1. Efficient Polymer Solar Cells Based on Non-fullerene Acceptors with Potential Device Lifetime Approaching 10 Years
- Author
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Thomas Heumueller, Andrej Classen, Christoph J. Brabec, Tobias Unruh, Wolfgang Gruber, Ning Li, and Xiaoyan Du
- Subjects
Fullerene ,Materials science ,Organic solar cell ,business.industry ,Production cost ,Energy conversion efficiency ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Polymer solar cell ,0104 chemical sciences ,General Energy ,Optoelectronics ,0210 nano-technology ,business - Abstract
Summary Organic solar cells (OSCs) based on non-fullerene acceptors (NFAs) have developed very fast in recent years. A proper balance among power conversion efficiency (PCE), stability, and production cost needs further elaboration. Here we investigate the industrial viability of highly efficient OSCs based on several representative NFAs. The most stable OSCs exhibit PCE of ∼8% along with extrapolated T80 lifetime (80% of the initial PCE) of over 11,000 hr under equivalent 1 sun illumination, which would lead to a very impressive operational lifetime approaching 10 years. Photo-stability is strongly dependent on the end-group and side-chain engineering of the NFAs. Breaking of conjugation during photo-aging leads to increased energetic traps. Fluorination of the end-group stabilizes molecules against light soaking, while adding methyl groups shows an opposite trend. Side-chain modification can significantly influence the morphological stability. Reducing synthetic complexity of this class of NFAs will ultimately push the organic photovoltaics technology into real-life applications.
- Published
- 2019
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