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The geochemical characterization of the mine deposits and soils in metal mining areas is essential in order to develop an effective mine reclamation strategy. The determination of total potentially toxic element (PTE) content, together with the application of chemical extraction procedures, can give insight into the behavior of contaminants after the application of different mine reclamation solutions, as well as identify the areas where urgent action is needed. This work presents a practical application to the evaluation of the pollution potential of trace elements in soils affected by mining activities, to be used in metallic mine reclamation. The PTE behavior was assessed by single extractions in order to simulate four environmental conditions: PTE mobility under rainfall conditions, acid mine drainage, reducing conditions, and plant uptake. The spatial distribution of contaminants in the study area was evaluated by determination of PTE total content in soil samples. Trace elements with high natural mobility, such as Zn, appeared concentrated at water and sediment discharge areas, while As, Pb, and Cu contents were higher near the mine wastes. The results obtained after the extractions suggested that the highest PTE content was extracted in the complexing–reducing medium, due to the dissolution of secondary sulfates and Fe3+ oxyhydroxides and the subsequent release of PTEs associated with those mineral phases. Reclamation strategies applied in the study area should promote efficient water drainage, infiltration, and subsuperficial water circulation in order to maintain oxidant conditions in the soil. The methodology applied in this study may constitute a valuable tool to define the geochemical constraints in metal mining areas, as well as help to develop appropriate mine reclamation solutions.

Fluvial geomorphic approaches for reclamation landform design have been applied since 2000, mostly in mined lands, as an alternative to conventional landform design methods. Those approaches aim to reconstruct mature landforms and drainage networks that would develop within a natural catchment, after thousands of years of work performed by geomorphic processes. Some fluvial geomorphic design methods take specific measurements from natural and stable reference areas for initial input values for reclamation design. Valid reference areas can be difficult to find, can be in highly anthropized environments, or may be difficult to access. This paper evaluates the use of remote sensing tools to measure morphometric parameters in upper sections of agricultural land catchments considered for use as reference areas. The ridge to head of channel distance (Xrh) was the parameter of interest. We used land surface profiles developed from LiDAR (Laser Imaging Detection and Ranging) data and planimetric measurements from orthoimages to estimate Xrh. The results obtained by the two methods were encouraging but showed a significant difference. Ground truthing showed that ploughing obliterated between 19.5 and 22.4 m (on average) of the headwater section of first-order channels, reducing the channel length by 15.1 to 32.4%. Using a greater Xrh value than appropriate for near steady-state conditions as a design input for a geomorphic reclamation project would be expected to result in active erosion processes in the constructed reclamation to regain their missing channel length. We recognize the advantages and limitations of remote sensing methods for measuring the morphometric parameters of the landform relief design inputs. We show how these tools may be used to help select and prioritize reference areas, and warn about the use of disturbed landscapes as reference areas to assure the geomorphic stability of the constructed reclamation designs.

The research on tailings deposits regarding geomorphic approaches, aeolian activity and integrated physical–chemical dynamics and instability is almost inexistent. This work performs such analysis at the San Quintín Mine site, located on the Alcudia Valley region of central-south Spain. The first evidence of mining activity on San Quintín goes back to 1559 and the last one to 1988. The mine activity here produced two very different deposits. ‘Old tailings’ correspond to early concentration procedures between 1889 and 1923. The resulting piles look chaotic and the tailings vertically and laterally alternate with rock wastes. These deposits have been eroded, mostly, by fluvial processes. ‘Modern tailings’ deposits correspond to more efficient froth flotation treatments, between 1973 and 1988, when part of the old tailings were reprocessed. The grain size of these latter tailings is more homogenous, mostly sandy, which favour intense aeolian erosion. By means of a detailed inventory, we were able to identify and catalogue both fluvial and aeolian landforms, along with those produced by weathering or mass movement. We also quantified aeolian erosion, obtaining a single net wind transport rate of 12.6 t ha−1 year−1, related to WSW winds. From an understanding of the geomorphic activity of the mined area, we propose guidelines for the restoration and remediation of the site, comprising wind erosion prevention measures for the modern tailings and physical stabilization through geomorphic restoration for the old tailings, combined with chemical remediation measures that have been proved useful on similar cases: open limestone channels connected to constructed wetlands., This study has been funded by: (1) Project CGL2015-67644-R (Spanish Ministry of Economy and Competitiveness) (2) The Ecological Restoration Network REMEDINAL-3 of the Madrid Community (S2013/MAE-2719).

This work presents an integral methodological approach to assess the environmental potential hazards posed by metals and metalloids hosted by spolic technosols derived from old tailings from a mining operation for galena (PbS, with high Ag contents)-sphalerite (ZnS, with a varied cohort of trace elements contents) in central Spain. We studied the total and soluble concentrations and spatial distribution of Pb, Zn, Cd, As, and Fe and the mineralogy of these soils, as well as an ecotoxicological evaluation by means of bioassays. The indices assessing soil contamination such as pollution load index (PI) and natural mobility index (NMI) have been calculated. Furthermore, the phytotoxic effect of the soil samples has been determined and a chronic sediment toxicity test using the benthic ostracod Heterocypris incongruens was applied. The geochemical study of 33 spolic technosols samples indicates large to extremely large metal and metalloid total contents: up to 48,600 mg kg&minus, 1 Pb, 34,000 mg kg&minus, 1 Zn, 500 mg kg&minus, 1 Cd, and 1000 mg kg&minus, 1 As. Given that sphalerite is usually the most important host mineral for cadmium in hydrothermal mineral deposits, there is a high correlation (R = 0.75) between this element and Zn. On the other hand, despite being two metallogenically intertwined elements in ore deposits, Pb and Zn show a less significant relationship, which can be attributed both to heterogeneities in the mineralogical composition of the veins, and to the complex history of the mineral concentration process: In the older process, the interest was only for Pb, meanwhile in the late period, the interest was focused in Zn. The Phytotoxkit&reg, bioassay showed that soils with high PTEs presented very high toxicity, particularly the inhibition germination is related to Pb, As, and Cd content and root inhibition with Pb content. Both indexes were correlated with pH and electrical conductivity, samples with lower pH and higher soluble salt content are those with higher seed germination inhibition and root growth inhibition. On the other hand, the Ostracodtoxkit&reg, bioassay showed very high sensitivity, with 100% mortality. The applied bioassays confirmed the soil toxicity and it is highly recommended to complement the results from environmental chemistry with results from bioassays, in order to provide a more complete and relevant information on the bioavailability of contaminants and to characterize the risk of contaminated areas.