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We present an updated look at Carboniferous brachiopod biozonation from most of the world framed into a revised Carboniferous palaeogeography, based on a selection of the literature published on Carboniferous brachiopods since the nineteenth century. The biostratigraphic significance of the most important brachiopod taxa is synthesized in seven geographical correlations. The Mississippian is characterized by rich brachiopod faunas, with widespread taxa with a good potential for global correlation, such as Rugosochonetes , Delepinea , Buxtonia , Antiquatonia , Spinocarinifera , Marginatia , Fluctuaria , Ovatia , Rhipidomella , Lamellosathyris , Unispirifer , Tylothyris and Syringothyris . From the mid-Visean to the late Serpukhovian, taxa of gigantoproductidines are biostratigraphically significant, and occur everywhere except South America and Australia, which remain as distinct faunal successions for most of the period. A major turnover occurs at the beginning of the Pennsylvanian, characterized by a higher degree of provincialism. Pennsylvanian brachiopod faunas are diverse in China, Russia and North America, but otherwise they are less developed and are characterized mostly by endemic taxa, hampering long-distance correlation. An exception is the rapid diversification of taxa of the Choristitinae, which were widespread from the Bashkirian to the Moscovian, allowing long-distance correlation.

Since the beginning of the 21st century, the geoscience research has been entering a significant transitional period with the establishment of a new knowledge system as the core and with the drive of big data as the means. It is a revolutionary leap in the research of geoscience knowledge discovery from the traditional encyclopedic discipline knowledge system to the computer-understandable and operable knowledge graph. Based on adopting the graph pattern of general knowledge representation, the geoscience knowledge graph expands the unique spatiotemporal features to the Geoscience knowledge, and integrates geoscience knowledge elements, such as map, text, and number, to establish an all-domain geoscience knowledge representation model. A federated, crowd intelligence-based collaborative method of constructing the geoscience knowledge graph is developed here, which realizes the construction of high-quality professional knowledge graph in collaboration with global geo-scientists. We also develop a method for constructing a dynamic knowledge graph of multi-modal geoscience data based on in-depth text analysis, which extracts geoscience knowledge from massive geoscience literature to construct the latest and most complete dynamic geoscience knowledge graph. A comprehensive and systematic geoscience knowledge graph can not only deepen the existing geoscience big data analysis, but also advance the construction of the high-precision geological time scale driven by big data, the compilation of intelligent maps driven by rules and data, and the geoscience knowledge evolution and reasoning analysis, among others. It will further expand the new directions of geoscience research driven by both data and knowledge, break new ground where geoscience, information science, and data science converge, realize the original innovation of the geoscience research and achieve major theoretical breakthroughs in the spatiotemporal big data research.

The Permian marine-terrestrial system of the North China block provides an exceptional window into the evolution of northern temperate ecosystems during the critical transition from icehouse to greenhouse following the late Paleozoic ice age (LPIA). Despite many studies on its rich hydrocarbon reserves and climate-sensitive fossil flora, uncertain temporal constraints and correlations have hampered a thorough understanding of the records of geologic, biologic, and climatic change from the North China block. We present a new chronostratigraphy based on high-precision U-Pb chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) geochronology of tuffs from a near-complete latest Carboniferous–Permian succession in North China. The results indicate that the predominance of continental red beds, climate aridification, and the disappearance of coals and characteristic tropical flora were well under way during the Cisuralian (Early Permian) in the North China block, significantly earlier than previously thought. A nearly 20 m.y. hiatus spanning the early Kungurian to the mid-Guadalupian (or later) is revealed in the northern North China block to have close temporal and spatial associations with the closure and/or subduction of the Paleo-Asian Ocean and its related tectonic convergence. This long hiatus was concomitant with the prominent loss of the highly diverse and abundant Cathaysian floras and the widespread invasion of the monotonous Angaran floras under arid climate conditions in the North China block. Similarities in the floral and climate shift histories between Euramerica and North China suggest that aside from the regional tectonic controls and continental movement, extensive volcanism during the Cisuralian may have played a major role in the global warming and aridification in the aftermath of the LPIA.

The end-Permian mass extinction (EPME; ca. 251.94 Ma) is the most severe mass extinction in the geological record. Detailed paleobiological investigations show a very rapid EPME event, and recently published δ238U data show a large negative excursion and thus a massive shift to globally expanded anoxia at the main extinction phase in the latest Permian. The negative shift in δ238U is in correlation with a globally characterized negative δ13C excursion near the Permian-Triassic boundary (PTB). In some highly expanded PTB carbonate sections, however, there are two distinct negative δ13C excursions whereas uranium isotopes (δ238U) from such sections have not yet been examined, leaving a gap in the understanding of the global perturbations of marine redox conditions immediately following the EPME. Here, we present a new δ238U study of syn-depositional dolostones from a well-characterized and highly expanded drill core, which recorded two pronounced negative δ13C excursions across the PTB, from the Carnic Alps, Austria. This drill core extends 331-meters across the PTB and provides a unique opportunity to explore the detailed timing, duration, and extent of marine redox chemistry changes before, during, and immediately after the EPME. Our new δ238U record shows two negative shifts, which are correlated with the two negative δ13C excursions. The first negative δ238U excursion preceding the EPME confirms the recently published δ238U records from across the EPME and support that syndepositional marine dolostones can record δ238U trends of seawater similar to that of limestones. Modeling of uranium isotope cycling in the latest Permian and earliest Triassic oceans suggests two distinct stages of expanded marine anoxia separated by a brief interval (∼100 kyr) of reoxygenation across the PTB. The first anoxic episode lasted for ∼ 60 kyr while anoxic seafloor area expanded to cover >18% of the entire seafloor, coeval with the main EPME horizon, agreeing with marine anoxia as a proximate kill mechanism for the EPME. The second anoxic event was less intense compared to the first anoxic pulse but sustained for a longer duration. A global modeling of coupled C, P, and U cycles show that two pulses of volcanic carbon injection that drives global warming and increased phosphorus weathering rate can reasonably reproduce our data to match two phases of anoxia. The model also demonstrates that the loss of terrestrial vegetation in the EPME is crucial to generating an intervening interval of oxygenated ocean. Our new study adds to a growing body of evidence that the global marine redox conditions underwent rapid oscillations during the EPME event and continued afterward, which may have played a central role in delaying the marine ecosystem recovery in the Early Triassic.

Sedimentary deposits of the Permian–Triassic transition are well-exposed in numerous outcrops of South China. Depending on the palaeogeographic positions of the sections, their lithofacies vary from fully marine, shallow marine, lagoonal, lacustrine, and fluvial to alluvial. In the present study, conchostracans (Crustacea: Branchiopoda) were newly collected from the continental deposits of the Kayitou and Jialingjiang formations around the Kangdian Highland elevated by the Emeishan Basalt in the southern Sichuan, western Guizhou, and northeastern Yunnan provinces. The conchostracan fauna of the Kayitou Formation is composed of Pseudestheria chatangensis, Euestheria fuyuanensis, and Euestheria sp. aff. E. gutta. These species occur in varying lithofacies types of different sections. In particular, the late Permian Pseudestheria chatangensis occurs in grey siltstones interbedded with pebbly sandstones, which are interpreted as lacustrine deposits. Euestheria fuyuanensis and Euestheria sp. aff. E. gutta were obtained from yellowish to greenish–grey clay- and siltstones, interpreted as coastal plain deposits. In comparison to other regions, occurrences of Euestheria gutta are indicative of an early Induan to Olenekian (Early Triassic) age. The fossil record of Euestheria fuyuanensis is so far restricted to a few occurrences in the Kayitou Formation of Southwest China and, therefore, using this species for long-distance biostratigraphic correlation requires further investigation. The distribution of late Permian pseudestheriid and Early Triassic euestheriid species in the respective sections possibly depends on the local lithofacies and, therefore, a diachronous age of the Kayitou Formation within the study area can be assumed. Additionally, Magniestheria sp. aff. M. mangaliensis and Magniestheria sp. aff. M. subcircularis were recorded in the Jialingjiang Formation, which represents a lithostratigraphic unit considered as late Early Triassic (Olenekian). Further investigations of both taxonomy and the real stratigraphic ranges of the conchostracan species as well as cross-correlations with other age data are recommended, in order to better constrain the position of the Permian–Triassic boundary and the specific timing of the terrestrial end-Permian mass extinction in continental deposits of Southwest China.

Nonmarine biostratigraphic/biochronologic schemes have been created for all or parts of the late Carboniferous–Middle Triassic using palynomorphs, megafossil plants, conchostracans, blattoid insects, tetrapod footprints and tetrapod body fossils, and these provide varied temporal resolution. Cross correlation of the nonmarine biochronologies to the Standard Global Chronostratigraphic Scale has been achieved in some parts of the late Carboniferous–Middle Triassic in locations where nonmarine and marine strata are intercalated, the nonmarine strata produce biochronologically significant fossils and the marine strata yield fusulinids, conodonts and/or ammonoids. Other cross correlations have been aided by magnetostratigraphy, chemostratigraphy and a growing database of radioisotopic ages. A synthetic nonmarine biochronology for the late Carboniferous–Middle Triassic based on all available nonmarine index fossils, integrated with the Standard Global Chronostratigraphic Scale, is presented here. The focus is on the nonmarine biostratigraphy/biochronology of blattoid insects, conchostracans, branchiosaurid amphibians, tetrapod footprints and tetrapod body fossils within the biochronological framework of land-vertebrate faunachrons. Correlation to the Standard Global Chronostratigraphic Scale presented here is divided into seven time intervals: Pennsylvanian, Carboniferous–Permian boundary, Cisuralian, Guadalupian, Lopingian, Permian–Triassic boundary and Early to Middle Triassic. The insects, conchostracans and branchiosaurs provide robust nonmarine correlations in the Pennsylvanian–Cisuralian, and the footprints and tetrapod body fossils provide robust correlations of varied precision within the entire Pennsylvanian–Middle Triassic. Radioisotopic ages are currently the strongest basis for cross correlation of the nonmarine biostratigraphy/biochronology to the Standard Global Chronostratigraphic Scale, particularly for the Pennsylvanian–Cisuralian. Chemostratigraphy and magnetostratigraphy thus far provide only limited links of nomarine and marine chronologies. Improvements in the nonmarine-marine correlations of late Paleozoic–Triassic Pangea require better alpha taxonomy and stratigraphic precision for the nonmarine fossil record integrated with more reliable radioisotopic ages and more extensive chemostratigraphic and magnetostratigraphic datasets.

Permian plant fossils have never been reported from the Shan Plateau in eastern Myanmar. Recently, a black to gray carbonaceous mudstone unit containing abundant plant fossils was discovered just below the lowest part of Thitspin Limestone Formation from the Linwe Area, eastern Myanmar. Although only five taxa were identified, the plant assemblage provides the first evidence of the occurrence of Cathaysian elements in eastern Myanmar and potentially indicates the presence of a highly diverse Permian flora. Among the five species, Cordaites principalis and Annularia mucronata were cosmopolitan species; while Callipteridum cf. koraiense, Taeniopteris crassinervis Mo and Rhipidopsis lobata were mostly recorded in the Cathaysia Flora. Therefore, the present assemblage generally indicates a palaeobiogeographical affinity to the Cathaysian Province. Stratigraphically, Callipteridum cf. koraiense was mainly reported from Cisuralian to Wordian; whereas Taeniopteris crasssnervis Mo and Rhipidopsis lobata were recorded from Capitanian to Changhsingian, which suggests a general Permian age based on the plant assemblage itself only. However, the carbonaceous mudstone at the outcrop is overlain by the Thitspin Limestone Formation containing middle Guadalupian fusulinids. Based on previous faunal analyses, the Sibumasu terrane contains typical Gondwanan cold-water faunas during the early Cisuralian, warm-water faunas occurred after Sakmarian. Thus, age of the fossil-plant-containing carbonaceous mudstone is very likely between late Cisuralian and early Guadalupian as constrained by its overlying fusulinids and its warm Cathaysian palaeobiogeographical affinity.

We report extensive major and trace element data for the Permian-Triassic boundary (PTB) at Meishan, China. Analyses of 64 samples from a 2.5 m section span the last 75 kyr of the Permian and the first 335 kyr of the Triassic, from beds 24 to 34. We also report data for 20 acetic acid extracts that characterize the carbonate fraction. Whole rock major element data reflect the change of lithology from carbonate in the Permian to mudstone and marl in the Triassic, indicate an increase of siliciclastic input and MgO in and above the extinction interval (beds 24f–28), and silica diagenesis in carbonates below the extinction horizon. Above bed 27, enrichment factors calculated with respect to Al and Post-Archean Australian Shale (PAAS) are ∼1 for most trace elements, confirming that siliciclastic input dominates trace element distributions in the Triassic. Within the extinction interval, beds 24f and 26 show increases in As, Mo, U and some transition metals. V, Cr, Co, Ni, Cu, Zn, Pb, and Ba are variably enriched, particularly in bed 26. Below the extinction interval, the top of bed 24d shows enrichment of V, Cr, Co, Ni, Cu, Zn, Pb, and Ba in a zone of diagenetic silicification. Trace elements thus reflect siliciclastic input, diagenetic redistribution, and responses to redox conditions. Trace element patterns suggest either a change in provenance of the detrital component, or a change in the proportion of mechanical to chemical weathering that is coincident with the beginning of the extinction in bed 24f. Ba, Zr, and Zn behave anomalously. Ba shows little variation, despite changes in biological activity and redox conditions. The enrichment factor for Zr is variable in the carbonates below bed 24f, suggesting diagenetic Zr mobility. Zn shows a sharp drop in the extinction horizon, suggesting that its distribution was related to phytoplankton productivity. Rare earth element content is controlled by the siliciclastic fraction, and carbonate extracts show middle rare earth enrichment due to diagenesis. Ce and Eu anomalies are not reliable indicators of the redox environment at Meishan.

We report high-resolution, high-precision δ44/40Ca, δ88/86Sr, and 87Sr/86Sr records spanning the Permian-Triassic boundary (PTB) from the Meishan and Dajiang carbonate successions in south China. The goal of the study was to understand the behavior of Ca and Sr isotopes during a time period in Earth history characterized by severe biological and environmental perturbations, including a major mass extinction, flood basalt volcanism, ocean acidification, and sea level fluctuations. Dajiang displays negative δ44/40Ca and δ88/86Sr excursions and invariant 87Sr/86Sr ratios in the

Permian faunal affinity in the Lhasa Block plays a critical role in reconstructing its paleogeographic evolution. Cisuralian and Guadalupian faunas have been described from the Lhasa Block, but very few Lopingian (late Permian) brachiopods have been reported so far. In this paper, a new diverse brachiopod fauna consisting of 17 species of 17 genera and an unidentifiable Orthotetoidea is described from the uppermost part of the Xiala Formation at the Aduogabu section in the central part of the Lhasa Block. The age of this fauna can be assigned to the Changhsingian (late Lopingian) as indicated by the associated foraminifersColaniella parva(Colani, 1924) andReichelina pulchraMiklukho-Maklay, 1954. Characteristic brachiopods includeSpinomarginifera chengyaoyenensisHuang, 1932,Haydenella wenganensis(Huang, 1932), andAraxathyriscf.dilatatusShen, He, and Zhu, 1992. They also generally suggest a Changhsingian age. Paleobiogeographically, this fauna is uniformly composed of typical Tethyan elements represented bySpinomarginiferaHuang, 1932 andHaydenellaReed, 1944, and some cosmopolitan elements, but no typical cold-water taxa of Gondwanan affinity. This is in contrast to the contemporaneous brachiopod faunas from the Tethys Himalayan region that are characterized by typical cold-water taxa of Gondwanan affinity, e.g.,Costiferina indica(Waagen, 1884),Retimarginifera xizangensisShen et al., 2000,Neospirifer(Quadrospina)tibetensisDing, 1962. Thus, it is strongly indicative that the Lhasa Block had drifted into a relatively warm-water regime during the Changhsingian. An analysis of the paleobiogeographic change of brachiopods in the Lhasa Block throughout the entire Permian further suggests that the Lhasa Block probably had rifted away from the northern peri-Gondwanan margin between the latest Cisuralian and middle Guadalupian, that is, the Neotethys Ocean had opened before middle Guadalupian.

Earth's transition from an icehouse to hothouse during the Late Paleozoic was characterized by a series of high paleolatitude glacial-interglacial events. However, the exact timing of these events remains unresolved. Here, we report on fifty-five calcitic shells of brachiopods and bivalves screened to obtain reliable 87Sr/86Sr ratios for Cisuralian (298.9-272.95 Ma) and Guadalupian (272.95-259.1 Ma) seawater. Specifically, we used well-preserved shells to build a 87Sr/86Sr seawater curve for the Sydney Basin, and then with the marine Look-up Table of the Permian calculated numerical ages of the stratigraphic succession. This allowed us to match seawater changes to the coeval P1 – P3 glacial-interglacial cycles recorded in the sedimentary successions of the Sydney Basin. Evaluation of the 87Sr/86Sr results revealed that onsets of the P2 and P3 glaciations in the Sydney Basin should be assigned to the early Artinskian and late Wordian, respectively. The range of 87Sr/86Sr values recorded by brachiopods from the Wandrawandian Siltstone coupled with recent geochronological dating of the Broughton Formation suggest that glacial phase P3 lasted about 2 Myr and was confined to the late Wordian – early Capitanian. Dating obtained using the Sr-isotope proxy from brachiopods agrees with the geochronologic ages, and they suggest that the glacial phases P1 to P3 became progressively shorter in duration and less intense. Conversely, the corresponding interglacials became progressively longer, and thus, documenting the gradual transition of the Permian icehouse to an ice-free greenhouse world. Our study confirms that strontium isotopes measured in screened brachiopod shell archives are sufficiently robust to date Paleozoic marine sedimentary successions, and are most valuable in sedimentary successions that otherwise lack geo-chronological dating.

Two new Middle Permian foraminifer faunas are described from the Xiala Formation in the Zhabuye and Xiadong sections in the central Lhasa Block. The presence of some significant taxa in paleobiogeography such as Shanita, Lysites biconcavus, Hemigordiopsis subglobosa, indicates that the Lhasa Block was in the Cimmerian Province in paleobiogeography during the Middle Permian. Furthermore, the Nankinella-Chusenella fusuline assemblage that occurs in the upper part of the Xiala Formation in the Xiadong section resembles contemporaneous fusuline faunas from the Xainza and Bashor areas in the Lhasa Block and the northern part of the Tengchong Block. The endemism of the Nankinella-Chusenella assemblage in the Lhasa and Tengchong blocks indicates that these two blocks were isolated from both the South Qiangtang Block and the northern Gondwanan margin during the Middle Permian. It further suggests that both the Bangong-Nujiang Ocean and the Neotethys Ocean would have opened before the Middle Permian. A new species Chusenella tsochenensis sp.nov. was described.

The Lopingian is the uppermost series of the Paleozoic and it is bracketed by two major biological events, including the pre-Lopingian crisis and the end-Permian mass extinction (EPME). A high resolution temporal framework is essential to understand the patterns and causes of the extinction. Lopingian strata of South China have been intensively studied because three GSSPs have been defined in the region. Based on the review and updates to data from the Shangsi section as well as correlation with the Meishan section, the time framework for the Lopingian is revised, including biostratigraphy, chemostratigraphy, magnetostratigraphy, cyclostratigraphy and geochronology. The temporal framework is constrained by both precise geochronologic data and a high resolution conodont succession, and provides the possibility that the current high resolution marine international standard can also be applied to nonmarine strata by means of geochronology, magnetostratigraphy and cyclostratigraphy. The entire Lopingian high resolution conodont succession is for the first time, since the Lopingian Series was adopted as the international standard, recognized at a single section in South China and the succession correlates very well with the Lopingian GSSP sections at Penglaitan and Meishan. The Permian-Triassic boundary (PTB) of the Shangsi section is constrained to the basal 6 cm interval of Bed 28b in view of ammonoids, bivalves, conodonts, U-Pb ages and the EPME. The mass extinction interval is between Bed 27 and lower Bed 28a according to the EPME pattern at the Shangsi section, and the alternative interval between extinct Permian species and new Triassic species is from upper Bed 28a to lower Bed 28b. Unitary Association (UA) analysis of Lopingian conodonts reveals 15 unitary association zones (UAZs) based on seven important Lopingian sections of South China. Most of the UAZs correlate well with the standard biozonation, except for UAZ 3 to UAZ 5 and UAZ 12. The correspondence between UAZs and standard conodont biozones at the Shangsi section provides a practical example to understand controls on conodont UAZ determination. The Lopingian conodont succession is temporally calibrated by geochronologic ages, identified 405-kyr eccentricity cycles, and a Monte Carlo analysis at the Shangsi and Meishan sections. Updated ages for the base of the Lopingian and base of the Changhsingian are provided.

Current barriers hindering data-driven discoveries in deep-time Earth (DE) include: substantial volumes of DE data are not digitized; many DE databases do not adhere to FAIR (findable, accessible, interoperable and reusable) principles; we lack a systematic knowledge graph for DE; existing DE databases are geographically heterogeneous; a significant fraction of DE data is not in open-access formats; tailored tools are needed. These challenges motivate the Deep-Time Digital Earth (DDE) program initiated by the International Union of Geological Sciences and developed in cooperation with national geological surveys, professional associations, academic institutions and scientists around the world. DDE’s mission is to build on previous research to develop a systematic DE knowledge graph, a FAIR data infrastructure that links existing databases and makes dark data visible, and tailored tools for DE data, which are universally accessible. DDE aims to harmonize DE data, share global geoscience knowledge and facilitate data-driven discovery in the understanding of Earth's evolution., Deep-time Digital Earth is to promote data-driven discovery by harmonizing deep-time Earth data and creating ‘Geological Google’.

Although the precise age and magnitude of the end-Guadalupian biodiversity crisis is still debated, this “mass” extinction has been customarily linked with the onset of massive volcanism in the Emeishan Large Igneous Province (ELIP) in south China. The onset of ELIP eruptive activity at least partly coincides in time with episodes of regional subsidence interrupting the predominant regime of carbonate platforms during Capitanian times. Here, we present a strikingly similar but younger (early Wuchiapingian) subsidence episode from the Pingtang syncline in southern Guizhou, termed the Mapojiao Event. Shallow-marine, light-grey, thick-bedded bioclastic limestone of the Wuchiaping Formation (Unit A) are overlain by deep-marine radiolarian-sponge spicule, thin-bedded black limestone (Unit B). The latter is followed by volcaniclastic distal turbidites (Unit C). The base of the next overlying unit consists of cherty, nodular limestone (Unit D) rich in radiolarians and sponge spicules, whose respective abundances decline up-ward within a few meters. Concomitant replacement by a shallow marine benthic fauna documents the uplift that terminates the event. A total of five index species of Clarkina conodonts indicating an early Wuchiapingian age were obtained from Units A and B. Brachiopods of Wuchiapingian age were also documented in units A, B and D. Compilation of drowning events in the Guadalupian-Lopingian (G-L) interval suggests clustering into three episodes; 1: middle Capitanian, 2: possibly latest Capitanian, 3: early Wuchiapingian. The first drowning event is overlain by ELIP volcanics in sections near the center of the volcanic province. In peripheral areas, the first drowning is intercalated within carbonate platforms (e.g. Maoershan). A second drowning event cannot be excluded close to G-L boundary but it is obscured by the unconformity associated with an eustatic regression and by ambiguous conodont age control. Overlying this unconformity, the Wangpo Shale, which contains ELIP-derived volcanic materials, rests on the first (e.g. in Chaotian) drowning event. The striking similarities of the facies architecture shared by the first and third drowning events suggest a similar driving mechanism. Hence, we propose that the Mapojiao Event represents the youngest, early Wuchiapingian, burst of ELIP eruptive activity. There is no one-to-one correlation between these episodes related to ELIP eruptive activity and extinction phases of marine clades. Only the end-Guadalupian extinction has been correlated with the first eruptive episode. In marked contrast, the newly discovered Mapojiao drowning episode occurred within a diversification phase, which undermines any causal relations between the younger phases of ELIP volcanism and additional extinctions.

A new carbon isotope excursion was recovered from the Capitanian marine carbonates at the Rencunping (RCP) section of South China. Significantly, a pronounced excursion with elevated δ13Ccarb values over +5‰ was coeval with the conodont Jinogondolella prexuanhanensis Zone and resembles the Kamura event recorded in Tethys. The excursions in δ13Ccarb, constrained by conodont biostratigraphy, however, present inconsistent carbon cycle behaviors, especially between the separated basins in South China, and evidently reflect regional litho-facies controls. In addition, a transitional environment in association with a fall in sea level, was recovered from deposits of anoxic cherty carbonates subsequent to shallow-water carbonates around the positive excursion in δ13Ccarb. Accordingly, instead of this being a signal of global-scale climatic cooling, we suggest that the positive excursion in δ13Ccarb can be attributed to eutrophication effects regionally along a continental shelf. In this scenario, the increasing dissolved O2 level in the mixing zone that induced by the initial sea-level fall will efficiently impede denitrification and increase the bio-available N in N:P ratio to satisfy the demands of primary producers in surface waters. Subsequently, deposits of shallow-water carbonates comprising calcareous algae and massively-bedded lime muds accumulated widely around South China. These deposits appear to represent an unusual environment and ecosystem fertilized, perhaps, by the weathering products from the earliest stages of volcanism prior to the main Emeishan flood basalt eruptions at the Guadalupian-Lopingian boundary (GLB)., NASA Astrobiology Institute (Award NNA13AA90A)

Two negative carbon isotope excursions (3.5–6.5‰) across the Wuchiapingian-Changhsingian boundary (WCB) are observed globally (sections in China, Canada, and Iran); however, the causative mechanism of these excursions is debated. Here, high-resolution osmium isotope (187Os/188Os or Osi) chemostratigraphy of four globally correlated WCB sections (3 in China - Meishan, Shangsi and Lianyuan and 1 in Canada - Buchanan Lake) show two separate Osi excursions to less radiogenic compositions that are coincident with the carbon isotope shifts for two of the South China sections (Lianyuan, Meishan). In contrast, only a single Osi excursion to less radiogenic compositions, coinciding with the earliest Changhsingian carbon isotope shift, is observed for the Shangsi and Buchanan Lake sections. The Osi shift is interpreted to reflect increased unradiogenic Os input from basaltic magmatism in South China, possibly related to the Emeishan large igneous province (LIP). However, 187Os/188Os data suggest that only the earliest Changhsingian volcanism had global impact on both the ocean and atmosphere. The lack of any evidence for a biotic event associated with the WCB therefore may have been due to the more regional rather than global impact of volcanism during the latest Wuchiapingian. In contrast, during the earliest Changhsingian, volcanism was sufficient to cause a more global signal in the ocean osmium record, but was inadequate, or too prolonged, to drive any significant environmental change. Volcanism, however, may have provided the isotopically light carbon that drove the negative carbon isotope excursions across the WCB.

Nearly all extant animal phyla first appeared during the Ediacaran-Cambrian transition. A revolution in primary producer ecology and marine productivity has been proposed as a bottom-up ecological driver for this rapid diversification of metazoans. However, the control(s) driving the evolution of primary producers and primary productivity around the Ediacaran-Cambrian transition, and their potential relationship to the Cambrian Explosion, are not fully understood. In this study, we measured the nitrogen content and the nitrogen isotopic composition of kerogen in the Piyuancun and Hetang Formations, using samples collected from the Chunye-1 well, on the Lower Yangtze Block in western Zhejiang. Our isotope results suggest that nitrate was the dominant N source fueling primary productivity during deposition of the entire Piyuancun Formation and lower Hetang Formation, with only a minor contribution from N 2 fixation. Quantitative reconstructions of paleoproductivity based on organic carbon and pyrite content and sedimentation rate indicate that productivity either stayed the same or increased during the transition from the Piyuancun Formation to the overlying Hetang Formation. Thus, fixed N availability was not the ultimate factor limiting primary productivity during the Ediacaran-Cambrian transition. Combining our data with published nitrogen isotope records from the Early-Middle Ediacaran to Cambrian Stage 4 suggests that NO 3 − was the dominant N species fueling phytoplanktonic productivity during the broad Cambrian Explosion interval, from its earliest roots in the Ediacaran through the main episode in Cambrian Stage 3. Eukaryotes lack the ability to fix nitrogen, and preferentially assimilate nitrate. The NO 3 − -dominated euphotic zone from the Early-Middle Ediacaran to Cambrian Stage 3 may have promoted the radiation of relatively large eukaryote phytoplankton, which may have been an important driver of early animal diversification.

A continuous strontium isotope profile with high-resolution sampling is desirable to calibrate multiple global events, realize temporal correlation among different continents, and understand tectonic history of the Permian Period. In this paper, we analyzed 90 micritic limestone samples from South China and 7 samples from Iran, with the aim to gain new 87Sr/86Sr data and obtain a curve of Sr isotopes for the Permian. The concentrations of Mg, Fe, Mn, and Sr are used to discriminate possible diagenesis of the samples. A comparison of those 87Sr/86Sr values between South China and southern Urals confirms that Sr-isotope proxy has the potential to be used for time calibration and correlation in regions where biostratigraphic or radiometric markers are not available. The 87Sr/86Sr curve obtained in this study shows a trend comparable with the LOcally WEighted Scatterplot Smoothing (LOWESS) regression curve from the previous studies. A continuous decline trend from the latest Carboniferous to late Guadalupian was shown, and the lowest 87Sr/86Sr values in the late Capitanian was constrained within the interval from the conodont Jinogondolella shannoni/J. altudaensis to J. xuanhanensis zones. It is followed by an increasing trend to more radiogenic values in the Lopingian with a minor fluctuation in the early Wuchiapingian. We consider that mid-ocean ridge spreading and increasing continental weathering during the transition from convergence to the breakup of Pangea as the dominant factors driving the changes of the seawater Sr isotope ratios.

Carbon isotope compositions of carbonates (δ13Ccarb) document a new 3.5‰ CIE toward lower values concomi- tant with an Emeishan Large Igneous Province (ELIP)-related drowning event (Mapojiao Event, southern Gui- zhou) during the early Wuchiapingian. Organic carbon isotope data (δ13Corg) have a 2‰ shift toward higher values across the drowning event, showing decoupling with the δ13Ccarb evolution. Rock-Eval and palynofacies analyses suggest an elevated flux of terrestrial organic matter (OM) during the drowning episode. Therefore, the decoupling between δ13Ccarb and δ13Corg is best explained by the mixing of different organic carbon pools in the δ13Corg curve. Strontium isotope data (87Sr/86Sr) also show a transient shift from 0.70715 to 0.70694 asso- ciated with this early Wuchiapingian carbon isotope excursion (CIE), which is superimposed on the late Permian prolonged global rising trend. This short-lived 87Sr/86Sr excursion is best interpreted as an enhanced hydrother- mal flux related to a short pulse of ELIP-related volcanism. Comparison of the Mapojiao Event with other C isotope records from South China and other parts of Tethys re- veals substantial discrepancies. Moreover, older Capitanian CIEs concomitant with ELIP-related drownings are also not laterally reproducible in time. The local distribution of CIEs across Guadalupian-Lopingian (G-L) interval indicates the influence of local factors such as bathymetry and increased burial rate of terrestrial OM, rather than perturbations in the global carbon cycle to due volcanism. This prevents the C isotope record to be used as a global correlation tool during Capitanian and Wuchiapingian times. Comparison of palaeobiodiversity changes with perturbations in C isotope compositions across the G-L interval shows that only the oldest CIE was associated with a modest extinction event as documented in South China. Hence, this study undermines any systematic cou- pling and causal relation between extinctions and iterative perturbations of the C isotope record during the G-L interval.

Earth's penultimate icehouse (ca. 340-285 Ma) was a time of low atmospheric pCO(2) and high pO(2), formation of the supercontinent Pangaea, dynamic glaciation in the Southern Hemisphere, and radiation of the oldest tropical rainforests. Although it has been long appreciated that these major tectonic, climatic, and biotic events left their signature on seawater Sr-87/Sr-86 through their influence on Sr fluxes to the ocean, the temporal resolution and precision of the late Paleozoic seawater Sr-87/Sr-86 record remain relatively low. Here we present a high-temporal-resolution and high-fidelity record of Carboniferous-early Permian seawater Sr-87/Sr-86 based on conodont bioapatite from an open-water carbonate slope succession in south China. The new data define a rate of long-term rise in Sr-87/Sr-86 (0.000035/m.y.) from ca. 334-318 Ma comparable to that of the middle to late Cenozoic. The onset of the rapid decline in Sr-87/Sr-86 (0.000043/m.y.), following a prolonged plateau (318-303 Ma), is constrained to ca. 303 Ma. A major decoupling of Sr-87/Sr-86 and pCO(2) during 303-297 Ma, coincident with the Paleozoic peak in pO(2), widespread low-latitude aridification, and demise of the pan-tropical wetland forests, suggests a major shift in the dominant influence on pCO(2) from continental weathering and organic carbon sequestration (as coals) on land to organic carbon burial in the ocean.

A major discrepancy for the age of the Selong Group from middle Cisuralian (Early Permian) to Changhsingian resulted from previous reports of Sakmarian, Kungurian and Guadalupian (Middle Permian) conodonts and Lopingian (Late Permian) brachiopods. Recently, Cisuralian and Guadalupian conodonts were reported again from the Selong Group and the basal part of the Kangshare Formation at the Selong section, but the age discrepancy remains. We present our conodont materials based on large samples collected from the Selong Group and our interpretation based on identifications using a sample population approach. Three conodont zones are recognized in our re-investigation of the upper part of the Selong Group. They include the Vjalovognathus sp., the Mesogondolella hendersoni, and the M. sheni zones, in ascending order. These zones are overlain by the basal Triassic Hindeodus parvus Zone and the Otoceras woodwardi Zone. Our reassessment of conodonts reported by previous studies from Selong and nearby sections suggest that all specimens consistently point to a Lopingian age; the upper part of the Selong Group is latest Changhsingian in age based on the presence of Clarkina orchardi and Mesogondolella sheni. Previously reported early Cisuralian and Guadalupian conodonts are misidentified using a form species concept. A hiatus may be present at the erosional surface between the Selong Group and the Waagenites Bed of the basal part of the Kangshare Formation. However, the hiatus is minimal because conodont and brachiopod assemblages above and below this surface are very similar, and it results from a latest Changhsingian transgression just before the extinction that follows a global latest Changhsingian regression. There is a distinct rapid end-Permian mass extinction at Selong within the Waagenites Bed, as indicated by the disappearances of all benthic brachiopods, rugose corals and Permian bryozoans. The burst of Clarkina species in the Waagenites Bed and throughout the entire Lower Triassic at Selong is interpreted as a southward migration of equatorial conodont animals associated with the rapid global warming beginning at the end of the Permian. The cool- or cold-water species of Mesogondolella, in the upper part of the Selong Group and the basal part of the Kangshare Formation, are representative of the uppermost Permian in the bipolar/bi-temperate cold-water province and are not reworked from the underlying Selong Group or any other unknown Cisuralian or Guadalupian deposits.

The Permian–Triassic boundary (PTB) is defined by the conodont Hindeodus parvus at Meishan section D in the palaeotropical Tethyan region, where basal Triassic ammonoids are rare and poorly preserved. Here we describe some basal Early Triassic ammonoids from the lower part of the Kangshare Formation at the Qubu section in the Mt. Everest area in southern Tibet, China. Our study recognizes three distinct ammonoid zones, the Otoceras woodwardi, Ophiceras tibeticum, and Ambites zones in ascending order. The occurrence of Otoceras, a key basal Triassic taxon, is here documented for the first time in this area. The first occurrence of Triassic conodonts at Qubu indicates that the PTB is not higher than the level 0.81 m above the base of the dolomite unit of the Kangshare Formation, and the first occurrence of the ammonoid Otoceras woodwardi is 0.89 m higher up at the section. At Qubu, the Griesbachian–Dienerian boundary is placed between the Ophiceras tibeticum Zone and the Ambites Zone. Our work represents a valuable addition for the construction of a high resolution of Griesbachian and Dienerian ammonoid biozonations in southern Tibet and provides a framework for the basal Triassic correlation in the Mt. Everest area.

The Late Paleozoic Ice Age (LPIA) is a critical interval for marine ecosystems when marine fauna was viewed to have experienced a second-order mass extinction and a “sluggish” evolution with low origination and extinction rates. However, our recent study discovered that this ice age was accompanied by a rapid, significant increase of marine fauna species and genus richness. Here, we present the precise details of this biodiversification process, including the high-resolution species and genus richness changes, to decipher its timing and magnitude, as well as the divergent species richness changes of major marine clades during the event. The temporal resolutions are as high as 36 kyr and 21 kyr for the Carboniferous and Permian, respectively, and as a result provide the ability of uncovering the process in great detail. This marine biodiversification event lasted 41.2 Myr from the middle Visean of the Carboniferous to the late Asselian of the Permian with species number increased 246%, therefore named Carboniferous-earliest Permian Biodiversification Event (CPBE). CPBE includes a slow increase episode in the middle Visean to early Bashkirian and a main radiation episode of Bashkirian to Asselian. The radiation pattern is most distinct in fusulinid foraminifera while brachiopods species also kept the trend of increase. However, nektonic conodonts and cephalopods both exhibit stepwise drops during this time interval. These biotic changes might relate to the marine environmental shifts, such as suppressed marine circulation and fragmented niches, mainly raised by the Rheic Ocean closure.

Despite a continuous increase in fossil charcoal records from Late Palaeozoic deposits, which are used as direct evidence for palaeo-wildfires, detailed studies on the charcoal particles are still rare. To investigate the relationship between wildfire activities and the evolution of the terrestrial ecosystem at the end of the Permian, we report on the charcoal recovered from the classic non-marine Permian–Triassic Dalongkou section in Jimsar, Xinjiang Uygur Autonomous Region, Northwest China. Allochthonous and parautochthonous charcoals, identified by both macroscopic and microscopic morphological techniques, were collected from several stratigraphic horizons. These charcoals were classified into 11 categories (which do not represent the taxonomic group) according to their anatomical characteristics and gross morphology. The reflectance values of the charcoals indicate that surface fires were dominant throughout the sequence, with fire regime changing in a distinct interval. The distribution and abundance of all categories and the reflectance of the charcoals suggest that the intensity of wildfires increased in the upper part of the Guodikeng Formation. This trend coincides with the Hg/TOC peaks and a conspicuous excursion in the organic carbon isotope (δ13Corg) values, which may indicate volcanic activities and the disturbance of the carbon cycle that occurred during the Permian–Triassic transition. It is reasonable to infer that the end-Permian mass extinction (EPME) is located at the intensive wildfire interval. The reduction in spore pollen and the decrease in charcoal reflectance hint at a vegetational impoverishment that occurred after this interval. We proposed that increased wildfires, promoted by dry climate conditions and volcanism, aggravated the collapse of the forest ecosystem during the latest Permian.

The Permian Period is punctuated by Earth system changes unlike any other in geological history. The start of the Permian witnessed the termination of the Late Paleozoic Ice Age, followed by the climatic transition from icehouse to greenhouse conditions. The Guadalupian-Lopingian (Middle-Late Permian) was characterized by two biocrises associated to volcanisms: (i) the end-Guadalupian crisis and (ii) the end-Permian mass extinction. Seawater Sr isotope (87Sr/86Sr) records can shed light on the evolution of the Permian Earth system. The Permian 87Sr/86Sr record suffers from a number of issues including low resolution and potential diagenetic alteration. In this paper, we summarize the existing Permian 87Sr/86Sr records and focus on the current challenges. We also present a new, high-resolution Permian 87Sr/86Sr curve derived from pristine brachiopod shells based on data resulting from careful diagenetic screening. Our new record shows that the 87Sr/86Sr of seawater decreased continuously from the earliest Permian to the middle Capitanian (late Guadalupian), with the lowest ratio of 0.706832 registered in the Colania douvillei-Kahlerina pachiytheca Zone. Subsequently, 87Sr/86Sr ratios increased from the late Capitanian to the latest Permian and reached a ratio of 0.707167 just 0.8 m below the first occurrence of the Hindeodus parvus. We employed a stochastic oceanic box model to explore the potential drivers of the Permian seawater Sr isotope record. Our results support that changes in the hydrothermal input, rather than changes in continental weathering intensity, are the most likely controlling factor for the observed variations in Permian seawater 87Sr/86Sr. Therefore, we suggest that the marine hydrothermal system (and hence ocean basin dynamics and deep-sea temperatures) may have been the driver of the pronounced decreasing 87Sr/86Sr trend across the Permian.

The Cimmerian continent is composed of a series of blocks that were attached to the northern margin of Gondwana during the Carboniferous-Permian time, and as a consequence therefore, developed glacial sediments during the Late Paleozoic Ice Age (LPIA). These blocks rifted from Gondwana in the Early Permian, and then drifted towards the tropical area, and as a result their deposits are characterized by the mixture of warm and cool water sediments. With these previously acknowledged diagnostic features, the recognized Cimmerian blocks include Shan-Thai, Tengchong, Baoshan, Lhasa, southern Qiangtang, southern Afghanistan, and southern Iran. Carboniferous and Permian sediments and faunas in these blocks are reviewed in detail here, and disclose the most significant character of Cimmerian blocks, that is the absence of upper Carboniferous sediments, which makes them more similar to Australia and India/Pakistan, and significantly different from South China and other Tethyan regions. By the same token, central Iran, central Afghanistan, and central Pamir should be excluded from the Cimmerian blocks for distinct geological histories. The lower Carboniferous sediments present in all the Cimmerian blocks are composed of Tournaisian and Visean stages, characterized by chert nodules or lenses and oolites. Tournaisian brachiopod Syringothyris, rugose coral Cyathaxonia fauna and Siphonophyllia, and Visean bryozoan Fenestella are typical components, but overall the early Carboniferous fauna shows a Eurasian affinity. Lower Permian deposits are glacial-marine siliciclastic sequence containing cool/cold-water bivalves, small solitary non-dissepimented corals, characteristic brachiopods, low diversified but highly abundant fusulinds Pseudofusulina and Eoparafusulina, which belong to the Peri-Gondwanan fauna. The basaltic magmatism event that took place in the Cimmerian blocks was mainly in the Artinskian, which was most likely related to the initial rifting of the Cimmerian from the northern margin of Gondwana. Upper Lower Permian to Middle Permian include siliciclastics and carbonates in which cold- and warm-water mixed fauna and warm-water genera developed indicating the northward drifting of Cimmerian blocks. The marine fossils in this period are named as the Cimmerian fauna to include such characteristic taxa as the rugose coral Thomasiphyllum, fusulinids Monodiexodina and Eopolydiexodina, as well as some tropically-distributed Tethyan elements. The Upper Permian are mainly dolomitic limestones which contain the typical Cimmerian foraminifera Shanita and Hemigordius in addition to other Tethyan taxa such as the compound coral Waagenophyllum.

The middle–late Cambrian is a key interval between the Cambrian Explosion and the Great Ordovician Biodiversification Event (GOBE) that marks a major biologic evolutionary transition in the geologic record. Diversity (i.e. richness) patterns in this interval show that macro-biota experienced evolutionary setbacks for the first time. However, relatively little attention has been paid to this interval in previous macroevolutionary studies and very different conclusions about the diversity patterns in coarse time-resolution have been documented. As a dominate group of marine benthic organisms in the Cambrian, trilobites provide insightful information to understand the history of biodiversity in the Cambrian marine ecosystem from the Cambrian Explosion to the GOBE. South China is a region with relatively good preservation of Cambrian fossil materials and sections, and 4 out of 6 Cambrian GSSPs were established in South China. In this paper, we use constrained optimization (CONOP) to correlate 19 sections from South China to reduce the Signor-Lipps effect and integrate the results with high-resolution chronostratigraphic data to evaluate the middle–late Cambrian trilobite diversity pattern in South China. This study, for the first time, constructs a high time-resolution (about 60 kyr) trilobite species-level richness curve with estimated time from Age 4 to the Paibian. A double-peaked species diversification is separated by a minor extinction in Stage 4; this is followed by a gradual decline of species diversity over the entire Wuliuan Age. A radiation of three times increase of species diversity in the Drumian and Guzhangian is exhibited and the diversity remains high for most of the Guzhangian Stage; this is followed by a great extinction at the end of the Guzhangian with around 50% species lost. Detailed comparison with previous composite studies and fossil material from single sections revealed that the Signor-Lipps effect could produce large biases in diversity pattern. In addition, a precise analysis of species evolution features compared with environmental indices provides a perspective about trilobite evolutionary mechanisms associated with environmental changes related to the carbon cycle and biotic competition.

South China has become the most important area to establish a global stratigraphic framework of the Wuchiapingian Stage because complete Wuchiapingian sequences include the GSSPs for the base and top of the stage. As the markers of the Wuchiapingian GSSP, conodonts are the most important fossil group to establish the Wuchiapingian biostratigraphic framework. However, few documents have investigated in detail the conodont biostratigraphic succession through the entire Wuchiapingian Stage. Furthermore, the conodont taxonomy of several WuchiapingianClarkinaspecies is still debated. Therefore, we here review all WuchiapingianClarkinaspecies from South China and figure ontogenetic growth series from juvenile to adult individuals for each valid and important species in order to revise both Wuchiapingian conodont taxonomy and the biostratigraphic succession. Based on the Penglaitan, Dukou, and Nanjiang sections, seven conodont zones (Clarkina postbitteri postbitteri,C.dukouensis,C.asymmetrica,C.leveni,C.guangyuanensis,C.transcaucasica, andC.orientalis) are recognized. The WuchiapingianClarkinaspecies lineage is also reviewed to confirm the conodont biostratigraphic framework. The Guadalupian-Lopingian boundary (GLB) interval represents a sequence boundary. The time framework of the pre-Lopingian extinction interval indicates that the beginning of the end-Guadalupian regression is in the upper part of theJinogondolella postserrataZone, and the beginning of the early Lopingian transgression is in the lower part of theClarkina dukouensisZone in South China.

The “Cambrian explosion” is one of the most fascinating episodes of diversification in the history of life; however, its relationship to the oxygenation of the oceans and atmosphere around the Ediacaran–Cambrian transition is not fully understood. Marine inventories of redox-sensitive trace elements reflect the relative balance of oxidative weathering on land and deposition in anoxic water masses, and can be used to explore the evolution of oceanic and atmospheric redox conditions. For this study, we conducted a series of geochemical analyses on the upper Lantian, Piyuancun, and Hetang formations in the Chunye-1 well, part of the lower Yangtze Block in western Zhejiang. Iron speciation results indicate that the entire studied interval was deposited under anoxic conditions, with three intervals of persistent euxinia occurring in the uppermost Lantian Fm., the lower Hetang Formation (Fm.), and the upper Hetang Fm. Molybdenum (Mo) and uranium (U) contents and Mo/TOC and U/TOC ratios from the anoxic/euxinic intervals of the Chunye-1 well, combined with published data from the sections in the middle and upper Yangtze Block, suggest that the oceanic Mo reservoir declined consistently from the Ediacaran to Cambrian Stage 3, while the size of the oceanic U reservoir remained relatively constant. Both metals were depleted in the ocean in lower Cambrian Stage 4, before increasing markedly at the end of Stage 4. The lack of an apparent increase in the size of the marine Mo and U reservoir from the upper Ediacaran to Cambrian Stage 3 suggests that oxic water masses did not expand until Cambrian Stage 4. The increase in marine Mo and U availability in the upper Hetang Fm. may have been due to the expansion of oxic water masses in the oceans, associated with oxygenation of the atmosphere during Cambrian Stage 4. This expansion of oxic waters in the global ocean postdates the main phase of Cambrian diversification, suggesting that pervasive oxygenation of the ocean on a large scale was not the primary control on animal diversity following the Ediacaran–Cambrian transition.

Based on analyses of 565 conodonts from Meishan, Liangfengya, and Daijiagou (South China), and Abadeh (central Iran), we propose a revision of the seawater 87Sr/86Sr curve for the time period spanning 200 kyr prior to the Permian-Triassic boundary (PTB) to 330 kyr after the PTB. With carefully designed sample cleaning, conodonts faithfully record seawater 87Sr/86Sr. Seawater 87Sr/86Sr was 0.707030 ± 10,200 kyr prior to the PTB, rose to 0.707070 ± 10 approximately 39 kyr prior to the PTB (at the marine extinction horizon, the top of Bed 24e at Meishan), to 0.707080 ± 10 at the PTB, and to 0.707120 ± 20 at 330 kyr after the PTB. The rate of change of seawater 87Sr/86Sr was 0.0000185/Myr from the Capitanian minimum to ~ 100 kyr before the PTB, and was 0.00020 ± 7.5/Myr between ~ 100 kyr before and 330 kyr after the PTB. Over 6 Myr, this rate of change would result in a maximum 87Sr/86Sr of ~ 0.70825 at the end of the Early Triassic, compared with a model value of ~ 0.7080. The Sr data are consistent with the interpretation that the rise in marine 87Sr/86Sr was due primarily to an increase in the continental weathering and erosional flux, and that soil-binding vegetation was not re-established during most of the Early Triassic. The rapid rise in seawater 87Sr/86Sr began at least 30 kyr prior to the marine extinction at Meishan, indicating that the terrestrial extinction preceded that in the oceans.

The end-Permian extinction is typically ascribed to massive volcanic eruptions, but direct geochemical evidence linking the two independent events is generally lacking. Zinc is an important micronutrient of marine phytoplanktons, and Zn isotope (δ66Zn) ratios of seawater are markedly higher than those of volcanic rocks and riverine waters. We conducted high-resolution Zn concentration and Zn isotope analyses on carbonate rocks across the Permian-Triassic boundary (PTB) in the Meishan section of south China. An abrupt increase of Zn concentration and a concomitant 0.5‰ decrease in δ66Zn occur ∼35 k.y. before the mass extinction and carbon isotope (δ13C) minima. Mass balance calculation demonstrates that a 0.5‰ negative shift in δ66Zn within thousands of years requires rapid and massive input of isotopically light Zn from volcanic ashes, hydrothermal inputs, and/or extremely fast weathering of large igneous provinces. A positive δ66Zn shift of as much as 1.0‰ following the mass extinction demonstrates that primary productivity recovered and reached a maximum in fewer than 360 k.y. Our finding provides insights into the marine Zn cycling across the PTB and clarifies the temporal relationship and duration of events, including intensive volcanism, carbon isotope excursion, mass extinction, and widespread ocean anoxia.

The Guadalupian Epoch represents one of the most critical intervals during the Earth history which is characterized by a series of global geological and biological events. However, it is poorly constrained by radioisotopic ages in comparison with the high-precision dates from the Lopingian and lowest Triassic in South China and the Cisuralian in southern Urals, Russia. In this study, we report combined CA-ID-TIMS and SIMS U-Pb zircon geochronology for three ash beds from the base and lower part of the Kuhfeng Formation in the Chaohu area, southeastern China. Zircons from Ash Beds A, C and D were initially analyzed by SIMS and yielded weighted mean 206Pb/238U dates of 269.0 ± 1.4 Ma (MSWD = 1.03, n = 31), 266.3 ± 2.2 Ma (MSWD = 2.2, n = 29) and 262.2 ± 1.7 Ma (MSWD = 1.0, n = 20) in ascending order. However, high-precion U-Pb geochronology of the same ash beds by the CA-ID-TIMS method point to important inaccuracies in the SIMS results due to Pb-loss in zircons. Ash Beds A and C yielded two TIMS weighted mean 206Pb/238U dates of 272.95 ± 0.11 Ma (MSWD = 1.9, n = 7) and 271.038 ± 0.097 Ma (MSWD = 2.2, n = 8), respectively. The depositional age of 272.95 ± 0.11 Ma for Ash Bed A is postulated as the traditional Cisuralian-Guadalupian boundary (CGB) age in South China. Our new geochronology suggests that the Guadalupian Series in South China had a total duration of 13.85 ± 0.52 myr given a Guadalupian-Lopingian boundary (GLB) age of 259.1 ± 0.5 Ma. The new age calibration of the base of the Guadalupian Series is ca. 0.65 (± 0.51) myr older than – and improves upon – the previous estimates for the CGB age and the duration of the Guadalupian Epoch based on the 2016 International Chronostratigraphic Chart (ICC) and the 2012 Geologic Time Scale (GTS).

A brachiopod fauna including 15 species belonging to 14 genera is described from a thin carbonate succession of the Lugu Formation at the Anmu section in the northern part of the South Qiangtang Block, which is about 15 km south to the Longmu Co-Shuanghu Suture. The brachiopod fauna is late Kungurian or early Guadalupian in age in terms of the presence of the brachiopod species Vediproductus punctatiformis, “Cryptospirifer” omeishanensis, and Paraplicatifera regularis. This is also generally consistent with the age indicated by the fusulines (e.g., Cancellina, Chusenella, Monodiexodina, Nankinella, Neofusulinella, Pseudofusulina, and Sphaerulina) from this formation at the nearby Mari and Duoma A (DMA) sections. Palaeobiogeographically, the brachiopod fauna exhibits a typical Cathaysian affinity and all the species are reported commonly from the equivalents in South China and Cimmerian blocks, which strongly suggest that the South Qiangtang Block had drifted to a position in the warm-water or temperate regime close to South China.

Additional specimens of rhynchonellide brachiopods from the marly limestones in the Yidade Formation at the Panxi section in eastern Yunnan have been ascribed to the species “ Paurorhyncha ” squamosa Wang, 1956 and “ P. ” depressa Wang, 1956 . The two species have been used frequently as index fossils for the Frasnian (Upper Devonian), but their taxonomic assignments are problematic because their internal structures remain unknown. In this study, detailed systematical examinations on both external characters and internal structures revealed by serial sections suggest that the two species are more appropriately assigned to the genus Hadrotatorhynchus Sartenaer, 1986 . Based on the stratigraphical distributions of Hadrotatorhynchus and the conodonts in the upper unit of the Yidade Formation, the Hadrotatorhynchus -bearing horizons are re-considered as the uppermost Givetian (Middle Devonian) rather than Frasnian stage, although the precise position of the Middle/Upper Devonian boundary still depends on further investigations of high-resolution biostratigraphy.

We investigated the kill mechanisms of the end-Permian mass extinction by analyzing patterns in biomineralization of marine invertebrates. The microstructures of Upper Permian brachiopod organocarbonate shells show the demise of the production of fabrics with a columnar layer—which has less organic matrix—in favor of more organic-rich shells at the end of Permian. Also, in the 100–120 k.y. interval prior to the Permian-Triassic boundary (PTB), the Rhynchonellata had small calcite structural units (fibers) and thus a higher shell organic content, whereas the Strophomenata were not able to produce smaller units. This suggests that the two classes had a different capacity to cope with environmental change, with the Rhynchonellata being more able to buffer against pH changes and surviving the PTB, whereas the Strophomenata became extinct. The observed trends in biomineralization are similar to the patterns in extant marine invertebrates exposed to increasing p CO 2 and decreasing pH, indicating that ocean acidification could have been one of the kill mechanisms of the mass extinction at the PTB.

The terrestrial Permian-Triassic transitional section at Chahe in western Guizhou Province, South China has served as a key reference section for the study of terrestrial PTB, as well as the end-Permian mass extinction on land in South China. However, Bourquin et al. (2018) recently reported that the PTB interval at Chahe has undergone serious tectonic deformation and thus is not suitable for studying the PTB transition or the terrestrial end-Permian extinction due to an unknown amount of stratigraphy removed/displaced by faulting. In order to clarify the observations of Bourquin et al. (2018), we re-surveyed the Chahe section in further detail recently and our observations suggest that the interpreted deformation by Bourquin et al. (2018) cannot be verified and it also contradicts the regional litho- and bio-stratigraphic and chemostratigraphic results. We provide detailed outcrop imagery and data for all colleagues who are interested in this section to check our observations.

The Permian–Triassic transition witnessed the largest mass extinction event in Earth's history, multiple mechanisms have been proposed to explain the cause of this catastrophe, however, relatively less attention has been paid to the paleogeography and major element chemistry of seawater and its possible link to mass extinction during this interval. Syndepositional massive marine dolostones could record the Mg isotope signature of contemporaneous seawater that hold clues of ancient Mg cycling. In this study, we investigated Mg isotopes of dolomite from three widely spaced carbonate sections in the Paleotethys to trace oceanic Mg cycling during this critical period. The latest Permian dolostones from all studied sections have similar δ 26 Mg values around − 2.1 ± 0.1 ‰ . However, a remarkable and consistent increase in δ 26 Mgdolomite across the extinction interval occurred in both eastern and western margins of the Paleotethys. The results suggest that δ 26 Mg of seawater in Paleotethys fluctuated by 0.4‰ within ∼750 kyr across the Permian-Triassic transition. Modeling reveals that the high rate of change in δ 26 Mgseawater required an extremely short residence time for seawater Mg. This is attributed to dramatically intensified dolomitization in a restricted oceanic environment, with Mg isotope evidence revealing that the Paleotethys Ocean experienced transient restriction events, in association with radical changes in the major cation composition of seawater, around the end-Permian mass extinction event (EPME).

Climate warming, probably as a result of massive degassing of greenhouse gases from the Siberian Traps magmatism, has often been acclaimed as a major cause of the end-Permian mass extinction. Indeed, several studies have documented a sudden rise in seawater temperatures during the latest Permian-earliest Triassic, as evidenced by oxygen isotopic records measured on conodont apatite. However, whether such a rapid increase in seawater temperatures occurred before, during, or after the mass extinction remains controversial. Moreover, the pattern of this rise in seawater temperatures and its timing relative to the latest Permian-earliest Triassic carbon cycle disruption, mass extinction, as well as the Siberian Traps magmatism still need to be rigorously examined in various regions. In this study, we present high-resolution oxygen isotopic records of conodont apatite (δ18Oapatite) from the Upper Permian-lowermost Triassic interval at the Abadeh section, central Iran that are analyzed with in situ secondary ion mass spectrometry (SIMS) method. The δ18Oapatite results from Abadeh demonstrate a clear pattern consisting of three phases: (1) From the lower Wuchiapingian Clarkina dukouensis Zone to the end-Permian mass extinction horizon, δ18Oapatite values are relatively stable, fluctuating in the range of 18.28-20.15‰ with an average of 19.44‰. (2) δ18Oapatite value remains high as 19.26‰ at the mass extinction horizon. Above this horizon, a sudden decrease occurs in the Clarkina hauschkei Zone and reaches a low value of 17.05‰ close to the Permian-Triassic boundary. (3) In the lowermost Triassic, δ18Oapatite values maintain a low baseline in the range of 16.92-17.39‰ with an average of 17.11‰. Overall, the most dramatic change in δ18Oapatite values (i.e., a decrease of ~2‰), converting into an abrupt warming of ~10 °C, occurred above the mass extinction horizon and below the Permian-Triassic boundary at Abadeh. The Abadeh δ18Oapatite record is consistent with previous results documented in South China, Iran, and Armenia in terms of the timing and magnitude of a substantial warming, and therefore represents a global signature. If applying the high-precision temporal framework established in the well-dated Meishan GSSP section to Abadeh, the abrupt warming of ~10 °C took only a maximum duration of ~37 kyr (thousand years). By projecting the carbon cycle change, temperature rise, mass extinction at the Abadeh and Meishan sections, and the temporal evolution of the Siberian Traps magmatism onto a unified timescale, the temporal correlation strongly suggests that the switch from dominantly extrusive eruptions to widespread sill intrusions is probably the most annihilating phase of the Siberian Traps magmatism, and is temporally consistent with the end-Permian mass extinction.

The Guadalupian Epoch is marked by the formation of the Pangean supercontinent, global sea-level change, rifting and drifting of the Cimmerian continents, formation of large igneous provinces and dramatic biotic changes. A high-resolution biostratigraphic, chemostratigraphic and high-precision geochronologic framework of this critical transition is fundamental to understanding these events. Extensive studies of the latest Cisuralian and Guadalupian Series in both South China and North America reveal the same conodont lineages, but the conodont interval zones based on Jinogondolella within the Guadalupian Series are slightly diachronous. High-precision U-Pb geochronological studies (CA-ID-TIMS method) calibrate the base of the Guadalupian Series (base Roadian) at 273.01 ± 0.14 Ma. A previously reported age from an ash bed overlying the Emeishan flood basalts, 259.51 ± 0.21 Ma, is adopted for the Guadalupian/Lopingian boundary (GLB). Based on recently published geochronology and Bayesian age modeling from the Guadalupian Series, the base of the Capitanian is constrained at 264.28 ± 0.16 Ma and the base of the Wordian is interpolated to be 266.9 ± 0.4 Ma. The Illawarra Reversal is of early-middle Wordian age. Both North America and South China possess a distinct negative δ13Ccarb excursion of 3-5‰ at the latest Kungurian and early Roadian (LK-ER CIE), which coincides with the early stages of a significant 3rd order sea-level rise. The large end-Guadalupian δ13Ccarb negative excursion may have been affected by post-depositional diagenesis or a warming event associated with the Emeishan volcanism. The 87Sr/86Sr ratios in both regions declined from the latest Kungurian to the late Capitanian, but have different ratios and reveal several fluctuations in the middle Guadalupian. Measured δ18Oapatite values suggest that the Delaware Basin was 3-4°C cooler than the eastern Yangtze Block. Analysis of a new high-resolution database of marine taxa indicates only a minor pre-Lopingian diversity drop from 261.04 Ma to 259.98 Ma, which coincides with the peak Emeishan volcanism. The widely-perceived “end-Guadalupian mass extinction” in North America is evidently masked by, and possibly an artefact of, a stratigraphic truncation effect due to rapid lithofacies changes from limestone to laminated evaporites with the closure of the west Texas basins.

A non-fusuline foraminiferal fauna consisting of 20 genera and 27 species was documented from the middle part of the Xiala Formation at the Mujiucuo section of Xainza County, central Tibet. This fauna consists mostly of porcelaneous-walled genera such as Agathammina, Midiella, Hemigordiopsis, Neodiscus, Multidiscus , and a new genus Megacrassispirella Zhang gen. nov. These taxa indicate a Midian (Capitanian) age. The climatic amelioration, triggered by climatic warming after the Late Paleozoic Ice Age or by northern drift of the Lhasa Block, promoted diversification of the non-fusuline foraminifers in the middle part of the Xiala Formation. Warm oceanic currents also played an important role in bringing biota from low latitude areas to the northern Gondwanaland margin through the newly-formed Neotethys Ocean. One new genus, Megacrassispirella gen. nov., with Megacrassispirella xarlashanensis (Wang, 1986) emend. Zhang as type species, and one new species, Agathammina vachardi Zhang sp. nov., are described.

A high-resolution and continuous conodont apatite oxygen isotope record spanning the late Visean to Middle Permian is reported from South China, which is interpreted with respect to the ice volume and/or tropical seawater temperature history of the Late Paleozoic Ice Age (LPIA). The presented δ18O record shows significant fluctuations in δ18O from the late Visean to Middle Permian with highest values observed in the Bashkirian (Early Pennsylvanian). The δ18O maximum coincides with a major eustatic sea level fall recorded in low-latitude successions and postdates the significant increases in 87Sr/86Sr and δ13Ccarb measured on well-preserved brachiopod calcite, which can be interpreted as reflecting intensified weathering as consequence of the closure of Rheic Ocean as well as enhanced carbon burial. Both processes may have contributed to lower greenhouse gas levels and cooled down the Earth's surface, triggering the maximum glaciation. The high Bashkirian δ18O values are interpreted to represent the glacial maximum of the LPIA. A coeval change in faunal composition and a decreasing diversity in climate-sensitive marine invertebrates can be ascribed to icehouse cooling and/or loss of habitat. Despite inconsistencies with earlier interpretations that the Early Permian represented the glacial maximum of the LPIA as inferred from Gondwanan glacial sediments records, the suggested Bashkirian glacial maximum agrees well with ice extent estimates based on the regional tectonic history in Gondwana, which suggests that the Bashkirian glaciation occurred during Gondwana interior uplift promoting maximum ice cover of the entire LPIA. However, maximum glaciation is only poorly represented in the depositional record because large parts of the glacial deposits were possibly removed by erosion as outlined by a major regional unconformity.

Body size is a fundamental and defining character of an organism, and its variation in space and time is generally considered to be a function of its biology and interactions with its living environment. A great deal of body size related ecological and evolutionary research has been undertaken, mostly in relation to extant animals. Among the many body size-related hypotheses proposed and tested, the size–bathymetry relationship is probably the least studied. In this study, we compiled a global body size dataset of Changhsingian (Late Permian, ca. 254 Ma–252 Ma) brachiopod species from low-latitude areas (30°S–30°N) and analyzed their species diversity and body size distribution patterns in relation to the nearshore–offshore–basin bathymetric gradient. The dataset contained 1768 brachiopod specimens in 435 species referred to 159 genera and 9 orders, from 135 occurrences (localities) of 18 different palaeogeographic regions. Treating the whole of the Changhsingian Stage as a single time slice, we divided the nearshore–offshore–basin bathymetric gradient into three broad depth-related environments: nearshore, offshore and basinal environments, and compared how the species diversity and body size varied along this large-scale bathymetric gradient. Here, we report an array of complex patterns. First, we found a clear overall inverse correlation between species diversity and water depth along the nearshore–offshore–basin gradient, with most species concentrating in the nearshore environment. Second, when the median sizes of all low-latitude brachiopod species from the three environments were compared, we found that there was no significant size difference between the nearshore and offshore environments, suggesting that neither the wave base nor the hydrostatic pressure exerts a critical influence on the body size of brachiopods. On the other hand, the median sizes of brachiopods from the nearshore environment and, to a lesser extent, the offshore environment were found to be significantly larger than that of basinal brachiopods. This trend of significant size reduction in basinal brachiopods mirrors the relative low species diversity in the basinal environment, and neither can be easily explained by the tendency of decreasing food availability towards deeper sea environments. Rather, both trends are consistent with the hypothesis of an expanding Oxygen Minimum Zone (OMZ) in the bathyal (slope to deepsea) environments, where hypoxic to anoxic conditions are considered to have severely restricted the diversification of benthos and favored the relative proliferation of small-sized brachiopods. Finally, a significant difference was also found between eurybathic and stenobathic species in their body size response to the nearshore–offshore–basin gradient, in that eurybathic species (species found in all three environments) did not tend to change their body size significantly according to depth, whereas stenobathic forms (species restricted to a single environment) exhibit a decline in body size towards the basinal environment. This pattern is interpreted to suggest that bathymetrically more tolerant species are less sensitive to depth control with respect to their body size change dynamics, in contrast to stenobathic species which tend to grow larger in shallower water depths.

Previous studies suggest that the end-Permian mass extinction caused a dramatic drop of marine biodiversity near the Permian–Triassic boundary. However, it is unclear how profoundly this severe extinction might have changed the global provincialism, and how global provincialism responded to the protracted process of this extinction and subsequent recovery through the Triassic. In this paper, we carried out quantitative time-series analyses of global brachiopod palaeobiogeography over a timespan of nine consecutive stages/substages from the latest Permian Changhsingian to the latest Triassic Rhaetian based on a global brachiopod database of 483 genera and 2459 species from 1425 localities. Our results suggest that the extinction resulted in a global ‘biogeographical eclipse’ in the ensuing Early Triassic Griesbachian and Dienerian times in that neither biogeographic realm nor province could be recognized. It was characterized by an extreme low-diversity, mostly dwarfed and nearly globally distributed brachiopod fauna, coupled with persistently high sea surface temperature and a flattened global latitudinal thermal gradient. Global provincialization emerged again during the Olenekian at province level and reached its peak stage during the Carnian when three realms and six provinces were clearly recognized. Global provincialism became weakened again in the latest Triassic Rhaetian, marked by three general realms, but no province distinguished. Our analyses suggest that both palaeolatitude-related thermal gradient and the presence of Pangea (a profound geographic barrier) were most effective in explaining the spatial patterns. In addition, oceanic currents along the northwestern coast of Pangea also played an important (albeit regional) role in linking southern North and Central America brachiopod faunas with those of the Boreal Realm. This study also revealed that the brachiopod biodiversity center moved northwards over the studied interval, accompanied and hence accountable for by the northward drift of a large number of tectonic blocks in the Palaeotethys and Neotethys during the Triassic.

The end-Permian mass extinction (EPME) was the most severe extinction event of the Phanerozoic. To investigate oceanic redox conditions around the EPME, we conducted a series of geochemical analyses, including iron speciation, trace element geochemistry, total organic carbon (TOC), and nitrogen isotopes of kerogen (δ15Nkero), around the EPME at the Shangsi section, South China. Three intervals with different redox conditions can be distinguished based on iron speciation. During the first interval (early and middle Changhsingian), bottom waters were pervasively euxinic. In the second interval (late Changhsingian and the EPME), bottom water fluctuated between oxic and anoxic, but non-sulfidic conditions, with the oxic mode becoming increasingly predominant over time. During the third interval, following the EPME, bottom waters appeared to have been consistently anoxic, although again not pervasively euxinic. This redox history is supported by enrichments in the authigenic fraction of redox-sensitive elements. These relatively high δ15Nkero values (> 1.0‰) corresponding with Changhsingian euxinia suggest reducing bottom waters did not impinge on the photic zone. The shift to values near 0‰ within and above the EPME indicates an ecological expansion of diazotrophs. Stratigraphic trends of Nixs, Cdxs, Pxs, and TOC indicate that primary productivity was highest in the first interval, coinciding with euxinic bottom water, then decreased during the lower part of Interval 2 and remained at low level through the remainder of the studied section. The temporal relationship between redox condition and primary productivity suggests that euxinia was supported by high productivity and carbon export in the early Changhsingian. The expansion of N2 fixation coincides closely with the previously documented warming of the ocean surface at Shangsi and may be related to reduced oceanic circulation and suppressed vertical mixing. The temporal distribution of deepwater anoxia and euxinia suggests that they were not primary causes for the extinction of benthos at Shangsi.

The end-Permian mass extinction reflects the most severe life crisis during the Phanerozoic and was associated with major global environmental changes. However, the consistency of the time and pattern of the terrestrial and marine extinctions remains controversial. In this paper, we presented detailed analyses of the high-resolution biostratigraphical and geochemical data from terrestrial sections in South China. Our analyses show that the transitional Kayitou Formation actually recorded the process of terrestrial mass extinction as evidenced by the mass disappearance of the Gigantopteris megaflora in the lower part, the dramatic reduction in abundance of palynomorphs in the middle, and the last occurrences of plant remains and abundant charcoal fossils in the uppermost part. It is associated with a distinct negative shift of δ13Corg, beginning in the middle part of the formation, which is correlative with that in the top of Bed 26 at the marine Meishan section. In addition, the Kayitou Formation is characterized by a distinct shift of lithofacies of fresh lake-swamp or river flat environment from olive/grey/black mudstone, siltstone, fine to coarse sandstone in the lower part to gradually increasing maroon rocks, to purely maroon mudrocks with poorly-sorted breccia, calcic palaeosols and calcareous nodules in the lowest part of the Dongchuan Formation, which indicates a dramatic collapse of soil system associated with rapid deforestation and climatic warming and drying. In the coastal area, the Kayitou Formation contains marine beds with the typical Permian–Triassic mixed faunas and floras which are correlative with the latest Changhsingian marine mixed fauna 1 at Meishan. The Kayitou Formation also recorded a distinct transgression that began in the latest Changhsingian. All above phenomena suggest that the Kayitou Formation is actually the witness of the terrestrial end-Permian mass extinction; and it is mostly or entirely of latest Changhsingian (Permian), rather than Triassic age.