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The research reported in this paper was aimed mainly to investigate the different NDE techniques on specimens made by a new process labeled as "pulsed infusion", very crucial for voids content under critical loading conditions. The impact load, in fact, is critical for composite laminates due to their anisotropy, in particular in extreme temperature conditions due to their brittleness. An additional and very relevant aim was to collect a large number of experimental results to supply useful information for the numerical models needed to simulate the dynamic behavior of composite laminates. At the aim to investigate the response under dynamic loads of laminates fabricated by a new vacuum assisted technology labeled as "pulsed infusion", rectangular carbon fiber composite specimens were subjected to low velocity impact tests. Experimental tests up to complete penetration and at different energy levels, were carried out by a modular falling weight tower. All the parameters related to the phenomenon, like penetration energy, maximum force and indentation depths, were used to validate existing semi-empirical and numerical models. The largely used ultra sound technique (US) was adopted to investigate the delamination together with the thermo graphic technique. The results of the measurements were compared with data obtained on the same specimens by holographic analysis (ESPI). One of the scope was to investigate the crucial internal impact damage and assess the ability of an unconventional ND system (ESPI) in giving right information about non-visual damage generated inside composite laminates subjected to dynamic loads. Moreover, some of the specimens were cut to allow the fractographic analysis. The efficiency of the above mentioned new fabrication technology was studied also comparing the results with measurements from literature on impacted autoclave cured laminates. By the comparison between the results, good agreements were found denoting the efficiency and the applicability of the new fabrication and the used NDE methods. © 2015 Elsevier Ltd. All rights reserved.

The low-velocity impact behavior of polyester glass fiber composite laminates has been investigated under different clamping conditions, by wetting the specimens surface with fluids having different densities. Unidirectional composite laminates, based on polymer resin and fibers of naval interest, with different thicknesses have been manufactured by resin transfer molding process in order to have a high control of the final properties and a high fiber volume fraction. Impact tests in air have been, first, performed up to penetration on all manufactured composites having four different thicknesses to get information on the material impact behavior. The effect of the clamping conditions and the interaction of the laminates with two fluids different in density, i.e., water and paraffin oil, have been investigated, then, only on the thickest laminates that showed a lower tendency to impact damage. In particular, the impact tests have been performed by impacting the front surface of the sample and by wetting the back surface of the composite samples under unclamped and clamped conditions, replicating the boundary constraints suggested by ASTM D7136 Standard for the conventional impact tests. Experimental results showed a lower initial rigidity, higher absorbed energy and deflection for specimens exposed to liquids with respect to those exposed to air, confirming the need of taking into account the fluid interaction in the case of marine composite applications.

This paper aims to investigate the ability of ultrasonic and electronic speckle pattern interferometry to analyse the low-velocity impact internal damage mechanisms on basalt composite laminates and to provide information on the shape and the extent of the delamination in non-destructive way. Basalt/epoxy composites with different thicknesses have been realised and characterised by mechanical tests to investigate both fibre-dominated (tensile and flexural behaviour) and matrix-dominated properties (interlaminar shear strength). Specimens were impacted at penetration and at increasing energy values, to explore the damage onset and propagation. The results showed that the damage was concentrated under the impactor–material contact point and that the composite with intermediate thickness had the best balance between the different kinds of impact damages: delamination and indentation. Further, a good agreement was found between the overall data obtained by the two non-destructive techniques, confirming the capability of both techniques to examine the composite impact damage.

In this work, the evaluation of damaged areas due to low velocity impact tests at different impact energy values on Carbon Fibre (CF) laminates with 3D fabric, made by infusion technology and reinforced with epoxy resin, were investigated by NDI (Non-destructive Investigation) technique based on speckle interferometry. Composites are characterized by several interacting failure modes such as matrix breakage, fibre failure and delaminations, which can be simultaneously induced by low velocity impacts. It can be very difficult to detect by visual inspections of the structures such phenomena. The aim of this study is to evaluate the damaged area due to an impact event. CF composite laminates were impact damaged with four energy levels (5, 10, 20, 30J) at room temperature, by drop weight impact machine. The results showed that ESPI technique was able to identify barely visible low-velocity impact damages.

Scheduling of energy storage systems of distributed generation is a key element for optimal renewable energy sources (RES) exploitation in smart grids, demand side response strategies implementation and prosumers interaction with Distribution System Operators (DSOs). In this context, this paper presents the implementation of a management system for energy storage scheduling, which allows taking appropriate account of the storage system behavior in real cases. To properly consider the real system operation, the employed battery model is modified, in order to include also the hysteresis phenomena in state of charge estimation in both charging and discharging operation. The validation of the proposed methodology is supported by experimental tests which allow comparing two different battery models. The obtained results show that better results can be obtained with the model including the hysteresis effect.

The purpose of hybridization is to obtain a new material preserving advantages from all of its constituents. Hybridization offers intermediate properties respect to the original materials, by creating a balance effect within the fibres incorporated in the composite materials and leading to a composite with more tailored behaviour The increasing need to mitigate the environmental impact of synthetic fibres and polymers is promoting the use and application of natural materials orienting the research toward the development of biodegradable systems. In this framework, hybrid reinforced laminates with flax and basalt twill layers alternatively stacked, were manufactured by resin infusion fabrication technology and impacted at low velocity to investigate their dynamic behaviour, in an attempt to couple the impact resistance of basalt fibres with the environmentally friendly nature of flax fibres. For comparison purposes, the same experimental characterization has been performed on laminates reinforced with only basalt or flax fibres. The experimental results confirmed the positive role played by fibre hybridization in terms of damage. The Electronic Speckle Pattern Interferometry technique was adopted to analyze the internal damage and to provide information on the shape and the extent of the delamination, that was found concentrated under the impactor-material contact point for the basalt and flax/basalt laminates.

In this study the integration of a Solid Oxide Fuel Cell (SOFC) prime mover and a high temperature electrochemical Sodium Nickel Chloride (SNC) battery as storage has been investigated. The aim is to fulfil a domestic user energy demand and to reduce the primary energy consumption in comparison with a reference conventional scenario, thereby, to enhance the total efficiency in mu-CHP (Combined Heat and Power) application on a yearly basis. A realistic operational sequence of the SOFC-battery integration has been calculated using simple logic conditions. Both thermal and electric integration have been considered, where the innovative thermal integration has been proposed in order to exploit the SOFC residual heat for the battery stand-by feeding. The key advantage of this system architecture is that the SOFC is operated without major load variations close to constant load, resulting in longer lifetime and thus reducing total costs of operation. The thermal integration provides additional advantages, as calculated in this study. Eventually, a comparison with alternative mu-CHP technologies has been carried out, highlighting the potential of the system based on the SOFC. Benefits are mainly shown in terms of primary energy savings and admissible costs. (C) 2016 Elsevier Ltd. All rights reserved.

The integration of distributed storage systems (DSSs) at users and prosumers level can significantly contribute to energy efficiency and increase profits from renewable energy exploitation, thanks to suitable scheduling of charging and discharging periods. On the other hand, to preserve network stability and secure operation, Distribution Systems Operators (DSOs) are interested in DSSs control and cooperation with the grid. In this framework this work proposes a simple monitoring and management system for DSSs scheduling and its integration in a distributed measurement and control system architecture for smart grids. In the paper the proposed algorithm is tested on a simple case study at home level; the obtained results show its feasibility in addressing both users/prosumers economic interests and DSOs needs for grid secure operation.

Performance of an innovative storage system for renewable energy, based on the Power-to-Gas concept are numerically predicted. The investigated system is composed by a high temperature co-electrolyzer of Solid Oxide Electrolyte Cell technology and an experimental methanation section, based on structured catalyst, suitable for high temperature operation. With the aim to thermally integrate high temperature co-electrolysis and methanation, a parametric thermodynamic analysis of the Power-to-Gas system is carried-out with a lumped-parameters approach, including all the thermal and electric energy consumptions. In particular, in order to optimize the system thermal balance of plant, various configurations involving internal heat recovery and pressurization of components are also considered. Numerical results are provided in terms of different performance indicators, such as electric-to-fuel conversion index, first law efficiency and second law efficiency and output-fuel quality indicators. The study demonstrates the possibility to thermally integrate the co-electrolyzer and the high-temperature methanation section achieving significant energy savings. Moreover, the calculated results show that the system set-up providing higher quality of the produced synthetic natural gas do not always lead to larger values in energy conversion efficiency. Eventually, advanced configurations of the Power-to-Gas system including heat recovery allow to achieve first-law efficiency up to values around 80–85% and second-law efficiency around 70–78%; a second methanation section based on conventional low-temperature reactors is included in the system and pressurization of the methanation section, or pressurization of the co-electrolysis section, is mandatory, in order to achieve large fraction of methane (up to 95–99%) in the produced synthetic fuel.

The effect of stacking sequence on the impact damage mechanisms and the matrix-fiber dependent properties, such as flexural and interlaminar strength , of epoxy hybrid basalt/flax composites has been experimentally investigated. The basalt and flax fabrics have been appropriately selected with approximately the same areal weight and stacked in the same number in three different symmetrical analysed configurations to manufacture composites with comparable conditions regarding fibre content by weight. No influence of fibre sequence was observed for the flexural modulus , whereas some differences were exhibited by the flexural and the interlaminar shear strength depending on the resin content. The impact tests were carried out at penetration and different energy levels. After impact, indentation measurements have been performed by a confocal microscope to get information on the damage propagation and characteristics that resulted affected by the hybridisation type and by the impact energy. The results evidenced the relevance of the stacking sequence in the composite design to meet specific requirements.

Hydrophobic surfaces are highly desired for several applications due to their exceptional properties such as self-cleaning, anti-icing, anti-friction and others. Such surfaces can be prepared via numerous methods including plasma technology, a dry technique with low environmental impact. In this paper, the effect of a one-step sulfur hexafluoride (SF6) plasma treatment upon the low velocity impact behavior of basalt/epoxy composites has been investigated by using several characterization techniques. A capacitive coupled radiofrequency plasma system was used for the plasma surface treatment of basalt/epoxy composites, and suitable surface treatment conditions were experimentally investigated with respect to gas flow rate, chamber pressure, power intensity, and surface treatment time by measuring the water droplet contact angle of treated specimens. The contact angle measurements showed that treating with SF6 plasma would increase the hydrophobicity of basalt/epoxy composites, moreover, the impact results obtained on reinforced epoxy basalt fiber showed damage in a confined area and higher impact resistance for plasma-treated basalt systems.

The study proposes a tool developed within the TRNSYS environment aimed at integrating its building simulation features during the use phase with a Life Cycle Assessment approach. The tool can be used to investigate the relevance of each life-cycle step of the building on the primary energy consumption and global warming potential. The Life Cycle stages can be modelled with different approaches: direct input of the embodied energy and global warming potential values for each life cycle step as defined in the EN 15978, use of an internal database of embodied energy and global warming potential of construction materials and energy systems, direct connections of building simulation outputs to the tool for the use phase. The proposed component is able to model correctly the LCA of a case study, obtaining negligible deviations from the results of a LCA study performed with a state of the art LCA software (lower than 0.05% for all impacts).

Glass fiber composite materials in epoxy resin with different content of a nitrile rubber modified hybrid resin were manufactured by infusion with two different rubber concentrations. SX 10 epoxy resin was modified to improve the response of the laminates under impact loads. At the aim to test the improvement of the impact resistance over the conventional epoxy resin system, the rectangular specimens 100∗150 mm2 were dynamically loaded in the center by a falling weight machine, Ceast Fractovis, using a cylindrical impactor with a hemispherical nose 19,8 mm in diameter and a total mass of 3.6 kg. Impact tests were carried out at penetration to obtain the complete load-displacement curve useful to measure the penetration energy and to highlight the characteristics points for the increasing energies evaluation, 5J, 10J and 20J, to investigate the damage start and propagation. After the impact tests, the specimens were observed by visual inspection to investigate the delamination extension whereas a confocal microscope was used for the indentation measurements. The obtained results on the modified epoxy system were compared to neat GFRP laminates impact performances. No significant impact performance difference was recorded between samples with different nitrile rubber modifier content. A higher indentation was recorded on the modified samples related with a lower delamination extension. It could represent a good practical results since from a simple external damage measurement it can be possible to obtain information about a low internal delamination. © 2016 The Authors.

The aim of this work is the study of the influence of a large notch damage in a stiffened aeronautical panel. In particular, the damage onset and evolution due to a cut-out located in the bay of an omega stiffened composite panel subjected to a compressive load is investigated. Three different cut-outs are considered: parallel, normal, and 45° oriented respect to the load. The effects of such configurations are compared in terms of fibre and matrix failures, in order to better understand which configuration is the most sensitive to these type of damages.

Epoxy based laminates reinforced with woven basalt fibres have been manufactured and characterized by quasi-static mechanical tests and low-velocity impact tests. Samples were prepared by infusion of 16 plies of basalt under pre-optimized conditions. All the interlaminar shear strength, flexural and impact tests were carried out at room temperature, −25 °C and −50 °C to investigate the effect of temperature on the mechanical characteristics and the impact damage onset and propagation. Ultrasonic technique were adopted to provide information on the shape and the extent of the internal damage. The final aim was to be able to predict impact energy and delamination under different temperature conditions and to assess the influence of the resin matrix stiffening at low temperature on the composite behaviour. Results show that at low temperature due to the stiffening of the resin matrix, the composite tested is more resistant and less deformable. It is interesting since, at low temperatures, it is more straightforward the damage propagation. In particular, ILSS and flexural tests show a maximum increase of 39% and 12.78% respectively at T = −50 °C compared to the value at room temperature. A delamination area increase of wholly 40% at T = −50 °C, is detected.

Basalt-epoxy laminates are establishing gradually in engineering sectors due to increasing attention toward environmental matters. Some properties should be improved to extend their applications and the cold spray (CS) metallization provides a potential solution. Unfortunately, the fragile nature of thermosetting polymers makes it difficult the CS coating formation and grow-up. Therefore, this research work aims to study an innovative solution able to enhance the adhesion mechanisms between the cold sprayed metal particles and the thermosetting polymer-based substrates. For this purpose, an original manufacturing method that provides the surface PLA treatment for thermosetting samples was developed. AlSi10Mg particles were cold sprayed on the treated surface, and the low-velocity impact behaviour of the metallised hybrid structures was analysed in details. The outcomes prove the effectiveness of the method proposed on the deposition process and the beneficial effects of metallization on impact damage mechanisms.

To improve the impact behaviour of composite laminates and to reduce the problem of the complex damages after dynamic loads, a two-component commercial epoxy resin was modified with a commercial nitrile liquid rubber modified DGEBA epoxy prepolymer that, prior the cure, has been mechanically dispersed at two concentration levels (20%w/w; 30%w/w). Experimental characterization of both neat and modified resins was performed to investigate the effect of the rubber addition on the resin properties, i.e. glass transition temperature, modulus and dynamic mechanical characteristics. Further, the rubber domain distribution in the epoxy resin was analyzed by scanning electron microscopy (SEM). The hybrid rubber modified resins did not show high viscosity allowing to manufacture E-glass fiber reinforced composites by vacuum infusion process. The laminates were characterized by tensile mechanical tests that evidenced an overall enhancement of maximum stress and deformation for the hybrid composites. In particular, results demonstrated an improvement of 10% for the shear failure stress and of 110% for the shear failure strain. Further, impact tests were carried out at penetration, to evaluate the improvement of the impact resistance over the conventional epoxy resin system, and at increasing energy levels, 5 J, 10 J and 20 J, to investigate the damage start and propagation. A higher indentation has been observed for the modified composite samples related with a lower delamination extension. © 2017 Elsevier Ltd

In the framework of the Italian R&D project i-Next two pilots plants were realized aiming at demonstrate benefits coming from the adoption of electrochemical energy storages (Lithium ion batteries and hydrogen) integrated with renewable energy sources. In the present study the preliminary results coming from the demo sites operations are reported paying attention to the impacts to the grid.

In this paper, a new approach to modeling the hysteresis phenomenon of the open circuit voltage (OCV) of lithium-ion batteries and estimating the battery state of charge (SoC) is presented. A characterization procedure is proposed to identify the battery model parameters, in particular, those related to the hysteresis phenomenon and the transition between charging and discharging conditions. A linearization method is used to obtain a suitable trade-off between the model accuracy and a low computational cost, in order to allow the implementation of SoC estimation on common hardware platforms. The proposed characterization procedure and the model effectiveness for SoC estimation are experimentally verified using a real grid-connected storage system. A mixed algorithm is adopted for SoC estimation, which takes into account both the traditional Coulomb counting method and the developed model. The experimental comparison with the traditional approach and the obtained results show the feasibility of the proposed approach for accurate SoC estimation, even in the presence of low-accuracy measurement transducers.

The study aims at applying of Load Match and Grid Interaction indexes to a Net Zero Energy Building in order to optimize the performances of its energy systems. The case study is a modular prefabricated house that uses solar energy (photovoltaic) and natural gas (Fuel Cell) as energy sources and equipped with an Energy Management System addressing the optimal energy use.

The increasing penetration of renewable energy generation in the electric energy market is currently posing new critical issues, related to the generation prediction and scheduling, due to the mismatch between power production and utilization. In order to cope with these issues, the implementation of new large scale storage units on the electric network is foreseen as a key mitigation strategy. Among large scale technologies for the electric energy storage, the Power-to-Gas solution can be regarded as a long-term viable option, provided that the conversion efficiency is improved and aligned with other more conventional storage alternatives. In this study, a Power-to-Gas storage system is investigated, including as main components a high-temperature electrolyzer for hydrogen generation and a Sabatier reactor for methane production. The high-temperature Solide Oxide Electrolyser Cell (SOEC) technology, currently under development, is considered as a promising solution for hydrogen generation, due to the expected higher efficiency values, in comparison with conventional low-temperature electrolysis technologies. In order to evaluate the performance of the system and the energy efficiency, in this study a numerical model of the SOEC integrated with the Sabatier reactor has been implemented, including also the necessary additional auxiliaries, which can significantly affect the energy conversion performance. The whole energy conversion and storage system has been analyzed, taking into account different layout variants, by means of Aspen HysysTM numerical tool, based on a lumped modelling approach. The various Power-to-Gas storage configurations have been compared, with the aim to optimize both the system's efficiency and the composition of the produced gas stream.

The mechanical response of reinforced composite structures under impact loads is particularly challenging owing to the rising of multiple and simultaneous failure phenomena. Indeed, low velocity impacts may produce intra-laminar damages, like fibre breakage and matrix cracking, and inter-laminar damages, such as delaminations and skin-stringer debonding. As already remarked, these failure phenomena often take place simultaneously, leading to a significant reduction in strength and stability of the composite components. In this paper, the behaviour of stiffened composite panels, with omega shaped stringers, under low velocity impacts is numerically investigated by means of non-linear explicit FEM analyses. Different impact energy levels are considered and correlation with experimental data is provided, in terms of impact force, displacement and energy. A sensitivity analysis has been performed to investigate the influence of numerical models’ approximations on the accuracy of the obtained numerical results. Models with an increasing level of damage simulation details have been adopted to study the effects of combined and separated intra-laminar and inter-laminar failures providing an interesting insight on the modelling requirements for an accurate simulation of the investigated phenomena.