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Pollutant dispersion in urban street canyons has been widely investigated by large-eddy simulation (LES). Many LES studies focused on generic street canyons under a wind direction perpendicular to the street axis. Accurate LES simulations require a sufficiently large domain size to minimize the effects of the artificial boundary conditions at the domain faces on the results. As opposed to RANS simulations, there is a lack of guidelines for an appropriate domain size for LES simulations of wind flow and pollutant dispersion in street canyons. The present study systematically investigates the effect of the domain width, domain height and upstream and downstream domain lengths on the wind flow and pollutant dispersion within a generic 2.5D street canyon with spanwise periodic boundary conditions. Following a validation study, 16 LES simulations are performed for different domain sizes. The results show that the minimum requirement for the domain width is 2.5H, where H is the roof height of the street canyon. For the domain height, upstream domain length and downstream domain length, 7.5H, 5H and 10H are recommended, respectively. These guidelines should help to reduce the computational costs of this type of simulation without significantly compromising the accuracy.

Seeded growth is one of the most successful and well-studied methods of making nanorods of face-centered cubic (FCC) metals such as Ag, Au, Pt, etc. In this method separately prepared tiny metal seeds (typically smaller than 10 nm) are added to a growth solution containing metal precursor, a weak reducing agent such as ascorbic acid, and a capping agent. The mechanisms that lead to specific shape selection and growth of nanoparticles, in this method, are poorly understood. We propose a mechanism of nanorod growth based on the physical phenomenon of twinning and develop a population balance based model. Briefly, on mixing with growth solution, the seeds start growing isotropically, during which some of the seeds undergo twinning and transform their growth habit to form nanorod nuclei. The nanorod nuclei grow along one dimension to form nanorods, and a mixture of nanorods and nanospheres is obtained after a short aging time (typically < 3 h). The simulations capture the salient features of one-dimensional growth of nanorods, along with the kinetics. The trends in experimental data are reproduced well by this model, and we are able to predict the yield of nanorods. Simulations also reveal that the growth of nanospheres competes with the nucleation and growth of nanorods; their relative magnitudes decide the yield of specific shapes in the system. The model is quite general and will apply to the seeded growth of nanorods of any material that has an FCC crystal structure.

Deep eutectic solvents (DESs), a novel generation of solvents, have recently been described as efficient and timesaving fibrillation agents for proteins. In this context, the present work aims at assessing the effect of the hydrogen bond donor (HBD) of cholinium chloride ([Ch]Cl):carboxylic acid based DESs on the dimensions (length and width) of lysozyme nanofibers (LNFs). Mono-, di- and tri-carboxylic acids (acetic, lactic, levulinic, malic and citric acids) were used to prepare different DES formulations, which were successfully used on the fibrillation of lysozyme. The results showed that the carboxylic acid (i.e. the HBD) plays an important role on the fibrillation efficiency and on the length of the ensuing LNFs with aspect-ratios always higher than those obtained by fibrillation with [Ch]Cl. The longest LNFs were obtained using lactic acid as the HBD with an average length of 1004 ± 334 nm and width of 31.8 ± 6.8 nm, and thus an aspect-ratio of ca. 32. The potential of these protein nanofibers as reinforcing additives was evaluated by preparing pullulan (PL)-based nanocomposite films containing 5% LNFs with different aspect-ratios, resulting in highly homogenous and transparent films with improved mechanical performance.

Direct Numerical Simulations of the flow around a pair of flapping wings are presented. The wings are flying in forward flight at a Reynolds number Re=500, flapping at a reduced frequency K=1. Several values of the radius of flapping motion are considered, resulting in a database that shows a smooth transition from the wing rotating with respect to its inboard wingtip (flapping), to a vertical oscillation of the wing (heaving). In this transition from flapping to heaving, the spanwise-averaged effective angle of attack of the wing increases while the effect of the Coriolis and centripetal accelerations becomes weaker. The present database is analyzed in terms of the value and surface distribution of the aerodynamic forces, and in terms of 2D and 3D flow visualizations. While the former allows a decomposition of the force in pressure (i.e., the component of the force normal to the surface of the wing) and skin friction (i.e., tangential to the surface of the wing), the latter allows the identification of specific flow structures with the corresponding forces on the wing. It is found that the aerodynamic forces in the vertical direction (lift) tend to increase for wings moving with larger radius of flapping motion, becoming maximum for the heaving configuration. This is mostly due to the increase of the spanwise-averaged effective angle of attack of the wing with the radius of the flapping motion. Also, the local changes in the effective angle of attack have a strong effect on the structure of the leading edge vortex, resulting in changes in the distribution of suction along the span near the leading edge of the wing. The effect of the apparent accelerations is mostly felt on the spanwise position where the separation of the LEV occurs. On the other hand, the differences in the force in the streamwise direction (thrust/drag) between the configurations with different radius of flapping motion seems to be linked to the position of the stagnation point dividing the suction and pressure side boundary layers, which seems to be controlled by the local effective angle of attack. Finally, the results of the DNS are used to evaluate the performance of an unsteady panel method, and to explain its deficiencies. This work was supported by grants TRA2013-41103-P (MINECO/FEDER, UE) and DPI2016-76151-C2-2-R (AEI/FEDER, UE).

We study the problem of thermal convection in a laterally heated horizontal cylinder rotating about its axis. A cylinder of aspect ratio Gamma = H/2R = 2 containing a small Prandtl number fluid (sigma = 0.01) representative of molten metals and molten semiconductors at high temperature is considered. We focus on a slow rotation regime (Omega < 8), where the effects of rotation and buoyancy forces are comparable. The Navier-Stokes and energy equations with the Boussinesq approximation are solved numerically to calculate the basic states, analyze their linear stability, and compute several secondary flows originated from the instabilities. Due to the confined cylindrical geometry-the presence of lateral walls and lids-all the flows are completely three dimensional, even the basic steady states. Results characterizing the basic states as the rotation rate increases are presented. As it occurred in the nonrotating case for higher values of the Prandtl number, two curves of steady states with the same symmetric character coexist for moderate values of the Rayleigh number. In the range of Omega considered, rotation has a stabilizing effect only for very small values. As the value of the rotation rate approaches Omega = 3.5 and Omega = 4.5, the scenario of bifurcations becomes more complex due to the existence in both cases of very close bifurcations of codimension 2, which in the latter case involve both curves of symmetric solutions.

A local magnetic equilibrium model is presented, with finite aspect ratio and up-down asymmetrically shaped cross section, that depends on eight free parameters. In contrast with other local equilibria, which provide simple magnetic-surface parametrizations at the cost of complex poloidal-field flux descriptions, the proposed model is intentionally built to afford analytically tractable magnetic-field components. Therefore, it is particularly suitable for analytical assessments of equilibrium-shaping effects on a variety of tokamak-plasma phenomena., 6 pages, 3 figures

We demonstrate that surface-enhanced Raman scattering (SERS) spectroscopy can be used to monitor variations in the aspect ratio (AR) of colloidal gold nanorods (NRs) during a chemical etching process. The AR of colloidal Au NRs prepared by a seed method was deliberately decreased by addition of aqueous K2S2O8. SERS studies using a 1064 nm laser line revealed a decrease on the detection sensitivity as the nanorods became shorter and using the anion diethyldithiocarbamate (DTC) as the analytical probe. The morphological changes observed for distinct reaction times have also been confirmed by TEM and optical measurements. The dependence of the SERS sensitivity observed for Au NRs of variable AR has been investigated either by using colloids submitted to etching at distinct reaction temperatures or by using a distinct excitation laser line. Therefore, this spectroscopic method offers the possibility to probe in situ changes on the AR of colloidal Au NRs in analytical contexts in which other techniques cannot be easily implemented.

International audience; A novel one-pot synthesis method to prepare gold nanorods of different aspect ratios using radiolysis is presented. The gold nanorods are synthesized by radiolytic reduction of Au-III complexes in a micellar solution formed by a mixture of cationic surfactants (cetyltrimethylammonium bromide and tetraoctylammonium bromide) and in the presence of acetone and silver ions. The mechanisms of reduction of gold complexes and formation of the nanorods are discussed. The nanorods can be trapped in a poly(vinyl alcohol) gel formed under irradiation. The UV-visible absorption spectra of nanorod solutions are compared with calculations performed by using the discrete dipole approximation method, underlying the effect of the rod aspect ratio distribution.

Spaces of continuous piecewise linear finite elements are considered to solve a Poisson problem, and several numerical methods are investigated to recover second derivatives. Numerical results on 2D and 3D isotropic and anisotropic meshes indicate that the quality of the results is strongly linked to the mesh topology and that no convergence can be insured in general.

The harsh radiation environment at the Large Hadron Collider (LHC) requires radiation hard ASICs. This paper presents how a high tolerance for total ionizing dose can be obtained in commercial deep submicron technologies by using enclosed NMOS devices and guard rings. The method is explained, demonstrated on transistor and circuit level, and design implications are discussed. A model for the effective W/L of an enclosed transistor is given, a radiation-tolerant standard cell library is presented, and single event effects are discussed.

This paper describes the use of an a posteriori error estimator to control anisotropic mesh adaptation for computing inviscid compressible flows. The a posteriori error estimator and the coupling strategy with an anisotropic remesher are first introduced. The mesh adaptation is controlled by a single-parameter tolerance (TOE) in regions where the solution is regular, whereas a condition on the minimal element size h(min) is enforced across Solution discontinuities. This h(min) condition is justified on the basis of an asymptotic analysis. The efficiency of the approach is tested with a supersonic flow over an aircraft. The evolution of a mesh adaptation/flow solution loop is shown, together with the influence of the parameters TOL and h(min). We verify numerically that the effect of varying h(min) is concordant with the conclusions of the asymptotic analysis, giving hints on the selection of h(min) with respect to TOL. Finally, we check that the results obtained with the a posteriori error estimator are at least as accurate as those obtained with anisotropic a priori error estimators. All the results presented can be obtained using a standard desktop computer, showing the efficiency of these adaptative methods. Copyright (C) 2008 John Wiley & Sons, Ltd.