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A Bessel beam has the properties of propagation invariance and a self-healing effect, leading to a variety of interesting phenomena and applications. Recently, as a planar diffractive element with miniaturized size, metasurfaces are widely employed to manipulate light in the subwavelength region, including generating a Bessel beam. However, such a metasurface-generated Bessel beam allows output light with no tunable functions. Here, with the interplay of the geometric phase and the dynamic phase, we propose a method to generate and allow conversion from any orthogonal polarizations to independent Bessel beams with a single-layer dielectric metasurface. The simulation results indicate that the arbitrary conversion between different Bessel beams is related to the spin-dependent orbit motion caused by the tight-focusing effect, leading to the singularity of the spot. This physical mechanism is well studied and the theoretical model for revealing the dependence of different incident polarization on the conversion dynamics is presented. Our approach paves a way for efficient generation and multifunctional applications, ranging from high-numerical-aperture devices to compact nanophotonic platforms for spin-dependent structured beams.

We report the electrochemical applications of hybrid iodobismuthates [C3H5N2]3[Bi2I9] (IMB), [C2H4N3S][BiI4] (ADB) and [C3H5N2S][BiI4] (ATB), as a new type of environmentally-friendly anode for lithium-ion batteries. The materials show impressive Li-storage capacities along with very good rate capabilities and stability. The excellent properties of ATB, ADB and IMB indicate that further development and optimisation of this new family may be possible by further cation tuning within the series.

Metalens, a prominent application of two-dimensional metasurfaces, has demonstrated powerful abilities even beyond traditional optical lenses. By manipulating the phase distribution of metalens composed of appropriately arranged nanoscale building blocks, the wavefront of incident wave can be controlled based on Huygens principle, thus achieving the desired reflected and transmitted wave for many different purposes. Metalenses will lead a revolution in optical imaging due to its flat nature and compact size, multispectral acquisition and even off-axis focusing. Here, we review the recent progress of metalenses presenting excellent properties, with a focus on the imaging application using these metalenses. We firstly discuss the mechanism for achieving metalenses with high efficiency, large numerical aperture, controlling the chromatic dispersion or monochromatic aberrations and large area fabrication. Then, we review several important imaging applications including wide-band focusing imaging, polarization dependent imaging, light field imaging and some other significant imaging systems in different areas. Finally, we make a conclusion with an outlook on the future development and challenges of this developing research field.

Two organic–inorganic iodobismuthates, C5H6NBiI4 ([py][BiI4]) and C6H8NBiI4 ([mepy][BiI4]), have been prepared with their structures revealed by single-crystal X-ray diffraction. One-dimensional BiI4− anionic chains built by edge-sharing BiI6 octahedra were found in both materials; short I⋯I, I⋯C contacts and hydrogen bonding give rise to three-dimensional intermolecular interactions. Both compounds are semiconductors, with band gaps of around 2.0 eV, and the contribution from the organic moieties to the conduction band minimum has been derived by density functional theory. Solid-state optical and electrochemical studies performed on powders and thin films were carried out, and their stabilities under an ambient environment have been demonstrated. Their use as the absorber layer in printable mesoscopic solar cells without any hole transport material has led to efficiencies up to 0.9%, showing a promising new approach towards the development of lead-free third-generation photovoltaic materials.

To meet the requirement of high molar extinction coefficient, broad absorption spectrum, and photo/thermal stability for sensitizers of quasi-solid-state dye-sensitized solar cells (Qs-DSSCs) with reduced film thickness, a novel D-A-π-A configuration organic sensitizer IQ22 was specifically designed, in which the conjugation bridge of cyclopentadithiophene (CPDT) unit was incorporated to widen the light response and enhance molar coefficients for increasing the short-circuit current density (JSC), and the octane chain on CPDT was targeted for suppressing the charge recombination and improving the open-circuit voltage (VOC). As a result, the Qs-DSSC based on IQ22 exhibits very promising conversion efficiency as high as 8.76%, with a JSC of 18.19 mA cm–2, a VOC of 715 mV, and a fill factor (FF) of 0.67 under AM 1.5 illumination (100 mW cm–2), standing out in the Qs-DSSCs utilizing metal-free organic sensitizers.

Metasurfaces are 2D metamaterials composed of subwavelength nanoantennas according to specific design. They have been utilized to precisely manipulate various parameters of light fields, such as phase, polarization, amplitude, etc., showing promising functionalities. Among all meta-devices, the metalens can be considered as the most basic and important application, given its significant advantage in integration and miniaturization compared with traditional lenses. However, the resonant dispersion of each nanoantenna in a metalens and the intrinsic chromatic dispersion of planar devices and optical materials result in a large chromatic aberration in metalenses that severely reduces the quality of their focusing and imaging. Consequently, how to effectively suppress or manipulate the chromatic aberration of metalenses has attracted worldwide attention in the last few years, leading to variety of excellent achievements promoting the development of this field. Herein, recent progress in chromatic dispersion control based on metalenses is reviewed.

Distributed polarization coupling detection can be used for force sensing of polarization-maintaining fiber (PMF). In this paper, finite element analysis (FEA) is adopted to simulate the distributed polarization coupling force sensing of PMF. The initial thermal stress birefringence produced by the drawing process of PMF is simulated. In addition, the polarization coupling strength of PMF under transverse forces is analyzed. Also, the position of the dynamic force coupling point in a distributed white light interference (WLI) system is demodulated. The experimental results from a WLI system are in agreement with the FEA results. FEA is an effective numerical analysis method which can be used in the entire process of PMF production, force analysis, and sensing demodulation.

The chromatic aberration of metasurfaces limits their application. How to cancel or utilize the large chromatic dispersion of metasurfaces becomes an important issue. Here, we design Si-based metasurfaces to realize flexible chromatic dispersion manipulation in mid-infrared region. We demonstrate the broadband achromatic metalens and achromatic gradient metasurface to cancel the chromatic aberration over a continuous bandwidth (8–12 μm). In contrast, the metalens and gradient metasurface with enhanced chromatic dispersion have also been realized, where the focal length and deflection angle with different wavelengths vary more significantly than the conventional devices designed with geometric phase. These demonstrations indicate promising potential applications.

We report on the synthesis, crystal structures, optoelectronic properties and solar cell device studies of three novel organic-inorganic iodobismuthates -- [C3H4NS]3[Bi2I9] ([TH]3[Bi2I9]), [C3H4N2]3[Bi2I9] ([IM]3[Bi2I9]) and [C3H5N2S][BiI4] ([AT][BiI4]) as lead-free light harvesters. [TH]3[Bi2I9] and [IM]3[Bi2I9] show zero-dimensional structures, whereas a one-dimensional edge-sharing chain structure of BiI6-octahedra was observed in [AT][BiI4], with interchain short I…I contacts also giving rise to the possibility of three-dimensional charge transport ability. Accordingly, greater energy dispersion in the band structure of [AT][BiI4] can be observed, and less contribution from the organic moities at the conduction band minimum in [AT][BiI4] than [TH]3[Bi2I9] have been confirmed by density functional theory calculations. Moreover, bandgap values are redshiffted from 2.08 eV for [TH]3[Bi2I9] and 2.00 eV for [IM]3[Bi2I9] to 1.78 eV for [AT][BiI4], determined by UV-Vis reflectance spectroscopy. Power conversion efficiency of 0.47% has been achieved by using ([AT][BiI4]) as the light absorber in a hole-conductor-free, fully printable solar cell, with relatively good reproducibility. We also note the observation of a capacitance effect for the first time in a photovoltaic device with bismuth-based solar absorber, which may be related to the mesoporous carbon counter-electrode.

Recently, enormous research passion has been devoted to enhance the power conversion efficiency (PCE) of porphyrin sensitizers for dye-sensitized solar cells (DSSCs), but the major stumbling block is the absorption defect in the visible-light region. To address this challenge, high-performance DSSCs are reported based on a new donor-π-acceptor sensitizer FW-1, 7H-dibenzo[c,g]carbazole-substituted and fused zinc porphyrin, co-sensitized with a benzotriazole-containing dye (WS-5) in iodine and cobalt redox systems, and high PCEs of 10.21 and 10.42 %, respectively, were obtained. An unprecedented breakthrough was obtained by making one sensitizer suitable for several electrolyte systems because of its appropriate molecular orbitals and co-sensitizer.