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Quasar Q0059–2735, one of the first known iron low-ionization broad-absorption-line quasars (FeLoBAL), has a plethora of outflow absorption features at different velocities. Given multiple outflow systems, their troughs from high-ionization transitions form very wide BAL features, e.g. C iv troughs extend from ∼−1000 to −25 000 km s−1. The troughs from low-ionization transitions show more than 1000 narrow absorption lines (NALs) with velocities from −1000 to −3000 km s−1. These include troughs from iron-peak elements, e.g. Fe ii, Fe iii, Cr ii, Mn ii, Ni ii, and Co ii, which are rarely detected in quasar outflows. Most of these troughs are non-black saturated. We constrain the physical conditions of the NALs by fitting the observed Fe ii and Fe iii absorption troughs. We find that the Fe ii absorption arises from a region with an electron temperature (Te) of ∼8000 K and an electron number density (ne) of ∼108 cm−3. The same model also fits well the troughs from other iron-peak elements. In contrast to the Fe ii lines, Fe iii lines are formed in a hotter region, i.e. Te ∼20 000 K. To fit the Fe ii and Fe iii lines simultaneously in a single photoionized cloud, they require a supersolar iron abundance and/or other heating mechanisms for the Fe iii region. The distance (R) of the outflows to the central quasar is determined to be ∼40 pc. The high-resolution data afforded by the Very Large Telescope (VLT)/UVES observations from 2006 and 2018, along with the narrow lines, allow us to constrain the smallest outflow deceleration in any known quasars.

We analyze VLT/X-shooter data for 7 quasars, where we study the relationships between their broad absorption line (BAL) and emission line outflows. We find: 1) the luminosity of the [OIII] $\lambda$5007 emission profile decreases with increasing electron number density (n$_e$) derived from the BAL outflow in the same quasar, 2) the measured velocity widths from the [OIII] emission features and CIV absorption troughs in the same object are similar, and 3) the mean radial velocity derived from the BAL outflow is moderately larger than the one from the [OIII] emission outflow. These findings can be explained by the physical interpretation that the [OIII] and BAL outflow are different manifestations of the same wind. When we have outflows with smaller distances to the central source, their n$_e$ is higher. Therefore, the [OIII] emission is collisionally de-excited and the [OIII] luminosity is then suppressed. Comparisons to previous studies show that the objects in our sample exhibit broad [OIII] emission features similar to the ones in extremely red quasars (ERQs). This might imply that BAL quasars and ERQs have the same geometry of outflows or are at a similar evolutionary stage. We found that the physical parameters derived from the BAL outflows can explain the amount of observed [OIII] luminosity, which strengthens our claim of both BAL and [OIII] outflows are from the same wind. These estimates can be tested with upcoming James Webb Space Telescope observations., Comment: 16 pages, 9 figures

Tin oxide (SnO2) has been considered as a promising anode candidate for lithium ion batteries (LIBs) due to its high theoretical capacity (782 mA h g−1). However, the large volume change (>300%) and severe structural collapse during cycles are serious. Herein, we design and synthesize a composite composed of rice husk cellulose (RHC) encapsulated SnO2. The ultrafine SnO2 nanoparticles were embedded in carbon film via a facile hydrothermal approach. It is worthy of note that the proposed hydrothermal treatment plays an indispensable role in the formation of this SnO2@RHC composite. As a promising anode for lithium ion batteries, the SnO2@RHC composite exhibits a large initial discharge capacity (2090 mA h g−1) and high capacities of 930 and 587 mA h g−1 after 100 cycles, respectively, at 0.2C and even 1C. The outstanding performance may benefit from the well-designed versatile nanostructure and the synergistic effects between the SnO2 and RHC.

Determining the distance of quasar absorption outflows from the central source (R) and their kinetic luminosity are crucial for understanding their contribution to active galactic nucleus (AGN) feedback. Here we summarize the results for a sample of nine luminous quasars that were observed with the Hubble Space Telescope. We find that the outflows in more than half of the objects are powerful enough to be the main agents for AGN feedback, and that most outflows are found at R>100 pc. The sample is representative of the quasar absorption outflow population as a whole and is unbiased towards specific ranges of R and kinetic luminosity. Therefore, the analysis results can be extended to the majority of such objects, including broad absorption line quasars. We find that these results are consistent with those of another sample (seven quasars) that is also unbiased towards specific ranges of R and kinetic luminosity. Assuming that all quasars have absorption outflows, we conclude that most luminous quasars produce outflows that can contribute significantly to AGN feedback. We also discuss the criterion for whether an outflow is energetic enough to cause AGN feedback effects., 10 pages, 4 figures, accepted for publication in MNRAS

We present an analysis of the broad absorption line (BAL) velocity shift that appeared in one of the outflow systems in quasar SDSS J1042+1646. Observations were taken by the Hubble Space Telescope/Cosmic Origin Spectrograph in 2011 and 2017 in the 500 -- 1050 $\r{A}$ rest frame. The outflow's velocity centroid shifted by $\sim$ --1550 km s$^{-1}$ from --19,500 km s$^{-1}$ to --21,050 km s$^{-1}$ over a rest-frame time of 3.2 yr. The velocity shift signatures are most apparent in the absorption features from the Ne VIII $\lambda\lambda$ 770.41, 780.32 doublet and are supported by the absorption troughs from OV $\lambda$ 629.73 and the Mg X $\lambda\lambda$ 609.79, 624.94 doublet. This is the first time where a quasar outflow velocity shift is observed in troughs from more than one ion and in distinct troughs from a doublet transition (Ne VIII). We attribute the velocity shift to an acceleration of an existing outflow as we are able to exclude photoionization changes and motion of material into and out of the line of sight as alternate explanations. This leads to an average acceleration of 480 km s$^{-1}$ yr$^{-1}$ (1.52 cm s$^{-2}$) in the quasar rest frame. Both the acceleration and the absolute velocity shift are the largest reported for a quasar outflow to date. Based on the absorption troughs of the O V* multiplet, we derive a range for the distance of the outflow ($R$) from the central source, 0.05 pc $, Comment: 10 pages, 6 figures, published in ApJS

We present the analysis of two outflows (S1 at --5500 km s$^{-1}$ and S2 at --9700 km s$^{-1}$) seen in recent HST/COS observations of quasar SDSS J0755+2306 (z = 0.854). The outflows are detected as absorption troughs from both high-ionization species, including N III, O III, and S IV, and very high-ionization species, including Ar VIII, Ne VIII, and Na IX. The derived photoionization solutions show that each outflow requires a two ionization-phase solution. For S1, troughs from S IV* and S IV allow us to derive an electron number density, $n_{e}$ = 1.8$\times$10$^4$ cm$^{-3}$, and its distance from the central source of $R$ = 270 pc. For S2, troughs from O III* and O III yield $n_{e}$ = 1.2$\times$10$^3$ cm$^{-3}$ and $R$ = 1600 pc. The kinetic luminosity of S2 is $>$ 12% of the Eddington luminosity for the quasar and therefore can provide strong AGN feedback effects. Comparison of absorption troughs from O III and O VI in both outflow systems supports the idea that for a given element, higher ionization ions have larger covering fractions than lower ionization ones., Comment: 10 pages, 6 figures, published in ApJS

Aims. Our aim is to determine the distance of the UV outflow components from the central source, their abundances and total column density, and the mechanism responsible for their observed absorption variability. Methods. We studied the UV spectra acquired during the campaign as well as from three previous epochs (2002-2010). Our main analysis tools are ionic column-density extraction techniques and photoionization models (both equilibrium and time-dependent models) based on the code Cloudy. Results. For component 1 (at -600 km/s) our findings include the following: metallicity that is roughly twice solar; a simple model based on a fixed total column-density absorber, reacting to changes in ionizing illumination that matches the different ionic column densities derived from four spectroscopic epochs spanning 13 years; and a distance of R=6+2.5-1.5 pc from the central source. Component 2 (at -1430 km/s) has shallow troughs and is at a much larger R. For component 3 (at -1880 km/s) our findings include: a similar metallicity to component 1; a photoionization-based model can explain the major features of its complicated absorption trough variability and an upper limit of 60 or 150 pc on R. This upper limit is consistent and complementary to the X-ray derived lower limit of 12 or 31 pc for R. The total column density of the UV phase is roughly 1% and 0.1% of the lower and upper ionization components of the warm absorber, respectively. Conclusions. The NGC 7469 outflow shows super-solar metallicity similar to the outflow in Mrk 279, carbon and nitrogen are twice and four times more abundant than their solar values, respectively. Similar to the NGC 5548 case, a simple model can explain the physical characteristics and the variability observed in the outflow., 11 pages, 7 figures. accepted to A&A https://doi.org/10.1051/0004-6361/201935342

From Hubble Space Telescope/Cosmic Origins Spectrograph spectra of five quasars, 16 outflows are detected. For 11 outflows, we are able to constrain their distances to the central source (R) and their energetics. In instances of multiple electron number density determinations (used in the calculation of R) for the same outflow, the values are consistent within errors. For the 11 outflows, eight have measurements for R (between 10 and 1000 pc), one has a lower limit, another has an upper limit, and the last has a range in R. There are two outflows that have enough kinetic luminosity to be major contributors to active galactic nucleus feedback. The outflowing mass is found primarily in a very high-ionization phase, which is probed using troughs from, e.g., Ne VIII, Na IX, Mg X, and Si XII. Such ions connect the physical conditions of these ultraviolet outflows to the X-ray warm absorber outflows seen in nearby Seyfert galaxies. The ion Cl VII and several new transitions from Ne V have been detected for the first time., Comment: 29 pages, 3 figures, 4 tables, Accepted for publication in ApJS

Ultrafine SnO2 nanoparticles anchored in porous corn straw carbon as an anode material of Li-ion batteries are synthesized via a facile hydrothermal method. The unique three-dimensional porous structure of corn straw carbon provides ideal accommodation for SnO2 (SnO2/P-CSC), and effectively alleviates the free expansion of SnO2 during charging-discharging process. The SnO2/P-CSC composite exhibits a high capacity of 648 mA h g−1 after 100 cycles at 0.2 C. In particular, compared with porous corn straw carbon (P-CSC) and pure SnO2, the capacity of SnO2/P-CSC is 1.6 times of P-CSC and 2.7 times of SnO2 respectively. The high-performances may benefit from the 3D structure of P-CSC and the synergistic effects between the SnO2 and P-CSC. The as-proposed synthetic strategy not only provides a new scalable application for corn straw carbon as a sustainable anode but also solves the serious volume expansion problem of SnO2.

We analyze absorption troughs from two outflows within PKS J0352-0711 (S1 at $-$1950 km s$^{-1}$ and S2 at $-$3150 km s$^{-1}$) from spectra taken with Hubble Space Telescope/Cosmic Origin Spectrograph, which cover the diagnostic-rich 585-900 Angstrom rest frame wavelength range. In S2, for the first time we clearly detect absorption troughs from Ca IV, Ca V, Ca V*, Ca VII*, and Ca VIII*. The column density measurement of Ca V suggests S2 has a super-solar metallicity. Both outflows require at least two ionization phases where the column density of the very high-ionization phase is roughly 15 times larger than the corresponding high-ionization phase. These high column densities and very high-ionization potential ions are similar to X-ray warm absorbers. The two phases of S2 show a unique velocity centroid shift between associated troughs. Through Monte Carlo measurements of the O V* absorption troughs, we determine the electron number density of S2 (fully corroborated by independent measurements from the Ca V* and Ca VIII* troughs), yielding a distance of 9 pc and a kinetic luminosity of 2$\times$10$^{43}$ erg s$^{-1}$. S1 is located farther away at 500 pc from the central source with a kinetic luminosity of 10$^{43}$ erg s$^{-1}$., Comment: 12 pages, 9 figures, 5 tables

The Hubble Space Telescope/Cosmic Origins Spectrograph (COS) has opened a new discovery space for studying quasar absorption outflows and their contribution to AGN feedback. Specifically, COS provides high-quality far-ultraviolet (FUV) spectra covering the diagnostic-rich 500-1050 Angstrom rest frame (hereafter, EUV500) of medium redshift objects. The quality and quantity of EUV500 diagnostic troughs allow us to probe the very high-ionization phase, which carries 90% or more of the outflowing material, as well as to determine the distance of most outflows from the central source ($R$). The first objective is impossible to achieve with ground-based spectra, and $R$ can be measured in only $\sim$1% of them. Here, we summarize the main results of the first dedicated survey of such outflows, including the following: 1) Measurements of the three most energetic outflows to date, which can be the main agents for AGN feedback processes in the environments of the host galaxies. 2) All the outflows have a very high-ionization component, similar to the one found in warm absorbers, which carries most of the outflow's kinetic luminosity. This finding suggests that all the high-ionization outflows observed from the ground also have a similar undetected very high-ionization component. 3) Of the 13 studied EUV500 outflows, 9 have $100, Comment: 11 pages, 4 figures, 2 tables

We present a study of the BAL outflows seen in quasar SDSS J1042+1646 (z = 0.978) in the rest-frame 500 -- 1050 $\r{A}$ (EUV500) region. The results are based on the analysis of recent Hubble Space Telescope/Cosmic Origins Spectrograph observations. Five outflow systems are identified, where in total they include $\sim$70 outflow troughs from ionic transitions. These include the first non-solar detections from transitions of O V*, Ne V*, Ar VI, Ca VI, Ca VII, and Ca VIII. The appearance of very high-ionization species (e.g., Ne VIII, Na IX, and Mg X) in all outflows necessitates at least two-ionization phases for the observed outflows. We develop an interactive Synthetic Spectral Simulation method to fit the multitude of observed troughs. Detections of density sensitive troughs (e.g., S IV* $\lambda$ 657.32 $\r{A}$ and the O V* multiplet) allow us to determine the distance of the outflows ($R$) as well as their energetics. Two of the outflows are at $R$ $\simeq$ 800 pc and one is at $R$ $\simeq$ 15 pc. One of the outflows has the highest kinetic luminosity on record ($\dot{E_{k}}$ $ = 5\times 10^{46}$ erg s$^{-1}$), which is 20% of its Eddington luminosity. Such a large ratio suggests that this outflow can provide the energy needed for active galactic nucleus feedback mechanisms., Comment: 18 pages, 12 figures, published in ApJS

We detect four very energetic outflows in the Hubble Space Telescope/Cosmic Origin Spectrograph spectra of quasar 2MASS J1051+1247 with a combined kinetic luminosity ($\dot{E_k}$) of 10$^{46}$ erg s$^{-1}$. Remarkable similarities are seen in these outflows: velocity centroids between 4900 and 5700 km s$^{-1}$, distances from the central source ($R$) of a few hundred parsecs that are all consistent within the errors, and an $\dot{E_k}$ within a factor of two for all outflows. Hence, a common origin for the outflows is probable. Most of the outflowing mass resides in a very high-ionization phase evident by troughs from Ne VIII, Na IX, Mg X, and Si XII, which connect the physical conditions of these ultraviolet outflows to the X-ray warm absorber outflows seen in nearby Seyfert galaxies. Three of the outflows have two or three independent diagnostics for the electron number density, yielding consistent values for each outflow, which increase the robustness of the $R$ determinations. Troughs from never-before-seen ionic transitions of Ar VI, O IV*, Ne VI*, and Ne V* are identified. With a combined $\dot{E_k}$ that is $7.0^{+6.5}_{-2.3}$ % of the quasar's Eddington luminosity, these outflows are prime candidates to be major agents for various active galactic nuclei feedback effects., Comment: 11 pages, 3 figures, 4 tables

We analyze new HST/COS spectra for two quasar absorption outflows seen in the quasi-stellar object LBQS 1206+1052. These data cover, for the first time, absorption troughs from $S_{IV}$, $Si_{II}$, and $P_V$. From the ratio of the $S_{IV}$* to $S_{IV}$ column densities, we measure the electron number density of the higher-velocity ($-1400$ km s$^{-1}$, v1400) outflow to be log($n_e$) = $4.23^{+0.09}_{-0.09}$ cm$^{-3}$ and constrain the lower-velocity ($-730$ km s$^{-1}$, v700) outflow to log($n_e$) $>$ $5.3$ cm$^{-3}$. The $n_e$ associated with the higher-velocity outflow is an order of magnitude larger than reported in prior work. We find that the previous measurement was unreliable since it was based on density-sensitive absorption troughs that were likely saturated. Using photoionization models, we determine the best $\chi^2$-minimization fit for the ionization parameter and hydrogen column density of the higher-velocity outflow: log($U_H$) = $-1.73^{+0.21}_{-0.12}$ and log($N_H$) = $21.03^{+0.25}_{-0.15}$ cm$^{-2}$, respectively. We calculate from $U_H$ and $n_e$ a distance of $500^{+100}_{-110}$ pc from the central source to the outflow. Using an SED attenuated by the v700 outflow yields a two-phase photoionization solution for the v1400 outflow, separated by a $\Delta U \approxeq 0.7$. Otherwise, the resultant distance, mass flux, and kinetic luminosity are similar to the unattenuated case. However, the attenuated analysis has significant uncertainties due to a lack of constraints on the v700 outflow in 2017., Comment: 11 pages, 6 figures, 4 tables, accepted for publication in ApJ

The most robust way for determining the distance of quasar absorption outflows is the use of troughs from ionic excited states. The column density ratio between the excited and resonance states yields the outflow number density. Combined with a knowledge of the outflow's ionization parameter, a distance from the central source (R) can be determined. Here we report results from two surveys targeting outflows that show troughs from S IV. One survey includes 1091 SDSS and BOSS quasar spectra, and the other includes higher-quality spectra of 13 quasars observed with the Very Large Telescope. Our S IV samples include 38 broad absorption line (BAL) outflows, and four mini-BAL outflows. The S IV is formed in the same physical region of the outflow as the canonical outflow-identifying species C IV. Our results show that S IV absorption is only detected in 25% of C IV BAL outflows. The smaller detection fraction is due to the higher total column density ($N_H$) needed to detect S IV absorption. Since R empirically anticorrelates with $N_H$ the results of these surveys can be extrapolated to C IV quasar outflows with lower $N_H$ as well. We find that at least 50% of quasar outflows are at distances larger than 100 pc from the central source, and at least 12% are at distances larger than 1000 pc. These results have profound implications for the study of the origin and acceleration mechanism of quasar outflows and their effects on the host galaxy., Comment: 21 pages, 6 figures, 8 tables. Published, 2018, ApJ, 857, 60. Title typo corrected

To understand the nature of transient obscuring outflows in active galactic nuclei, we observed the Seyfert 1 galaxy NGC 3783 on two occasions in December 2016 triggered by Swift monitoring indicating strong soft X-ray absorption in November. We obtained ultraviolet spectra using COS on HST and optical spectra using FEROS on the MPG/ESO 2.2-m telescope that were simultaneous with X-ray spectra from XMM-Newton and NuSTAR. We find new components of broad, blue-shifted absorption associated with Ly$\alpha$, \ion{N}{v}, \ion{Si}{iv}, and \ion{C}{iv} in our COS spectra. The absorption extends from velocities near zero in the rest-frame of the host galaxy to $-6200$ $\rm km~s^{-1}$. These features appear for the first time in NGC 3783 at the same time as the heavy soft X-ray absorption seen in the XMM-Newton X-ray spectra. The X-ray absorption has a column density of $\sim 10^{23}~\rm cm^{-2}$, and it partially covers the X-ray continuum source. The X-ray absorption becomes more transparent in the second observation, as does the UV absorption. Combining the X-ray column densities with the UV spectral observations yields an ionization parameter for the obscuring gas of log $\xi =1.84^{+0.4}_{-0.2}$ $\rm erg~cm~s^{-1}$. Despite the high intensity of the UV continuum in NGC 3783, F(1470 \AA)=$8 \times 10^{-14}~\rm erg~cm^{-2}~s^{-1}~\AA^{-1}$, the well known narrow UV absorption lines are deeper than in earlier observations in unobscured states, and low ionization species such as \ion{C}{iii} appear, indicating that the narrow-line gas is more distant from the nucleus and is being shadowed by the gas producing the obscuration. Despite the high continuum flux levels in our observations of NGC 3783, moderate velocities in the UV broad line profiles have substantially diminished. We suggest that a collapse of the broad line region has led to the outburst and triggered the obscuring event., Comment: 24 pages, 29 figures, uses aa.cls. Accepted for publication in A&A, 10/29/2018

We conducted a survey of quasar outflows using the VLT/X-shooter spectrograph. When choosing the 14 BAL and mini-BALs comprising this sample, the data did not cover the S IV and S IV* troughs, whose ratio can be used to determine the distance of the outflows from the central source (R). Therefore, this "Blind Survey" is unbiased towards a particular distance scale. Out of the eight outflows where R can be measured, six have R > 100 pc (spanning the range 100-4500 pc), one has R > 10 pc, and only one (at R < 60 pc) is compatible with a much smaller R scale. At least two of the outflows have a kinetic luminosity greater than 0.5% of their Eddington luminosity, implying that they are able to provide significant AGN feedback. The outflows span a range of 0 to -10000 km s$^{-1}$ in velocity; total column density between 10$^{20}$ - 10$^{22.5}$ cm$^{-2}$ ; ionization parameter ($U_H$ ) in the range 0.01 - 1; and electron number density between 10$^3$ - 10$^{5.5}$ cm$^{-3}$ , with one upper and one lower limit. The results of this survey can be extrapolated to the majority of BAL outflows, implying that most of these outflows are situated far away from the AGN accretion disk; and that a significant portion of them can contribute to AGN feedback processes., 8 pages, 4 figures, 3 tables, submitted to ApJ

We determine the physical conditions and location of the outflow material seen in the mini-BAL quasar SDSS J1111+1437 (z = 2.138). These results are based on the analysis of a high S/N, medium-resolution VLT/X- shooter spectrum. The main outflow component spans the velocity range -1500 to -3000 km s$^{-1}$ and has detected absorption troughs from both high-ionization species: C IV , N V , O VI , Si IV , P V , and S IV ; and low-ionization species: H I , C II , Mg II , Al II , Al III , Si II , and Si III . Measurements of these troughs allow us to derive an accurate photoionization solution for this absorption component: a hydrogen column density, log ( N H ) = 21.47 $^{+0.21}_{-0.27}$ cm$^{-2}$ and ionization parameter, log (U_H) = -1.23$^{+0.20}_{-0.25}$. Troughs produced from the ground and excited states of S IV combined with the derived U_H value allow us to determine an electron number density of log (n_e) = 3.62$^{+0.09}_{-0.11}$ cm$^{-3}$ and to obtain the distance of the ionized gas from the central source: R = 880$^{+220}_{-260}$ pc., 9 pages, 6 figures, 2 tables. Published, 2018, ApJ, 858, 39