1. Controllable assembling of highly-doped linked carbon bubbles on graphene microfolds
- Author
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Chen Chen, Jixin Zhu, Kun Rui, Ruizi Li, Kang Hu, Yunfeng Hu, Tieqi Huang, Huijuan Lin, and Wenqing Wang
- Subjects
Materials science ,Carbon nanofiber ,Graphene ,Doping ,Energy Engineering and Power Technology ,chemistry.chemical_element ,Nanotechnology ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Oxygen reduction ,0104 chemical sciences ,law.invention ,Fuel Technology ,chemistry ,law ,Electrochemistry ,0210 nano-technology ,Thermal analysis ,Carbon ,Energy (miscellaneous) - Abstract
Carbon-based microassemblies (CMs) have attracted significant attention in numerous applications due to their unique hierarchical structures and delicate building blocks, especially when hollow carbon spheres (HCSs) are reasonably introduced into the construction. Herein, a new design for novel HCSs-combined CMs is proposed. Remarkably, the HCSs are linear carbon bubbles linked one-by-one, arranging into necklaces decorating on the graphene microfolds. Detailed thermal analysis confirm that high temperatures straighten the linked carbon bubbles into bamboo-like carbon nanofibers, evidently due to the attenuation of doping degree. Benefiting from the abundant active sites of carbon bubbles, the obtained CMs exhibit satisfactory electrocatalytic activity for oxygen reduction reactions. This work establishes a bridge to precisely control the synthesis of carbon-based hierarchical architectures.
- Published
- 2021
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