1. Wavelength-sensitive photocatalytic H2 evolution from H2S splitting over g-C3N4 with S,N-codoped carbon dots as the photosensitizer
- Author
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Limei Yu, Yunqian Zhong, Ying Zhou, Shan Yu, Xiang-Bing Fan, Fan Wu, Zhanghui Xie, Shiqian Wei, and Xue-Wang Gao
- Subjects
Materials science ,Photoluminescence ,Graphitic carbon nitride ,Energy Engineering and Power Technology ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Photochemistry ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Chemical state ,chemistry.chemical_compound ,Fuel Technology ,chemistry ,Photocatalysis ,Density functional theory ,0210 nano-technology ,Carbon ,Energy (miscellaneous) ,Nanosheet - Abstract
Photocatalytic splitting of hydrogen sulfide (H2S) for hydrogen evolution is a promising method to solve the energy and environmental issues. In this work, S,N-codoped carbon dots (S,N-CDs)/graphitic carbon nitride (g-C3N4) nanosheet is synthesized by hydrothermal method as an efficient photocatalyst for the decomposition of H2S. In addition to the characterization of the morphology and structure, chemical state, optical and electrochemical performances of S,N-CDs/g-C3N4, hydrogen evolution tests show that the activity of g-C3N4 is improved by introducing S,N-CDs, and the enhancement depends strongly on the wavelength of incident light. The photocatalytic hydrogen production rate of S,N-CDs/g-C3N4 composite reaches 832 μmol g−1h−1, which is 38 times to that of g-C3N4 under irradiation at 460 nm. Density functional theory calculations and electron paramagnetic resonance as well as photoluminescence technologies have altogether authenticated that the unique wavelength-dependent photosensitization of S,N-CDs on g-C3N4; meanwhile, a good match between the energy level of S,N-CDs and g-C3N4 is pivotal for the effective photocatalytic activity. Our work has unveiled the detailed mechanism of the photocatalytic activity enhancement in S,N-CDs/g-C3N4 composite and showed its potential in photocatalytic splitting of H2S for hydrogen evolution.
- Published
- 2021