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Well-preserved SSE-dipping low-angle normal faults (LANF) active during the Early Permian (Cisuralian) were recognized along the northern margin of the Orobic Basin (central Southern Alps, N Italy). These faults, which escaped most of the Alpine deformations, exhumed the Variscan basement during the deposition of the upper part of the Lower Permian succession (Pizzo del Diavolo Formation). Fault planes show evidence of frictional processes typical of the upper crust associated with hydrothermal circulation, responsible for the deposition of cm to m thick tourmalinite and Uranium mineralization. The recognized LANFs interacted with high-angle normal faults producing half grabens that stored the Lower Permian deposits, where synsedimentary fault activity in their hangingwall is testified by abrupt vertical and lateral facies changes, thickness variations and by soft-sediment deformations. Mesoscopic structures, exposed in the hangingwall of a major LANF (the Aga-Vedello Fault system) along a synthetic high-angle normal fault, include conjugate normal faults, horst-and-graben, domino-style planar and listric faults, which clearly record synsedimentary deformations testified by liquefaction and dewatering structures, typical of pre-consolidation hydroplastic conditions. This xceptional record indicates deformations at shallow crustal level which occurred during the Early Permian along highangle normal faults soling into the LANFs, forming the northern boundary of the Orobic Basin. The outcrop continuity, the perfectly preserved relationships among high- and low-angle normal faults together with the synsedimentary record of fault activity and the occurrence of mesoscopic faults developed during the deposition of the sediments, make this case-study an excellent reference for the analysis of extensional tectonics in synsedimentary conditions. In addition, the occurrence of large LANF systems, typical of a stress regime characterized by a vertical σ1, suggests that the Lower Permian Orobic Basin was dominated by pure extension at least in the study area, alternatively to existing interpretations, which favor a transtensional origin of the basin. Strike-slip tectonics can be responsible for a later partial tectonic inversion of the basin, as testified by the angular unconformity with the overlying Upper Permian succession (Verrucano Lombardo), marking a Middle Permian stratigraphic gap.

The shallowest part (about 3 sec two-way traveltime) of theCROP line M-2A/I, acquired during 1991 in the Bonifacio Strait(between Corsica and Sardinia), has been reprocessed to improveits geological interpretation. The original target of the M-2A/I profilewas the entire crust and therefore the shallowest part was onlypartially interpreted. In this context, the re-processing procedure wascarried out to improve the signal-to-noise ratio and the resolutionof the M-2A/I seismic profile at shallow depth. The geologicalinterpretation of the reprocessed data aimed at the reconstructionof the sedimentary succession and the contact with the underlyingHercynian basement.The M-2A/I seismic profile has been interpreted identifyingdiverse seismic facies, interpreted considering the geological unitsoutcropping to the north (in Corsica) and to the south (in Sardinia)of the seismic profile. The study supports the existence of a thickMesozoic succession, onlapping the Hercynian basement, preservedbelow the Cenozoic succession in the Asinara Gulf, suggesting that theNurra succession continues northward below the sea. The Mesozoic succession is bordered by a major, east-dipping normal fault, east the Asinara Island ridge. The faults recognized in the seismic profile indicate a prevailing strike slip/transtensional tectonics, questioning the role of compressional tectonics suggested in a previousinterpretation. The obtained results also indicate the potential of reprocessing of existing seismic profiles, whose interpretation can be significantly updated thanks to the development of new processing procedures and to the continuous upgrade of the regional geological knowledge.

The Triassic crinoid Encrinus aculeatus is described from a single bedding plane of uncertain Pelsonian or early Illyrian or (less probable) late Ladinian origin from Val Brembana (Alpi Orobie, Bergamo, Italy) based on 36 more or less complete crowns and columns. The specimens represent an obrutional echinoderm lagerstatte of the Muschelkalk type. The individuals are semi-adult and juvenile; adult individuals are lacking. Morphological description and comparison with the holotype and additional material from the Lower Muschelkalk and basal Middle Muschelkalk of Upper Silesia (Poland) prove the assignment to Encrinus aculeatus. However, the species concept of genus Encrinus is critical because several characters are inconsistent. E. aculeatus occurs in the Middle Triassic (Bithynian to early Illyrian, ? early Ladinian) of the western Tethys shelf and Peritethys basins (Southern Alps, Balaton Upland, Germanic Basin). Encrinus aculeatus is regarded ancestral to the Upper Muschelkalk (latest Illyrian) E. liliiformis. Until now, E. liliiformis has not yet been proven with certainty from outside the Germanic Basin; references are based on isolated and undiagnostic material.

The comparison of subsidence curves obtained from deep wells in sedimentary basins represents a powerful tool to identify major changes in subsidence distribution, both in time and space. The construction of subsidence curves from 19 wells, covering a time interval from the Cretaceous to the present in the Gabes Basin (Pelagian Domain of the eastern Tunisian Platform), provided the opportunity to reconstruct the subsidence patterns across the basin. Changes in the subsidence rates in different wells allowed the identification of six time-intervals (stages). Stage boundaries are defined by major changes in subsidence trends in the 19 wells: each stage is characterized by changes in the subsidence pattern of groups of wells, likely reflecting episodes of re-organization of the distribution of domains with different trends (increase or decrease) of subsidence. Comparisons among the subsidence curves highlighted, for each stage, parts of the basins with higher or lower subsidence, permitting to identify highs and lows and to reconstruct their significance in the different stages identified. The basin-scale changes in the distribution of subsidence rates reflect regional events of basin re-organization, potentially controlled by syndepositional faults or, for some stages, by halokinesis, due to the presence of salt deposits in the southern part of the study area. The comparison of the subsidence curves permitted to identify domains characterized, in different time intervals, by different patterns of subsidence rates, providing important elements for the characterization of the different stages in the stratigraphic and tectonic evolution of the basin.

The extensional Val Roveto Fault, which is the longest exhumed potentially-seismogenic structure of central Apennines, Italy, is examined to constrain earthquake-related fluid circulation and fluid sources within shallow carbonate-hosted faults. The study focuses on fault-related comb and slip-parallel veins that are calcite-filled and cut through the principal surface of the Val Roveto Fault. We observe multiple crack-and-seal events characterized by several veining episodes, probably related to different slip increments along the fault plane. We show that vein calcite precipitated in Late Pleistocene time below the present-day outcrop level at a maximum depth of similar to 350 m and temperatures between 32 and 64 degrees C from meteoric-derived fluids modified by reactions with crustal rocks and with a mantle contribution (up to similar to 39%). The observed warm temperatures are not compatible with a shallow (

The Upper Palaeozoic Godar-e-Siah Complex of Jandaq, Central Iran, comprises three isolated, fault-bounded outcrops exposing Palaeozoic fossiliferous carbonates, volcanics and siliciclastics, which are markedly distinct from the surrounding sedimentary successions. The three outcrops, that emerge below Cretaceous and younger sediments, are the Chah Rizab outcrop, the Godar-e-Siah northern outcrop, and the Godar-e-Siah central outcrop. Their sedimentary successions strongly differ from the typical passive margin successions of Gondwanan affinity that characterize the Yazd, Lut and Tabas blocks of Central Iran and the Alborz in North Iran. To understand the origin of these profound differences, we first calibrated the age of the Jandaq successions: U-Pb radiometric zircons ages, obtained from granitoid boulders in the conglomerates at Chah Rizab and in the Godar-e-Siah northern outcrop, gave a Late Devonian to Mississippian age. Biostratigraphic data from brachiopods and fusulinids from the Godar-e-Siah northern and central outcrops indicate a Pennsylvanian age. The age of the successions is thus post-Visean to Pennsylvanian. The petrographic composition of the siliciclastic deposits indicates the erosion of a magmatic arc. To understand where the Jandaq complex could have been located at that time, we have assessed the palaeobiogeographic affinity of the faunas. The collected brachiopods and fusulinids assemblages are mostly similar to coeval faunas from Spain, Donbass, Urals, and Yukon Territory (Canada) and have a North-Palaeotethyan affinity. The Godar-e-Siah Complex of Jandaq likely represents part of the southern active margin of Eurasia (northern margin of the Palaeotethys), in contrast to the surrounding Central and North Iran blocks, which were at that time located along the southern margin of the Neotethys. Our investigations confirm a complex palaeogeographic evolution for the studied outcrops, suggesting that they represent fragments of the southern Eurasian active margin - today preserved in NE Iran - displaced by crustal-scale wrench motions related to the opening and closure of the Sabzear Ocean and to the Cenozoic activity of the Great Kavir-Doruneh Fault and its possible precursors.

New age estimates obtained via Strontium Isotope (87Sr/86Sr) Stratigraphy and new paleoclimatic data are here presented for the Miocene Chilcatay and Pisco formations exposed in the East Pisco Basin, an Andean forearc basin of southern Peru, which is renowned worldwide for its exceptional content of fossil marine vertebrates. Mollusk and barnacle shells, carbonate nodules, and shark teeth were collected along three stratigraphic sections for applying Strontium Isotope Stratigraphy on both carbonates and phosphates. To avoid diagenetic biases, mollusk and barnacle shells were analyzed in detail by means of optical and scanning electron microscopy, cathodoluminescence, and inductively coupled plasma-optical emission spectrometry, whereas only the enameloid from the best-preserved shark teeth was sampled. The obtained 87Sr/86Sr ages confirm a late early Miocene (Burdigalian) age for the Chilcatay strata, and reveal middle Miocene (Langhian to Serravallian) ages for the lower Pisco unit (i.e., the P0 sequence) – a result that matches the relatively archaic aspect of its cetacean fossil assemblage. New and literature data about the fossil assemblage of the lower Pisco beds highlight the presence of several thermophilic invertebrates and vertebrates, thus suggesting a warm-water, tropical paleoenvironment for this middle Miocene sequence. Such a paleoenvironmental scenario recalls the warm conditions associated with the Chilcatay Formation, rather than the cooler setting inferred for the remainder of the Pisco Formation (i.e., the P1 and P2 sequences). This pattern likely reflects the late Miocene trend of global cooling, as well as a middle to early late Miocene strengthening of the Humboldt Current.

Fault inversion may lead to significant obliteration of earlier tectonic structures, thus preventing the straightforward interpretation of the complete kinematics and deformation history of faults. We adopt a multidisciplinary approach to: (1) reconstruct the tectonic evolution through space and in time of the extensionally-inverted Mt. Tancia Thrust (Central Apennines, Italy); (2) understand the deformation mechanisms and the transition and reactivation of compressional structures during negative tectonic inversion; and (3) constrain the origin of fluids involved during tectonic processes. To this end, we combined: (1) detailed geological mapping and multiscale structural analysis; (2) illite-smectite paleothermal indicators; (3) C, O, and clumped isotopes on calcite mineralizations and (4) K–Ar dating of authigenic and/or syn-kinematic illite from the Mt. Tancia Thrust fault rocks. We show that shortening occurred between ~9 and ~7 Ma, during possibly multiple events of fluid overpressure and shear rupturing involving fluids entrapped over long term within the host rocks. Post-compressive tectonic inversion occurred at ~3 Ma under fluid pressure fluctuations during shear events with an input of meteoric-derived fluids. Tectonic inversion is spatially confined within the first few metres below the thrust surface in a volume dominated by the partial overprinting, folding, transposition, and re-utilization of the earlier compressional fabric.

Lower Permian continental deposits of the fault-controlled Orobic Basin (Central Southern Alps; Northern Italy) include alluvial fan facies interfingering with muddy basin-floor deposits, consisting of three facies associations: heterolithic fine-grained siliciclastic facies, laminated sandstone facies, and oncoidal limestone facies. Besides oncoidal and microbial limestones, carbonates occur as nodules in sandy tabular beds within the laminated sandstone facies association. Microfacies analyses distinguish several types of oncoidal carbonate (consisting of an alternation of microbial carbonate and fibrous calcite) and carbonate nodules. Each type of carbonate has been characterized in terms of δ18O and δ13C. The two types of carbonate in the oncoids record a stable δ18O and a slightly varying δ13C, whereas the isotope composition of the calcite in nodules is completely different. Carbonate nodules in sandy beds of the laminated sandstone facies association have a diagenetic origin as indicated by cross-cutting relationships between nodules and lamination; the nodules are interpreted as groundwater calcrete, formed in the subsurface at the top of the unconfined water table. The exclusive sedimentation of oncoidal carbonate facies within siliciclastic deposits indicates that when oncoids were formed in ephemeral shallow ponds, siliciclastic input was minimal. The sedimentological and geochemical characteristics of the studied succession and the stable isotopic composition of the oncoids (the absence of covariance between δ18O and δ13C excludes deposition in evaporating basins) indicate persistent stable conditions for sufficient time to permit growth of centimeter-sized oncoids. Oncoids are interpreted to have formed in spring-fed ponds and outflow channels, with flowing, clean water, at the toe of major alluvial fans. Episodes of rapid delivery of sand and silt-sized sediments by flash floods, with an oscillating water table, caused the observed facies alternation. The precipitation of calcareous cements close to the water table surface produced nodules in sandy layers. Carbonate precipitation within laminated sandstone reduced porosity and permeability, causing a strong compartmentalization in the well-bedded continental succession.

Arragoni et al. (2016) suggest in their paper published on Tectonics that the carbonate succession of Eastern Sardinia represents a Cenozoic fold-and-thrust belt, related to the Alpine orogenesis. According to these Authors, this supposed fold-and-thrust belt represents the southward prosecution of the Alpine Corsica collisional chain and the missing link between the Alpine Chain and the Calabria-Peloritani domain. Field evidence and the published literature document instead that all the surfaces that Arragoni et al. interpret as thrust are actually stratigraphic contacts. The balanced geological section of Arragoni represents thus a geometric exercise missing the basic data needed to nurse the proposed model and it does not reflect the geology of eastern Sardinia. The data provided by Arragoni et al. (2016) do not supported the presence of an Alpine thrust and fold belt in eastern Sardinia and this paper may suggest to the geological community a misleading interpretation of the geodynamic evolution of the Alpine and Mediterranean area.

The demise of the high-relief, steep-slope, prograding Ladinian-Early Carnian carbonate platforms of the Esino Limestone (Central Southern Alps of Italy) is marked by subaerial exposure of the platform top associated with different erosional (mainly karst-related), depositional and diagenetic processes (Calcare Rosso). The exposure-related deposits consist of three major facies associations: 1) residual soils with thin lenses of conglomerates with black pebbles, and, locally, weathered vulcanites; 2) chaotic breccia lenses irregularly distributed in the uppermost part of the Esino Limestone carbonate platform, interpreted as collapse breccias in karstic setting: 3) inter-supratidal carbonate cycles with dissolution and development of paleosols and tepee structures. Facies distribution follows the sub-environments of the underlying Esino Limestone. Facies 1 and 2 typically characterize the core of the platform, covering the underlying inner platform facies. Facies 3 instead develops toward the edge of the platform, above reef-upper slope facies of the prograding facies of the Esino Limestone. The thickness of facies 3 decreases toward the core of the platform. Facies distribution reflects differences in the accommodation space and sedimentary processes from the rim (highest accommodation, favouring the deposition of peritidal-supratidal carbonates) to the core (reduced accommodation, causing pedogenesis and karstification) of the carbonate system. The observed thickness changes may be controlled by different factors: 1) syndepositional tectonics, 2) subsidence induced by magmatic activity or 3) differential subsidence controlled by the stratigraphic architecture of the Esino Limestone platform and adjoining basins. As evidence of tectonics was not observed and the presence of volcanic bodies is only documented tens of km away from the study area, the scenario involving the creation of accommodation space by compaction of the basinal sediments (resedimented, fine-grained calciturbidites) during the progradation of the carbonate platform is here investigated. Numerical modelling was performed to verify the compatibility of compaction-induced subsidence with the observed depositional architecture. The models were built to simulate the architectural evolution of the platform by progressively adding layers from deepest to shallowest, while compacting the underlying sediments, in order to evaluate compaction-induced subsidence (and accommodation space for the Calcare Rosso) after the deposition of the youngest platform strata. Modelling results allow us to conclude that the wedge geometry of the Calcare Rosso, deposited on top of the extinct Esino carbonate platform, can be explained by subsidence controlled by compaction of the basinal sediments present below the early-cemented, fast prograding platform slope deposits.

Continental successions in fault-controlled extensional–transtensional basins store a wide range of clastic deposits from various depositional environments, representing a challenging target for hydrocarbon exploration. Recent advances in field-based facies analysis and genetic interpretation of these sediments show that these successions are characterized by great variability in terms of volume, geometry, facies, and stacking patterns. This variability derives from a number of factors that govern the sedimentary processes, such as tectonic setting, basin size and morphology, type and amount of sediments, and climate. The study focuses on a well-exposed Early Permian continental succession (Southern Alps, northern Italy), which was deposited in an extensional–transtensional tectonic regime under a semiarid to arid climate. The study area is characterized by a thick (more than 1000 m) succession of prevailing continental clastics with intercalations of ignimbritic flows and tuffs (Pizzo del Diavolo) Formation resting on up to 800 m of prevailing pyroclastic flows (Cabianca Volcanite). These units are unconformably covered by the Upper Permian alluvial sediments of the Verrucano Lombardo. Sedimentological features reflect a proximal fan system where mass-flow phenomena dominate, a distal fan-terminal setting with prevailing sandy sheet-flow processes and a silty floodplain environment, where sheet-flood events dominate. Laterally continuous siltstones and dark shales with carbonate nodules and layers of microbial carbonates in the most depressed part of the basin indicate alternating conditions of shallow lake and desiccated floodplain. Syndepositional tectonic activity is documented in the succession by rapid vertical and lateral facies changes. In this study, we present a data-constrained reconstruction of the depositional architecture of the basin, a description of depositional processes and depositional environments, and a model of facies distribution. Outcrop data, integrated with laboratory analyses, provide a detailed understanding not only of the small-scale elements of the system (sub-seismic scale) but also of the entire basin, focusing on how those elements are interrelated. The studied succession can be considered an interesting outcrop analogue for subsurface extensional–transtensional basins, potentially useful to predict reservoir properties for similar subsurface settings.

The petrographic, cathodoluminescence (CL), stable isotope, and microthermometry investigation of inner platform facies of the pervasively dolomitized carbonate platform of the Norian (Upper Triassic) Dolomia Principale (Southern Alps, N Italy) identified two major dolomite phases. An early replacement fabric-retentive dolomite (D1 and D2, respectively replacing the sedimentary facies - from fenestral mudstone/wackestone to bioclastic packstone and mudstone and stromatolites- and early marine cements) is followed by a later, vug- and fracture-filling dolomite cement phase (D3, planar-s texture). The fabric-retentive dolomitized carbonates ( The δ13C values of the investigated dolomites (D1, D2, and D3) show a narrow range of variation (2.0–3.1‰ VPDB), pointing toward a fluid-buffered system. Differently, the δ18O values largely varies, ranging from −12.8 to +1.9‰ VPDB. In this range, D3 values cluster distinctively between −6.0 to −12.8‰ VPDB with respect to D1 and D2, which cluster from about −4 to +1.9‰ VPDB. The estimated oxygen isotope composition of the parent fluid of D1 and D2 (~0 to −5‰ VSMOW) suggests possible contributions from marine to slightly evaporated seawater, which is consistent with the arid climate and some basin restrictions suggested by earlier studies, whereas that of D3 (+1 to +5‰ VSMOW) is consistent with burial fluids. The followed integrated approach highlights the possibility to better characterize the occurrence of multiple diagenetic events in time and space, as well as their feedback effects on the porosity evolution of dolomitized carbonate reservoirs, framing the diagenetic events at regional scale.

The evolution of the Cambrian-Middle Ordovician carbonate systems in the east-central Tarim Basin, northwestern China, has been investigated using 2D seismic profiles and well data. Interpretation was performed on seismic profiles flattened along an originally horizontal surface (base of the Cambrian), to remove the effects of post-depositional deformations. Six seismic facies differently arranged in six seismic stratigraphic units record four major stages of architectural evolution, from ramp to flat-topped systems, with differences from north to south: (1) the onset of a homoclinal ramp over a clayey unit at the beginning of Early Cambrian; (2) the development of a prograding carbonate platform characterized by restricted (evaporitic) facies in the inner platform domain during Early Cambrian to Late Cambrian; (3) the development of a first prograding and a aggrading (retrograding to the north) platform during Lower Ordovician; (4) the development of a prograding/retrograding to aggrading final platform during Middle Ordovician. The basinward (eastward) progradation of the carbonate platform edge has been reconstructed in time steps, highlighting differences from the north to the south of the study area in terms of amount of progradation, platform-to-basin relief and depositional surfaces, likely controlled by differences in subsidence and environmental factors. The identification of the four major stages in the evolution of the lower Paleozoic succession of the Tarim Basin was likely controlled by changes in the rate of creation/destruction of accommodation space, due to the interplay between eustatic changes and tectonic events. The demise of the Cambrian to Middle Ordovician carbonate system in the study area is associated with a major tectonic event, recorded by a tilting of the succession toward the east (onlapped by sediments coming from the east) and an uplift (bulge) of the western part of the study area.

Quantitative analysis of depositional systems using numerical models can provide insights into the interaction of sedimentological and diagenetic processes, difficult to interpret from observation of the geological products alone. Numerical models can highlight the interactions between controlling parameters, and generate best estimate simulations of case studies from the geological record. Different data sources (e.g., outcrop data, uniformitarian constraints, paleogeography) need to be considered in the process of defining the parameters required to produce models that honour individual case studies. We present a best-estimate forward model of a high-relief Triassic carbonate platform (Southern Alps, Italy) generated using CARB3D+, a 3D process-based forward modelling package able to simulate sedimentary facies, geometries and early diagenesis of isolated carbonate platforms. The parameters used for the presented forward model have been deduced by the study of architectural, sedimentological and diagenetic features of the platform, and by data from modern and ancient analogues. Sensitivity analysis is used to tune values of the parameters within ranges defined from field, laboratory and uniformitarian constraints. Critical evaluation of the model allowed 1) verification of the validity of the used parameters; 2) evaluation of the interaction between controlling parameters; 3) development of a numerical model that can be used for quantitative elaborations. Furthermore, the process of generating the numerical model required a detailed interpretation of field and laboratory data, crucial to define the required input parameters. Modelling the studied carbonate platform also enabled evaluation of the effects of the interaction between productivity, environmental energy and creation of accommodation space, promoting the understanding of their role on the architecture of carbonate systems. Forward modelling also allows the integration of data from conventional data sets with data from present-day observations and seismic geometries, promoting a transition from a qualitative to a semi-quantitative/quantitative sedimentological approach. Forward models can further be used to parameterise petrophysical properties of complex geobodies, with potential application for the management of georesources.

The Esino Limestone of the western Southern Alps represents a differentiated Ladinian-Lower Carnian (?) carbonate platform comprised of margin, slope and peritidal inner platform facies up to 1000 m thick. A major regional subaerial exposure event lead to coverage by another peritidal Lower Carnian carbonate platform (Breno Formation). Multiphase dolomitization affected the carbonate sediments. Petrographic examinations identified at least three main generations of dolomites (D1, D2, and D3) that occur as both replacement and fracture-filling cements. These phases have crystal-size ranges of 3–35 μm (dolomicrite D1), 40–600 μm (eu-to subhedral crystals D2), and 200 μm to 5 mm (cavity- and fracture-filling anhedral to subhedral saddle dolomite D3), respectively. The fabric retentive near-micritic grain size coupled with low mean Sr concentration (76 ± 37 ppm) and estimated δ18O of the parent dolomitizing fluids of D1 suggest formation in shallow burial setting at temperature ∼ 45–50 °C with possible contributions from volcanic-related fluids (basinal fluids circulated in volcaniclastics or related to volcanic activity), which is consistent with its abnormally high Fe (4438 ± 4393 ppm) and Mn (1219 ± 1418 ppm) contents. The larger crystal sizes, homogenization temperatures (D2, 108 ± 9 °C; D3, 111 ± 14 °C) of primary two-phase fluid inclusions, and calculated salinity estimates (D2, 23 ± 2 eq wt% NaCl; D3, 20 ± 4 eq wt% NaCl) of D2 and D3 suggest that they formed at later stages under mid-to deeper burial settings at higher temperatures from dolomitizing fluids of higher salinity, which is supported by higher estimated δ18O values of their parent dolomitizing fluids. This is also consistent with their high Fe (4462 ± 4888 ppm; and 1091 ± 1183 ppm, respectively) and Mn (556 ± 289 ppm and 1091 ± 1183 ppm) contents, and low Sr concentrations (53 ± 31 ppm and 57 ± 24 ppm, respectively). The similarity in shale-normalized (SN) REE patterns and Ce (Ce/Ce*)SN and La (Pr/Pr*)SN anomalies of the investigated carbonates support the genetic relationship between the dolomite generations and their calcite precursor. Positive Eu anomalies, coupled with fluid-inclusion gas ratios (N2/Ar, CO2/CH4, Ar/He), high F− concentration, high F/Cl and high Cl/Br molar ratios suggest an origin from diagenetic fluids circulated through volcanic rocks, which is consistent with the co-occurrence of volcaniclastic lenses in the investigated sequence.