1. The role of emissions and meteorology in driving CO2 concentrations in urban areas
- Author
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Federico Carotenuto, Sara Di Lonardo, Carolina Vagnoli, Giovanni Gualtieri, Piero Toscano, Beniamino Gioli, and Alessandro Zaldei
- Subjects
Artificial neural network ,Meteorology ,Mean squared error ,Health, Toxicology and Mutagenesis ,Eddy covariance ,Self-organized maps ,General Medicine ,010501 environmental sciences ,Sensible heat ,01 natural sciences ,Pollution ,CO2 concentrations ,Wind speed ,Air temperature ,urban CO2 fluxes ,Meteorological conditions ,Environmental Chemistry ,Environmental science ,Relative humidity ,Negative correlation ,Urban scale ,0105 earth and related environmental sciences - Abstract
A multi-year dataset of measurements of CO2 concentrations, eddy covariance fluxes, and meteorological parameters over the city centre of Florence (Italy) has been analysed to assess the role of anthropogenic emissions and meteorology in controlling urban CO2 concentrations. The latter exhibited a negative correlation with air temperature, wind speed, solar radiation, and sensible heat flux and a positive one with relative humidity and emissions. A linear and an artificial neural network (ANN) model have been developed and validated for short-term modelling of 3-h CO2 concentrations. The ANN model performed better, with mean bias of 0.58 ppm, root mean square error within 30 ppm, and r2=0.49. Data clustering through the self-organized maps allowed to disentangle the role played by emissions and meteorological parameters in influencing CO2 concentrations. Sensitivity analysis of CO2 concentrations revealed a primary role played by the meteorological parameters, particularly wind speed. These results highlighted that (i) emission reduction actions at local urban scale should be better tied to actual and expected meteorological conditions and (ii) those actions alone have limited effects (e.g. a 20% emission reduction would result in a 3% CO2 concentrations reduction). For all these reasons, large-scale policies would be needed.
- Published
- 2021
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