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International audience; Synrift stratigraphy and the distribution of breakup-related erosional unconformities vary vastly between passive margins and cannot be explained by classical rifting models. Here we use numerical modeling to predict their spatiotemporal distribution. We show that synrift stratigraphy mimics rift architecture, which is controlled by lithospheric strength. Basinward rift migration during extension produces (1) oceanward younging, syntectonic and posttectonic sequences, (2) rift migration unconformities, RMUs, predating breakup, and (3) a breakup unconformity, BU, that only extends over the outermost margins, since breakup is not linked with a sudden stress drop. With small synrift sedimentation, the RMUs and BU laterally merge to form a margin-wide unconformity. In symmetric, wide conjugate margins, which arise for weak lithospheres such as the South China Sea, a long phase of distributed deformation with little subsidence results in early synrift sediment over most of the margins. RMUs merge into a single event that marks the subsequent focusing of deformation into a narrow breakup area, which experiences short-lived intense thinning and subsidence. In asymmetric conjugate margins, lateral rift migration transports shallowly deposited, early synrift sediments from the narrow to the wide, hyperextended margin, leading to a condensed syntectonic sequence and a single BU in the narrow margin and a series of RMUs in the wide one. For very weak lower crusts, lateral rift migration generates large synrift sag basins in the wide margin, as in Angola and Congo margins. Our models resemble the observed margins tectonic diversity and may be used as templates for interpreting their distal, unexplored areas.

Made available in DSpace on 2020-12-12T02:40:36Z (GMT). No. of bitstreams: 0 Previous issue date: 2020-08-01 Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) The Avalon biota (Ediacaran Period, 570–559 Ma) marks the first appearance of macroscopic and complex benthic communities in the fossil record. This assemblage is known from a few localities worldwide, mainly in Canada and England. Here, we report for the first time the presence of Ediacaran macrofossils in deposits of similar age from Gondwana (Itajaí Basin, southern Brazil). Our new radiometric date (~563 Ma) indicates that the Itajaí Basin can be chronocorrelated with the classic Avalonian deposits and thus represents one of the oldest records of the Ediacaran biota in Gondwana. We describe the presence of the Ediacaran genus Palaeopascichnus, as well as discs (Aspidella and Nimbia), and other problematic forms. Contrary to the deep-marine macroorganisms of the Avalon Assemblage, the Itajaí fossils are associated with abundant and exceptionally preserved three-dimensional microbial mats and microbially induced sedimentary structures (MISS) in relatively shallow settings (upper slope and distal delta front deposits). In this sense, the Itajaí biota could represent early adaptations of benthic macrobiota to the shallower and more photic environments that characterize the later White Sea Assemblage. Programa de Pós-Graduação em Ecologia e Recursos Naturais Universidade Federal de São Carlos, Washington Luiz, 325km Unité Mixte de Recherche (UMR) Centre National de la Recherche Scientifique (CNRS) IC2MP 7285 University of Poitiers Programa de Pós-Graduação em Geologia Universidade do Vale do Rio dos Sinos Petrobras Instituto de Geociências Universidade de São Paulo, Rua do Lago, 562, Cidade Universitária Petrobras Research Centre – CENPES Instituto de Geociências e Ciências Exatas (IGCE) Universidade Estadual Paulista (UNESP) Departamento de Biologia Universidade Federal de São Carlos – campus Sorocaba, Rod. João Leme dos Santos km 110 Instituto de Física Universidade de São Paulo, Rua do Matão, Travessa R 187 Instituto de Geociências e Ciências Exatas (IGCE) Universidade Estadual Paulista (UNESP) FAPESP: 2016/01827-4 FAPESP: 2018/21886-0

International audience; The up to 3000 m thick Mesoproterozoic and Neoproterozoic sedimentary succession exposed at the southern border of the São Francisco Craton, São João del Rei region (southern Minas Gerais State, Brazil), records the stacking of five sedimentary basins. These basins evolved due to multiple rifting episodes related to the southernmost Espinhaço rift system and were deformed around 600 Ma during the evolution of the Ribeira Orogen. These basins are the 1- São João del Rei Basin with quartzite units with maximum depositional age of ca. 1.5 Ga preserved in a half graben associated to the younger rift phases, 2- Carandaí Basin with rift related fault bounded debris flow deposits with maximum depositional age of ca. 1.38 Ga, and a sag carbonate infill recording the post-rift thermal relaxation, 3- Prados Basin, an NE-SW aulacogen linked to the passive margin Andrelândia Basin (

Continental breakup in magma-poor rifted margins can develop, in some instances, after the formation of a wide exhumed domain that can be several hundreds of km wide. As exhumation of the continental mantle occurs serpentinization, due to seawater circulation, can extend as far down as 5–6 km, as observed in refraction seismic data. The impact caused by the process of serpentinization within the evolving ocean may have the potential to change: (i) seawater chemistry; (ii) sustain the evolution of primitive life; (iii) control depositional environments; and (iv) form weak zones preferentially used during the formation, reactivation and subduction of distal rifted margins. Based on geological observations, and geophysical and geochemical data from present-day and fossil zones of exhumed continental mantle, we present a first-order quantification showing that approximately 0.380 km3 of water per km2 can be stored in the mantle. Using simple methods, it can be shown that serpentinization may account for a significant loss of Si, Mg, Fe, Mn, Ca, Ni and Cr during serpentinization of mantle rocks. In particular during latest stages of rifting, when basins are often restricted and seaways are not yet connected, exhumation and the serpentinization of large areas of continental mantle may result in a major transfer of elements between the main Earth reservoirs, such as the mantle and seawater.

International audience; Minerals and elements are important proxies that can provide information about variations in the delivery and deposition of coastal ocean sediments associated with past climate changes. In this study, postglacial changes in the accumulation of sediments on the upper shelf of southeastern Brazil are linked to the evolution of regional paleoceanographic and continental paleoclimatic conditions during the last 14.4 kyr CAL BP. Mineralogical and major and trace element analyses of a 14C-dated sediment core identify three main lithostratigraphic units of this core that reveal a succession of changes in sediment delivery and accumulation as postglacial sea level rose and Holocene climate on land evolved. The depositional setting has transitioned in response to the large sea level rise prior to 9.9 kyr CAL BP from being a shallow water high energy environment to a deeper water one. This location has since then been a lower energy environment that has persisted into modern times. Due to the high marine productivity associated with the Cabo Frio upwelling system in an oxygenated water column, the sediments have shown a complex and dynamic redox condition, making variations in redox-sensitive trace elements indicative of changes in primary production and organic matter diagenesis at this location. After sea level stabilized ~ 9 kyr CAL BP, variations in fluxes of Al, Fe, Ca, and minerals were small, indicating that climate driven changes had only secondary controls on delivery of detrital sediment components to the Cabo Frio shelf. Modern coastal upwelling conditions and the onset of mid-shelf organic-rich sediment deposition were established after 9.9 CAL kyr BP.

New, hitherto unpublished miospore information from the Middle and Upper Devonian of the Parnaiba Basin, northeastern and northcentral Brazil, has enabled refinement of the chitinozoan zonation recently proposed for that basin. To a large extent, Devonian miospore zones defined for the Amazonas Basin can be also recognized in the Parnaiba Basin and other Western Gondwanan basins. The miospore zones are discussed and compared to the coeval Southern Euramerican miospore zonation, the regional Petrobras palynozones, and to the chitinozoan zonation of the Parnaiba Basin, additional Western Gondwanan regions, and other parts of the world.

International audience; The existence of gas hydrate systems along Brazil's vast continental margin has been known since the 1980s, based on observations of bottom simulating reflectors (BSRs) in two large shelf-slope depocenters: (1) the Amazon deep-sea fan in the Foz do Amazonas Basin and (2) Rio Grande Cone in Pelotas Basin. These depocenters are both undergoing gravitational collapse above deep detachment surfaces, resulting in upslope extensional and downslope compressional domains. The BSR is discontinuous across the Amazon deep-sea fan, mainly observed at water depths of 600-2800 m and at anticlines within an upper slope thrust-fold belt related to the compressional domain of the fan. Conversely, a fairly continuous BSR extends across Rio Grande Cone at water depths of 520-3500 m, within both extensional and compressional domains. Interestingly, the well-defined BSR that spans Rio Grande Cone rises to meet the seafloor at water depths of 515-520 m, forming an unusual 'BSR outcrop'. This phenomenon has been observed previously in only a few locations worldwide. Gas hydrates have been recovered within piston cores taken from seafloor seeps in both depocenters, and analyses reveal that gas is dominated by methane of microbial origin.

Trace element distribution and Zr-in-rutile temperature have been investigated in accessory rutile from stratiform (UG2, Merensky Reef, Jacurici), podiform (Loma Peguera), and metamorphic chromitites in cratonic shields (Cedrolina, Nuasahi). Rutile from chromitite has typical finger-print of Cr-V-Nb-W-Zr, whose relative abundance distinguishes magmatic from metamorphic chromitite. In magmatic deposits, rutile precipitates as an intercumulus phase, or forms by exsolution from chromite, between 870 °C and 540 °C. The Cr-V in rutile reflects the composition of chromite, both Nb and Zr are moderately enriched, and W is depleted, except for in Jacurici, where moderate W excess was a result of crustal contamination of the mafic magma. In metamorphic deposits, rutile forms by removal of Ti-Cr-V from chromite during metamorphism between 650 °C and 400 °C, consistent with greenschist-amphibolite facies, and displays variable Cr-Nb, low V-Zr, and anomalous enrichment in W caused by reaction with felsic fluids emanating from granitoid intrusions. All deposits, except Cedrolina, contain Rutile+PGM composite grains (&lt, 10 µm) locked in chromite, possibly representing relics of orthomagmatic assemblages. The high Cr-V content and the distinctive W-Nb-Zr signature that typifies accessory rutile in chromitite provide a new pathfinder to trace the provenance of detrital rutile in placer deposits.

We question the timing of continental breakup and early oceanization in Baffin Bay, North-East Atlantic. North of the Ungava fault zone, the breakup was syn-magmatic and led to the development of conjugate volcanic passive margins (VPMs). We investigated the innermost part of the W-Greenland VPM where a remarkable inner-SDR is fully exposed in the Svartenhuk area. Our new radiometric ages and paleomagnetic data from syn-tectonic basaltic lavas indicate that continental stretching and thinning spanned the C26r to, at least, the C24r period, giving an Eocene lower boundary age for continental breakup in Baffin Bay. These results contradict the proposed flooring of Baffin Bay by a Paleocene oceanic crust older than C24n and also question the accretion of oceanic crust before C22. We confront our results to the dynamics of the northward oceanic-rift propagation across the Ungava transform fault system, and we suggest that plate breakup in Baffin Bay occurred ~8 m.y. later than in N-Labrador Sea as a result of the thermal and mechanical barrier effect induced by the Ungava transform zone.

International audience; This article presents an integrated approach based on stratigraphic forward modeling and reactive transport modeling to adequately represent the development of a mixed siliciclastic-carbonate sedimentary system and its diagenesis. This work was realized on a realistic case study, the Oligo-Miocene series of Carry-le-Rouet, South-East of France, characterized by a complex pattern of bioclastic, bioconstructed and siliciclastic deposits, and affected by several exposure surfaces and associated meteoric diagenesis. A first phase consisted in building a stratigraphic forward model (SFM), using the software DionisosFlow. The construction of the model was based on sensitivity tests on the two main parameters controlling basin sedimentation: 1) competition between carbonate production and siliciclastic supply; 2) subsidence. The results of the simulations, especially the facies distribution, the thickness of the deposits and the sedimentary architectures were compared with the observed data to validate the model. A second phase consisted in focusing on a specific stratigraphic event and performing reactive transport modeling (RTM) on a 2D section extracted from the DionisosFlow model to evaluate the mineralogical transformations and resulting petrophysical evolutions created by early diagenesis. The calculation results show the occurrence of two domains of salinity, that were associated with two distinct diagenetic environments: marine and meteoric phreatic. Globally, the simulated diagenetic trends are qualitatively consistent with the petrographic observations, except for the replacement of aragonite by a calcite cement, that systematically occurred in the model and is not always observed in thin sections. This preliminary study emphasizes the issues associated with the application of RTM to diagenetic phenomena, linked with the uncertainties inherent to specific parameters, such as minerals kinetic properties, and the mismatch between the space and time scales of the modeled processes and the upscaled description of each SFM cell. These results argue in favor of an alternative solution, that could conciliate the different processes. The combination of the various SFM output properties with simplified chemical reactions whose rates have been tuned for specific diagenetic processes of interest could provide diagenetic risk maps that would constitute useful guides for exploration at basin scale.

Ocean warming related to climate change has been proposed to cause the dissociation of gas hydrate deposits and methane leakage on the seafloor. This process occurs in places where the edge of the gas hydrate stability zone in sediments meets the overlying warmer oceans in upper slope settings. Here we present new evidence based on the analysis of a large multi-disciplinary and multi-scale dataset from such a location in the western South Atlantic, which records massive gas release to the ocean. The results provide a unique opportunity to examine ocean-hydrate interactions over millennial and decadal scales, and the first evidence from the southern hemisphere for the effects of contemporary ocean warming on gas hydrate stability. Widespread hydrate dissociation results in a highly focused advective methane flux that is not fully accessible to anaerobic oxidation, challenging the assumption that it is mostly consumed by sulfate reduction before reaching the seafloor., Ocean warming could enable the release of methane related to hydrate dissociation from the ocean floor, a process thought to have triggered abrupt climate changes in Earth history. Here the authors detect this process in action, observing a massive release of methane from a site in the South Atlantic Ocean.

Made available in DSpace on 2020-12-12T01:50:13Z (GMT). No. of bitstreams: 0 Previous issue date: 2020-03-15 Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Natural attenuation represents all processes that govern contaminant mass removal, which mainly occurs via microbial degradation in the environment. Although this process is intrinsic its rate and efficiency depend on multiple factors. This study aimed to characterize the microbial taxonomic and functional diversity in different aquifer sediments collected in the saturated zone and in situ microcosms (BACTRAP®s) amended with hydrocarbons (13C-labeled and non-labeled benzene, toluene and naphthalene) using 16S rRNA gene and “shotgun” Illumina high throughput sequencing at a jet-fuel contaminated site. The BACTRAP®s were installed to assess hydrocarbon metabolism by native bacteria. Results indicated that Proteobacteria, Actinobacteria and Firmicutes were the most dominant phyla (~98%) in the aquifer sediment samples. Meanwhile, in the benzene- and toluene-amended BACTRAP®s the phyla Firmicutes and Proteobacteria accounted for about 90% of total community. In the naphthalene-amended BACTRAP®, members of the SR-FBR-L83 family (Order Ignavibacteriales) accounted for almost 80% of bacterial community. Functional annotation of metagenomes showed that only the sediment sample located at the source zone border and with the lowest BTEX concentration, has metabolic potential to degrade hydrocarbons aerobically. On the other hand, in situ BACTRAP®s allowed enrichment of hydrocarbon-degrading bacteria. Metagenomic data suggest that fumarate addition is the main mechanism for hydrocarbon activation of toluene. Also, indications for methylation, hydroxylation and carboxylation as activation mechanisms for benzene anaerobic conversion were found. After 120 days of exposure in the contaminated groundwater, the isotopic analysis of fatty acids extracted from BACTRAP®s demonstrated the assimilation of isotopic labeled compounds in the cells of microbes expressed by strong isotopic enrichment. We propose that the microbiota in this jet-fuel contaminated site has metabolic potential to degrade benzene and toluene by a syntrophic process, between members of the families Geobacteraceae and Peptococcaceae (genus Pelotomaculum), coupled to nitrate, iron and/or sulfate reduction. Microbial Resources Division Research Center for Chemistry Biology and Agriculture (CPQBA) University of Campinas – UNICAMP, Paulínia, Brazil, Av. Alexandre Cazellato, 999 Graduate Program in Genetics and Molecular Biology Institute of Biology University of Campinas (UNICAMP), Rua Monteiro Lobato 255, Cidade Universitária, Campinas Laboratory of Basin Studies (LEBAC) São Paulo State University (UNESP) Rio Claro, Av. 24A PETROBRAS/ R&D Center (CENPES), Av. Horácio Macedo, 950. ZIP 21941-915 Ilha do Fundão Department Isotope Biogeochemistry Helmholtz Centre for Environmental Research (UFZ), Permoserstrasse 15 Laboratory of Basin Studies (LEBAC) São Paulo State University (UNESP) Rio Claro, Av. 24A FAPESP: 2017/16611-0

International audience; The stability of methane hydrates on continental margins worldwide is sensitive to changes in temperature and pressure conditions. It has been shown how gradual increases in bottom water temperatures due to ocean warming over post-glacial timescales can destabilize shallow oceanic hydrate deposits, causing their dissociation and gas release into the ocean. However, bottom water temperatures (BWT) may also vary significantly over much shorter timescales, including due to seasonal temperature oscillations of the ocean bottom currents. In this study, we investigate how a shallow methane hydrate deposit responds to seasonal BWT oscillations with an amplitude of up to 1.5 °C. We use the TOUGH + HYDRATE code to model changes in the methane hydrate stability zone (MHSZ) using data from the Rio Grande Cone, in the South Atlantic Ocean off the Brazilian coast. In all the cases studied, BWT oscillations resulted in significant gaseous methane fluxes into the ocean for up to 10 years, followed by a short period of small fluxes of gaseous methane into the ocean, until they stopped completely. On the other hand, aqueous methane was released into the ocean during the 100 years simulated, for all the cases studied. During the temperature oscillations, the MHSZ recedes continuously both horizontally and, in a smaller scale, vertically, until a permanent and a seasonal region in MHSZ are defined. Sensitivity tests were carried out for parameters of porosity, thermal conductivity and initial hydrate saturation, which were shown to play an important role on the volume of methane released into the ocean and on the time interval in which such release occurs. Overall, the results indicate that in a system with no gas recharge from the bottom, seasonal temperature oscillations alone cannot account for long-term gas release into the ocean.

The northernmost outcrops of the Triassic extensional Cuyo basin in western Argentina reveal a basal coarse conglomerate overlain by a thinning-fining upward siliciclastic red-bedded section with subordinated tuffs and microbial-rich carbonates (Cerro Puntudo Formation), unconformably covered by a second coarse conglomerate (El Relincho Formation), which were previously interpreted as two rifting events. An integrated analysis of facies associations, stacking patterns, paleocurrent and provenance was carried out in order to reveal the rift sedimentation using a source-to-sink approach. Besides the traditional controls in continental basins (e.g., sedimentation, tectonics and climate), this study considers possible drainage pattern evolution in order to differentiate isolated versus integrated depocenter stages. U-Pb zircon data corroborate our analysis and reveal a volcanic basement source of 256.8 ± 3.5 Ma (Permian/Lopingian) and a sedimentation age of 249.8 ± 2.5 Ma (Early Triassic) for a tuff interbedded within the Cerro Puntudo Formation, complementing previous age of 243.8 ± 1.9 Ma (Middle Triassic) at the top of this unit. Stratigraphic stacking allows the interpretation of three evolutionary stages. A first stage, represented by thick massive boulder-volcanic-rich conglomerates characterizing alluvial fan deposition, indicates strong tectonic activity of border faults (first rifting event). These features suggest high surface gradient and high available space controlling accommodation and dispersal of gravity and debris-flow deposits. Paleocurrents to the east reveal largely north-south normal faults located to the west and sediment supply from a proximal volcanic source area. A second stage, represented by a notable fining-thinning upward facies, including fluvial and palustrine (stromatolites with pedogenetic features) deposits, indicates a transition to tectonic quiescence. These facies associations developed in a context of low sedimentation rate, limited tectonic relief and low accommodation space. A third stage is represented by greenish well-rounded coarse-grained polymictic conglomerates of El Relincho Formation that unconformably truncate the Cerro Puntudo Formation. These conglomerates are interpreted as perennial braided fluvial systems (with paleocurrents to the northwest) indicating drainage reorganization primarily influenced by climate change and combined tectonic reactivation, previously considered the second rifting event. Climate change affected sediment delivery and allowed regionally connectivity and overfilling of the depocenters. In this last stage, northwest axial transport from variable sources within the Precordillera (to the southeast) is inferred from provenance analysis indicating open linked-depocenters. This study suggests a new stratigraphic correlation for the northern part of the Cuyo basin, implying that during the first rifting event a semi-arid climate prevailed with development of isolated and independent depocenters (first and second stages), whereas above the unconformity initiating the second rifting event (third stage) depocenters were interconnected. In the light of our source-to-sink analysis, such paleogeographic change allowed overfilling and laterally linkage of separate half-grabens along the Cuyo basin. Whereas tectonic reactivation may better explain renewed conglomerate deposition, climate change toward more humid conditions allowed previously separated depocenters to be connected through axial drainages. Fil: Teixeira, Bárbara M. N.. Petrobras. Petróleo Brasileiro S. A; Argentina Fil: Astini, Ricardo Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina Fil: Gomez, Fernando Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina Fil: Morales, Norberto. Universidade Estadual Paulista. Instituto de Geociências e Ciências Exatas; Brasil Fil: Pimentel, Marcio. Universidade do Brasília; Brasil

Made available in DSpace on 2020-12-12T02:46:11Z (GMT). No. of bitstreams: 0 Previous issue date: 2020-10-01 Fundação para o Desenvolvimento da UNESP (FUNDUNESP) Helmholtz-Zentrum für Umweltforschung Release of benzene, toluene, ethylbenzene, and xylene (BTEX) as components of the light non-aqueous phase liquids (LNAPL) contaminates soil and groundwater. Assessing the mechanisms of degradation and mineralization of BTEX in groundwater helps understand the migration of the dissolved plume, enabling the reduction of risks to humans. Here, we studied the fate of ethylbezene, m,p-xylenes and o-xylenes and the accompanying formation of methane in a Cenozoic lateritic aquifer in Brazil by compound-specific carbon stable isotope analysis (CSIA), to gain insights into the complex dynamics of release and biodegradation of BTEX in the LNAPL source zone. The enrichment of ∂13C in aromatic compounds dissolved in groundwater compared to the corresponding compounds in LNAPL indicate that CSIA can provide valuable information regarding biodegradation. The isotopic analysis of methane provides direct indication of oxidation mediated by aquifer oxygenation. The ∂13C-CO2 values indicate methanogenesis prevailing at the border and aerobic biodegradation in the center of the LNAPL source zone. Importantly, the isotopic results allowed major improvements in the previously developed conceptual model, supporting the existence of oxic and anoxic environments within the LNAPL source zone. São Paulo State University UNESP Environmental Studies Center (CEA) and Basin Studies Laboratory (LEBAC) Helmholtz Centre for Environmental Research – UFZ Petrobras Research Center – CENPES São Paulo State University UNESP Dept. of Applied Geology São Paulo State University UNESP Environmental Studies Center (CEA) and Basin Studies Laboratory (LEBAC) São Paulo State University UNESP Dept. of Applied Geology

This paper examines the role of momentum transfer across fluid-fluid interfaces in two-phase flow. A volume-of-fluid finite-volume numerical method is used to solve the Navier-Stokes equations for two-phase flow at the micro-scale. The model is applied to investigate viscous coupling effects as a function of the viscosity ratio, the wetting phase saturation and the wettability, for different fluid configurations in simple pore geometries. It is shown that viscous coupling effects can be significant for certain pore geometries such as oil layers sandwiched between water in the corner of mixed wettability capillaries. A simple parametric model is then presented to estimate general mobility terms as a function of geometric properties and viscosity ratio. Finally, the model is validated by comparison with the mobilities computed using direct numerical simulation.

The complexity of unconventional rock systems is expressed both in the compositional variance of the microstructure and the extensive heterogeneity of the pore space. Visualizing and quantifying the microstructure of oil shale before and after pyrolysis permits a more accurate determination of petrophysical properties which are important in modeling hydrocarbon production potential. We characterize the microstructural heterogeneity of oil shale using X-ray micro-tomography (µCT), automated ultra-high resolution scanning electron microscopy (SEM), MAPS Mineralogy (Modular Automated Processing System) and Focused Ion Beam Scanning Electron Microscopy (FIB-SEM). The organic-rich Eocene Green River (Mahogany zone) oil shale is characterized using a multi-scale multi-dimensional workflow both before and after pyrolysis. Observations in 2-D and 3-D and across nm-µm-mm length scales demonstrate both heterogeneity and anisotropy at every scale. Image acquisition and analysis using µCT and SEM reveal a microstructure of alternating kerogen-rich laminations interbedded with layers of fine-grained inorganic minerals. MAPS Mineralogy combined with ultrafast measurements reveal mineralogic textures dominated by dolomite, calcite, K-feldspar, quartz, pyrite and illitic clays along with their spatial distribution, augmenting conventional mineral analysis. From high resolution Backscattered electron (BSE) images, intra-organic, inter-organic-mineral, intra- and inter-mineral pores are observed with varying sizes and geometries. By using FIB milling and SEM imaging sequentially and repetitively, 3-D data sets were reconstructed. By setting 3-D gradient and marker-based watershed transforms, the organic matter, minerals and pore phases (including pore-back artifacts) were segmented and visualized and the pore-size distribution was computed. Following pyrolysis, fractures from the mm-to-µm scales were observed with preferential propagation along the kerogen-rich laminations and coalescence leading to an interconnected fracture network. The application of these techniques to worldwide oil shale deposits will allow significant insights into estimating mechanical and chemical proprieties of oil shale formations for modeling and designing oil shale pyrolysis processes.

Made available in DSpace on 2018-11-26T15:44:10Z (GMT). No. of bitstreams: 0 Previous issue date: 2017-06-01 project Carbonate rocks of the Cretaceous of Brazil UNESP Adali Spadini (PETROBRAS) PETROBRAS Late Aptian-early Albian limestones from the eastern Brazilian continental margin record the early evolution of the South Atlantic Ocean. In Tethyan and North Atlantic domains, a planktic foraminiferal turnover and organic-rich deposits related to Oceanic Anoxic Event lb (OAE lb) point to major ocean climate changes through this interval. Coeval organic-rich deposits of the South Atlantic Ocean have been interpreted as the product of restricted circulation rather than attributed to a global event. However, previous investigations of the early marine phase of South Atlantic lack data from more distal facies, making correlations to global events difficult. Here, we present C, O, and Sr isotopes, elemental geochemistry, TOC and pyrolysis data, as well as a microfacies analysis of an upper Aptian-lower Albian distal section from the Campos Basin (southeastern Brazil). Our focus is on the paleoenvironmental characterization of and the possible association between organic-rich deposits and major perturbations related to Aptian-Albian transition. Five microfacies associations (MA) were identified in the informal units I and III, which were deposited in the neritic region on a carbonate ramp. Organic-rich deposits were described in unit III, composed of planktic-dominated wackestones interbedded with black shales, in a distal dysoxic to anoxic environment. The carbonates Sr-87/Sr-86 ratios showed a drastic increase (0.7072-0.7074), interpreted as enhanced chemical weathering, supported by the increase of continental input to the top of section. This trend was accompanied by a long-term delta C-13(carb) negative excursion, which were assigned to the latest late Aptian-early Albian interval of the isotope reference curves, in accordance with the described occurrence of Colomiella recta. This scenario matches those proposed for the late Aptian-early Albian transition and OAE lb set, as an enhanced greenhouse stage, pointing to the influence of the referred ocean-climate changes on the deposition of organic-rich deposits of the early South Atlantic Ocean. This investigation gives more evidences that these perturbations were a widespread event, as a product of broad-scale disturbances in the global carbon cycle which also controlled organic deposition and preservation on restricted settings. (C) 2017 Elsevier Ltd. All rights reserved. Univ Estadual Paulista, UNESPetro, Ctr Geociencias Aplicadas Petr, BR-13506900 Rio Claro, SP, Brazil Univ Estado Rio de Janeiro, Fac Geol, BR-20550900 Rio De Janeiro, RJ, Brazil Petrobras SA, Rio De Janeiro, RJ, Brazil Univ Estadual Paulista, UNESPetro, Ctr Geociencias Aplicadas Petr, BR-13506900 Rio Claro, SP, Brazil

The microstructural evaluation of oil shale is challenging which demands the use of several complementary methods. In particular, an improved insight into the pore network structure and connectivity before, during, and after oil shale pyrolysis is critical to understanding hydrocarbon flow behavior and enhancing recovery. In this experimental study, bulk analyses are combined with traditional and advanced imaging methods to comprehensively characterize the internal microstructure and chemical composition of the world’s richest oil shale deposit, the Green River Formation (Mahogany Zone). Image analysis in two dimensions (2-D) using optical and scanning electron microscopy (SEM), and in three dimensions (3-D) using X-ray microtomography (µCT) reveals a complex and variable fine-grained microstructure dominated by organic-rich parallel laminations of the order of 10 µm thick which are tightly bound in a highly calcareous and heterogeneous mineral matrix. We also report the results of a detailed µCT study of the Mahogany oil shale with increasing pyrolysis temperature (300–500 °C) at 12 µm and 2 µm voxel sizes. The physical transformation of the internal microstructure and evolution of pore space during the thermal conversion of kerogen in oil shale to produce hydrocarbon products was characterized. The 3-D volumes of pyrolyzed oil shale were reconstructed and image processed to visualize and quantify the volume and connectivity of the pore space. The results show a significant increase in anisotropic porosity associated with pyrolysis between 400 and 500 °C with the formation of micro-scale connected pore channels developing principally along the kerogen-rich lamellar structures. Given the complexity and heterogeneity of oil shale, we also characterize the representative size at which porosity remains constant. Our results provide a direct observation of pore and microfracture development during oil shale pyrolysis and the petrophysical measurements from this study serve as valuable input parameters to modeling oil shale pyrolysis processes.

Made available in DSpace on 2018-11-26T17:13:48Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-12-01 Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Fossil bryophytes are rare because their preservation is compromised by the presence of a thin cuticle (if any) and a lack of lignin. Except for the occurrence of one bryophyte in the glacial Dwyka Group of the Karoo Basin, the other rare Late Paleozoic records in Gondwana are notably from the Parana Basin in Southeast/South Brazil. Four bryophyte sites (including a newly discovered one) were found in the lower part of the thick Permo-Carboniferous glacial succession of the Itarare Group, and one was found in the Guadalupian Teresina Formation, which was roughly assigned to an epeiric sea (or lake) dominated by a warm, semi-arid climate. This study describes the fossils from the new occurrence from the Itarare Group and discusses the context in which the bryophyte beds originated in the basin. The new samples confirm that all of the bryophytes of the Itarare Group can be classified as Dwykea araroii Ricardi-Branco et al. (a possible pleurocarp) and are associated with the lycophyte megaspore Sublagenicula brasiliensis (Dijkstra) Dybova-Jachowicz. In the much younger Teresina Formation, the bryophytes are Yguajemanus yucapirus Cristiano-de-Souza et al. and Capimirinus riopretensis Cristiano-de-Souza et al., and abundant charophytes and rare dwarf lycophyte stems and bracts are present in the same layers. Although the two stratigraphic units represent distinct paleoenvironments and climates, they seem to share some characteristics: a) the bryophyte assemblages were transported very little; b) they were deposited in very calm environments; c) they were the main components (along with some lycophytes) of local or poorly diversified regional vegetation. The low number of species, which is characteristic of opportunistic communities, can be explained by local or regional conditions that would have been stressful for the vascular plants in other areas. During the deposition of the Itarare Group, the main control was probably the cold climate in addition to a relative (liquid) water deficit because the bryophyte vegetation may have belonged to a tundra biome in areas of retreating glaciers. For the Teresina Formation, it is possible that the control was scarce freshwater, an unstable environment and water-saturated soil in a scenario of bryophyte vegetation living around temporary ponds in a wide marginal area of the epeiric sea. (C) 2016 Elsevier Ltd. All rights reserved. Univ Estadual Campinas, Inst Geociencias, P Box 6152, BR-13083970 Campinas, SP, Brazil Univ Estadual Paulista, Dept Geol Aplicada, Inst Geociencias & Ciencias Exatas, Campus Rio Claro,P Box 178, BR-13506900 Rio Claro, SP, Brazil Petrobras SA, CENPES, PDGEO, Gerencia Bioestratig & Paleoecol Aplicada, Ave Horacio Macedo,950 Predio,20 Sala, BR-21941915 Rio De Janeiro, RJ, Brazil Univ Estadual Campinas, Inst Geociencias, Programa Posgrad Geociencias, P Box 6752, BR-13083970 Campinas, SP, Brazil Univ Estadual Paulista, Dept Geol Aplicada, Inst Geociencias & Ciencias Exatas, Campus Rio Claro,P Box 178, BR-13506900 Rio Claro, SP, Brazil FAPESP: 97/03639-8 FAPESP: 2013/11563-6 CNPq: 304805/2014-9

International audience; Gas hydrate provinces occur in two sedimentary basins along Brazil’s continental margin: (1) The Rio Grande Cone in the southeast, and (2) the Amazon deep-sea fan in the equatorial region. The occurrence of gas hydrates in these depocenters was first detected geophysically and has recently been proven by seafloor sampling of gas vents, detected as water column acoustic anomalies rising from seafloor depressions (pockmarks) and/or mounds, many associated with seafloor faults formed by the gravitational collapse of both depocenters. The gas vents include typical features of cold seep systems, including shallow sulphate reduction depths (

International audience; The structure and nature of the crust underlying the Camamu-Almada-Jequitinhonha-Sergipe-Alagoas basins System, in the NE Brazilian margin, were investigated based on the interpretation of 12 wide-angle seismic profiles acquired during the SALSA (Sergipe ALagoas Seismic Acquisition) experiment in 2014. In this work, we present two 220-km-long NW-SE combined wide-angle and reflection seismic profiles, SL 01 and SL 02, that have been acquired using 15 ocean-bottom-seismometers along each profile, offshore the southern part of the Sergipe Alagoas Basin (SAB), north of the Vaza-Barris Transfer zone. The SL 02 has a 150-km long inland continuation with 20 land-seismic-stations until the Sergipano Fold Belt (SFB). Wide-angle seismic forward modeling allows us to precisely divide the crust in three domains: beneath the continental shelf, a ∼100 km wide necking zone is imaged where the continental crust thins from ∼35 km on the Unthinned Continental Domain, which displays a three-layered crust structure, to less than 8 km on the Oceanic Crust Domain. In the necking zone, the upper and the middle layers thin dramatically and almost disappear, while the Moho discontinuity shows clear PmPs. The Continental-Oceanic Crust Boundary (COB) is located at ∼80 km from the coastline and is marked by intracrustal seismic reflectors and changes in the seismic velocity, showing a sharp transition. On profile SL02, the oceanic crust is perturbed by a volcanic edifice together with an anomalous velocity zone underneath the area.

Made available in DSpace on 2018-12-11T17:28:27Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-07-15 The Araripe Basin, located in northeastern Brazil, originated during the Gondwana continental break-up responsible for the opening of the South Atlantic during the Early Cretaceous. In the Araripe Basin, the post-rift Aptian sequence corresponds to the Santana Group, which is composed, in upward succession, of mostly clastic continental and rare carbonate layers of the Barbalha, Crato, Ipubi and Romualdo Formations. The laminated limestones of the Crato Formation were deposited in a lacustrine environment preceding the deposition of the Ipubi Formation evaporites. They are age-equivalent to the limestones of the pre-salt interval of the east coast of Brazil, which contains large petroleum reserves. The excellent preservation of its macrofossils has made the Crato Formation known worldwide as a Fossil Lagerstätte. The limestones are macroscopically homogeneous, and their deposition has been previously attributed to chemical precipitation. Although the carbonate laminites are macroscopically undifferentiated, mineralogical variations, microscopic texture and distinctive biotic aspects supported the characterization of four microfacies: planar laminated, crustiform, nodular and rhythmic. The microfacies analysis indicated a strong and pervasive biological activity in the Crato limestone morphogenesis. Organominerals precipitated by the metabolic action of cyanobacteria and/or sulfate-reducing bacteria and methanogenic-oxidizing archea are represented by calcite and pyrite. Calcified coccoid and filaments are common, furthermore, the presence of calcified biofilms composed of exopolymeric substances (EPS) is ubiquitous. The presence of amorphous organic matter (AOM) and gypsum, particularly in the rhythmic microfacies, indicates anoxic/dysoxic conditions and stressful environments during periods of drought and low lake levels which favored the development and preservation of microbial biofilms. Phytoclasts and miospores when present in the succession indicate an extrabasinal contribution during wetter periods, although the environment remained of very low energy. The evidence of microbial influence in the formation of the laminated limestones of the Crato Formation is of great importance for understanding the excellent preservation of the unit's fossils and for modeling the evolution of the Aptian carbonate sequences in Brazil. Petrobras — Petroleo Brasileiro S.A., Avenida Chile UNESP — Universidade Estadual Paulista Instituto de Geociencias e Ciencias Exatas, Avenida 24A UNESP — Universidade Estadual Paulista Instituto de Geociencias e Ciencias Exatas, Avenida 24A

Made available in DSpace on 2018-11-27T14:33:31Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-05-01 Petrobras (Petroleo Brasileiro S.A.) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) LEBAC (Laboratorio de Estudo de Bacias, Universidade Estadual Paulista) University of Alberta The aim of this research is to understand the tectonic setting of the Bauru Basin. This basin in central eastern South America has been classified as intracratonic, but the basin-fill geometry, the involved subsidence mechanisms and the age of the deposits are poorly understood. In this work, the ranges of the fossil taxa are analyzed and ages are proposed for the lithostratigraphic units. Isopach maps were used to reconstruct the stratigraphic intervals of the basin fill. The stratigraphy of the Bauru Basin is compared with that of the adjacent basins, and the data are integrated with the available information on South American geodynamics. The fossil record indicates that sediment accumulated from the Cenomanian to early Paleocene, beginning after the Mochica Phase of the Andean orogeny. The basin-fill geometry demonstrates migration of the depocenter through time, which occurred simultaneously with migration of the Andean Basin and immediately after the orogenic events of the Peruvian Phase. We propose that the Bauru Basin is a component of a retroarc foreland system developed during the early stages of the Andean evolution and that it was developed in the back-bulge province of this system. The Andean Basin constitutes the foredeep depozone of this foreland system (including the Potosi, Oriente, Acre and Maranon basins). In addition, the Upper Cretaceous of the Parecis and Solimoes basins were likely also developed in the back-bulge province. The thickness of the Bauru accumulation indicates that other mechanisms might have overlapped the flexural subsidence in this back-bulge province. (C) 2016 Elsevier Ltd. All rights reserved. Univ Petrobras, Petr Brasileiro SA, Rua Julio Carmo 323, BR-20211160 Rio De Janeiro, Brazil Univ Alberta, Dept Earth & Atmospher Sci, 1-26 Earth Sci Bldg, Edmonton, AB T6G 2E3, Canada Univ Estadual Paulista, Lab Estudos Bacias, Ave 24-A,1515, BR-13506900 Sao Paulo, Brazil Univ Estadual Paulista, Lab Estudos Bacias, Ave 24-A,1515, BR-13506900 Sao Paulo, Brazil CNPq: 242946/2013-5

International audience; Remote sensing techniques offer useful tools for estimating forest biomass to large extent, thereby contributing to the monitoring of land use and landcover dynamics and the effectiveness of environmental policies. The main goal of this study was to investigate the potential use of discrete return light detection and ranging (lidar) data to produce accurate aboveground biomass (AGB) maps of mangrove forests. AGB was estimated in 34 small plots scatted over a 50 km 2 mangrove forest in Rio de Janeiro, Brazil. Plot AGB was computed using either species-specific or non-species-specific allometric models. A total of 26 descriptive lidar metrics were extracted from the normalized height of the lidar point cloud data, and various model forms (random forest and partial least squares regression with backward selection of predictors (Auto-PLS)) were tested to predict the recorded AGB. The models developed using species-specific allometric models were distinctly more accurate (R 2 (calibration) = 0.89, R 2 (validation) = 0.80, root-mean-square error (RMSE, calibration) = 11.20 t·ha −1 , and RMSE(validation) = 14.80 t·ha −1). The use of non-species-specific allometric models yielded large errors on a landscape scale (+14% or −18% bias depending on the allometry considered), indicating that using poor quality training data not only results in low precision but inaccuracy at all scales. It was concluded that under suitable sampling pattern and provided that accurate field data are used, discrete return lidar can accurately estimate and map the AGB in mangrove forests. Conversely this study underlines the potential bias affecting the estimates of AGB in other forested landscapes where only non-species-specific allometric equations are available.

Made available in DSpace on 2018-11-26T15:45:55Z (GMT). No. of bitstreams: 0 Previous issue date: 2018-02-01 An integrated geophysical and geological analysis of a carbonate reservoir can offer an effective method to better understand the paleogeographical evolution and distribution of a geological reservoir and non-reservoir facies. Therefore, we propose a better method for obtaining geological facies from geophysical facies, helping to characterize the permo-porous system of this kind of play. The goal is to determine the main geological phases from a specific hydrocarbon producer (Albian Campos Basin, Brazil). The applied method includes the use of a petrographic and qualitative description from the integrated reservoir with seismic interpretation of an attribute map (energy, root mean square, mean amplitude, maximum negative amplitude, etc), all calculated at the Albian level for each of the five identified phases. The studied carbonate reservoir is approximately 6 km long with a main direction of NE-SW, and it was sub-divided as follows (from bottom to top): (1) the first depositional sequence of the bank was composed mainly of packstone, indicating that the local structure adjacent to the main bank is protected from environmental conditions; (2) characterized by the presence of grainstone developed at the higher structure; (3) the main sequence of the peloidal packstone with mudstones oncoids; (4) corresponds to the oil production of carbonate reservoirs formed by oolitic grainstone deposited at the top of the carbonate bank; at this phase, rising sea levels formed channels that connected the open sea shelf with the restricted circulation shelf; and (5) mudstone and wackestone represent the system's flooding phase. Univ Estadual Paulista, FUNDUNESP, Rio Claro, Brazil Univ Fed Rio de Janeiro, Rio De Janeiro, Brazil Petrobras SA, Cenpes, Rio De Janeiro, Brazil Univ Estadual Paulista, FUNDUNESP, Rio Claro, Brazil

Made available in DSpace on 2019-10-06T02:14:28Z (GMT). No. of bitstreams: 0 Previous issue date: 2019-01-01 Petrobras Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Accurate daily rainfall estimation is required in several applications such as in hydrology, hydrometeorology, water resources management, geomorphology, civil protection, and agriculture, among others. CMORPH daily rainfall estimations were integrated with rain gauge measurements in Brazil between 2000 and 2015, in order to reduce daily rainfall estimation errors by means of the statistical objective analysis scheme (SOAS). Early comparisons indicated high discrepancies between daily rain gauge rainfall measurements and respective CMORPH areal rainfall accumulation estimates that tended to be reduced with accumulation time span (e.g., yearly accumulation). Current results show CMORPH systematically underestimates daily rainfall accumulation along the coastal areas. The normalized error variance (NEXERVA) is higher in sparsely gauged areas at Brazilian North and Central-West regions. Monthly areal rainfall averages and standard deviation were obtained for eleven Brazilian watersheds. While an overall negative tendency (3mmh(-1)) was estimated, the Amazon watershed presented a long-term positive tendency. Monthly areal mean precipitation and respective spatial standard deviation closely follow a power-law relationship for data-rich watersheds, i.e., with denser rain gauge networks. Daily SOAS rainfall accumulation was also used to calculate the spatial distribution of frequencies of 3-day rainfall episodes greater than 100mm. Frequencies greater than 3% were identified downwind of the Peruvian Andes, the Bolivian Amazon Basin, and the La Plata Basin, as well as along the Brazilian coast, where landslides are recurrently triggered by precipitation. Univ Sao Paulo, Inst Astron Geofis & Ciencias Atmosfer, Dept Ciencias Atmosfer, Sao Paulo, Brazil Univ Estadual Paulista, Inst Geociencias & Ciencias Exatas, Sao Paulo, Brazil Inst Nacl Pesquisas Espaciais, Sao Paulo, Brazil Inst Pesquisas Tecnol, Sao Paulo, Brazil Univ Sao Paulo, Escola Engn Sao Carlos, Sao Paulo, Brazil Eberhard Karls Univ Tubingen, Tubingen, Germany Petrobras Res & Dev Ctr, Rio De Janeiro, Brazil Univ Estadual Paulista, Inst Geociencias & Ciencias Exatas, Sao Paulo, Brazil Petrobras: 2014/00438-9 CNPq: 302349/2017-6

International audience; The behavior of biodiesel blend spills have received limited attention in spite of the increasing and widespread introduction of biodiesel to the transportation fuel matrix. In this work, a controlled field release of biodiesel B20 (100L of 20:80 v/v soybean biodiesel and diesel) was monitored over 6.2years to assess the behavior and natural attenuation of constituents of major concern (e.g., BTEX (benzene, toluene, ethyl-benzene and xylenes) and PAHs (polycyclic aromatic hydrocarbons)) in a sandy aquifer material. Biodiesel was preferentially biodegraded compared to diesel aromatic compounds with a concomitant increase in acetate, methane (near saturation limit (≈22mgL-1)) and dissolved BTEX and PAH concentrations in the source zone during the first 1.5 to 2.0years after the release. Benzene and benzo(a)pyrene concentrations remained above regulatory limits in the source zone until the end of the experiment (6.2years after the release). Compared to a previous adjacent 100-L release of ethanol-amended gasoline, biodiesel/diesel blend release resulted in a shorter BTEX plume, but with higher residual dissolved hydrocarbon concentrations near the source zone. This was attributed to greater persistence of viscous (and less mobile) biodiesel than the highly-soluble and mobile ethanol in the source zone. This persistence of biodiesel/diesel NAPL at the source zone slowed BTEX and PAH biodegradation (by the establishment of an anaerobic zone) but reduced the plume length by reducing mobility. This is the first field study to assess biodiesel/diesel blend (B20) behavior in groundwater and its effects on the biodegradation and plume length of priority groundwater pollutants.

International audience; Full waveform inversion using the conventional $L^2$ distance to measure the misfit between seismograms is known to suffer from cycle skipping. An alternative strategy is proposed in this study, based on a measure of the misfit computed with an optimal transport distance. This measure allows to account for the lateral coherency of events within the seismograms, instead of considering each seismic trace independently, as is done generally in full waveform inversion. The computation of this optimal transport distance relies on a particular mathematical formulation allowing for the non-conservation of the total energy between seismograms. The numerical solution of the optimal transport problem is performed using proximal splitting techniques. Three synthetic case studies are investigated using this strategy: the Marmousi 2 model, the BP 2004 salt model, and the Chevron 2014 benchmark data. The results emphasize interesting properties of the optimal transport distance. The associated misfit function is less prone to cycle skipping. A workflow is designed to reconstruct accurately the salt structures in the BP 2004 model, starting from an initial model containing no information about these structures. A high-resolution $P$-wave velocity estimation is built from the Chevron 2014 benchmark data, following a frequency continuation strategy. This estimation explains accurately the data. Using the same workflow, full waveform inversion based on the $L^2$ distance converges towards a local minimum. These results yield encouraging perspectives regarding the use of the optimal transport distance for full waveform inversion: the sensitivity to the accuracy of the initial model is reduced, the reconstruction of complex salt structure is made possible, the method is robust to noise, and the interpretation of seismic data dominated by reflections is enhanced.

Based on a dense 2D seismic reflection dataset and information from 8 exploration wells, we reinterpreted the stratigraphic evolution of the Colorado Basin. The basin is located on the continental shelf and slope within 50 to 2250 m of bathymetry. The total sediment fill can be up to 16,000 m. Seismic-to-well log correlations provide a chrono-stratigraphic framework for the interpreted seismic sequences. We show that the Colorado Basin records the development of a Permian pre-rift period, a Triassic/Jurassic to Early Cretaceous rift phase and a Lower Cretaceous to Tertiary drift phase. This passive margin represents the evolution of lithospheric extension from active rifting to the thermal subsidence/drift stage. Several Cretaceous to Cenozoic slumping episodes were identified and related to progradation of the sequences and sediment build-up in the slope, as well as to the development of seaward dipping extensional faults. Assuming an accumulation time span of 25 Ma for the syn-rift succession, which corresponds to the duration of extensional phases preceding the final break-up of the South Atlantic, sedimentation rates are in the order of 118 m/Ma. By Late Cretaceous, the Gondwana break-up had stopped in almost all areas and post-rift thermal subsidence dominated the basin development. During the early phase of subsidence, high sedimentation rates of up to 122 m/Ma are recorded. An important decrease of sediment supply (30 m/Ma) occurred until the end of the sag phase during the deposition of the Colorado Formation and sedimentation took place in elongated depocenters with oceanward progradation. A second phase of increased sediment supply takes place during the Oligocene and Miocene, resulting in the development of large basinward prograding sedimentary wedges. This event seems to be associated to the interaction between continental dynamics, subsidence, and increased continental erosion during climate shift from greenhouse to icehouse conditions.

International audience; This 3D structural model of the Colorado Basin provides new insights into the crustal geometry of the basin and its evolution in relation with the Argentine passive margin. Three NW-SE segments (oblique to the N30°E-trending margin) structure the basin. The oldest infill is generally thought to be coeval with the rifting of the South Atlantic margins in Late Jurassic-Early Cretaceous. This coeval development of the Colorado Basin and of the passive margin is still under debate and gives rise to several hypotheses that we investigate in the light of our observations. We propose that reactivation of inherited structures is predominant in the evolution of the Colorado Basin: (1) the Western segment follows the continental continuation of the Colorado transfer zone; (2) the Central segment consists in the continental continuation of the Tona deformation zone; (3) the Eastern segment is superimposed over the Palaeozoic Claromecó Basin. In addition to the 3 segments, the Central High, separating the Central segment to the Eastern segment, corresponds to the Palaeozoic Sierras Australes Fold Belt. The direction of extension responsible for the South Atlantic opening cannot explain the syn-rift infill and thinning of the basin. The structural analysis shows two phases of syn-rift deformation with different directions. Thus, we suggest that the Colorado Basin and the South Atlantic margin are not coeval but that a first extensional event, probably oblique, predates the extension responsible for the South Atlantic opening. This event is then followed by the formation of the N30°-trending distal margin and the reactivation of Palaeozoic N70°-trending faults occurs under the NW-SE opening of the South Atlantic. This two-phase evolution is consistent with the fault chronology and the two directions of thinned crust observed in the distal margin.

International audience; In order to precisely establish the bio- and chronostratigraphic position of several levels of the Silurian-Devonian succession of Bolivia, with respect to the International Time Scale, additional Silurian and Devonian localities belonging to the Eastern Cordillera and the Interandean Zone areas have been recently revised and sampled, both for macrofossils and palynomorphs. Specifically, the localities are Nunumayani, and Muruhuta from the late Silurian-early Devonian time interval. Correlations with other fossiliferous localities are discussed, namely Huacallani and Rumicorral. A new outcrop yielding Middle Devonian tabulate corals at Pisacavina is described; its faunal content is described, and compared with the historical coral collection. As a result, it appears clearly that the Silurian-Devonian Bolivian fauna needs a thorough revision, as well as the selection of stratigraphically significant macrofossils. Besides macrofossils, the analysis of palynomorph assemblages is significant in establishment of both intra-Bolivian and international correlations before any reliable biogeographic reconstruction is done. This paper records the first discovery of a plant of the genus Protolepidodendron from the Devonian of Bolivia. An ostracod assemblage from Pisacavina is described, illustrated, and discussed for the first time; it suggests an Early Devonian or an Eifelian age. Newly described taxa include the coral Parastriatopora boliviana sp. nov., and the chonetoidean brachiopods Sanjuanetes glemareci sp. nov., and Kentronetes giae sp. nov.

The structural restoration of two parallel cross-sections in the central portion of the Santos Basin enables a first understanding of existent 3D geological complexities. Santos Basin is one of the most proliferous basins along the South Atlantic Brazilian margin. Due to the halokinesis, geological structures present significant horizontal tectonic transport. The two geological cross-sections extend from the continental shelf to deep waters, in areas where salt tectonics is simple enough to be solved by 2D restoration. Such crosssections display both extensional and compressional deformation. Paleobathymetry, isostatic regional compensation, salt volume control and overall aspects related to structural stylewere used to constrain basic boundary conditions. Several restoration algorithms, such as simple shear, flexural slip and free methods, were used to restore the sedimentary deformation, including salt gravity gliding. The results of the 2D restoration are consistent with five major sequences of sedimentary evolution: (1) the brittle pre-salt deformation, (2) the significant and fast salt deposition, (3) the initial post-salt deformation with predominant rafting tectonics, (4) the Late Cretaceous progradational deposition and coeval development of compressional minibasins, and (5) the Cenozoic sedimentary deposition, with less intense salt tectonics. A 1D subsidence analysis based on the 2D restored results is shown as a useful restoration control tool. The 1D results indicate that an initially proximal infill evolves towards distal regions under salt tectonics control. The 1D diagrams also record the history of the overburden movements through lateral depocenter migration in minibasins areas, submitted to large horizontal salt spreading. The results highlight an important isostatic movement during salt deposition, large but not enough to eliminate a needed depression to accommodate the thick evaporites. By quantifying the halokinetic lateral deformation through time, the results suggest less intensity of the phenomenon throughout the Paleogene, with minor impacts on the petroleumsystemin this period.

Recognizing extinction events and determining their cause at the Triassic/Jurassic (T/J) transition and near the Pliensbachian–Toarcian (Lower Jurassic) boundary is a field of growing interest. We provide arguments for these events through a literature based new evaluation of coral diversity from Triassic to Dogger and a new palaeobiogeographical map. The T/J extinction of corals is clearly related to the breakdown of reef environments. Origination curves show that Hettangian (the lowest Jurassic stage) was not only a survival phase but already rather a recovery phase. Post-extinction evolution of reefs and their survival only in the northernmost margin of the Tethys support the hothouse hypothesis for the T/J extinction event. During Pliensbachian, many new taxa appear, but mostly solitary corals, not really framebuilders. Many of these taxa do not occur anymore during the following stages. The new increase in diversity is related to the development of Bajocian (Middle Jurassic) reefs.

International audience; Realistic geological modeling can be considered as the first objective in a reservoir characterization workflow. This term describes the process of building static 3-D reservoir models based on available a priori information, geological interpretations and quantitative geological, seismic, and production data. The definition of the best “realistic geological model” to be produced has to be discussed depending on the target objective: to produce a simulation which honors at best the geological parameters and the seismic derived constraints or to produce a simulation which will fit at best the production data. The incorporation of seismic information is a crucial element in reservoir geological modeling. Many recent research works have focused on the introduction in probabilistic models of secondary datacharacterized by a relationship, often indirect, with the reservoir properties. Due to the different scales of resolution between seismic and geology and to the complex relationship between rock properties andseismic response, a logical process can be to firstly extract geological properties from seismic data and second to constrain the facies simulation using these properties. The extraction of soft geologicalinformation from seismic data relies on statistical calibration with well data. Mainly two approaches can be used, either based on supervised segmentation or on estimation techniques. The obtained informationconsists in variables correlated with the facies distribution. Depending on the available information the variables can be related to the total thickness of the studied stratigraphic unit (leading to 2D constraintsas maps) or to small volumes inside the unit (3D constraints). IFP-CG (Institut français du pétrole - Centre de Géostatistique of the École des Mines) have developed an innovative methodology to generate facies proportions grids from well data, sedimentological conceptual models (maps and zonations), and constrained with seismic derived information. The objective of this paper is to present an analysis and evaluation of the real impact of these seismic derived constraints on the reservoir geological model in terms of quantification of uncertainties,heterogeneities distribution, and key geological characteristics. In the geomodelisation workflow, this work takes place when the structural framework of the reservoir is determined and also when thegeological conceptual model is defined in terms of interpretation, environment, and layering. Its purpose is to investigate possible variations in parameterization of the scenarios of filling the space with geological properties. Using a real data case, different constraints and different methods of seismic integration are compared. Their impact of seismic in the framework of the truncated gaussian methodology and compared to theimpact of the uncertainty on geological data.

著者人数: H.E.S.S. Collaboration 261名 (所属. 宇宙航空研究開発機構宇宙科学研究所(JAXA)(ISAS): 桂川, 美穂; 中島, 真也; 小高, 裕和; 高橋, 忠幸), Number of authors: H.E.S.S. Collaboration 261 (Affiliation. Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency(JAXA)(ISAS): Katsuragawa, Miho; Nakashima, Shinya; Odaka, Hirokazu; Takahashi, Tadayuki), Accepted: 2017-04-22, 資料番号: SA1170360000