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We present a summary of peridotite in the Subantarctic (46 to 60°S) surrounding the Antarctic Plate. Peridotite xenoliths occur on Kerguelen and Auckland islands. Kerguelen islands are underlain by a plume whereas the Auckland Islands are part of continental Zealandia, which is a Gondwana-rifted fragment. Small amounts of serpentinised peridotite has been dredged from fracture zones on the Southeast Indian, Southwest Indian, and Pacific Antarctic Ridge, and represents upwelled asthenosphere accreted to form lithosphere. Supra-subduction zone peridotite has been collected from two locations on the Sandwich Plate. Peridotites from most Subantarctic occurrences are moderately to highly depleted, and many show signs of subsequent metasomatic enrichment. Os isotopes indicate that the Subantarctic continental and oceanic lithospheric mantle contains ancient fragments that underwent depletion long before formation of the overlying crust. Supplementary material at https://doi.org/10.6084/m9.figshare.c.5424956

Cratons are Earth’s ancient continental land masses that remain stable for billions of years. The mantle roots of cratons are renowned as being long-lived, stable features of Earth’s continents, but there is also evidence of their disruption in the recent1–6 and more distant7–9 past. Despite periods of lithospheric thinning during the Proterozoic and Phanerozoic eons, the lithosphere beneath many cratons seems to always ‘heal’, returning to a thickness of 150 to 200 kilometres10–12; similar lithospheric thicknesses are thought to have existed since Archaean times3,13–15. Although numerous studies have focused on the mechanism for lithospheric destruction2,5,13,16–19, the mechanisms that recratonize the lithosphere beneath cratons and thus sustain them are not well understood. Here we study kimberlite-borne mantle xenoliths and seismology across a transect of the cratonic lithosphere of Arctic Canada, which includes a region affected by the Mackenzie plume event 1.27 billion years ago20. We demonstrate the important role of plume upwelling in the destruction and recratonization of roughly 200-kilometre-thick cratonic lithospheric mantle in the northern portion of the Slave craton. Using numerical modelling, we show how new, buoyant melt residues produced by the Mackenzie plume event are captured in a region of thinned lithosphere between two thick cratonic blocks. Our results identify a process by which cratons heal and return to their original lithospheric thickness after substantial disruption of their roots. This process may be widespread in the history of cratons and may contribute to how cratonic mantle becomes a patchwork of mantle peridotites of different age and origin. Upwelling of mantle plumes is proposed as a mechanism for craton healing after substantial disruption of their roots, enabling them to return to their original lithospheric thickness.

The ultramafic mantle sections of the Yarlung-Zangbo ophiolites (YZO) along the suture of India and Asia in Tibet preserve the mantle history of the formerly intervening oceanic lithosphere. Fifty-two ophiolitic peridotites from three localities (Purang, Baigang and Zedang) reveal that these rocks comprise Mesozoic depleted mantle (peak mode 187Os/188Os = 0.126), mixed with more ancient mantle domains (187Os/188Os: 0.113–0.121, with model ages up to 2.2 Ga), probably through subduction or delamination of older lithosphere prior to its re-encapsulation into Mesozoic oceanic lithosphere. Whole-rock major and trace elements indicate that this composite mantle lithosphere experienced moderate to high degrees (∼10–30%) of partial melting in the Permian-Triassic, possibly due to the rifting of the back-arc basin in the northern margin of East Gondwana and the opening of Neo-Tethys. However, the generally flat primitive upper mantle-normalized highly siderophile element patterns do not match the depleted lithophile element characteristics. Sub-vertical (Pd/Ir)N-Al2O3 variations, coupled with the occurrence of variable amounts of interstitial base metal sulfides (BMS) and correlations with (Pd/Ir)N and Cu contents, indicate the addition of S-saturated (or BMS-rich) melts or fluids into this oceanic lithosphere. This may have occurred at ∼130–120 Ma during a new episode of Neo-Tethyan subduction, during which S-saturated forearc basaltic magmas were produced and subsequently overprinted the overlying peridotitic lithospheric mantle. The Tibetan YZO illustrate the complex life cycle of ophiolitic peridotites related to multi-stage regional tectonic events, and provide insights into understanding geodynamic mechanisms that have operated in the Earth’s upper mantle.

The North China Craton (NCC) is an atypical ancient landmass that suffered lithospheric destruction. Previous studies suggest that the eastern part of the lithospheric mantle of the NCC has been thinned and modified in the Mesozoic. However, the initiation time and mechanism of the destruction remain controversial. Mafic magmatism could provide a unique window into deciphering the lithospheric mantle composition and its evolution. Here we present geochemical and geochronological data of the diamond-bearing alkaline basalts from Lan'gan, located in the southeastern margin of the NCC. Zircon U-Pb dating yielded an average age of 174 ± 14 Ma, representing the first reported Jurassic basalts in the eastern NCC. The Lan'gan basalts are enriched in light rare earth elements (LREE) and large ion lithosphile elements (LILE). Sr-Nd-Pb-Hf isotopic compositions (87Sr/86Sr(t) = 0.70646–0.70925, eNd(t) = −2.1 to −4.9, 206Pb/204Pb(t) = 17.14–18.12, 207Pb/204Pb(t) = 15.28–15.61, 208Pb/204Pb(t) = 37.82–38.67, and zircon eHf(t) = −17 to −21) are enriched compared to depleted mantle. The presence of primary amphibole indicates that the magma source of the basalts was water enriched. These observations suggest that, the lithospheric mantle of the eastern NCC were significantly refertilized, likely by slab derived fluids/melts from the Paleo-Pacific subduction. Owing to the Paleo-Pacific subduction, the lithospheric mantle of the eastern NCC were reduced in viscosity and intensity, and finally promoted partial melting in a limited scale to generate the investigated alkaline basalts. Hence, the discovery of diamond in the Lan'gan basalts demonstrates that the lithosphere of the NCC remained thick, and that large-scale destruction had not initiated in the early Jurassic beneath this region.

We studied the petrography, mineralogy, thermobarometry and whole-rock chemistry of 120 peridotite and pyroxenite xenoliths collected from the 156–138 Ma Chidliak kimberlite province (Southern Baffin Island). Xenoliths from pipes CH-1, -6, -7 and -44 are divided into two garnet-bearing series, dunites–harzburgites–lherzolites and wehrlites–olivine pyroxenites. Both series show widely varying textures, from coarse to sheared, and textures of late formation of garnet and clinopyroxene. Some samples from the lherzolite series may contain spinel, whereas wehrlites may contain ilmenite. In CH-6, rare coarse samples of the lherzolite and wehrlite series were derived from P = 2·8 to 5·6 GPa, whereas predominant sheared and coarse samples of the lherzolite series coexist at P = 5·6–7·5 GPa. Kimberlites CH-1, -7, -44 sample mainly the deeper mantle, at P = 5·0–7·5 GPa, represented by coarse and sheared lherzolite and wehrlite series. The bulk of the pressure–temperature arrays defines a thermal state compatible with 35–39 mW m–2 surface heat flow, but a significant thermal disequilibrium was evident in the large isobaric thermal scatter, especially at depth, and in the low thermal gradients uncharacteristic of conduction. The whole-rock Si and Mg contents of the Chidliak xenoliths and their mineral chemistry reflect initial high levels of melt depletion typical of cratonic mantle and subsequent refertilization in Ca and Al. Unlike the more orthopyroxene-rich mantle of many other cratons, the Chidliak mantle is rich (∼83 vol%) in forsteritic olivine. We assign this to silicate–carbonate metasomatism, which triggered wehrlitization of the mantle. The Chidliak mantle resembles the Greenlandic part of the North Atlantic Craton, suggesting the former contiguous nature of their lithosphere before subsequent rifting into separate continental fragments. Another, more recent type of mantle metasomatism, which affected the Chidliak mantle, is characterized by elevated Ti in pyroxenes and garnet typical of all rock types from CH-1, -7 and -44. These metasomatic samples are largely absent from the CH-6 xenolith suite. The Ti imprint is most intense in xenoliths derived from depths equivalent to 5·5–6·5 GPa where it is associated with higher strain, the presence of sheared samples of the lherzolite series and higher temperatures varying isobarically by up to 200 °C. The horizontal scale of the thermal-metasomatic imprint is more ambiguous and could be as regional as tens of kilometers or as local as

We present major- and trace-element concentrations, Sr–Nd–Hf isotopic compositions, Re Os isotopes, and highly siderophile element (HSE) abundances of 17 xenolithic mantle peridotites from the Nuomin volcanic field to constrain the assembly and evolution of the Xing'an–Mongolia Orogenic Belt (XMOB), Northeast China. The Nuomin peridotites are divided into five groups (harzburgite groups Haz-1, Haz-2, and Haz-3, and lherzolite groups Lhz-1 and Lhz-2). The Haz-1 peridotites are characterized by refractory chemical compositions (Al2O3 contents of 1.03–2.30 wt% and olivine forsterite (Fo) numbers of 90.7–92.5) that are best interpreted as residues after high degrees of mantle partial melting. The Haz-2 and Haz-3 peridotites exhibit slightly more fertile compositions (Al2O3 of 1.72–1.80 wt% and Fo of 89.0–89.9 for the Haz-2, and Al2O3 of 2.86 wt% and Fo of 91.2 for the Haz-3), resulting from refertilization by silicate melts. The Lhz-1 samples are more fertile (Al2O3 of 2.90–3.64 wt% and Fo of 89.1–90.3) than the Lhz-2 samples (Al2O3 of 1.64–2.16 wt% and Fo of 90.9–91.3). The combination of trace-element data (Ti/Eu ratio) and Sr–Nd–Hf isotopic compositions indicates the presence of at least three peridotite end-members (Haz-1, Haz-2, and Lhz-1–Lhz-2) beneath the Nuomin area, which can be explained by the infiltration of two distinct metasomatic agents (MA1: composition similar to potassic basaltic rocks in the Wudalianchi–Erkeshan–Keluo area, and MA2: Fe–Ti-enriched melt). HSE abundances and Os isotopic data show that the Os isotopic compositions of the Haz-1, Lhz-1, and Lhz-2 peridotites were not significantly affected by lithophile-element-dominated metasomatism and can be used to constrain the melt extraction ages of these peridotites. The lower 187Os/188Os ratios of Haz-1 peridotites define a prominent rhenium depletion age (TRD) of ~1.6 Ga and represent fragments of the Paleo–Mesoproterozoic lithospheric mantle rather than reflecting the heterogeneous characteristics of the asthenosphere or extraneous emplacement. In contrast, the Lhz-1 and Lhz-2 lherzolite groups together have a narrow range of 187Os/188Os ratios that give younger TRD ages (~0.5 to 1.0 Ga). Our data demonstrate that both the Paleo–Mesoproterozoic and Neoproterozoic subcontinental lithospheric mantle coexist beneath the XMOB and that they correspond respectively to the bimodal age peaks of crustal growth of ~1.6 Ga and ~0.8 Ga defined by the XMOB granitoids. The XMOB was assembled primarily during the Phanerozoic by multiple blocks that had formed from the Paleoproterozoic to Neoproterozoic. The similar chemical and Sr–Nd–Hf isotopic signatures of both young and old lithospheric mantle indicate that the large-scale metasomatism event involving potassic melts most likely occurred during the evolution of the Paleo–Asian Ocean. The crustal materials carried to the mantle by multiple subduction events could be an effective source of potassium for the origin of potassic basaltic rocks.

Earth’s habitability is closely tied to its late-stage accretion, during which impactors delivered the majority of life-essential volatiles. However, the nature of these final building blocks remains poorly constrained. Nickel (Ni) can be a useful tracer in characterizing this accretion as most Ni in the bulk silicate Earth (BSE) comes from the late-stage impactors. Here, we apply Ni stable isotope analysis to a large number of meteorites and terrestrial rocks, and find that the BSE has a lighter Ni isotopic composition compared to chondrites. Using first-principles calculations based on density functional theory, we show that core-mantle differentiation cannot produce the observed light Ni isotopic composition of the BSE. Rather, the sub-chondritic Ni isotopic signature was established during Earth’s late-stage accretion, probably through the Moon-forming giant impact. We propose that a highly reduced sulfide-rich, Mercury-like body, whose mantle is characterized by light Ni isotopic composition, collided with and merged into the proto-Earth during the Moon-forming giant impact, producing the sub-chondritic Ni isotopic signature of the BSE, while delivering sulfur and probably other volatiles to the Earth., Based on Nickel isotope analysis of meteorites and terrestrial rocks, the authors suggest that the Bulk Silicate Earth has a sub-chondritic Nickel isotope composition. This signature is thought to result from the impact and accretion of a Mercury-like impactor which originated from the innermost Solar System.

International audience; Highly depleted Archean peridotites have proven very amenable to Re-Os model age dating. In contrast, due to the increasing heterogeneity of mantle Os isotope compositions with time, the Re-Os system has not been as effective in dating post-Archean peridotites. The timing of depletion and accretion of post-Archean lithospheric mantle around cratons is important to understand within the context of the evolution of the continents. In an attempt to precisely date post-Archean peridotite xenoliths, we present a study of the petrology, mineralogy and geochemistry, including whole-rock Re-Os isotopes, highly siderophile elements and clinopyroxene-orthopyroxene Sr-Nd-Hf isotopes of peridotite xenoliths from Lake Nyos in the Cameroon Volcanic Line (CVL). Eight Nyos peridotite xenoliths, all fresh spinel lherzolites, are characterized by low to moderate olivine Fo contents (88.9–91.2) and low spinel Cr# (8.4–19.3), together with moderate to high whole-rock Al2O3 contents (2.0–3.7%). These chemical characteristics indicate that they are mantle residues of a few percent to

International audience; The authors regret two errors within the Oman dunite samples, these should be corrected as follows

Mantle xenoliths exhumed from beneath the South Island of New Zealand offer an opportunity to investigate the role of lithospheric mantle water in influencing deep lithosphere deformation and formation of the narrow Southern Alps mountain range during orogeny along the Australia–Pacific plate boundary. Fourier transform infrared spectrometry (FTIR) water measurements on clinopyroxene (cpx), orthopyroxene (opx) and olivine of peridotite xenoliths from seven localities across the Zealandia continent reveal a lateral variation of H2O within the Oligocene–Miocene lithospheric mantle. There is a “wet” domain beneath what is now the Southern Alps mountain range with average measured H2O concentrations of 610 ppm for cpx and 298 ppm for opx. In contrast, dominantly “dry” domains with average H2O concentrations of 110 ppm for cpx and 49 ppm for opx reside beneath East Otago, Chatham Island and Auckland Islands. Contrasting H2O concentrations within olivine (calculated to be 60 to 100 ppm for the wet domain versus

While the mantle roots directly beneath Archean cratons have been relatively well studied because of their economic importance, much less is known about the genesis, age, composition and thickness of the mantle lithosphere beneath the regions that surround the cratons. Despite this knowledge gap, it is fundamentally important to establish the nature of relationships between this circum-cratonic mantle and that beneath the cratons, including the diamond potential of circum-cratonic regions. Here we present mineral and bulk elemental and isotopic compositions for kimberlite-borne mantle xenoliths from the Parry Peninsula and Central Victoria Island, Arctic Canada. These xenoliths provide key windows into the lithospheric mantle underpinning regions to the North and Northwest of the Archean Slave craton, where the presence of cratonic material has been proposed. The mantle xenolith data are supplemented by mineral concentrate data obtained during diamond exploration. The mineral and whole rock chemistry of peridotites from both localities is indistinguishable from that of typical cratonic mantle lithosphere. The cool mantle paleogeotherms defined by mineral thermobarometry reveal that the lithospheric mantle beneath the Parry Peninsula and Central Victoria Island terranes extended well into the diamond stability field at the time of kimberlite eruption, and this is consistent with the recovery of diamonds from both kimberlite fields. Bulk xenolith Se and Te contents, and highly siderophile element (including Os, Ir, Pt, Pd and Re) abundance systematics, plus corresponding depletion ages derived from Re-Os isotope data suggest that the mantle beneath these parts of Arctic Canada formed in the Paleoproterozoic Era, at ∼2 Ga, rather than in the Archean. The presence of a diamondiferous Paleoproterozoic mantle root is part of the growing body of global evidence for diamond generation in mantle roots that stabilized well after the Archean. In the context of regional tectonics, we interpret the highly depleted mantle compositions beneath both studied regions as formed by mantle melting associated with hydrous metasomatism in the major Paleoproterozoic Wopmay-Great Bear-Hottah arc systems. These ∼2 Ga arc systems were subsequently accreted along the margin of the Slave craton to form a craton-like thick lithosphere with diamond potential thereby demonstrating the importance of subduction accretion in building up Earth’s long-lived continental terranes.

The timing and mechanisms of continental crust formation represent major outstanding questions in the Earth sciences. Extinct-nuclide radioactive systems offer the potential to evaluate the temporal relations of a variety of differentiation processes on the early Earth, including crust formation. Here, we investigate the whole-rock 182W/184W and 142Nd/144Nd ratios and zircon Δ 17 O values of a suite of well-studied and lithologically-homogeneous meta-igneous rocks from the Acasta Gneiss Complex, Northwest Territories, Canada, including the oldest-known zircon-bearing rocks on Earth. In the context of previously published geochemical data and petrogenetic models, the new 142Nd/144Nd data indicate that formation of the Hadean–Eoarchean Acasta crust was ultimately derived from variable sources, both in age and composition. Although 4.02 Ga crust was extracted from a nearly bulk-Earth source, heterogeneous μ 142Nd signatures indicate that Eoarchean rocks of the Acasta Gneiss Complex were formed by partial melting of hydrated, Hadean-age mafic crust at depths shallower than the garnet stability field. By ∼3.6 Ga, granodioritic–granitic rocks were formed by partial melting of Archean hydrated mafic crust that was melted at greater depth, well into the garnet stability field. Our 182W results indicate that the sources to the Acasta Gneiss Complex had homogeneous, high-μ182W on the order of +10 ppm—a signature ubiquitous in other Eoarchean terranes. No significant deviation from the terrestrial mass fractionation line was found in the triple oxygen isotope (16O–17O–18O) compositions of Acasta zircons, confirming homogeneous oxygen isotope compositions in Earth's mantle by 4.02 Ga.

High-precision measurements of W isotopic ratios have enabled increased exploration of early Earth processes. However, when applying W isotopic data to understand the geological processes, it is critical to recognize the potential mobility of W and hence evaluate whether measured W contents and isotopic compositions reflect the primary petrogenetic processes or instead are influenced by the effects of secondary inputs/mobility. Furthermore, if we are to better understand how W is partitioned between different minerals during melting and metasomatic processes it is important to document the likely sinks for W during these processes. In addition, an understanding of the main hosts for W in the crust and mantle is critically important to constrain how W is cycled and stored in the crust-mantle geochemical cycle. As a first step to investigate these issues, we have carried out in situ concentration measurements of W and other HFSEs in mineral phases within a broad spectrum of crustal and mantle rocks, along with whole-rock concentration measurements. Mass balance shows that for tonalitic gneiss and amphibolite, the major rock-forming minerals can adequately account for the bulk W budget, and for the pristine ultramafic rocks, olivine and orthopyroxene are the major controlling phases for W whereas for metasomatized ultramafic rocks, significant W is hosted in Ti-bearing trace phases (e.g., rutile, lindsleyite) along grain boundaries or is inferred to reside in cryptic W-bearing trace phases. Formation or decomposition of these phases during secondary processes could cause fractionation of W from other HFSEs, and also dramatically modify bulk W concentrations in rocks. For rocks that experienced subsequent W enrichment/alteration, their W isotopic compositions may not necessarily represent their mantle sources, but could reflect later inputs. The relatively small suite of rocks analyzed here serves as a reconnaissance study but allows some preliminary speculations on their significance for crust-mantle HFSE and siderophile element budgets – to be tested in future studies. The significant concentration of W, as well as Nb and Ta hosted in rutile and titanite has interesting implications for the budget of W during crust-mantle recycling. Crust-mantle recycling models invoking the recycling of rutile-bearing eclogites to satisfy the mantle Nb/Ta ratio carry the penalty that the very high W/U and W/Th ratios of these rocks results in a concomitant large deviation from the primitive mantle-like ratios estimated for bulk continental crust. Similarly, data from the single amphibolite sample investigated in this study are inconsistent with models implicating the partial melting of amphibolite-bearing subducted slabs as a major process for formation of continental crust in the Earth’s early history. Either the current widely accepted estimates for bulk continental crust W/U and W/Th ratios are in error, or partial melting or other processes lowers the W/U or W/Th of melt residues during their return to the mantle. The present small dataset cannot properly evaluate this, requiring further investigation. Finally, the lithospheric mantle has the potential to store substantial amounts of W, for example via infiltration by W-rich melts/fluids, and thus may act as a source for W mineralization in the crust.

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio analyses by both solution-nebulisation MC-ICP-MS and laser ablation-ICP-MS, as well as of radioactive isotope geochronology by LA-ICP-MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis, however it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro-XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.

This contribution presents a new method for Re–Os isotope dating organic-rich sedimentary (ORS) rocks by thermal ionization mass spectrometry using an H 2 O 2 –HNO 3 solution as the digestion medium, rather than CrO 3 –H 2 SO 4 or inverse aqua regia . The main underlying principle of this method is that H 2 O 2 –HNO 3 digestion would preferentially liberate hydrogenous Re and Os, and minimize the dissolution of non-hydrogenous detrital Re and Os, thereby providing more accurate and precise ages. A series of tests were performed, and the experimental data demonstrate the fundamental controls on spike–sample equilibrium and that the amount of detrital Re and Os incorporated into the system are subjected to the volumetric ratio of H 2 O 2 to HNO 3 . The optimum method is a H 2 O 2 :HNO 3 ratio of 5 to complete spike–sample equilibration, and to minimize the amount of detrital Re and Os in the system. A comparison of our new method with inverse aqua regia and CrO 3 –H 2 SO 4 showed that the three techniques yield indistinguishable Re–Os results, suggesting complete spike–sample equilibrium was achieved by all of the digestion techniques. Moreover, the data show that our new technique leaches out the least amount of detrital Re and Os isotopes relative to conventional methods Thus, we propose the H 2 O 2 –HNO 3 method may increase the precision and accuracy of Re–Os depositional ages of organic-rich sedimentary systems.

An important task in assessing the magma source of an intraplate volcanic province is establishing the composition of the underlying lithospheric mantle. Pyroxenes in peridotite xenoliths from the ∼10,000 km2 Dunedin Volcanic Group in New Zealand reveal that the underlying lithospheric mantle is chemically and isotopically heterogeneous and has a complex thermal history. Portions of this mantle have light rare earth element–depleted clinopyroxene trace element concentrations and distinctly radiogenic Nd compositions (eNd(20 Ma) ≥ + 15.5) with model depleted mantle ages that are ≥100 m.y. older than the overlying Jurassic crust (type 1). The Nd isotopic composition of these moderately fertile domains is distinct from any Dunedin Volcanic Group magma, but the domains are embedded within enriched peridotitic mantle (type 2) that has formed through reaction with a light rare earth element–rich fluid that imparted an isotopic composition in strongly metasomatized xenoliths of 87Sr/86Sr(20 Ma) = 0.7028–0.7029, eNd(20 Ma) = + 5.0 to + 5.1, and 206Pb/204Pb = 19.9, 207Pb/204Pb = 15.5, and 208Pb/204Pb = 39.6. These isotope ratios overlap with the isotopically homogeneous high time-integrated U/Pb–like source signature of the host Dunedin Volcanic Group. However, all metasomatic and nonmetasomatic pyroxenes are zoned in temperature-sensitive elements (Al, Cr, Mg ± Ca), with trends indicating element exchange during cooling and the results of diffusion calculations implying that the zoning formed over hundreds of thousands to millions of years prior to late Oligocene–Miocene xenolith entrainment. These data, along with calculated pyroxene rare earth element homogenization diffusion rates, indicate that mantle metasomatism predated entrainment in the host magmas by millions of years. Furthermore, the presence of the cooling trends in all but one sample indicates that this upper lithosphere mantle preserves little or no sign of a rise in the geotherm at the time of magmatism. Zoning patterns in peridotite pyroxenes can therefore provide useful insight into the role of portions of the lithospheric mantle in formation of intraplate alkaline basalts.

The zinc (Zn) stable isotope system has great potential for tracing planetary formation and differentiation processes due to its chalcophile, lithophile and moderately volatile character. As an initial approach, the terrestrial mantle, and by inference, the bulk silicate Earth (BSE), have previously been suggested to have an average δ 66 Zn value of ∼+0.28‰ (relative to JMC 3-0749L) primarily based on oceanic basalts. Nevertheless, data for mantle peridotites are relatively scarce and it remains unclear whether Zn isotopes are fractionated during mantle melting. To address this issue, we report high-precision (±0.04‰; 2SD) Zn isotope data for well-characterized peridotites ( n = 47) from cratonic and orogenic settings, as well as their mineral separates. Basalts including mid-ocean ridge basalts (MORB) and ocean island basalts (OIB) were also measured to avoid inter-laboratory bias. The MORB analyzed have homogeneous δ 66 Zn values of +0.28 ± 0.03‰ (here and throughout the text, errors are given as 2SD), similar to those of OIB obtained in this study and in the literature (+0.31 ± 0.09‰). Excluding the metasomatized peridotites that exhibit a wide δ 66 Zn range of −0.44‰ to +0.42‰, the non-metasomatized peridotites have relatively uniform δ 66 Zn value of +0.18 ± 0.06‰, which is lighter than both MORB and OIB. This difference suggests a small but detectable Zn isotope fractionation (∼0.1‰) during mantle partial melting. The magnitude of inter-mineral fractionation between olivine and pyroxene is, on average, close to zero, but spinels are always isotopically heavier than coexisting olivines (Δ 66 Zn Spl-Ol = +0.12 ± 0.07‰) due to the stiffer Zn-O bonds in spinel than silicate minerals (Ol, Opx and Cpx). Zinc concentrations in spinels are 11–88 times higher than those in silicate minerals, and our modelling suggests that spinel consumption during mantle melting plays a key role in generating high Zn concentrations and heavy Zn isotopic compositions of MORB. Therefore, preferential melting of spinel in the peridotites may account for the Zn isotopic difference between spinel peridotites and basalts. By contrast, the absence of Zn isotope fractionation between silicate minerals suggests that Zn isotopes are not significantly fractionated during partial melting of spinel-free garnet-facies mantle. If the studied non-metasomatized peridotites represent the refractory upper mantle, mass balance calculation shows that the depleted MORB mantle (DMM) has a δ 66 Zn value of +0.20 ± 0.05‰ (2SD), which is lighter than the primitive upper mantle (PUM) estimated in previous studies (+0.28 ± 0.05‰, 2SD, Chen et al., 2013b; +0.30 ± 0.07‰, 2SD, Doucet et al., 2016). This indicates that the Earth’s upper mantle has a heterogeneous Zn isotopic composition vertically, which is probably due to shallow mantle melting processes.

International audience; The Earth's major heat and mass fluxes are output from the mantle to surface via mid-ocean-ridge-basalt (MORB) magmatism. The variations of MORBs are determined both by the heterogeneity of mantle source and the melt migration processes from mantle source to seafloor. However, before the MORB magmas enter crust, the role of the major melt migration passageways within the mantle (dunite channel systems) in regulating the compositions of MORBs has been rarely evaluated, especially from the perspective of Re-Os isotopes. Here, we report new Re-Os isotopic compositions of base-metal sulfides (BMS), chromites and dunites from dunite lenses with low spinel Cr# [Cr3+/(Cr3++Al3+) ≤0.66] (products of interaction between MORB-like melts and upper-mantle harzburgites) from the Zedang ophiolite (South Tibet). Rhenium-Os isotopic compositions of low-Cr# dunites from the Samail and Wadi Tayin massifs (typical MOR segments) of the Oman ophiolite are also shown for comparison to reveal the melt plumbing processes at mantle depths beneath mid-ocean ridges. Mineralogical evidence suggests that the Zedang sulfides and desulfurized alloy portions were originally precipitated as monosulfide solid solutions. The highly variable 187Os/188Os initial ratios (0.1191-0.1702) and low 187Re/188Os (

To examine how the mantle lithosphere stabilises continents, we present a synthesis of the mantle beneath Zealandia in the SW Pacific Ocean. Zealandia, Earth's “8th continent”, occurs over 4.9 M km2 and comprises a fore-arc, arc and back-arc fragment rifted from the Australia–Antarctica Gondwana margin 85 Myr ago. The oldest extant crust is ∼500 Ma and the majority is Permian–Jurassic. Peridotitic rocks from most known locations reveal the underpinning mantle to comprise regional domains varying from refractory (Al2O3 < 1 wt%, olivine Mg# > 92, spinel Cr# up to 80, Pt/Ir < 1) to moderately depleted (Al2O3 = 2–4 wt%, olivine Mg# ∼90.5, spinel Cr# < ∼60). There is no systematic distribution of these domains relative to the former arc configuration and some refractory domains underlie crust that is largely devoid of magmatic rocks. Re-depletion Os model ages have no correlation with depletion indices but do have a distribution that is very similar to global convecting mantle. Whole rock, mineral and isotopic data are interpreted to show that the Zealandia mantle lithosphere was constructed from isotopically heterogeneous convecting mantle fragments swept into the sub-arc environment, amalgamated, and variably re-melted under low-P hydrous conditions. The paucity of mafic melt volumes in most of the overlying crust that could relate to the depleted domains requires melting to have been followed by lateral accretion either during subduction or slab rollback. Recent Australia–Pacific convergence has thickened portions of the Zealandia mantle to >160 km. Zealandia shows that the generation of refractory and/or thick continental lithosphere is not restricted to the Archean. Since Archean cratons also commonly display crust–mantle age decoupling, contain spinel peridotites with extreme Cr# numbers that require low-P hydrous melting, and often have a paucity of mafic melts relative to the extreme depletion indicated by their peridotitic roots, they too may – in part – be compilations of peridotite shallowly melted and then laterally accreted at subduction margins.

A suite of peridotite xenoliths from the Chidliak kimberlite province provides an ideal opportunity to assess the age of the mantle lithosphere beneath the eastern Hall Peninsula Block (EHPB) in southern Baffin Island, Nunavut and to provide constraints on the lithospheric architecture of this region. The new dataset comprises highly siderophile element (HSE) abundances and Re Os isotopic compositions for 32 peridotite xenoliths sampled from four Late Jurassic-Early Cretaceous kimberlite pipes (CH-1, -6, -7, and -44). These peridotites represent strongly depleted mantle residues, with bulk-rock and olivine chemistry denoting melt extraction extents of up to 40%. The vast majority of samples show PPGE (Pt and Pd) depletion relative to IPGE (Os, Ir, and Ru) ((Pt/Ir)N: 0.10–0.96, median = 0.57; (Pd/Ir)N: 0.03–0.79, median = 0.24), coupled with mostly unradiogenic Os isotopic compositions (187Os/188Os = 0.1084–0.1170). These peridotites display strong correlations between 187Os/188Os and melt depletion indicators (such as olivine Mg number and bulk-rock Al2O3, (Pd/Ir)N), suggesting that an ancient (~2.8 Ga) melt depletion event governed the formation of the Chidliak lithosphere. The prominent mode of TRDerupt model ages at ca. 2.8 Ga matches the main crust-building ages of the EHPB, demonstrating temporal crust-mantle coupled in the Meso-Neoarchean. These ancient melt-depletion ages are present throughout the depth of the ~200 km thick lithospheric mantle column beneath Chidliak. The Meso-Neoarchean formation age of the EHPB mantle broadly coincides with the timing of stabilization of the lithospheric mantle beneath the Greenlandic portion of the North Atlantic Craton (NAC). This, along with the similarity in modal mineralogy, chemical composition and evolutionary history, indicates that the EHPB, southern Baffin Island was once contiguous with the Greenlandic NAC. The mantle lithosphere beneath both the EHPB and the NAC show a similar metasomatic history, modified by multiple pulses of metasomatism. These multiple metasomatic events combined to weaken and thin the lithospheric mantle, culminating in the formation of the Labrador Sea and Davis Strait separating the EHPB from the Greenlandic NAC in the Paleocene.

Although trace element concentrations in clinopyroxene serve as a useful tool for assessing the depletion and enrichment history of mantle peridotites, this is not applicable for peridotites in which the clinopyroxene component has been consumed (~ 25% partial melting). Orthopyroxene persists in mantle residues until ~ 40% melting and it is therefore this mineral that offers petrological insights into the evolution of refractory peridotites. Major and trace element concentrations in orthopyroxene ± clinopyroxene from two spinel facies harzburgitic xenolith suites from New Zealand are examined. Samples from Cape L'Evique (CLEV) on Chatham Island contain traces of clinopyroxene ( 45) and low orthopyroxene Al2O3 (generally

Well-resolved W-182 isotope anomalies, relative to the present mantle, in Hadean-Archean terrestrial rocks have been interpreted to reflect the effects of variable late accretion and early mantle differentiation processes. To further explore these early Earth processes, we have carried out W concentration and isotopic measurements of Eoarchean ultramafic rocks, including lithospheric mantle rocks, metakomatiites, a layered ultramafic body and associated crustal gneisses and amphibolites from the Uivak gneiss terrane of the Saglek Block, northern Labrador, Canada. These analyses are augmented by in situ W concentration measurements of individual phases in order to examine the major hosts of W in these rocks. Although the W budget in some rocks can be largely explained by a combination of their major phases, W in other rocks is hosted mainly in secondary grain-boundary assemblages, as well as in cryptic, unidentified W-bearing `nugget' minerals. Whole rock W concentrations in the ultramafic rocks show unexpected enrichments relative, to elements with similar incompatibilities. By contrast, W concentrations are low in the Uivak gneisses. These data, along with the in situ W concentration data, suggest metamorphic transport/re-distribution of W from the regional felsic rocks, the Uivak gneiss precursors, to the spatially associated ultramafic rocks. All but one sample from the lithologically varied Eoarchean Saglek suite is characterized by generally uniform similar to+11 ppm enrichments in W-182 relative to Earth's modern mantle. Modeling shows that the W isotopic enrichments in the ultramafic rocks were primarily inherited from the surrounding W-182-rich felsic precursor rocks, and that the W isotopic composition of the original ultramafic rocks cannot be determined. The observed W isotopic composition of mafic to ultramafic rocks in intimate contact with ancient crust should be viewed with caution in order to plate constraints on the early Hf-W isotopic evolution of the Earth's mantle with regard to late accretionary processes. Although W-182 anomalies can be erased via mixing in the convective mantle, recycling of W-182-rich crustal rocks into the mantle can produce new mantle sources with anomalous W isotopic compositions that can be tapped at much later times and, hence, this process should be considered as a mechanism for the generation of W-182-rich rocks at any subsequent time in Earth history. (C) 2016 Elsevier B.V. All rights reserved.

Canada is host to at least six separate cratons that comprise a significant proportion of its crustal extent. Of these cratons, we possess knowledge of the cratonic lithospheric roots beneath only the Slave craton and, to a lesser extent, the Superior craton, despite the discovery of many new diamond-bearing kimberlites in Canada's North. Here we present the first age, composition and geothermal information for kimberlite-borne peridotite xenoliths from two localities within the central Rae craton: Pelly Bay and Repulse Bay. Our aim is to investigate the nature and evolution of the deep lithosphere in these regions and to examine how events recorded in the mantle may or may not correlate with the complex history of crustal evolution across the craton. Peridotite xenoliths are commonly altered by secondary processes including serpentinization, silicification and carbonation, which have variably affected the major element compositions. These secondary processes, as well as mantle metasomatism recorded in pristine silicate minerals, however, did not significantly modify the relative compositions of platinum-group elements (PGE) and Os isotope ratios in the majority of our samples from Pelly Bay and Repulse Bay, as indicated by the generally high absolute PGE concentrations and mantle-like melt-depleted PGE patterns. The observed PGE signatures are consistent with the low bulk Al2O3 contents (mostly lower than 2.5%) of the peridotites, as well as the compositions of the silicate and oxide minerals. Based on PGE patterns and Os model ages, the peridotites from both localities can be categorized into three age groups: Archean (3.0–2.6 Ga overall; 2.8–2.6 Ga for Pelly Bay and 3.0–2.7 Ga for Repulse Bay), Paleoproterozoic (2.1–1.7 Ga), and “Recent” (

The accretionary mobile belts surrounding ancient cratonic cores are an important facet of the growth and preservation of continental landmasses. Peridotites from Nuominhe in the Xing'an Mongolia Orogenic Belt (XMOB) provide an additional opportunity to examine the age, structure and evolution of mantle lithosphere separating two of the largest existing ancient continental nuclei: the North China Craton and the Siberian Craton. This suite of mantle rocks comprises fertile to refractory garnet- and spinel-facies harzburgites and lherzolites. Their lithophile element systematics show that the peridotites were metasomatized to variable extent by silicate‑carbonate melts. Despite this, the highly siderophile element and Os isotope systematics appear to have been largely undisturbed. The Nuominhe peridotites have Re-depletion Os model ages (TRD) that range from 0.5 Ga to 2.4 Ga, with three peaks/major ranges at ~2.0–2.4 Ga, ~1.4–1.5 Ga and ~ 0.8 Ga, of which the latter two are closely similar to those data from other XMOB localities reported in the literature. The only section of the mantle that appears to have ages which correlate with crust formation is the suite with Neoproterozoic (~0.8 Ga) depletion ages, while the older mantle domains document older episodes of mantle depletion. Given the lack of correlation between equilibrium temperatures and bulk composition or TRD ages, the Nuominhe peridotites were inter-mixed in the mantle column, most likely as a result of incorporation of recycled older continental mantle fragments into juvenile Neoproterozoic mantle during the orogenic processes responsible for new lithosphere formation. Geothermobarometry of the Nuominhe peridotites indicates a conductive geotherm of ~60 mWm−2 and therefore a lithosphere thickness of ~125 km, which is thicker than most Phanerozoic continental terranes, and even thicker than Proterozoic regions that comprise the larger cratonic unit of the Siberian craton. This thick Proterozoic lithosphere sandwiched between the converging North China and Siberian cratons was evidently partly constructed from recycled refractory continental mantle fragments, perhaps extant in the convecting mantle, or in-part derived from the surrounding cratons, leading to a composite nature of the mantle in this re-healed continental suture. Re-accretion of recycled refractory old continental mantle fragments plays a significant role in affecting mantle composition and controlling the thickness of circum-cratonic landmasses between cratonic blocks.

Geothermal energy is one of the keys for understanding the mechanisms driving the plate tectonics and mantle dynamics. The surface heat flux, as measured in boreholes, provides limited insights into the relative contributions of primordial versus radiogenic sources of the interior heat budget. Geoneutrino, electron antineutrino that is produced from the radioactive decay of the heat producing elements, is a unique probe to obtain direct information about the amount and distribution of heat producing elements in the crust and mantle. Cosmochemical, geochemical, and geodynamic compositional models of the Bulk Silicate Earth (BSE) individually predict different mantle neutrino fluxes, and therefore may be distinguished by the direct measurement of geoneutrinos. Due to low counting statistics, the results from geoneutrino measurements at several sites are inadequate to resolve the geoneutrino flux. However, the JUNO detector, currently under construction in South China, is expected to provide an exciting opportunity to obtain a highly reliable statistical measurement, which will produce sufficient data to address several vital questions of geological importance. However, the detector cannot separate the mantle contribution from the crust contribution. To test different compositional models of the mantle, an accurate a-priori estimation of the crust geoneutrino flux based on a three-dimensional (3-D) crustal model is important. This paper presents a 3-D crustal model over a surface area of 10° × 10° grid surrounding the JUNO detector and a depth down to the Moho discontinuity, based on the geological, geophysical and geochemical properties. This model provides a distinction of the thickness of the different crustal layers together with the corresponding Th and U abundances. We also present our predicted local contribution to the total geoneutrino flux and the corresponding radiogenic heat. Compared to previous studies where the surface layer is subdivided into a few geologic units and each of them is considered to have the same geochemical property, our method has provided an effective approach to reduce the uncertainty of geoneutrino flux prediction by constructing the composition of the surface layer through cell by cell which are independent to each other.

Accurately dating the formation and modification of Earth’s sub-cratonic mantle still faces many challenges, primarily due to the long and complex history of depletion and subsequent metasomatism of this reservoir. In an attempt to improve this, we carried out the first study on peridotites from the Kaapvaal craton (Finsch Mine) that integrates results from Re-Os, Lu-Hf, Sm-Nd and Sr-isotope systems together with analyses of major-, trace- and platinum-group elements. The Finsch peridotites are well-suited for such a study because certain compositional features reflect they were highly depleted residues of shallow melting (1.5 GPa) at ambient Archean mantle temperatures. Yet, many of them have overabundant orthopyroxene, garnet and clinopyroxene compared to expected modal amounts for residues from partial melting. Finsch peridotites exhibit a wide range of rhenium depletion ages (TRD) from present day to 2.7 Ga, with a prominent mode at 2.5 Ga. This age overlaps well with a Lu-Hf isochron of 2.64 Ga (eHf (t) = +26) which records silico-carbonatitic metasomatism of the refractory residues. This late Archean metasomatism is manifested by positive correlations of Pt/Ir and Pd/Ir with 187Os/188Os ratios and good correlations of modal amounts of silicates, especially garnet, with Os isotope ratios. These correlations suggest that the Highly Siderophile Elements (HSE) and incompatible element reenrichment and modal metasomatism result from one single major metasomatic event at late Archean. Our detailed study of Finsch peridotites highlights the importance of using multiple isotopic systems, to constrain the ages of events defining the evolution of lithospheric mantle. The Re-Os isotope system is very effective in documenting the presence of Archean lithosphere, but only the oldest TRD ages may accurately date or closely approach the age of the last major partial melting event. For a meaningful interpretation of the Re-Os isotope systematics the data must be combined with HSE patterns, trace-element compositions and ideally other isotopic systems, e.g. Lu-Hf. This is highlighted by the widespread evidence in Finsch peridotites of Pt, Pd and Re enrichment through significant Base Metal Sulfide (BMS) addition (mainly in the range of 0.002–0.08 wt%) that systematically shifts the mode of TRD model ages to younger ages.

Genetic contributions to the final stages of planetary growth, including materials associated with the giant Moon-forming impact, late accretion, and late heavy bombardment are examined using siderophile elements. Isotopic similarities between the Earth and Moon for both lithophile and siderophile elements collectively lead to the suggestion that the genetics of the building blocks for Earth, and the impactor involved in the Moon-forming event were broadly similar, and shared some strong genetic affinities with enstatite chondrites. The bulk genetic fingerprint of materials subsequently added to Earth by late accretion, defined as the addition of similar to 0.5 wt.% of Earth's mass to the mantle, following cessation of core formation, was characterized by Os-187/Os-188 and Pd/Ir ratios that were also similar to those in some enstatite chondrites. However, the integrated fingerprint of late accreted matter differs from enstatite chondrites in terms of the relative abundances of certain other HSE, most notably Ru/Ir. The final = 0.05 wt.% addition of material to the Earth and Moon, believed by some to be part of a late heavy bombardment, included a component with much more fractionated relative HSE abundances than evidenced in the average late accretionary component. Heterogeneous W-182/(184)Wisotopic compositions of some ancient terrestrial rocks suggest that some very early-formed mantle domains remained chemically distinct for long periods of time following primary planetary accretion. This evidence for sluggish mixing of the early mantle suggests that if late accretionary contributions to the mantle were genetically diverse, it may be possible to isotopically identify the disparate primordial components in the terrestrial rock record using the siderophile element tracers Ru and Mo. (C) 2015 Elsevier B.V. All rights reserved.