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We have investigated the effect of supercritical drying (SD) on the porosity and the BET-N2 specific surface area (SSA) of five allophane-rich and three non-allophanic topsoils. The contribution of organic matter (OM) and short-range ordered (SRO) constituents to the nanoscale porosity (

As soils under permanent pasture and grasslands have large topsoil carbon (C) stocks, the scope to sequester additional C may be limited. However, because C in pasture/grassland soils declines with depth, there may be potential to sequester additional C in the subsoil. Data from 247 continuous pasture sites in New Zealand (representing five major soil Orders and ~80% of the grassland area) showed that, on average, the 0.15-0.30 m layer contained 25-34 t ha-1 less C than the top 0.15 m. High production grazed pastures require periodic renewal (re-seeding) every 7-14 years to maintain productivity. Our objective was to assess whether a one-time pasture renewal, involving full inversion tillage (FIT) to a depth of 0.30 m, has potential to increase C storage by burying C-rich topsoil and bringing low-C subsoil to the surface where C inputs from pasture production are greatest. Data from the 247 pasture sites were used to model changes in C stocks following FIT pasture renewal by predicting: 1) the C accumulation in the new 0-0.15 m layer, and 2) the decomposition of buried-C in the new 0.15-0.30 m layer. In the 20 years following FIT pasture renewal, soil C was predicted to increase by an average of 7.3-10.3 (Sedimentary soils) and 9.6-12.7 t C ha-1 (Allophanic soils), depending on the assumptions applied. Adoption of FIT for pasture renewal across all suitable soils (2.0-2.6 M ha) in New Zealand was predicted to sequester ~20-36 Mt C, sufficient to offset 9.6-17.5% of the country's cumulative greenhouse gas emissions from agriculture over 20 years at the current rate of emissions. Given that grasslands account for ~70% of global agricultural land, FIT renewal of pastures or grassland could offer a significant opportunity to sequester soil C and offset greenhouse gas emissions.

Even small increases in the large pool of soil organic carbon could result in large reductions in atmospheric CO2 concentrations sufficient to limit global warming below the threshold of 2 °C required for climate stability. Globally, grasslands occupy 70% of the world’s agricultural area, so interventions to farm management practices to reduce losses or increase soil carbon stocks in grassland are highly relevant. Here, we review the literature with particular emphasis on New Zealand and report on the effects of management practices on changes in soil carbon stocks for temperate grazed grasslands. We include findings from models that explore the trade-offs between multiple desirable outcomes, such as increasing soil carbon stocks and milk production. Farm management practices can affect soil carbon stocks through changes in net primary production, the proportions of biomass removed, the degree of stabilisation of carbon in the soil and changes to the rate of soil carbon decomposition. The carbon saturation deficit defines the potential for a soil to stabilise additional carbon. Earlier reviews have concluded that, while labile carbon is the dominant substrate for soil carbon decomposition, a fraction of soil carbon stocks is stabilised and protected from decomposition by the formation of organo-mineral complexes. Recent evidence shows that the rate of organic carbon decomposition is determined primarily by the extent of soil organic carbon protection and, therefore, the availability of substrates to microbial activity. New Zealand grassland systems have moderate to high soil carbon stocks in the surface layers (i.e., upper 0.15 m) where most roots are located, so the carbon saturation deficit is relatively low and the scope to increase soil carbon stocks by carbon inputs from primary production may be limited. International studies have shown that the addition of fertilisers, feed imports, and applications of manure and effluent can increase soil carbon stocks, especially for degraded soils, but the responses in New Zealand soils are uncertain because of the limited number of studies. However, recent evidence shows that irrigation can reduce soil carbon stocks in New Zealand, but neither the processes nor the long-term trends are known. Studies of sward renewal have shown that short-term losses of carbon losses resulting from the disturbance can be mitigated using rapid replacement of the new sward, minimum tillage and avoidance of times when the soil water content is high. Swards comprising multiple species have also shown that soil carbon stocks may be increased after periods of several years. Model simulations have shown that the goal of increasing both soil carbon and milk production could be achieved best by increasing carbon inputs from supplementary animal feed. However, losses of carbon at feed export sites need to be minimised to achieve overall net gains in soil carbon. Grazing intensity can have a big influence on soil carbon stocks but the magnitude and direction of the effects are not consistent between studies. Biochar addition could possibly increase soil carbon stocks but it is not yet an economical option for large-scale application in New Zealand. There is some evidence that the introduction of earthworms and dung beetles could potentially increase soil carbon stabilisation, but the greenhouse gas benefits are confounded by possible increases in nitrous oxide emissions. The new practice of full inversion tillage during grassland renewal has the potential to increase soil carbon stocks under suitable conditions but full life-cycle analysis including the effects of the disruptive operations has yet to be completed. We conclude with a list of criteria that determine the success and suitability of management options to increase soil carbon stocks and identify priority research questions that need to be addressed using experimental and modelling approaches to optimise management options to increase soil carbon stocks.

Understanding soil organic carbon (SOC) sequestration is important to develop strategies to increase the SOC stock and, thereby, offset some of the increases in atmospheric carbon dioxide. Although the capacity of soils to store SOC in a stable form is commonly attributed to the fine (clay + fine silt) fraction, the properties of the fine fraction that determine the SOC stabilization capacity are poorly known. The aim of this study was to develop an improved model to estimate the SOC stabilization capacity of Allophanic (Andisols) and non-Allophanic topsoils (0–15 cm) and, as a case study, to apply the model to predict the sequestration potential of pastoral soils across New Zealand. A quantile (90th) regression model, based on the specific surface area and extractable aluminium (pyrophosphate) content of soils, provided the best prediction of the upper limit of fine fraction carbon (FFC) (i.e. the stabilization capacity), but with different coefficients for Allophanic and non-Allophanic soils. The carbon (C) saturation deficit was estimated as the difference between the stabilization capacity of individual soils and their current C concentration. For long-term pastures, the mean saturation deficit of Allophanic soils (20.3 mg C g−1) was greater than that of non-Allophanic soils (16.3 mg C g−1). The saturation deficit of cropped soils was 1.14–1.89 times that of pasture soils. The sequestration potential of pasture soils ranged from 10 t C ha−1 (Ultic soils) to 42 t C ha−1 (Melanic soils). Although meeting the estimated national soil C sequestration potential (124 Mt C) is unrealistic, improved management practices targeted to those soils with the greatest sequestration potential could contribute significantly to off-setting New Zealand's greenhouse gas emissions. As the first national-scale estimate of SOC sequestration potential that encompasses both Allophanic and non-Allophanic soils, this serves as an informative case study for the international community.

Conversion of soils supporting native vegetation to agricultural production has led to a loss of soil carbon stocks. Replacing a portion of the lost stocks will sequester atmospheric carbon with the concurrent benefit of enhancing soil sustainability. The ability of the fine fraction of soils (≤50-µm fraction) to adsorb organic carbon (OC) is considered a key mechanism capable of stabilising soil OC against loss. The difference between the current and maximum concentrations of OC in the soil fine fraction (FFC) has been termed the ‘saturation deficit’ (SatDef) and used to define the potential for a soil to sequester carbon. For New Zealand surface 0–15 cm soil layers, pedotransfer functions have been derived to quantify the soil carbon SatDef. The ability of combining infrared spectroscopy (IR) with partial least squares regression (PLSR) to derive predictive algorithms for soil properties included in these pedotransfer functions, the capacity of the soil fine fraction to stabilise carbon and the SatDef of the soil fine fraction were assessed in this study. A total of 168 air-dried and finely ground New Zealand surface soils representative of the major soil orders used for agricultural production were included. Principal components analysis of IR spectra showed a grouping by soil order that was related to mineralogy. Predictive IR/PLSR algorithms were derived for specific surface area, pyrophosphate-extractable aluminium, the FFC content, the 90th quantile regression of FFC and the SatDef of the fine fraction (R2 values ≥0.85; ratio of performance to interquartile range values ≥2.9). The results indicate that IR/PLSR provides a rapid and cost-effective mechanism for deriving information related to the amount of FFC in soils and the SatDef of the fine fraction. The IR/PLSR approach could be used to define the potential of soils to sequester carbon and identify the soil types to target for carbon sequestration technologies. The approach would also generate valuable data for soil carbon in national inventories or national soil condition monitoring programs.

In New Zealand, pastoral soils have substantial organic carbon (OC) stocks, which may be vulnerable to loss from disturbance and environmental perturbations. We assessed OC vulnerability using two approaches. For the first approach, we postulated that the OC deficit of continuously cropped soils relative to nearby pastoral soils would provide a measure of the quantity of potentially vulnerable OC in pastures. As a test, soils were sampled to a depth of 15 cm at 149 sites and the total organic carbon (TOC) and particulate organic carbon (POC) contents were measured. The second approach involved measurement of OC mineralisation in a laboratory assay (98 day aerobic incubation at 25°C). For the pastoral soils, the mean TOC and POC was about twice that of the cropped soils. On average, 89% more OC was mineralised from the pastoral soils compared with the cropped counterparts. However, the quantity of OC mineralised in pasture soils was small relative to the potential for OC loss inferred from the difference in TOC between pastoral and cropped soils. Carbon mineralisation was explained using a two-pool exponential model with rate constants of the ‘fast’ and ‘slow’ pools equating to 0.36 ± 0.155 and 0.007 ± 0.003 day–1 respectively. The larger, slow OC pool correlated strongly with hot water extractable OC whereas the fast pool was related to OC extracted using cold water. Our results suggest that water extraction (using cold and hot water) can provide a rapid estimate of the quantity of mineralisable OC across a wide range of New Zealand soils.