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To understand the modern sedimentation and land-sea interaction processes in the Asian margin seas, we analyze rare earth element contents (REE, i.e., La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) and grain sizes, detrital minerals from 158 surface sediment samples collected from the western Gulf of Thailand (GoT). The results reveal that the REE contents ranged from 25.42 μg/g to 201.21 μg/g, with an average value of 137.21 μg/g, and that the GoT is characterized by higher accumulations of LREE relative to HREE, together with negative Eu anomalies. Based on the spatial distribution characteristics of REE contents, δCe and δEu, the western GoT can be classified into three geochemical provinces. The Province I covers the northern and northwestern coastal zones of the GoT, including the entire upper GoT; its coarse size fraction and distribution pattern of hornblende- and quartz-dominated minerals caused REE contents to be the lowest, and these sediments were mainly derived from the rivers around the upper GoT, including the Chao Praya River and the Kea Klong River. The Province II is located in the central GoT and has the highest REE concentrations due to finer sediment composition and higher contents of zircon, authigenic pyrite, and biogenetic limestone. The Province II has two accumulation centers around Samui Island and Koh Chang Island, with REE spatial distribution influenced by the seasonal setting and mixed derived from multiple provenances around the GoT. The Province Ш is located in the lower GoT, close to Malaysia. The sediment type in this region is similar to that of Province I except for different detrital mineral compositions, especially the presence of siderite that is responsible for higher REE contents. The sediments in this region exhibits similar distribution patterns to those of terrestrial materials from the Malaysian peninsula such as that from the Kelantan River. The transportation processes of sediments in this region are mainly controlled by the coastal current.

Investigating the composition and distribution of pelagic marine sediments is fundamental in the field of marine sedimentology. The spatial distributions of surface sediment are unclear due to limited investigation along the Emperor Seamount Chain of the North Pacific. In this study, a suite of sedimentological and geochemical proxies were analyzed, including the sediment grain size, organic carbon, CaCO3, major and rare earth elements of 50 surface sediment samples from the Emperor Seamount Chain, spanning from ∼33°N to ∼52°N. On the basis of sedimentary components, we divide them into three Zones (I, II, and III) spatially with distinct features. Sediments in Zone I (∼33°N–44°N) and Zone III (49.8°N–53°N) are dominated by clayey silt, and mainly consist of sand and silty sand in Zone II. The mean grain size of the sortable silt shows that the hydrodynamic condition in the study area is significantly stronger than that of the abyssal plain, especially at the water depth of 1,000–2,500 m. The CaCO3 contents in sediments above 4,000 m range from 20 to 84% but decrease sharply to less than 1.5% below 4,000 m, confirming that the water depth of 4,000 m is the carbonate compensation depth of the study area. Strong positive correlations between Al2O3 and Fe2O3, TiO2, MgO, and K2O (R > 0.9) in the bulk sediments indicate pronounced contributions of terrigenous materials from surrounding continent mass to the study area. Furthermore, the eolian dust makes contributions to the composition of bulk sediments as confirmed by rare earth elements. There is no significant correlation between grain size and major and minor elements, which indicates that the sedimentary grain size does not exert important effects on terrigenous components. There is significant negative δCe and positive δEu anomalies at all stations. The negative Ce anomaly mainly exists in carbonate-rich sediments, inheriting the signal of seawater. The positive Eu anomaly indicates widespread volcanism contributions to the study area from active volcanic islands arcs around the North Pacific. The relative contributions of terrestrial, volcanic, and biogenic materials vary with latitude and water depth in the study area.

The Sea of Japan (JS) is a unique marginal sea in the western North Pacific that is characterized by four shallow straits. It can provide information about the paleoenvironment, for instance indicating variations in the East Asian Monsoon, Tsushima Warm Current, sea ice coverage, and Westerly Jet. Compared with other marginal seas in the western North Pacific, the JS is currently the only marginal sea without influx from large rivers. It is, therefore, of interest to determine the source of terrigenous sediments over time, particularly in the western JS, which has been less investigated in previous reports. In this study, a suite of multi-proxies including Sr and Nd isotopes and minor elements were measured for fine fractions (

The heavy metal contents (Cr, Cu, Zn, Cd, Pb, Hg, and As) of 88 surface sediment samples from the western Sunda Shelf were analyzed to determine their spatial distribution patterns and contamination status. The results demonstrated that high enrichment regions of heavy metals were focused in the Kelantan, Pahang, and Ambat river estuaries, and deep water regions of the study area. These high enrichment regions were mainly controlled by riverine inputs and their hydrodynamic conditions. The enrichment factor (EF), geoaccumulation index (Igeo), and potential ecological risk index (PERI) were used to assess heavy metal accumulation. The results indicated that the study area was not significantly contaminated overall at the time of the study; however, Cd, As, and Hg were at levels corresponding to moderate contamination at many stations located in the Pahang River estuary, Kelantan River estuary, and north-eastern region of the study area, primarily because of anthropogenic activities.

In this study, sediments were collected from two different sites in the deep-sea hydrothermal region of the South Atlantic Ocean. Two microbial enrichment cultures (H7S and H11S), which were enriched from the sediments collected at two sample sites, could effectively degrade petroleum hydrocarbons. The bacterial diversity was analyzed by high-throughput sequencing method. The petroleum degradation ability were evaluated by gas chromatography–mass spectrometry and gravimetric analysis. We found that the dominant oil-degrading bacteria of enrichment cultures from the deep-sea hydrothermal area belonged to the genera Pseudomonas, Nitratireductor, Acinetobacter, and Brevundimonas. After a 14-day degradation experiment, the enrichment culture H11S, which was obtained near a hydrothermal vent, exhibited a higher degradation efficiency for alkanes (95%) and polycyclic aromatic hydrocarbons (88%) than the enrichment culture H7S. Interestingly, pristane and phytane as biomarkers were degraded up to 90% and 91% respectively by the enrichment culture H11S, and six culturable oil-degrading bacterial strains were isolated. Acinetobacter junii strain H11S-25, Nitratireductor sp. strain H11S-31 and Pseudomonas sp. strain H11S-28 were used at a density ratio of 95:4:1 to construct high-efficiency oil-degrading consortium H. After a three-day biodegradation experiment, consortium H showed high degradation efficiencies of 74.2% and 65.7% for total alkanes and PAHs, respectively. The degradation efficiency of biomarkers such as pristane and high-molecular-weight polycyclic aromatic hydrocarbons (such as CHR) reached 84.5% and 80.48%, respectively. The findings of this study indicate that the microorganisms in the deep-sea hydrothermal area are potential resources for degrading petroleum hydrocarbons. Consortium H, which was artificially constructed, showed a highly efficient oil-degrading capacity and has significant application prospects in oil pollution bioremediation.

Rare earth elements (REEs) and yttrium (Y), together known as REY, are extremely enriched in deep-sea pelagic sediments, attracting much attention as a promising new REY resource. To understand the influence of hydrothermal processes on the enrichment of REY in deep-sea sediments from the eastern South Pacific Ocean, we conducted detailed lithological, bulk sediment geochemical, and in situ mineral geochemical analyses on gravity core sample S021GC17 from the Yupanqui Basin of eastern South Pacific. The REY-rich muds of S021GC17 are dark-brown to black zeolitic clays with REY contents (&Sigma, REY) ranging from 1057 to 1882 ppm (average 1329 ppm). The REY-rich muds display heavy rare earth elements (HREE) enriched patterns, with obvious depletions in Ce, and positive anomalies of Eu in Post-Archean Australian Shale (PAAS)-normalized REE diagrams. In contrast, the muds of S021GC17 show light rare earth elements (LREE) enriched patterns and positive anomalies of Ce and Eu in the seawater-normalized REE diagrams. Total REY abundances in the core show positive correlations with CaO, P2O5, Fe2O3, and MnO concentrations. In situ analyses of trace element contents by laser ablation-inductively coupled plasma&ndash, mass spectrometry (LA-ICP-MS) demonstrate that bioapatite fossils contain high REY concentrations (998 to 22,497 ppm, average 9123 ppm), indicating that they are the primary carriers of REY. The in situ Nd isotope values of bioapatites are higher than the average values of seawater in Pacific Ocean. Fe&ndash, Mn micronodules are divided into hydrogenetic and diagenetic types, which have average REY concentrations of 1586 and 567 ppm, respectively. The high contents of Fe-Mn-Ba-Co-Mo, the positive correlations between &Sigma, REY and Fe-Mn, the ratios of Fe/Ti and Al/(Al + Fe + Mn), and the LREE-enriched patterns in the REY-rich muds, combined with high Nd isotope values shown by bioapatite fossils, strongly indicate that the hydrothermal fluids have played an important role in the formation of the REY-rich sediments in the eastern South Pacific Ocean.

Lithogenic grain-size, geochemical elements of core sediments from the central Bay of Bengal (BoB) were analyzed to identify sediment provenance and explore the regional “source-sink” processes since 25 ka. Based on the geochemical compositions of core BoB-88, relative contributions of three end-member sources (Himalayan, Myanmar, Indian Peninsula) were calculated and support the general understanding that Himalayan sources were dominant since the last glacial period, which could reach 70% on average in our study. However, sediments from the Indian Peninsula and Myanmar also contributed nonnegligible materials to the central BoB since 25 ka, especially the former shows an obvious increase since 7.5 ka, which was neglected in the previous studies. To trace the sedimentary processes of different provenance terrigenous materials and reveal their response to climate changes, four typical stages with obvious provenance percent variation, including the Last Glacial Maximum period (LGM), Heinrich 1 (H1), Early Holocene Climate Optimum (EHCO), and mid-late Holocene period, were highlighted and discussed. Sea-level change played a dominant role in the glacial-interglacial scale by controlling the transition of deposition center between the shelf/subaquatic delta and the Bengal Fan, especially for sediment from the Himalayan source, exerting influence on contributions from different provenance end-members between the Holocene and the last glacial period. The opposite directions of the southwest and northeast monsoon current in the BoB have a significant influence on the transfer of the Indian Peninsula and Myanmar materials to the studied core, which led to an increase of up to 11% than the average of the Indian Peninsula and a decrease of up to 9% than the average of the Myanmar source during the Holocene. The balance between sea level (limited transport to the deep sea) and ISM (improved erosion production and output to the BoB) during the mid-late Holocene period maintained the stability of Himalayan source percent. Due to the control of the ISM variations, the Himalayan source showed a decrease of up to 20% and 21% than average during the LGM and H1 period, respectively, and an increase of up to 14% than average during the EHCO. The Myanmar source exhibited fluctuations around the average value during the LGM period, but an obvious increase of up to 21% during the H1 period and a decrease up to 8% during the EHCO, while the Indian Peninsula source percent showed little variations during the LGM and H1, but a decrease of up to 6% during the EHCO. Obvious 1/4 processional and millennial periodic changes (5.0 kyr and 1.1 kyr) of contribution proportions from three end-members provide additional evidences for the climate control on the regional source-sink processes and proved the controlled mechanisms of the orbital parameters and possible influence from the solar activity on millennial scales.

The Huoshenmiao intrusion, which is located in the western domain of the Luanchuan ore district, comprises quartz diorite, monzogranite, and granite porphyry. LA–(MC)–ICPMS zircon U–Pb dating, whole-rock geochemistry, and Sr–Nd–Hf isotopes were conducted to constrain the timing of magmatism, and to reveal the petrogenesis and tectonic setting. Zircon U–Pb dating of the quartz diorite, monzogranite, and granite porphyry yielded ages of 150.3 ± 0.6 Ma, 146.0 ± 0.6 Ma, and 145.1 ± 0.5 Ma, respectively, indicating emplacement of the intrusion took place in the Late Jurassic. The three petrofacies are characterized by arc-like trace-element distribution, enriched in large ion lithophile elements and light rare earth elements, and depleted in high field strength elements. The quartz diorite is characterized by relatively low SiO2 content (56.79–61.96%), high Mg# (0.44–0.46), and Na2O-rich (Na2O/K2O = 0.95–1.43). However, the monzogranite and granite porphyry are characterized by relatively high SiO2 content (69.70–71.96%), low Mg# (0.23–0.28), and K2O-rich (K2O/Na2O = 1.20–1.93). The eNd(t) values of the quartz diorite range from −14.6 to −14.1 and the eHf(t) values range from −19.6 to −14.8, with model ages ranging from 2.09 to 2.44 Ga. The monzogranite and granite porphyry have eNd(t) values ranging from −16.8 to −14.7 and eHf(t) values in the range of −31.9 to −16.7, with model ages ranging from 2.13 to 3.21 Ga. The differences in elemental and Sr–Nd–Hf isotopic characteristics suggest that the quartz diorite was derived from a different magma source from the monzogranite and granite porphyry. Based on these new data, we propose that the quartz diorite was derived from partial melting of an enriched lithospheric mantle that experienced metasomatism owing to dehydration of the subducted continental crust of the Yangtze Craton. The monzogranite and granite porphyry were derived from partial melting of the Taihua TTG and the enriched lithospheric mantle. Model calculations using Sr–Nd isotopic data suggest that 50–70% of enriched lithospheric mantle material would be required to generate the monzogranite and granite porphyry. We propose that the Huoshenmiao intrusion was most likely associate with two subduction events, and generated in a back-arc extensional setting related to the subduction of the Izanagi Plate beneath the Eurasian continental margin.

Deep-sea sediments containing high concentrations of rare earth elements (REE) and yttrium (Y), termed REY-rich sediments, have attracted considerable attention and are widely distributed in the Pacific Ocean. However, the processes and mechanisms of REY enrichment in REY-rich sediments remain controversial. Here, we present our investigation of the mineralogical and geochemical characteristics of deep-sea sediments in three sediment cores from the western North Pacific Ocean. REY-rich sediments with very high total REY (ΣREY) concentrations (>3000 ppm) were discovered within the study area, which is characterized by middle REE (MREE) and heavy REE (HREE) enrichment. REY-rich sediments have unique geochemical characteristics and are different from known onshore REE ore deposits. Our results suggest that the pelagic clay sediments have higher ΣREY concentrations than the carbonate ooze sediments. Bioapatite fossil and micronodule are the main host minerals of REY in REY-rich sediments, whereas terrigenous, volcaniclastic, and calcareous materials can dilute ΣREY concentrations. The contribution of micronodule to REY enrichment in REY-rich sediments is relatively moderate compared to that of bioapatite fossil. Seawater is the main source of REY in REY-rich sediments. During diagenesis, bioapatite fossils absorb REY from seawater/porewater by substitution, whereas micronodules release REY (especially Ce) into the ambient solution. Thus, a migration of REY from micronodules to bioapatite fossils occurs. The bioapatite fossil is likely to act as the ultimate host of REY, while the micronodule acts as a temporary sink for REY. The enrichment and transformation of REY in the bioapatite fossils and micronodules mainly occur in the seawater column and the sea-sediment interface. The REY enrichment in deep-sea sediments was caused by the physical enrichment of REY-rich materials (bioapatite fossil and micronodule). The sedimentation rate, therefore, is an important controlling factor for REY enrichment. The formation of REY-rich sediments with ΣREY concentrations > 2000 ppm was likely to occur due to the additional contributions of enriched bottom currents.

Deep-sea sediments in the eastern South Pacific Ocean were recently found to contain high concentrations of rare-earth elements and yttrium (REY). To understand the genesis of REY enrichment in the sediments, we performed detailed element and isotope geochemical analyses on samples from gravity core S028GC23 recovered from the Tiki Basin in the eastern South Pacific Ocean. The REY-rich sediments in core S028GC23 are dark-brown to black zeolite clays, with REY (∑REY) contents of 1136–2213 ppm (average of 1857 ppm). The ∑REY contents in the sediments are positively correlated with P2O5 and negatively correlated with Ce anomalies. The REY-rich sediments display obvious Ce depletion and positive Y anomalies in the post-Archean Australian shale (PAAS)-normalized REY diagrams. Bioapatite fossils contain the highest REY concentrations (average of 8921 ppm) among the constituents, indicating that they are the primary hosts of REY. The REY enter through the roots and diffuse to the tops in the bioapatite fossils. Fe–Mn micronodules are divided into two different types based on Ce and Y anomalies in the PAAS-normalized REY patterns, and they have average REY concentrations of 781 ppm and 937 ppm, respectively. The phillipsite has low REY contents (average of 106 ppm) and is associated with a low sedimentation rate. REY patterns and Sr-Nd isotopic signatures show that seawater was the main ore-forming fluids during the formation of REY-rich sediments. The sedimentation rate of the sediments calculated by the 230Thex activities was 0.8 mm/Ka. The REY accumulation process can be explained by two-stage fluid-bioapatite fossil interactions and small contributions of Fe-Mn micronodules in an oxidized environment with slow sedimentation rate.

As an integral part of the Earth's climate system, the Kuroshio Current (KC) plays a crucial role in shaping the regional oceanography and climate in the Northern Hemisphere. However, how the KC dynamics have varied over glacial-interglacial cycles is still under debate. The dynamic transfer and accumulation of submarine hydrothermal source materials by deep-reaching KC offer us a unique opportunity to examine the variations in dynamics of the KC. Here, we used novel proxies of sedimentary mercury (Hg) and antimony (Sb) in core MD01-2404 retrieved from the middle Okinawa Trough (OT) to reconstruct the evolution of the KC hydrodynamics over the last 92,000 years. We infer the enrichments of sedimentary Hg and Sb to signify hydrothermal input, which is delivered laterally to the study site by deep circulation in association with the KC, thus indicating the dynamics of KC. Overall, both the sedimentary Hg and Sb in core MD01-2404 indicate a persistent influence on the KC dynamics within the OT over the last glacial-interglacial cycles. Furthermore, our Hg and Sb proxies suggest a significantly weakened influence during the last deglaciation and last glacial period while a strengthened influence during the Holocene and late Marine Isotope Stage 5. Our studies imply that the orbital-scale dynamics of KC are controlled by tropical atmosphere-ocean interactions induced by sea surface temperature changes and regulated by the extratropical climate conditions.

Numerical simulation suggests that the Holocene sediments re-suspension and distribution in the Bohai Sea was mainly controlled by tidal current regime, which was closely related with sea-level change. Study on sediments in the Bohai Sea thus can provide insights into the evolution of tidal-influenced sedimentary environment and its links with sea-level change. Our understanding of this issue remains incomplete, however, owing to the lack of comprehensive study on sediment core with high-resolution proxies to test such inference. In this study, analyses of sedimentary facies, proxies (grain size, total organic carbon and total nitrogen, X-ray fluorescence scanning Sulfur and Chlorine ratio) and accelerator mass spectrometry 14C dates of a sediment core recovered from the eastern Bohai Sea were carried out to clarify the Holocene sedimentary environment, tidal current change and its relation to the sea-level. The results indicate that the eastern Bohai Sea was dominated by fluvial-coastal environment prior to 12,400 cal a BP due to the sea-level lowstand and changed to tidal-influenced environment from 12,400 to 6700 cal a BP following the rapid sea-level rising. Thereafter shelf environment with minor tidal influence dominated the eastern Bohai Sea under the condition of a deceleration of sea-level rise. The significant change at ∼6700 cal a BP both in sedimentary environment and sediment proxies, indicating an environmental transition from strong tidal-influenced to less tidal-influenced setting. With the sea-level rising from the early Holocene to the mid-Holocene, tidal-current was much strong due to the low sea-level stand and became weak after the maximum transgression at ∼6700 cal a BP. These results are consistent with the numerical simulation, which suggested that less strong tidal current were the consequence of the most highstand sea-level since the mid-Holocene. Our study thus provides a sedimentary record to support the interpretation of numerical simulation-based tidal-influenced depositional process in the eastern Bohai Sea since the deglacial period.

In this study, we analyzed heavy metals in 404 surface sediment samples from the Bohai Sea to measure contamination status and distribution. We found Zn levels to be the highest, whereas Hg concentrations were the lowest of measured heavy metals. We found that the samples containing the most heavy metals were those collected from Fuzhou Bay, Jinzhou Bay, central Bohai Sea mud area, and the Yellow River Delta. Further analyses suggest that these heavy metals in surface sediments in the Jinzhou Bay and Fuzhou Bay pose a serious ecological risk, with substantial Cd and Hg accumulation in the Jinzhou Bay and Yellow River Delta regions being indicative of intense human activities.

Coastal sediments not only contain a majority of trace metals, but they also act as a source of dissolved metal ions to the overlying water column. Distinguishing the level of trace metal enrichment from the natural input in sediments is therefore important to determine the distribution and sources of land-derived detritus and pollutants in the coastal region. This study investigates fine (2) for As, Cd, and Pb, suggesting that the sediments were likely enriched by these elements. A comparative study of trace metals concentrations and EF with other coastal regions of China, however, revealed that the study area is in a pristine environmental condition compared to other coastal regions of eastern China. Factor analysis identified three dominant sedimentological and geochemical associations, accounting for ∼70% of total variance, recognize terrigenous input, heavy mineral role and anthropogenic input in controlling the distribution of most elements in the study area.

Millennial scale variations of terrigenous provenance in marine realm are closely related to regional environment and climate changes. Therefore, a wealth of information of past environment and climate can be constrained via fingerprinting sediment provenance. The Sea of Japan is a unique marginal sea in the North Pacific due to its high sill and distinct thermohaline circulation. The modern hydrography in the Sea of Japan is mainly affected by the East Asian Monsoon and Tsushima Warm Current, one branch of the Kuroshio Current. The Sea of Japan communicates with neighboring seas through four shallow and narrow straits, indicating great effects of global eustatic sea level change on its environment over glacial-interglacial cycles. Here we examine the terrigenous provenance in fine-grained fraction ( 85% terrigenous material is derived from the Yangtze and Yellow Rivers over the last 48 ka. Moreover, abrupt variations in sediment provenance occurred at ~18 ka and ~ 7 ka, which coincide with variations in oceanic surface circulation and deep ventilation recorded in the Sea of Japan. We suggest that paleo-Tsushima Warm Current invaded into the Sea of Japan with reopening of the Tsushima Strait at HS1 and the Tsushima Warm Current substantially entered the Sea of Japan after 7 ka due to intensified Kuroshio Current and rising eustatic sea level. The inflow of Tsushima Warm Current gives rise to a range of changes in surface hydrography, deep ventilation, ecological communities and productivity and sediment texture. The combination of fluxes of paleo-rivers and the intensity of Kuroshio Current, which are closely tied to the eustatic sea level and the East Asian Monsoon, plays a key role in controlling the variations in sediment provenance in the Ulleung Basin. Our study provides unique insight into the tight coupling between changes in sediment provenance and oceanic environment over the last 48 ka in the Sea of Japan.

Anthropogenic activities have increased lead (Pb) emissions and impacted their spatiotemporal distributions in coastal seas. To quantify the increasing variability of Pb and identify the specific origins and their corresponding magnitudes, Pb and Pb isotopes are investigated in a well-placed sediment core covering the period of 1928–2008 in the Central Yellow Sea Mud (CYSM). The concentration of Pb varied from 27.17 μg/g to 37.30 μg/g upwardly along the core, with pronounced anthropogenic disturbance since the late 1960s. The Pb input history of the CYSM experienced five stages according to industrialization levels and Pb contamination, with relative pristine stages from 1928 to 1969 and human activity-impacted stages from 1969 to 2008. The 206Pb/207Pb ratio demonstrated an overall decreasing profile while the 208Pb/206Pb ratio displayed the reverse trend upwardly along the core, possibly due to the atmospheric delivery of anthropogenic Pb emissions from northern China. Furthermore, 208Pb/206Pb vs. 206Pb/207Pb shows certain linearity between natural sediment sources and anthropogenic emissions of Pb (atmospheric deposition); thus, atmospheric inputs account for 34–43% of the Pb in the sediment since Pb enrichment using the two-endmember mixing model. Moreover, the steep decrease in 206Pb/207Pb and rapid increase in 208Pb/206Pb since the 1970s suggest the introduction of leaded gasoline and the increasing proportionate consumption of gasoline relative to total energy consumption. The continuously decreasing 206Pb/207Pb ratio and increasing 208Pb/206Pb ratio since 2000 are the combined results of coal consumption, nonferrous smelting, and residual Pb contamination from leaded gasoline, which is quite distinctive from cases in North America and Europe. The relatively high 206Pb/207Pb and low 208Pb/206Pb ratios before 1969 represent the natural Pb isotopic signatures. Hence, Pb input is significantly affected by regional energy consumption and restructuring, and the Pb isotopic ratios may be a potential proxy for the shift in energy consumption.

Organic carbon cycling in SE Asia is data-sparse and poorly studied, although high sediment yield and organic carbon intensity occur in the tropical region. In the present study, we evaluated the role of tropical monsoon pertaining to fluvial discharge, sediment load, coastal current and water stratification on seasonal organic carbon dynamics during four sampling campaigns in the Upper Gulf of Thailand (UGoT). This study demonstrates that particulate organic carbon (POC) is closely correlated with the river influx of suspended sediment, which is generally regulated by the local rainfall. Higher POC is found near the large estuarine section (Chao Phraya River, CHAO) during southwest monsoon period and the small estuarine section (Mae Klong River, MK) during November 2013 when tropical cyclones impacted. POC in the estuarine sections is more significantly influenced by the seasonal shift compared with the coastal sections. Land-derived organic matter prevails in the small estuarine and coastal sections, while marine-derived organic matter dominates in the estuarine sections impacted by CHAO and MK. Anthropogenic inputs and dam regulation also influences the river export of organic matter during the high precipitation periods. Total organic carbon (TOC) however displays less significant seasonal monsoon variations than POC. Further, TOC tends to accumulate in the sub-silt fraction of sediments, which mainly occurs in the small estuarine and eastern coastal sections and is more obviously influenced by marine-derived factors. TOC in sediment of the CHAO and MK influenced sections however displays more seasonal variations with prevailing river input evidenced by coarser sediment and higher C/N ratios. Moreover, the almost year round water stratification across the region acts as the barrier in retaining organic carbon in the estuaries and their vicinities from dispersal into the lower portion of Gulf of Thailand. High sedimentation rate (~1.1 cm·yr−1) further facilitates the organic carbon burial in the study area. The delivery, dispersal and burial of organic carbon are closely associated with the climate-controlled precipitation, and thus the tropical monsoon climatology under the global warming in particular is an important factor influencing the organic carbon in the UGoT.

Sediment accumulation in continental margins during the Quaternary Period was substantially influenced by both sea-level fluctuations and climate changes. However, the response of sediment accumulation to these changes on an orbital timescale, remains poorly understood, for two main reasons: the scarcity of sedimentary records with a high-resolution chronology, and the difficulty in distinguishing the role of sea-level from regional climate signals. Here we present the results of sediment color reflectance (c*), grain size and total organic carbon (TOC) content of core BH08 (212.4 m in length, spanning the last ~1 Myr) recovered from the Bohai Sea, China. The chronology of core BH08 on the orbital timescale is constrained by both magnetostratigraphy and astronomical tuning. Sedimentary facies analysis suggests that the sedimentary sequence is dominated by the alternation of a deltaic system and floodplain deposition. Principal components analysis of the grain-size data reveals two principal components (PCs), including PC1, reflecting the 31–500 μm fraction, and PC2, reflecting the 18–66 μm fraction. Comparison of sample scores on PC1, PC2 and c* with the alternation of sedimentary environments reveals that PC1 and c* reflect cycles of deltaic and floodplain deposition at ~100-kyr and ~40-kyr periodicities, while PC2 exhibits a ~20-kyr periodicity, in addition to the ~100-kyr and ~40-kyr cycles. We infer that PC1 and c* are mainly sea-level dependent, whereas PC2 is controlled by the combination of changes in monsoon climate and sea level. We suggest that Milankovitch-scale monsoon climate fluctuations controlled the sediments supply to the Bohai Sea during the last ~1 Myr, while the redistribution of sediments by marine processes (e.g., tidal currents) has partially obscured the monsoonal signal in the grain-size proxy (e.g., PC1) which instead is sensitive to sea-level change. Our results provide an example of the influence of climate and sea-level on sediment accumulation in a shallow continental margin setting influenced by monsoonal climate in an icehouse world.

The present study aims to examine the distribution, sources and potential risks of toxic metals in the northern Bay of Bengal, Bangladesh. We found Cu, Pb, Zn and Hg exhibited similar spatial distribution pattern. Influenced by the Ganges-Brahmaputra River and the Karnafuli River, there were higher concentrations of these metals associated with the finer sediment and higher TOC in the northeastern portion of the study area. Moreover, coal transportation was assumed to account for the distinctive spatial distribution of As with higher concentration down the Port of Chittagong in the eastern boundary. Chemical-screening level assessment demonstrated the majority of the metals exceeded the threshold effect values, indicating certain possibility of adverse effect. The concentrations of Ni were higher than the possible hazardous values, suggesting high possibility of harmful consequences. The uncontaminated sediments mainly distributed in northwestern and the central portions affected by the delta erosion and marine transported sediments.

Sediment core OS03-1 retrieved from the Akademia Nauk Rise in Southern Okhotsk Sea was analyzed for the contents of rare earth elements (REEs) and combined with carbon isotope (δ13C) time series of benthic foraminifera to infer changes in terrigenous accumulation and bottom water ventilation on glacial–interglacial timescales in the study area. The age model of OS03-1 was constructed by a combination of foraminifer δ18O stratigraphy and 14C AMS dating, revealing that the 380 cm long core provides a window on climate change in the southern Okhotsk Sea since ∼180 ka. A grain size-controlled-REE content shows strong glacial–interglacial changes. The Cerium and Europium anomalies vary from 0.89 to 1.32 and from 1.14 to 1.37, respectively. The (La/Yb)N values range between 0.55 to 0.92. Both results suggest a significant contribution of volcanic debris in the core sediments. In addition, the relationships between Sm vs. Nd suggest main contribution origin from the Amur River and sea ice during warm intervals and from the sea ice during cold intervals, indicating that the sea ice played an important role in transporting terrigenous materials to the study site in the southern Okhotsk Sea. During the last 180 ka, the mass accumulation rates (MAR) of ∑REEs are relatively higher during glacials and lower during interglacials with a peak accumulation during the early deglacial period. We infer that an intensified Mongolia High is responsible for the first-order accumulation pattern of ∑REEs in the southern Okhotsk Sea by mediating the dynamic changes in sea ice extent. Furthermore, six δ13C minima are associated with intensified Asian monsoon (AM) precipitation and maximum MARs of ∑REEs, indicating that the dominance of barrier layer effects by high fresh water input through sea ice melting. The maximum MAR of ∑REEs during the Marine Isotope Stage (MIS) 5c coincides with the minimum of benthic foraminiferal δ13C, indicating a major interruption of ventilation in the bottom water in the Okhotsk Sea. The major low ventilation event in the deep water of the Okhotsk Sea appears to be dampened by a cooling condition and a major blooming of surface productivity preceded the event.

The Bengal Fan, the largest submarine fan in the world, receives a large amount of terrestrial material from the Himalayas and the Indian Peninsula, making it an ideal area for studying land-sea interactions in different time scales. Using the major and trace element compositions of 98 surface sediment samples from the lower Bengal Fan, we identified the provenances of the sediments, calculated the relative contributions of each provenance, and further assessed their controlling factors. The statistic results of the major and trace elements confirm that terrigenous materials comprise the majority on the sediment and that the study area can be divided into three depositional provinces. The main sources of sediments are the Himalayas and Indian river systems, which can be distinguished in the Fe/Al-K/Al scatter diagram. Based on calculation results of a two end-member mixing model, the relative contributions of the Himalayas and the Indian rivers are 55% and 45%, respectively. However, the spatial distributions of sediments from these two sources in the three provinces exhibit a large variation. The Himalayan contributions decrease from 63% in province I (southeast part of the study area) to 53% in province II (central part of the study area) and 45% in province III (northwest part of the study area). Correspondingly, the contributions of Indian rivers increase from province I through province III. During the high sea levels of modern time, seasonal monsoonal currents play a key role in controlling the sediments transport from South Asia continent to the lower fan.