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Objectives : Volatile organic compounds discharged from industrial complexes need to be managed. They make PM, O3 etc from NOx and photochemical reaction in the atmosphere and become a major source of odor.Methods : The environmental impacts around Sasang industrial area and Shinpyeong-Jangrim general industrial complex were investigated by SIFT-MS, which can continuously real-time measure air pollutants such as volatile organic compounds. A map of air pollution around industrial complexes was drawn up and major impact substances were identified.Results and Discussion : Benzene was all within the atmospheric standard and hexane was the highest concentration. Alkane, aldehyde and alcohol groups were relatively high in Sasang industrial area. Amide and thiol groups were relatively high in Shinpyeong-Jangrim general industrial complex. Most of volatile organic compounds were high in May, and some odorous substances were high in summer. The pollution map of Sasang industrial area was high around Nakdong-daero and Gamjeoncheon. And the pollution map of Shinpyeong-Jangrim general industrial complex was various according to the source of discharge, but the northern point with dyeing wastewater treatment plant was relatively high. The correlation between PM-2.5 and VOCs was investigated at a low value, and further research on fixed points should be conducted.Conclusions : As a result of analyzing 84 types of SIFT-MS and 2 types of OPC, most items in Sasang industrial area were higher concentration than those in Shinpyeong-Jangrim general industrial complex.

Volatile organic compounds are released by different sources causing air pollution. Moreover, some of these carbon-based organic chemicals are considered as biomarkers in the exhaled breath of individuals and can be used to identify various kinds of diseases. Hence, the increasing demand to control air quality and human health has promoted the development of monitoring systems based on high-performance gas sensing structures. This review highlights the achievements in sensing technologies for the detection of volatile organic compounds. Particularly, chemiresistive gas sensors and detection systems based on the terahertz spectroscopy method are outlined. The progress in research studies is discussed and the potential of both techniques is evaluated considering the current challenges. Afterward, a brief summary is also provided along with the advances and issues for future investigations and the manufacturing of highly sensitive and selective monitoring systems.

Graphical abstract, Highlights • The FIR can effectively remove bioaerosols, odors and VOCs simultaneously. • Compounds with different levels of hydrophobicity were degraded in different units. • The BF and AZ are complementary in particle size adsorption of bioaerosols. • Health risks are associated with H2S rather than with bioaerosols at the outlet., Biological control of odors and bioaerosols in wastewater treatment plants (WWTPs) have gained more attention in recent years. The simultaneous removal of odors, volatile organic compounds (VOCs) and bioaerosols in each unit of a full-scale integrated-reactor (FIR) in a sludge dewatering room was investigated. The average removal efficiencies (REs) of odors, VOCs and bioaerosols were recorded as 98.5 %, 94.7 % and 86.4 %, respectively, at an inlet flow rate of 5760 m3/h. The RE of each unit decreased, and the activated carbon adsorption zone (AZ) played a more important role as the inlet flow rate increased. The REs of hydrophilic compounds were higher than those of hydrophobic compounds. For bioaerosols, roughly 35 % of airborne heterotrophic bacteria (HB) was removed in the low-pH zone (LPZ) while over 30 % of total fungi (TF) was removed in the neutral-pH zone (NPZ). Most bioaerosols removed by the biofilter (BF) had a particle size larger than 4.7 μm while bioaerosols with small particle size were apt to be adsorbed by AZ. The microbial community in the BF changed significantly at different units. Health risks were found to be associated with H2S rather than with bioaerosols at the FIR outlet.

Graphical abstract, Highlights • Exposure to volatile organic compounds represents a threat for workers' health and safety, even using protective equipment. • Spray-painting exposure is at higher risk than roller-painting. • Exposure to organic solvents may induce DNA and RNA oxidation, urine metabolite excretion and miRNA up- or down-regulation. • miR-589-5p and miR-941, miR-146b-3p and miR-27a-3p have been identified as potential biomarkers of effect in exposed workers. • KEGG pathway analysis showed that miRNA-1, related to lung cancer, is significantly downregulated in exposed workers., In the framework of a project aimed at finding novel predictive biomarkers of VOCs exposure-related diseases, the effect of exposure to ethylbenzene, toluene, and xylene has been analyzed in a group of painters (spray- and roller-painters) working in the shipyard industry. Airborne levels of solvents were higher in spray- than in roller-painters, and comparable to the Occupational Exposure Limits (OELs), particularly for toluene and xylene. The urinary concentration of each volatile organic compound (VOC) and of the corresponding metabolites were also concurrently measured. A set of oxidative stress biomarkers, i.e., the products of DNA and RNA oxidation, RNA methylation, and protein nitration, were measured, and found significantly higher at the end of the work shift. MicroRNA (MiRNA) expression was analyzed in the VOC-exposed workers and in a control group, finding 56 differentially expressed (DE) miRNAs at a statistically significant level (adjusted p ≤ 0.01). The Receiver-Operating Characteristic curves, computed for each identified miRNA, showed high sensitivity and specificity. A pathway analysis in the Kyoto Encyclopedia of Genes and Genomes (KEGG) showed that miRNA-1, which was found downregulated in exposed workers, is involved in the lung cancer oncogenesis. A subset of 10 miRNAs (out of the 56 DE) was selected, including those with the highest correlation to the urinary dose biomarkers measured at the end of work-shift. Multivariate ANOVA analysis showed a statistically significant correlation between the urinary dose biomarkers (both the VOCs urinary concentration and the VOCs’ metabolite concentration), and the identified miRNA subset, indicating that the exposure to low VOC doses may be sufficient to activate the miRNA response. Four miRNAs belonging to the subset strongly related to the VOCs and VOCs’ metabolites concentration were individuated, miR-589-5p, miR-941, miR-146b-3p and miR-27a-3p, with well-known implications in oxidative stress and inflammation processes.

To locate mating partners and essential resources such as food, oviposition sites and shelter, insects rely to a large extent on chemical cues. While most research has focused on cues derived from plants and insects, there is mounting evidence that indicates that micro‐organisms emit volatile compounds that may play an important role in insect behaviour. In this study, we assessed how volatile compounds emitted by phylogenetically diverse bacteria affected the olfactory response of the primary parasitoid Aphidius colemani and one of its secondary parasitoids, Dendrocerus aphidum. Olfactory responses were evaluated for volatile blends emitted by bacteria isolated from diverse sources from the parasitoid's habitat, including aphids, aphid mummies and honeydew, and from the parasitoids themselves. Results revealed that A. colemani showed a wide variation in response to bacterial volatiles, ranging from significant attraction over no response to significant repellence. Our results further showed that the olfactory response of A. colemani to bacterial volatile emissions was different from that of D. aphidum. Gas chromatography‐mass spectrometry analysis of the volatile blends revealed that bacterial strains repellent to A. colemani produced significantly higher amounts of esters, organic acids, aromatics and cycloalkanes than attractive strains. Strains repellent to D. aphidum produced significantly higher amounts of alcohols and ketones, whereas the strains attractive to D. aphidum produced higher amounts of the monoterpenes limonene, linalool and geraniol. Overall, our results indicate that bacterial volatiles can have an important impact on insect olfactory responses, and should therefore be considered as an additional, so far often overlooked factor in studying multitrophic interactions between plants and insects. A free Plain Language Summary can be found within the Supporting Information of this article. ispartof: FUNCTIONAL ECOLOGY vol:34 issue:2 pages:507-520 status: published

Lung cancer is characterized by a tremendously high mortality rate and a low 5-year survival rate when diagnosed at a late stage. Early diagnosis of lung cancer drastically reduces its mortality rate and improves survival. Exhaled breath analysis could offer a tool to clinicians to improve the ability to detect lung cancer at an early stage, thus leading to a reduction in the associated survival rate. In this paper, we present an electronic nose for the automatic analysis of exhaled breath. A total of five a-specific gas sensors were embedded in the electronic nose, making it sensitive to different volatile organic compounds (VOCs) contained in exhaled breath. Nine features were extracted from each gas sensor response to exhaled breath, identifying the subject breathprint. We tested the electronic nose on a cohort of 80 subjects, equally split between lung cancer and at-risk control subjects. Including gas sensor features and clinical features in a classification model, recall, precision, and accuracy of 78%, 80%, and 77% were reached using a fourfold cross-validation approach. The addition of other a-specific gas sensors, or of sensors specific to certain compounds, could improve the classification accuracy, therefore allowing for the development of a clinical tool to be integrated in the clinical pipeline for exhaled breath analysis and lung cancer early diagnosis.

To evaluate the effectiveness of measures to reduce the levels of volatile organic compounds (VOCs), which are important precursors of ground-level ozone formation, the real-time monitoring data of VOCs at the urban Zhaohui supersite (ZH), the Dianshan Lake regional supersite (DSL) and the urban Yixing station (YX) in the Yangtze River Delta region were analyzed from 23 August to 15 September 2016 during the G20 Hangzhou Summit. The average mole ratios of VOCs at the three sites were 6.56, 21.33 and 19.62 ppb, respectively, which were lower than those (13.65, 27.72 and 21.38 ppb) after deregulation. The characteristics of the VOCs varied during the different control periods. Synoptic conditions and airmass transport played an important role in the transport and accumulation of VOCs and other pollutants, which affected the control effects. Using the positive matrix factorization (PMF) method in source apportionment, five factors were identified, namely, vehicle exhaust (19.66–31.47%), plants (5.59–17.07%), industrial emissions (13.14–33.82%), fuel vaporization (12.83–26.34%) and solvent usage (17.84–28.95%) for the ZH and YX sites. Factor 4 was identified as fuel vaporization + incomplete combustion (21.69–25.35%) at the DSL site. The Non-parametric Wind Regression (NWR) method showed that regional transport was the main factor influencing the VOC distribution.

Ozone and PM2.5 (all particulate matter with diameter of 2.5 µm or smaller) are currently two disturbing environmental issues in most cities of China. Black carbon (BC), mainly from incomplete combustion, is one of the most important components of PM2.5 because it can absorb light and contribute to haze pollution and global warming. Meanwhile, volatile organic compounds (VOCs) have become a major air pollutant due to their association with haze, ozone (O3), global warming and human health by direct or indirect processes. In this study, one year-long observation campaign of BC, VOCs and other conventional air pollutants was conducted in the Northern Region of the Hangzhou Bay (NRHB) in Shanghai, China. The results indicated that higher concentration of BC mainly occurred in the autumn and winter, especially in December. In December, higher BC concentrations were found when the air mass came from northwest where there is an important local freeway, or southwest where some adjacent southwest chemical industrial parks are located. Different from the characteristics of BC in urban areas reported by previous studies, the diurnal variation of BC exhibited three peaks, two of which coincided with the morning and evening rush hours which are related to the heavy diesel traffic from a nearby freeway, and the third peak was often found late at night, around 2 am, which might be associated with abnormal emissions from an industrial park or marine traffic in the ocean waterway. BC had weakly negative correlation with O3 and NO, and a strongly positive correlation with PM2.5, SO2, NO2 and NOx, which implies that some incomplete combustion sources might occur in the nearby regions. With regard to VOCs, BC had a strong positive correlation with alkane, alkenes, alkynes, aromatic and non-sulfur VOCs, particularly with aromatic organic matter. Unlike the stronger correlation with aromatics in the morning rush hours, a stronger correlation between BC and alkenes and alkynes during the evening rush hour was observed. The relationships between BC and VOCs, particularly with some specific VOCs species related to the neighboring chemical industrial park, demonstrated that the contribution of the surrounding chemical industrial parks to BC should not be neglected.

Plant-associated microbes can shape plant phenotype, performance, and productivity. Cultivation methods can influence the plant microbiome structure and differences observed in the nutritional quality of differently grown fruits might be due to variations in the microbiome taxonomic and functional composition. Here, the influence of organic and integrated pest management (IPM) cultivation on quality, aroma and microbiome of raspberry (Rubus idaeus L.) fruits was evaluated. Differences in the fruit microbiome of organic and IPM raspberry were examined by next-generation sequencing and bacterial isolates characterization to highlight the potential contribution of the resident-microflora to fruit characteristics and aroma. The cultivation method strongly influenced fruit nutraceutical traits, aroma and epiphytic bacterial biocoenosis. Organic cultivation resulted in smaller fruits with a higher anthocyanidins content and lower titratable acidity content in comparison to IPM berries. Management practices also influenced the amounts of acids, ketones, aldehydes and monoterpenes, emitted by fruits. Our results suggest that the effects on fruit quality could be related to differences in the population of Gluconobacter, Sphingomonas, Rosenbergiella, Brevibacillus and Methylobacterium on fruit. Finally, changes in fruit aroma can be partly explained by volatile organic compounds (VOCs) emitted by key bacterial genera characterizing organic and IPM raspberry fruits.

Cadophora luteo-olivacea represents a critical problem for kiwifruit in the post-harvest phase, mainly for its little note epidemiology. The study presented some results about the possibility of preserving kiwifruit from skin pitting symptoms using alternative methods to fungicides. By in vitro assays, antagonist mechanisms of action against pathogen isolates were tested. Trichoderma harzianum (Th1) showed the highest inhibitory activity against C. luteo-olivacea isolates by volatile, non-volatile, and by dual culture assay, displaying an inhibition respectively by 90%, 70.6%, and 78.8%, and with respect to Aureobasidium pullulans (L1 and L8) by 23.3% and 25.8%, 50% and 34.7%, and 22.5% and 23.6%, respectively. Further, the sensitivity on CFU and mycelial growth of C. luteo-olivacea isolates to fludioxonil, and CaCl2 was tested, displaying interesting EC50 values (0.36 and 0.92 g L−1, 22.5 g L−1, respectively). The effect of Brassica nigra defatted meal was tested as biofumigation assays and through FT-IR (Fourier-Transform Infrared) spectroscopy. The above-mentioned treatments were applied in vivo to evaluate their efficacy on kiwifruits. Our data demonstrated that alternative solutions could be considered to control postharvest pathogens such as C. luteo-olivacea.

The ZnO/Ag/cellulose composite (ZAC) with excellent photocatalytic activity of degrading benzene and phenol in VOCs has been successfully synthesized. EDS, TEM, XPS and UV-vis analyses show that the ZAC is a ternary composite. It is composed of Ag, ZnO and cellulose, where the cellulose works as the substrate to anchor the other two components. The X-ray diffraction patterns find well-crystallized ZnO nanoparticles. Multiple PL peaks in the visible region measured for ZAC, imply rich defects on ZnO. It is observed that Ag nanoparticles are mainly attached on ZnO in the composite, which would raise the separation efficiency of photogenerated electrons and holes. Photocatalytic degradation shows that ZAC is able to decompose almost 100% phenol and 19% benzene in VOCs under UV light irradiation (6 W) which is almost no harm to human body. Due to the renewable cellulose, our ternary composite ZAC imparts low-cost, easily recycled and flexible merits, which might be applied in the indoor VOCs treatment.

We investigated the effects of microbial volatile organic compounds (mVOC) emitted by Bacillus amyloliquefaciens GB03on Mentha piperita growing under different levels of NaCl stress, by evaluating their growth-promoting potential and abilityto increase salt tolerance effects. Plants were exposed to bacterial VOCs without having any physical contact with therhizobacteria. The VOCs emitted by the rhizobacteria (mVOCs) were analyzed using SPME fibers. An increase in the levelof salt concentration led to a decrease in plant growth. However, these negative effects of salinity were inhibited in theplants exposed to mVOCs. Plants grown in a saline media and exposed to GB03 VOCs had significantly better morphologicalcharacteristics and higher total chlorophyll content compared to controls. The level of endogenous jasmonic acid (JA),salicylic acid, and abscisic acid increased in salt-stressed plants compared to controls. The level of JA did not show anychange in plants grown in a saline media either exposed to mVOCs or not. In contrast, the amount of salicylic acid increasedremarkably in salt-stressed plants exposed to mVOCs compared to controls (salt-stressed plants not exposed to mVOCs),but the levels of abscisic acid decreased in salt-stressed plants exposed to mVOCs. The chromatographic analyses of themVOCs produced by salt-stressed GB03 bacteria were similar, regardless of the concentration of salt in the media wherethe bacteria were grown, although it was observed that the relative percentage of acetoin increased with salt concentration.After determining that acetoin was the main VOCs compound, we exposed plants to acetoin, which demonstrated that acetoincaused similar effects on plants grown under salt stress conditions as those exposed to GB03 mVOCs. Based on these results,the use of mVOCs from PGPR is suggested as a useful technological innovation to facilitate the growth of M. piperita insalt-stressed environments. Fil: Cappellari, Lorena del Rosario. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Biotecnología Ambiental y Salud - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Cordoba. Instituto de Biotecnología Ambiental y Salud; Argentina Fil: Banchio, Erika. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Biotecnología Ambiental y Salud - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Cordoba. Instituto de Biotecnología Ambiental y Salud; Argentina

In the last few decades, incredible advances have been made in understanding the way of communication among members of kingdom plantae. Some plants fight for their existence and try to suppress the growth of other plants, while some share resources to benefit each other for their survival. During all these processes, plants use several biotic and abiotic mediums such as root exudates, volatile organic compounds (VOCs), and light for the interactions. Plant can change its physiological behaviors, such as change in gene regulation and induction of defense mechanism, when linked with neighboring plant through common mycorrhizal networks (CMNs). Root exudates are also critical in plant–plant interaction, since they share information, shape microbial community, and mediate recourse competition. Moreover, plants have been found warning their neighbors about pathogen attack and herbivory through the release of VOCs. This review will advance the understandings of roles of various communication media from the prospective of intra- and interspecific interactions as well as kin recognition.

Anthurium is an important ornamental crop in the world market and its floral scent can enhance its ornamental value. To date, studies of the components and formation mechanism of the floral scent of Anthurium are relatively few. In this study, the scent profiles of two Anthurium varieties were measured by gas chromatograph-mass spectrometer (GC-MS). There were 32 volatile organic compounds (VOCs) identified in Anthurium&nbsp, ‘Mystral’, and the most abundant compound was eucalyptol (57.5%). Extremely small amounts of VOCs were detected in Anthurium ‘Alabama’. Compared with A. ‘Alabama’, most genes related to floral scent synthesis exhibited a higher expression in A.‘Mystral’, including AaDXS, AaDXR, AaMDS, AaHDS, AaTPS, AaDAHPS,&nbsp, AaADT2, AaPAL1, and AaPAL2. In order to produce new varieties of Anthurium with fragrance, 454 progenies of two crossbred combinations of A.&nbsp, ‘Mystral’ and A. ‘Alabama’ were obtained. Four F1 generation plants with different floral scent intensities were selected for further study. The major components of floral scent in the progenies were similar to that of the parental A.‘Mystral’ plant. The expression patterns of genes related to floral scent synthesis were consistent with the relative contents of different types of VOCs. This study revealed the profiles of volatile compounds and associated gene expression in two Anthurium cultivars and their F1 hybrids, which provided a basis for the floral scent inheritance of Anthurium andraeanum.

Peaches are climacteric and highly perishable fruits, with a short shelf life, and are prone to rapid deterioration after harvest. In this study, the chemical proprieties, aroma profile and a sensory evaluation were conducted to: (1) characterize and compare fruits of 13 different peach and nectarine cultivars, harvested at physiological maturation, and (2) assess the suitability of these cultivars, that are successfully used in long food supply chains (LFSCs), for their use in short food supply chains (SFSCs). Through statistical analysis clear differences were found among the studied cultivars, and in particular between cultivars suited to SFSCs compared to those suited for LFSCs. Results indicate that, despite all cultivars being planted in the same orchards and with the same pre-harvest management and practices, their post-harvest performances were mainly influenced by the cultivar genetic makeup. Therefore, cultivars conventionally used in SFSCs, such as “Guglielmina” and “Regina di Londa”, had the best aroma, sweetness and juiciness compared to LSCPs ones. In contrast, the LSCPs varieties showed interesting values for firmness and crunchiness.

Background The floral scents of plants play a key role in plant reproduction through the communication between plants and pollinators. Aquilegia as a model species for studying evolution, however, there have been few studies on the floral scents and relationships between floral scents and pollination for Aquilegia taxa. Methods In this study, three types of solid-phase micro-extraction (SPME) fiber coatings (DVB/PDMS, CAR/PDMS, DVB/CAR/PDMS) were evaluated for their performance in extracting volatile organic compounds (VOCs) from flowers of Aquilegia amurensis, which can contribute to the future studies of elucidating the role of floral scents in the pollination process. Results In total, 55 VOCs were identified, and among them, 50, 47 and 45 VOCs were extracted by the DVB/CAR/PDMS fiber, CAR/PDMS fiber and DVB/PDMS fibers, respectively. Only 30 VOCs were detected in A. japonica taxa. Furthermore, the relative contents of 8 VOCs were significant different (VIP > 1 and p A. amurensis and A. japonica. Conclusions The results can be applied in new studies of the relationships between the chemical composition of floral scents and the processes of attraction of pollinator. It may provide new ideas for rapid evolution and frequent interspecific hybridization of Aquilegia.

Species of Mycobacteriaceae cause disease in animals and humans, including tuberculosis and leprosy. Individuals infected with organisms in the Mycobacterium tuberculosis complex (MTBC) or non-tuberculous mycobacteria (NTM) may present identical symptoms, however the treatment for each can be different. Although the NTM infection is considered less vital due to the chronicity of the disease and the infrequency of occurrence in healthy populations, diagnosis and differentiation among Mycobacterium species currently require culture isolation, which can take several weeks. The use of volatile organic compounds (VOCs) is a promising approach for species identification and in recent years has shown promise for use in the rapid analysis of both in vitro cultures as well as ex vivo diagnosis using breath or sputum. The aim of this contribution is to analyze VOCs in the culture headspace of seven different species of mycobacteria and to define the volatilome profiles that are discriminant for each species. For the pre-concentration of VOCs, solid-phase micro-extraction (SPME) was employed and samples were subsequently analyzed using gas chromatography–quadrupole mass spectrometry (GC-qMS). A machine learning approach was applied for the selection of the 13 discriminatory features, which might represent clinically translatable bacterial biomarkers.

Infrared absorption spectroscopy is a powerful analytical tool that enables the identification of molecular species. The sensitivity of this technique, that is strongly limited by the small absorption cross-section of molecular vibration, can be greatly improved by resonant interaction with nano-antennas via the surface-enhanced infrared absorption (SEIRA) mechanism. However, most of the examples of SEIRA concern solid-state molecular layers adsorbed on the nano-antennas, while the detection of gas traces still remains elusive due to the spatial extent of the near-field that is used to amplify the molecular vibrations resonantly. Here, a hybrid system composed of a plasmonic nanoantenna array coupled with nanosized zeolite coating for detection of volatile organic compounds in the near field of the resonators is demonstrated. The concerted action of the coating and the nano-antennas enabled the authors to detect record traces of benzene (25 ppb) within 10 min. This approach may ultimately allow the fabrication of a compact system for rapid detection of pharmaceutical and biocompounds with high sensitivity and high selectivity.

Coronavirus disease 2019 (COVID-19) is probably the most commonly heard word of the last 12 months. The outbreak of this virus (SARS-CoV-2) is strongly compromising worldwide healthcare systems, social behavior, and everyone's lives. The early diagnosis of COVID-19 and isolation of positive cases has proven to be fundamental in containing the spread of the infection. Even though the polymerase chain reaction (PCR) based methods remain the gold standard for SARS-CoV-2 detection, the urgent demand for rapid and wide-scale diagnosis precipitated the development of alternative diagnostic approaches. The millions of tests performed every day worldwide are still insufficient to achieve the desired goal, that of screening the population during daily life. Probably the most appealing approach to consistently monitor COVID-19 spread is the direct detection of SARS-CoV-2 from exhaled breath. For instance, the challenging incorporation of reliable, highly sensitive, and cost-efficient detection methods in masks could represent a breakthrough in the development of portable and noninvasive point-of-care diagnosis for COVID-19. In this perspective paper, we discuss the critical technical aspects related to the application of breath analysis in the diagnosis of viral infection. We believe that, if achieved, it could represent a game-changer in containing the pandemic spread.

Inland oil spillage is one of the widespread sources of crude oil volatile organic compound emissions (CVEs) for which the long-term remedial solutions are often complex and expensive. This paper investigates the potential of a low-cost containment solution for contaminated solids by volatile organic compounds (VOCs) using biochar. The results of an extensive experimental investigation are presented on the sorption kinetics of xylene isomers (one type of the most frequently detected CVEs) on commercial biochar produced by prevalent feedstocks (wheat, corn, rice and rape straw as well as hardwood) at affordable temperatures (300–500 °C ). Chemical and physical properties of biochar were analysed in terms of elemental composition, scanning electron microscopy, specific surface area, ATR-FTIR spectra and Raman spectrometry. We show that for high-temperature biochar with similar surface chemistry, the sorption efficiency is mainly controlled by porous structure and pore size distribution. Biochar samples with higher specific surface area and higher volume of mesopores showed the highest sorption capacity (45.37–50.88 mg/g) since the sorbate molecules have more access to active sites under a greater intra-particle diffusion and elevated pore-filling. P-xylene showed a slightly higher sorption affinity to biochar compared to other isomers, especially in mesoporous biochar, which can be related to its lower kinetic diameter and simpler molecular shape. The sorption capacity of biochar produced at higher pyrolysis temperatures was found to be more sensitive to changes in ambient temperature due to dominant physical adsorption. Elovich kinetic model was found to be the best model to describe xylenes’ sorption on biochar which indirectly indicates π–π stacking and hydrogen bonding as the main mechanism of xylene sorption on these types of biochar.

Although asthma mortality has been declining for the past several decades, asthma morbidity is on the rise, largely due to deteriorating indoor air quality and comorbidities, such as allergies. Consumer products and building materials including paints emit volatile organic compounds (VOCs), such as propylene glycol (PG), which is shown to dehydrate respiratory tracts and can contributor to airway remodeling. We hypothesize that paint exposure increases the risk of asthma attacks among children because high levels of VOCs persist indoors for many weeks after painting. Children 1–15 years old visiting two of the University of Miami general pediatric clinics were screened for their history of asthma and paint exposure by interviewing their parents and/or guardians accompanying them to the clinic. They were also asked questions about asthma diagnosis, severity of asthma and allergies and their sociodemographics. The risk of asthma attack among asthmatic children was modeled with respect to paint exposure adjusting for potential confounders using multivariate logistic regressions. Of 163 children, 36 (22%) reported physician-diagnosed asthma and of these, 13 (33%) had an asthma attack during the last one year. Paint exposure was marginally significant in the univariate analysis (OR = 4.04; 95% CI = 0.90–18.87; p < 0.1). However, exposed asthmatic children were 10 times more likely to experience an asthma attack than unexposed asthmatic children (OR = 10.49; CI = 1.16–94.85, p < 0.05) when adjusted for other risk factors. Given paint is one of the sources of indoor VOCs, multiple strategies are warranted to manage the health effects of VOC exposure from paint, including the use of zero-VOC water-based paint, exposure avoidance and clinical interventions.

The chemical profile and allelopathic effect of the volatile organic compounds (VOCs) produced by a dominant shrub Serphidium kaschgaricum (Krasch.) Poljak. growing in northwestern China was investigated for the first time. Serphidium kaschgaricu was found to release volatile compounds into the surroundings to affect other plants’ growth, with its VOCs suppressing root elongation of Amaranthus retroflexus L. and Poa annua L. by 65.47% and 60.37% at 10 g/1.5 L treatment, respectively. Meanwhile, volatile oils produced by stems, leaves, flowers and flowering shoots exhibited phytotoxic activity against A. retroflexus and P. annua. At 0.5 mg/mL, stem, leaf and flower oils significantly reduced seedling growth of the receiver plants, and 1.5 mg/mL oils nearly completely prohibited seed germination of both species. GC/MS analysis revealed that among the total 37 identified compounds in the oils, 19 of them were common, with eucalyptol (43.00%, 36.66%, 19.52%, and 38.68% in stem, leaf, flower and flowering shoot oils, respectively) and camphor (21.55%, 24.91%, 21.64%, and 23.35%, respectively) consistently being the dominant constituents in all oils. Eucalyptol, camphor and their mixture exhibited much weaker phytotoxicity compared with the volatile oils, implying that less abundant compounds in the volatile oil might contribute significantly to the oils’ activity. Our results suggested that S. kaschgaricum was capable of synthesizing and releasing allelopathic volatile compounds into the surroundings to affect neighboring plants’ growth, which might improve its competitiveness thus facilitate the establishment of dominance.

Soil microorganisms are well studied for their beneficial effects on plant growth and their impact on biocontrol agents. The production of volatile antifungal compounds emitted from soil fungi is considered to be an effective ability that can be applied in biofumigants in the control of plant diseases. A soil fungus, Trichoderma asperelloides TSU1, was isolated from flamingo flower cultivated soil and identified on the basis of the morphology and molecular analysis of the internal transcribed spacer (ITS), rpb2, and tef1-α genes. To test T. asperelloides TSU1-produced volatile organic compounds (VOCs) with antifungal activity, the sealed plate method was used. The VOCs of T. asperelloides TSU1 inhibited the mycelial growth of fungal pathogens that were recently reported as emerging diseases in Thailand, namely, Corynespora cassiicola, Fusarium incarnatum, Neopestalotiopsis clavispora, N. cubana, and Sclerotium rolfsii, with a percentage inhibition range of 38.88–68.33%. Solid-phase microextraction (SPME) was applied to trap VOCs from T. asperelloides TSU1 and tentatively identify them through gas chromatography–mass spectrometry (GC/MS). A total of 17 compounds were detected in the VOCs of T. asperelloides TSU1, and the dominant compounds were identified as fluoro(trinitro)methane (18.192% peak area) and 2-phenylethanol (9.803% peak area). Interestingly, the commercial 2-phenyethanol showed antifungal activity against fungal pathogens that were similar to the VOCs of T. asperelloides TSU1 by bioassay. On the basis of our study’s results, T. asperelloides TSU1 isolated from soil displayed antifungal abilities via the production of VOCs responsible for restricting pathogen growth.

To clarify the relationship between changes in photochemical oxidants’ (Ox) concentrations and their precursors in Kawasaki, a series of analyses were conducted using data on Ox, their precursors, nitrogen oxides (NOx) and volatile organic compounds (VOCs), and meteorology that had been monitored throughout the city of Kawasaki for 30 years from 1990 to 2019. The trend in air temperature was upward, wind speed was downward, and solar radiation was upward, indicating an increasing trend in meteorological factors in which Ox concentrations tend to be higher. Between 1990 and 2013, the annual average Ox increased throughout Kawasaki and remained flat after that. The three-year moving average of the daily peak increased until 2015, and after that, it exhibited a slight decline. The amount of generated Ox is another important indicator. To evaluate this, a new indicator, the daytime production of photochemical oxidant (DPOx), was proposed. DPOx is defined by daytime averaged Ox concentrations less the previous day’s nighttime averaged Ox concentrations. The trend in DPOx from April to October has been decreasing since around 2006, and it was found that this indicator reflects the impact of reducing emissions of NOx and VOCs in Kawasaki.

Volatile organic compounds (VOCs) have been assessed in breath samples as possible indicators of diseases. The present study aimed to quantify 29 VOCs (previously reported as potential biomarkers of lung diseases) in breath samples collected from controls and individuals with lung cancer, chronic obstructive pulmonary disease and asthma. Besides that, global VOC profiles were investigated. A needle trap device (NTD) was used as pre-concentration technique, associated to gas chromatography-mass spectrometry (GC-MS) analysis. Univariate and multivariate approaches were applied to assess VOC distributions according to the studied diseases. Limits of quantitation ranged from 0.003 to 6.21 ppbv and calculated relative standard deviations did not exceed 10%. At least 15 of the quantified targets presented themselves as discriminating features. A random forest (RF) method was performed in order to classify enrolled conditions according to VOCs’ latent patterns, considering VOCs responses in global profiles. The developed model was based on 12 discriminating features and provided overall balanced accuracy of 85.7%. Ultimately, multinomial logistic regression (MLR) analysis was conducted using the concentration of the nine most discriminative targets (2-propanol, 3-methylpentane, (E)-ocimene, limonene, m-cymene, benzonitrile, undecane, terpineol, phenol) as input and provided an average overall accuracy of 95.5% for multiclass prediction.

Plant secondary metabolites (PSMs) play many roles including defense against pathogens, pests, and herbivores; response to environmental stresses, and mediating organismal interactions. Similarly, plant microbiomes participate in many of the above-mentioned processes directly or indirectly by regulating plant metabolism. Studies have shown that plants can influence their microbiome by secreting various metabolites and, in turn, the microbiome may also impact the metabolome of the host plant. However, not much is known about the communications between the interacting partners to impact their phenotypic changes. In this article, we review the patterns and potential underlying mechanisms of interactions between PSMs and plant microbiomes. We describe the recent developments in analytical approaches and methods in this field. The applications of these new methods and approaches have increased our understanding of the relationships between PSMs and plant microbiomes. Though the current studies have primarily focused on model organisms, the methods and results obtained so far should help future studies of agriculturally important plants and facilitate the development of methods to manipulate PSMs–microbiome interactions with predictive outcomes for sustainable crop productions.

NOx, COx, and volatile organic compounds (VOCs) widely exist in motor vehicle exhaust, coke oven flue gas, sintering flue gas, and pelletizing flue gas. Potassium species have an excellent promotion effect on various catalytic reactions for the treatment of these pollutants. This work reviews the promotion effects of potassium species on the reaction processes, including adsorption, desorption, the pathway and selectivity of reaction, recovery of active center, and effects on the properties of catalysts, including basicity, electron donor characteristics, redox property, active center, stability, and strong metal-to support interaction. The suggestions about how to improve the promotion effects of potassium species in various catalytic reactions are put forward, which involve controlling carriers, content, preparation methods and reaction conditions. The promotion effects of different alkali metals are also compared. The article number about commonly used active metals and promotion ways are also analyzed by bibliometric on NOx, COx, and VOCs. The promotion mechanism of potassium species on various reactions is similar; therefore, the application prospect of potassium species for the coupling control of multi-pollutants in industrial flue gas at low-temperature is described.

Volatile organic compounds (VOCs) are commonly found in consumer products, including furniture, sealants and paints. Thus, indoor VOCs have become a public health concern, especially in high-income countries (HICs), where people spend most of their time indoors, and indoor and outdoor air exchange is minimal due to a lack of ventilation. VOCs produce high levels of reaction with the airway epithelium and mucosa membrane and is linked with pulmonary diseases. This paper takes a stock of the literature to assess the strength of association (measured by effect size) between VOCs and pulmonary diseases with the focus on asthma and its related symptoms by conducting a meta-analysis. The literature was searched using the PubMed database. A total of 49 studies that measured VOCs or VOC types and pulmonary health outcomes were included in the analysis. The results of these studies were tabulated, and standard effect size of each study was computed. Most studies were conducted in high-income countries, including France (n = 7), Japan (n = 7) and the United States (n = 6). Our analysis suggests that VOCs have a medium-sized effect on pulmonary diseases, including the onset of asthma (effect size (or Cohen’s d) ~0.37, 95% confidence interval (CI) = 0.25–0.49, n = 23) and wheezing (effective size ~0.26, 95% CI = 0.10–0.42, n = 10). The effect size also varied by country, age and disease type. Multiple stakeholders must be engaged in strategies to mitigate and manage VOC exposure and its associated pulmonary disease burden.

Existing studies suggest various potential daytime sources of atmospheric nitrous acid (HONO), including photolysis surface reactions and photo-enhanced NO2 conversion on organic surfaces. However, the understanding of daytime HONO sources is still inadequate. In this study, we report the HONO formation on asphalt surfaces under various NO2, VOCs (toluene and hexane), and UV irradiance conditions using a continuous flow chamber. Although no HONO formation was found without light exposure, the light threshold for HONO formation on the asphalt surface was very low, with a total UV (TUV) of 0.7 W m−2. HONO formation on the asphalt surface was linearly dependent on NO2 up to 300 ppb in the presence of VOCs, but no HONO formation was observed with humified air and NO2. HONO production was saturated at high hydrocarbon concentrations and light intensities. The calculated first-order NO2 conversion rate to HONO on the asphalt surface was 1.2 × 10−4 s −1. The observed mean HONO emission flux was 1.3 × 109 molecules cm−2 s −1 with a similar range of those on other urban covered surfaces. The calculated vertical HONO profile using the measured HONO emission flux and 1-D steady state model revealed that the asphalt surface may account for 13% of daytime HONO in the elevated on-road pollutant concentrations in Seoul. However, we show that its HONO contribution could be much higher on real-life road surfaces directly exposed to much higher NO2 emissions from vehicle exhaust.

Coriandrum sativum L. is a medicinal and aromatic plant spread around the world, with beneficial properties that are well recognized. Both coriander seeds and leaves are used for pharmaceutical and flavoring purposes. Even though coriander seeds tend to be more popular, the leaves are receiving a consistently growing interest, especially because of popularization of Mexican, Northern African, and Indian cuisines. This increased attention brings about the necessity for providing the product with guaranteed quality, which will retain its valuable characteristics, even after post-harvest treatment. For this reason, it is highly necessary to determine reliable protocols for cilantro preservation, which usually include drying procedures, in order to identify the optimal drying treatments, a spectrum of drying techniques—convective, vacuum-microwave, and a combination of convective and vacuum-microwave—were evaluated. Cilantro-based dried products were examined from the perspectives of volatile organic constituent composition and sensory quality. After headspace solid-phase microextraction-GC/MS analysis and sensory tests, the results demonstrate that convective drying at 70 °C for 120 min followed by vacuum-microwave drying at 360 W and convective drying at 70 °C were the optimal drying methods for preserving cilantro aroma quality, while convective drying at 70 °C for 120 min followed by convective finishing drying at 50 °C decreased cilantro aroma quality.

GC-FID/MS is a powerful technique used to analyze food and beverage aromas. Volatile organic compounds (VOCs) in grape berries play an important role in determining wine quality and are affected by many factors, such as climate and soil that mainly influence their relative concentrations. Wine aroma is generated by a complex mixture of compounds, and the sensory relevance of individual VOCs is far from elucidated. Herein, the VOC content (free and glycosylated) of Cannonau grape skin and juice and of Cannonau wine collected in different areas of Sardinia is explored. Wine sensory analysis was also carried out and the relationship between sensory attributes and VOCs was investigated. Although Cannonau grapes showed the same VOC fingerprint, great variability was identified between samples, although only the differences in 2-phenylethanol and benzyl alcohol concentration in the grape skins and benzyl alcohol and a terpenoid in grape juice were significantly different according to ANOVA. The correlation between VOC content and the sensory profile highlights the role played by 2-methyl-1-butanol and 2-phenylethanol in increasing wine sensory complexity.

The association between humans and cats (Felis catus) is well known. This domestic animal is also known for its malodorous urine and feces. The complexity of the odorous urine and feces impacts human life by triggering the human sensory organ in a negative way. The objective of this research was to identify the volatile organic chemicals (VOCs) and associated odors in cat urine and feces using gas chromatography–mass spectrometry and simultaneous sensory analysis of fresh and aged samples. The solid-phase microextraction (SPME) technique was used to preconcentrate the VOCs emitted from urine or feces samples. Twenty-one compounds were identified as emitted from fresh urine, whereas 64 compounds were emitted from fresh feces. A contrasting temporal impact was observed in the emission of VOCs for urine and feces. On aging, the emission increased to 34 detected chemicals for stale urine, whereas only 12 chemicals were detected in stale feces. Not all compounds were malodorous, some compounds had a pleasant hedonic smell to the human nose. Although trimethylamine, low-molecular-weight organic acids, and ketones were contributors to the odor to some extent, phenolic compounds and aromatic heterocyclic organic N compounds generated the most intense odors and substantially contributed to the overall malodor, as observed by this study. This work might be useful to formulate cat urine and feces odor remediation approaches to reduce odor impacts.

Sampling, separation, detection, and characterization of microplastics (MPs) dispersed in natural water bodies and ecosystems is a challenging and critical issue for a better understanding of the hazards for the environment posed by such nearly ubiquitous and still largely unknown form of pollution. There is still the need for exhaustive, reliable, accurate, reasonably fast, and cost-efficient analytical protocols allowing the quantification not only of MPs but also of nanoplastics (NPs) and of the harmful molecular pollutants that may result from degrading plastics. Here a set of newly developed analytical protocols, integrated with specialized techniques such as pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS), for the accurate and selective determination of the polymers most commonly found as MPs polluting marine and freshwater sediments are presented. In addition, the results of an investigation on the low molecular weight volatile organic compounds (VOCs) released upon photo-oxidative degradation of microplastics highlight the important role of photoinduced fragmentation at a molecular level both as a potential source of hazardous chemicals and as accelerators of the overall degradation of floating or stranded plastic debris. Supplementary Information The online version contains supplementary material available at 10.1007/s11356-021-12466-z.

International audience; This study provides cultivar-specific metabolic fingerprints of volatile organic compounds in the headspace of cloudy apple juices. Cloudy juices from 47 "true to type" apple cultivars grown under identical agricultural and climatic conditions in South Tyrol, Italy, have been analysed through headspace solid-phase microextraction gas chromatography coupled with high-resolution time-of-flight mass spectrometry (HS-SPME/GC-HRTOF-MS), yielding cultivar-specific volatile organic compound (VOC) profiles. Apple cultivars included 10 old cultivars with local relevance, 18 commercial cultivars, dominating the current international market, 10 scab-resistant and 9 red-fleshed ones. The 28 most abundant VOCs were found in the whole dataset, indicating a remarkable chemodiversity within juices. The main discriminant metabolites were butyl acetate; pentyl acetate; 2-methylbutyl acetate; pentan-1-ol; hexan-1-ol; n-hexanal and (E)-2-hexenal. A principal component analysis (PCA) and a hierarchical cluster analysis (HCA) have not identified a clear separation of the analysed cultivar classes. Nevertheless, a series of scab-resistant and red-fleshed cultivars with VOC profiles similar to established commercial cultivars were identified; these data could help substituting current cultivars with more sustainable ones. On a more general basis, our study supports a knowledge-driven selection of apple cultivars for specific consumer preferences and helps appreciating the biodiversity of apples across old local and more recent (scab-resistant and red-fleshed) cultivars.

Plants produce considerable amounts of volatile organic compounds (VOCs) with several biological functions, including protection against biotic agents such as viruses and their vectors. In citrus species, these metabolites can be related with their different susceptibility/tolerance toward the Tristeza virus (CTV), one of the main biotic constraints for the citrus industry. The objective of this study was to compare the VOCs pattern from the leaves of a CTV-susceptible citrus variety such as Citrus aurantium and from three CTV-tolerant varieties: Citrus volkameriana, Carrizo citrange, and Forner-Alcaide no. 5. The VOCs emitted were analyzed via the headspace SPME method, while plant metabolites sequestered in the leaves were analyzed by heptane extraction followed by GC-MS. The results indicated that the majority of the VOCs emitted and sequestered in the leaves of the varieties tolerant and susceptible to CTV are constituted mainly by volatile terpenes (VTs) that exhibit strong qualitative/quantitative differences among the profiles of the four citrus species. In detail, the VOC emission indicated different patterns between C. aurantium and C. volkameriana and from both of them in comparison with Forner-Alcaide no. 5 and Carrizo citrange that exhibited more similarities, with the last two characterized by a higher presence of sesquiterpenes. The data obtained from the analysis of the VOCs sequestered in leaf tissues of the CTV-tolerant varieties indicated a higher presence of monoterpenes such as limonene, α-pinene, and p-cymene, known to be the main components of several plant extracts showing deterrent properties toward viruses and insect vectors. As VOC evaluation is a fast and noninvasive measure of phenotypic dynamics, allowing the association of plant phenotypes in accordance to plant disease resistance and/or stress tolerance, the possible implications of such differences in terms of tolerance grade to CTV and/or its related vectors are discussed.

International audience; The abatement of toluene was studied in a sequential adsorption-plasma catalysis (APC) process. Within this process, Hopcalite was used as bifunctional material: as adsorbent (storage stage) and as catalyst via the oxidation of adsorbed toluene (discharge stage). It was observed that the desorption and oxidation activity of the adsorbed toluene was significantly affected the process variables. In addition, the adsorption time influenced the CO2 selectivity and CO2 yield by changing the interaction between the catalyst and the plasma generated species. At least four APC sequences were performed for each examined condition suggesting that Hopcalite is very stable under plasma exposure during all the sequences. Consequently, these results could contribute to advance the plasma–catalyst system with an optimal VOC oxidation efficiency. The catalytic activity, amount of toluene adsorbed, amount of toluene desorbed and product formation have been quantified by FT-IR. Moreover, the catalyst was characterized by XRD, H2-TPR, N2 adsorption–desorption analysis and XPS. Hopcalite shows a good CO2 selectivity and CO2 yield when the APC process is performed with an adsorption time of 20 min and a plasma treatment with a discharge power of 46 W which leads to a low energy cost of 11.6 kWh·m−3 and energy yields of toluene and CO2 of 0.18 (±0.01) g·kWh−1 and 0.48 (±0.06) g·kWh−1 respectively.; La dépollution du toluène a été étudiée dans un processus séquentiel d'adsorption et de catalyse par plasma (APC). Dans ce procédé, l'hopcalite a été utilisée comme matériau bifonctionnel : comme adsorbant (étape de stockage) et comme catalyseur via l'oxydation du toluène adsorbé (étape de décharge). Il a été observé que l'activité de désorption et d'oxydation du toluène adsorbé était significativement affectée par les variables du procédé. En outre, le temps d'adsorption influence la sélectivité et le rendement du CO2 en modifiant l'interaction entre le catalyseur et les espèces générées par le plasma. Au moins quatre séquences APC ont été réalisées pour chaque condition examinée, suggérant que l'Hopcalite est très stable sous exposition au plasma pendant toutes les séquences. Par conséquent, ces résultats peuvent contribuer à améliorer les systèmes plasma-catalyseur pour une efficacité optimale d'oxydation des COV. L'activité catalytique, la quantité de toluène adsorbée, la quantité de toluène désorbée et la formation de produits ont été quantifiées par FT-IR. De plus, le catalyseur a été caractérisé par XRD, H2-TPR, analyse d'adsorption-désorption de N2 et XPS. L'hopcalite montre une bonne sélectivité et un bon rendement en CO2 lorsque le processus APC est réalisé avec un temps d'adsorption de 20 min et un traitement plasma avec une puissance de décharge de 46 W, ce qui conduit à un faible coût énergétique de 11,6 kWh-m-3 et à des rendements énergétiques du toluène et du CO2 de 0,18 (±0,01) g-kWh-1 et 0,48 (±0,06) g-kWh-1 respectivement.

Aroma is an essential trait in melon fruit quality, but its complexity and genetic basis are still poorly understood. The aim of this study was the identification of quantitative trait loci (QTLs) underlying volatile organic compounds (VOCs) biosynthesis in melon rind and flesh, using a Recombinant Inbred Line (RIL) population from the cross ‘Piel de Sapo’ (PS) × ‘Védrantais’ (VED), two commercial varieties segregating for ripening behavior. A total of 82 VOCs were detected by gas chromatography–mass spectrometry (GC–MS), and 166 QTLs were identified. The main QTL cluster was on chromosome 8, collocating with the previously described ripening-related QTL ETHQV8.1, with an important role in VOCs biosynthesis. QTL clusters involved in esters, lipid-derived volatiles and apocarotenoids were also identified, and candidate genes have been proposed for ethyl 3-(methylthio)propanoate and benzaldehyde biosynthesis. Our results provide genetic insights for deciphering fruit aroma in melon and offer new tools for flavor breeding., This work was supported by the Spanish Ministry of Economy and Competitiveness grants AGL2015–64625-C2–1-R and RTI2018-097665-B-C2, the Severo Ochoa Programme for Centres of Excellence in R&D 2016-2010 (SEV-2015-0533), the CERCA Programme/Generalitat de Catalunya and 2017 SGR 1319 grant from the Generalitat de Catalunya to JGM. The authors also wish to thank the support of the Secretaria d'Universitats i Recerca del Departament d'Empresa i Coneixement de la Generalitat de Catalunya for having funded the 2019 FI_B 00124 project, and the co-funding of the European Social Fund (ESF – “ESF is investing in your future”) from the European Union.

Breath analysis is an alternative approach for disease diagnosis and for monitoring therapy. The lack of standardized procedures for collecting and analysing breath samples currently limits its use in clinical practice. In order to overcome this limitation, the ‘Peppermint Consortium’ was established within the breath community to carry out breath wash-out experiments and define reference values for a panel of compounds contained in the peppermint oil capsule. Here, we present a needle trap micro-extraction technique coupled with gas chromatography and tandem mass spectrometry for a rapid and accurate determination of alpha-pinene, beta-pinene, limonene, eucalyptol, menthofuran, menthone, menthol and menthyl acetate in mixed breath samples. Detection limits between 1 and 20 pptv were observed when 25 ml of a humidified standard gas mixture were loaded into a needle trap device at a flow rate of 10 ml min−1. Inter- and intra-day precisions were lower than 15%, thus confirming the reliability of the assay. Our procedure was used to analyse breath samples taken from a nominally healthy volunteer who was invited to swallow a 200 mg capsule of peppermint oil. Six samples were collected at various times within 6 h of ingestion. Analyte concentrations were not affected by the sampling mode (i.e. mixed vs. end-tidal fraction), whereas respiratory rate and exhalation flow rate values slightly influenced the concentration of the target compounds in breath samples.

International audience; Biological treatments are used in gas treatment when containing Volatile Organic Compounds (VOC). Key factor to enhance treatment efficiency is to maximize mass transfer from gas to liquid. VOCs can be removed from the gas flow by absorption in a separate gas–liquid contactor before entering a Two-Phase Partitioning Bioreactor (TPPB) (Two-stage unit). The Non-Aqueous Phase Liquid (NAPL), a silicone oil in this study, is able to solubilize large amounts of hydrophobic VOCs while avoiding toxicity effects on the microorganisms. The aim of this study is to provide a designing tool for the degradation process occurring in the TPPB. Simulations considering mass transfer coupled with biodegradation kinetics were considered when investigating the TPPB mechanisms. A single VOC (toluene) was first taken as a reference to assess the accuracy of the model in comparison with experimental results. A mixture of seven VOCs (toluene, m-xylene, 1,3,5 trimethylbenzene, n-heptane, ethyl acetate, methyisobutylketone and isopropyl alcohol) presenting a wide range of hydrophobicity was then implemented in the model considering no interaction regarding their biodegradation. Degradation kinetics of the mixture (representing an actual exhaust gas from an industrial plant) were compared with experimental results. The developed model tends to highlight that modeling results are closed to experimental results. The results delivered by the model shows that mass transfer, through the “kLa” value, is a key parameter to enhance efficiency of NAPL renewal by biological regeneration.

Aerogels are open, three-dimensional, porous materials characterized by outstanding properties, such as low density, high porosity, and high surface area. They have been used in various fields as adsorbents, catalysts, materials for thermal insulation, or matrices for drug delivery. Aerogels have been successfully used for environmental applications to eliminate toxic and harmful substances—such as metal ions or organic dyes—contained in wastewater, and pollutants—including aromatic or oxygenated volatile organic compounds (VOCs)—contained in the air. This updated review on the use of different aerogels—for instance, graphene oxide-, cellulose-, chitosan-, and silica-based aerogels—provides information on their various applications in removing pollutants, the results obtained, and potential future developments.

COVID-19 is a highly transmissible respiratory illness that has rapidly spread all over the world causing more than 115 million cases and 2.5 million deaths. Most epidemiological projections estimate that the Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2) virus causing the infection will circulate in the next few years and raise enormous economic and social issues. COVID-19 has a dramatic impact on health care systems and patient management, and is delaying or stopping breath research activities due to the risk of infection to the operators following contact with patients, potentially infected samples or contaminated equipment. In this scenario, we investigated whether virus inactivation procedures, based on a thermal treatment (60 °C for 1 h) or storage of tubes at room temperature for 72 h, could be used to allow the routine breath analysis workflow to carry on with an optimal level of safety during the pandemic. Tests were carried out using dry and humid gaseous samples containing about 100 representative chemicals found in exhaled breath and ambient air. Samples were collected in commercially available sorbent tubes, i.e. Tenax GR and a combination of Tenax TA, Carbograph 1TD and Carboxen 1003. Our results showed that all compounds were stable at room temperature up to 72 h and that sample humidity was the key factor affecting the stability of the compounds upon thermal treatment. Tenax GR-based sorbent tubes were less impacted by the thermal treatment, showing variations in the range 20%–30% for most target analytes. A significant loss of aldehydes and sulphur compounds was observed using carbon molecular sieve-based tubes. In this case, a dry purge step before inactivation at 60 °C significantly reduced the loss of the target analytes, whose variations were comparable to the method variability. Finally, a breath analysis workflow including a SARS-CoV-2 inactivation treatment is proposed.

This paper describes the in situ monitoring of indoor air quality (IAQ) in two dwellings, using low-cost IAQ sensors to provide high-density temporal and spatial data. IAQ measurements were conducted over 2-week periods in the kitchen and bedroom of each home during the winter, spring, and summer seasons, characterized by different outside parameters, that were simultaneously measured. The mean indoor PM2.5 concentrations were about 15 μg m−3 in winter, they dropped to values close to 10 μg m−3 in spring and increased to levels of about 13 μg m−3 in summer. During the winter campaign, indoor PM2.5 was found mainly associated with particle penetration inside the rooms from outdoors, because of the high outdoor PM2.5 levels in the season. Such pollution winter episodes occur frequently in the study region, due to the combined contributions of strong anthropogenic emissions and stable atmospheric conditions. The concentrations of indoor volatile organic compounds (VOCs) and CO2 increased with the number of occupants (humans and pets), as likely associated with consequent higher emissions through breathing and metabolic processes. They also varied with occupants’ daily activities, like cooking and cleaning. Critic CO2 levels above the limit of 1000 ppm were observed in spring campaign, in the weeks close to the end of the COVID-19 quarantine, likely associated with the increased time that the occupants spent at home.

The main objective of this work was to bring to date the exhaust and evaporative volatile organic compound (VOC) profiles from light-duty gasoline vehicles, carrying out a sampling and analysis campaign in two tunnels of Mexico City. The abundance of exhaust-emission VOC profiles was the same in 2018 as in 1998 (alkanes &gt, aromatics &gt, olefins &gt, acetylene), albeit exhibiting large differences (67%, 17%, 12%, and 4% for 2018, and 50%, 26%, 16%, and 8% for 1998, respectively). An important reduction of 69% and 77% in VOC concentrations was registered inside and outside of the tunnel, respectively, in comparison with 1998. In the ambient air, alkanes accounted for 77%, since high concentrations of liquefied petroleum (LP) gas species are still present. Ethylene, propylene, 1-butene, and toluene from tunnel emissions contributed prominently to ozone formation, while the most reactive gasoline vapors were pentenes, pentanes, and butenes, although the ozone formation potential due to VOCs in tunnel emissions and ambient air also had a significant reduction. These results demonstrate that strategies carried out in the last 20 years were successful in achieving a better air quality, although the aromatic and olefin content in gasolines needs to be further reduced to lower the concentrations of toxic and reactive species.

The construction and building field represents a key sector for the recent Circular Economy Action Plan (March 2020). Therefore, the production of low impact materials represents an essential step towards the implementation of a sustainable market. In this regard, the present paper focused on the production of painting wooden products for interior design. These industrial processes include an essential phase consisting of the reduction of odor emissions, which produce negative impacts on the environment and a persistent annoyance for the population close to the facilities. The main cause of the odor emissions in wood painting manufacturing is the production of volatile organic compounds (VOCs). In this context, the present research aimed to develop an innovative process able to combine the use of lower impact paints with a more efficient UV system for the abatement of the emissions.

In recent years, ozone (O3) concentrations in the southeastern coastal areas of China have shown a gradual upward trend. As precursors and intermediates in the formation of O3, carbonyl compounds play key roles in the atmospheric photochemical oxidation cycle. To explore the main pollution characteristics of carbonyl compounds in a typical coastal city in southeast China, ambient samples were collected in Fuzhou (the provincial capital of Fujian province, located on the southeast coast of China) and analyzed using high-performance liquid chromatography with ultraviolet detection. The study was continuously carried out at an urban site (Jinjishan) and a suburban site (Gushan) in Fuzhou from May 8 to 20, 2018. The total concentration of 16 carbonyl compounds at the urban site was 15.45 ± 11.18 ppbv, and the total concentration at the suburban site was 17.57 ± 12.77 ppbv. Formaldehyde (HCHO), acetaldehyde, and acetone were the main species detected in the samples, and acetone had the highest concentration among the species detected. The suburban site had a higher formaldehyde/acetaldehyde ratio and lower acetaldehyde/propionaldehyde ratio than the urban site, implying that biogenic sources potentially contributed to the carbonyl compound concentrations at the suburban site. The results of an observation-based model showed that anthropogenic hydrocarbons promoted HCHO production on May 17 at the urban site. Compared to biogenic emissions, anthropogenic activity is a more important source of carbonyl compounds.

International audience

The production of phagostimulant and attractive volatile organic compounds (VOCs) by yeasts can be exploited to improve the efficacy of attract-and-kill formulations against the spotted wing drosophila (SWD). This study evaluated the persistence over one week of a yeast-based formulation under greenhouse conditions. Potted grape plants were treated with: (i) potato dextrose broth (PDB), (ii) PDB containing spinosad (PDB + S), and (iii) H. uvarum fermentation broth grown on PDB containing spinosad (H. u. + S). Laboratory trials were performed to determine the survival and the oviposition rate of SWD after exposure to treated leaves. Ion-exchange chromatography was performed to measure carbohydrates, sugar alcohols, and organic acids on leaf surfaces, while amino acids were assessed through liquid chromatography&ndash, mass-spectrometry. Additionally, the VOCs released by plants treated with H.uvarum were collected via closed-loop-stripping analysis and compared to those emitted by untreated leaves. A higher mortality was observed for adult SWDs in contact with H. uvarum containing spinosad compared to PDB containing spinosad. Generally, a decrease in the amounts of non-volatile compounds was observed over time, though numerous nutrients were still present one week after treatment. The application of the yeast-based formulation induced the emission of VOCs by the treated leaves. The concentration of 2-phenylethanol, one of the main VOCs emitted by yeasts, decreased over time. These findings describe the presence of potential phagostimulants and compounds attractive to SWD in a yeast-based attract-and-kill formulation and demonstrate the efficacy of the formulation over one week.

Chronic obstructive pulmonary disease (COPD) is a common progressive disorder of the respiratory system which is currently the third leading cause of death worldwide. Exhaled breath analysis is a non-invasive method to study lung diseases, and electronic noses have been extensively used in breath research. Studies with electronic noses have proved that the pattern of exhaled volatile organic compounds is different in COPD. More recent investigations have reported that electronic noses could potentially distinguish different endotypes (i.e., neutrophilic vs. eosinophilic) and are able to detect microorganisms in the airways responsible for exacerbations. This article will review the published literature on electronic noses and COPD and help in identifying methodological, physiological, and disease-related factors which could affect the results.

International audience; tCellulose acetate (CA) has been widely used since the second half of the 20th century as a transparent support for photographs and movie films in order to replace the flammable cellulose nitrate. Over time, hydrolysis occurs and the deacetylation of the CA produces acetic acid (AA), a well-known phenomenon in film archives, the so-called “vinegar syndrome”. However, beside AA, other off-gassing compounds maybe present, and very few studies have been devoted to their quantitative and qualitative assessment. Proton Transfer Reaction “Time-of-Flight” Mass Spectrometer (PTR-ToF-MS) combines high sensitivity with high mass resolution for real-time detection of multiple Volatile Organic Compounds (VOCs). This technique was used to evaluate the air composition from 41 films dated from the second half of the 20th century, which showed different degradation levels (ranked using A-D strips®: level 0–1.5). More than 100 VOCs were detected, and their distribution was different from one film to another. AA was the most abundant VOC in 27 film cans. In others, it was either N,N dimethylformamide (DMF), butanol, acetaldehyde, acetone or formic acid. This study shows that PTR-MS is a powerful tool to monitor in real-time, and non-invasively, objects degradation in a museum environment via the quantitative and qualitative analysis of their VOCs emissions, and that this can be used for hierarchical cluster analysis classification.

Cotton genotypes displayed similar volatile organic compound (VOC) profiles, but major differences in terpenoid aldehyde (TA) content. The differences in VOC production were minor among genotypes, but these differences are crucial for boll weevil attraction. Weevils did not display any preference in feeding behaviour towards cotton genotypes, suggesting physiological adaptation to cope with cotton chemical defence mechanisms. Plant cultivar selection for resistance to herbivore pests is an effective, environmentally safe and inexpensive method to implement in integrated pest management programmes. In this study, we evaluated seven cotton genotypes with respect to the production of volatile organic compounds (VOCs) and non-volatile compounds [terpenoid aldehydes (TAs)], and the attraction and feeding preference of adult boll weevils. Chemical analyses of VOCs from BRS-293, BRS-Rubi, CNPA TB-15, CNPA TB-85, CNPA TB-90, Delta Opal, and Empire Glandless showed that there were few qualitative and quantitative differences across the range of genotypes. In contrast, major differences in TA content were observed, with CNPA TB-15 and CNPA TB-85 producing higher levels of TAs compared to the other genotypes. Our results showed that boll weevil attraction to cotton genotypes varied, suggesting that the ratios and quantities of emitted cotton VOCs are important for host location. However, boll weevil feeding behaviour was neither positively nor negatively influenced by the terpenoid content (non-volatile compounds) of cotton genotypes. The results in this study suggest that boll weevils have adapted physiologically to cope with cotton chemical defence mechanisms.