a crucial role in maintaining the quality of the power supply. AGC ensures a balance between power generation, demand, and losses to sustain frequency stability and variation in tie‐line power within a set limit, even when the load changes. To accomplish this, it is always beneficial to consider new approaches to controlling the situation. This paper introduces the design of new AGC regulators that consider deviation in DC tie‐line power as an extra control variable for the turbine controller. In this study, three different deregulated power systems (containing two control areas), namely three thermal generations, the combination of one thermal and two hydro generations, and three hydro generations, including two power distribution companies (DISCOs) in each control area. These optimal AGC regulators are implemented in the proposed thermal–thermal–thermal system to carry out the various power contracts. The results have shown that the dynamic outcomes meet the AGC standards. To improve further dynamic results and the proposed systems' stability margins by incorporating redox flow batteries (RFB). In actual operating conditions, the system parameters do not remain constant due to the aging effect, assumptions made in simplifying the mathematical model, etc. Thus, ±50% deviations in the nominal value of system parameters to assess how well the optimal AGC regulators perform in the system under investigation. The suggested realistic AGC system incorporates many parameter fluctuations and works well with the optimal AGC regulators developed for the proposed plans. This study expanded to include a two‐area, thermal‐hydro‐hydro (THH) system under a deregulated framework connected via an asynchronous transmission link with or without a thyristor‐controlled phase shifter (TCPS) and RFB. The genetic algorithm (GA) can solve many issues and has global search, flexibility to varied problem types, intrinsic parallelism, and the ability to handle massive, complex search spaces. Thus, a two‐area deregulated hydro‐hydro‐hydro system with parallel tie‐lines utilizes GA‐PID, GA‐FOPID, and GA‐(1 + PI)‐FOPID controllers. Moreover, a random load disturbance (RLD) is employed in each section of the offered approach to show the resilience and elite performance of the proposed control strategy. To produce various dynamic reactions in the plans, MATLAB software version R2013a is employed. [ABSTRACT FROM AUTHOR]

Basic studies on concentrated solutions are becoming more and more important due to the practical industrial and geological applications. The use in redox flow batteries is one of the most important applications of these solutions. Specifically, in this paper we investigated highconcentrated copper chloro-complexes solutions with different additives. The concentration of ligands and additives affects the physicochemical and electrochemical properties of 2 M solutions of Cu(I) and Cu(II). Solutions with calcium chloride and HCl as Cl-source were investigated with Cu:Cl ratios of 1:5 and 1:7, the 1:5 Cu:Cl ratio being the best performing. The substitution of calcium chloride with ammonium chloride increased the conductivity. However, while the effect on the positive electrode process was not very evident, the reversibility of the copper deposition-stripping process was greatly improved. Orthophosphoric acid could be a viable additive to decrease the complexation of calcium with chloride anions and to improve the stability of Cu(II) chlorocomplexes. Absorption spectroscopy demonstrated that phosphate ions do not coordinate copper(II) but lead to a shift in the distribution of copper chloro-complexes toward more coordinated species. Electrochemically, the increased availability of chloride anions in solution stabilized the Cu(II)-rich solution and led to increased reversibility of the Cu(II)/Cu(I) redox process. [ABSTRACT FROM AUTHOR]

Basic studies on concentrated solutions are becoming more and more important due to the practical industrial and geological applications. The use in redox flow batteries is one of the most important applications of these solutions. Specifically, in this paper we investigated high-concentrated copper chloro-complexes solutions with different additives. The concentration of ligands and additives affects the physicochemical and electrochemical properties of 2 M solutions of Cu(I) and Cu(II). Solutions with calcium chloride and HCl as Cl− source were investigated with Cu:Cl ratios of 1:5 and 1:7, the 1:5 Cu:Cl ratio being the best performing. The substitution of calcium chloride with ammonium chloride increased the conductivity. However, while the effect on the positive electrode process was not very evident, the reversibility of the copper deposition–stripping process was greatly improved. Orthophosphoric acid could be a viable additive to decrease the complexation of calcium with chloride anions and to improve the stability of Cu(II) chloro-complexes. Absorption spectroscopy demonstrated that phosphate ions do not coordinate copper(II) but lead to a shift in the distribution of copper chloro-complexes toward more coordinated species. Electrochemically, the increased availability of chloride anions in solution stabilized the Cu(II)-rich solution and led to increased reversibility of the Cu(II)/Cu(I) redox process.

We introduce a theoretical design approach aiming at improving energy density of redox flow batteries (RFBs) via the utilization of redox non-innocent ligands capable of stabilizing a metal center in a wide range of oxidation states. Our findings suggest that this promotes the possibility of multiple redox events as well as high open circuit voltages. Specifically, we have proposed two Fe-coordination complexes (I, Fe(Me2Pytacn)(C2N3H2), and II, Fe(H2pmen)(C2N3H2)) combining two different types of ligands, i.e., catalyst-inspired scaffolds and triazole ring, which were previously shown to promote high and low oxidation states in transition metals, respectively. These complexes exhibit as many as six theoretical redox events in the full range of charge states +4 → −2, several of which reside within the electrochemical window of acetonitrile. Electronic structure calculations show that the Fe center exhibits oxidation states ranging from the very rare Fe4+ to Fe1+. Values of the reduction potentials as well as nature of the redox events of both complexes is found to be similar in their high +4 → +1 charge states. In contrast, while exhibiting qualitatively similar redox behavior in the lower 0 → −2 range, some differences in the electronic ground states, delocalization patterns as well as reduction potential values are also observed. The calculated open circuit voltages can reach values of 5.09 and 6.14 V for complexes I and II, respectively, and hold promise to be experimentally accessible within the electrochemical window of acetonitrile expanded by addition of ionic liquids. The current results obtained for these two complexes are intended to illustrate a more general principle based on the simultaneous utilization of two types of ligands responsible for the stabilization of high and low oxidation states of the metal that can be used to design the next-generation charge carriers capable of supporting multi-electron redox and operating in a broad range of charge states, leading to RFBs with greater energy density.

In this paper, Proportional Integral Derivative with Filter (PIDF) is proposed for Automatic Generation Control (AGC) of a multi-area power system in deregulated environment. Initially, a two area four units thermal system without any physical constraints is considered and the gains of the PIDF controller are optimized employing Differential Evolution (DE) algorithm using ITAE criterion. The superiority of proposed DE optimized PIDF controller over Fuzzy Logic controller is demonstrated. Then, to further improve the system performance, an Interline Power Flow Controller (IPFC) is placed in the tie-line and Redox Flow Batteries (RFB) is considered in the first area and the controller parameters are tuned. Additionally, to get an accurate insight of the AGC problem, important physical constraints such as Time Delay (TD) and Generation Rate Constraints (GRC) are considered and the controller parameters are retuned. The performance of proposed controller is evaluated under different operating conditions that take place in a deregulated power market. Further, the proposed approach is extended to a two area six units hydro thermal system. Finally, sensitivity analysis is performed by varying the system parameters and operating load conditions from their nominal values.