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In direct-injection engines, the formation of fuel wall film on piston surface and liner wall is a primary cause for emissions of unburnt hydrocarbons and particulate matter. It is therefore important to investigate the behavior and effect of a wall fuel film under typical engine conditions. Following our previous study of wall film effects on flame propagation and quenching under constant thermodynamic conditions (Tao et al. IJER, 2018), more complexities rooted in real engine conditions have been considered in the current work, including two real engine in-cylinder thermodynamic trajectories occurring at catalyst warming (CW) and low-speed high-load (LSHL) conditions, varying fuel wall film thickness accounting for both vaporization and condensation, and the stagnation boundary layer flow over the wall film. To shed light on the role of wall heat transfer, parameter sweeping of wall temperature is conducted from 303 K to 363 K. Two representative wall film models using empirical vaporization rate and gas-liquid interface heat flux are compared with our numerical simulation. A good correlation between vapor boundary thickness and quenching distance has been found. Competition between enhanced vaporization due to tangential convection and aggravate condensation from elevated pressure is also demonstrated. The results lead to useful insights into the behavior of a wall film in real engine in-cylinder thermodynamic conditions and could be used to construct low dimensional empirical wall film models in three-dimensional engine combustion modeling. more...

The formation of fuel wall film is a primary cause for efficiency loss and emissions of unburnt hydrocarbons and particulate matters in direct injection engines, especially during cold start. When a premixed flame propagates toward a wall film of liquid fuel, flame structure and propagation could be fundamentally affected by the vaporization flux and the induced thermal and concentration stratifications. It is, therefore, of both fundamental and practical significance to investigate the consequent effect of a wall film on flame quenching. In this work, the interaction of a laminar premixed flame and a fuel wall film has been studied based on one-dimensional direct numerical simulation with detailed chemistry and transport. The mass and energy balance at the wall film interface have been implemented as boundary condition to resolve vaporization. Parametric studies are further conducted with various initial temperatures of 600–800 K, pressures of 7–15 atm, fuel film and wall temperatures of 300–400 K. By comparing the cases with an isothermal dry wall, it is found that the existence of a wall film always promotes flame quenching and causes more emissions. Although quenching distance can vary significantly among conditions, the local equivalence ratio at quenching is largely constant, suggesting the dominant effects of rich mixture and rich flammability limit. By further comparing constant volume and constant pressure conditions, it is observed that pressure and boiling point variation dominate the vaporization boundary layer development and flame quenching, which further suggests that increased pressure during compression stroke in engines can significantly suppress film vaporization. Emissions of unburnt hydrocarbon, soot precursor and low-temperature products before and after flame quenching are also investigated in detail. The results lead to useful insights on the interaction of flame propagation and wall film in well-controlled simplified configurations and shed light on the development of wall film models in three-dimensional in-cylinder combustion simulation. more...

Substantial research effort has been spent on the development of advanced compression ignition (ACI) engine combustion strategies over the past decades, including homogeneous charge compression ignition (HCCI), reactivity controlled compression ignition (RCCI), and gasoline direct-injection compression-ignition (GDCI), etc. The behavior of gasoline-type fuels under compression ignition conditions has subsequently attracted extensive experimental and kinetic modeling interest. On the other hand, towards the development of future transportation fuels and engines, the evaluation of general fuel properties, instead of endless testing of specific fuels, should be the future research focus. In this study, the individual roles of the research and motor octane numbers (i.e., RON and MON) and fuel sensitivity (S) in characterizing the ignition performance of gasoline surrogates have been systematically investigated under a typical ACI engine condition using well-validated surrogate and kinetic models. The crank angle corresponding to 50% total heat release (CA50) was utilized as an indicator of the overall fuel reactivity, and iso-contours of CA50 were mapped out in the full engine operating domain characterized by the temperature and pressure at intake valve closing (IVC). By comparing the ignition performance of toluene primary reference fuel blends (TPRF) with the same RON, MON or S values, the distinctive effects and dominant ACI operating conditions of these fuel properties are clearly demonstrated. The role of equivalence ratio is also discussed by comparing the intrinsic stoichiometric condition of the standard octane rating tests and the lean mixture conditions required by ACI operation. The results show that octane sensitivity manifests itself in the high pressure low temperature operating regime for fuels with identical RON or MON, through different low temperature reactivities and heat release rates, while in low pressure high temperature conditions, combustion phasing is less sensitive to all fuel properties, including RON, MON and S. TPRFs with the same sensitivity show the largest variation of CA50 in the intermediate operating conditions, where the thermodynamic traces pass primarily through the ignition delay regime characterized by negative-temperature coefficient (NTC) behavior. Finally, by comparing the combustion phasing of five different gasoline surrogates with nearly identical RON and MON, potential compositional effects for gasoline fuels under ACI condition are further discussed via kinetic modeling. This study also demonstrates that the controlling fuel properties of gasoline-like fuels depend on ACI operating conditions (pressure and temperature trajectory), which should be carefully considered when constructing fuel metrics and comparing experimental results of ACI engines. more...

In the current work, we utilize a recently developed staged Livengood–Wu (L–W) correlation to evaluate and predict the two-stage ignition behaviors of different primary reference fuels (PRFs) under homogeneous reciprocating engine conditions, to demonstrate its capability in capturing detailed ignition kinetics in combustion simulation. Based on the understandings of the global and detailed kinetics of low-temperature chemistry, simplified Arrhenius-based global expressions were developed for both ignition stages, and a linear correlation was applied for the cool flame temperature rise at the end of the first stage, for PRFs with various octane number (ON) 0, 20, 60 and 87 under constant volume conditions. For their performance under homogeneous charge compression ignition (HCCI) conditions, it is shown that for the same engine speed, the inlet temperature range allowing for two-stage ignition shrinks with increased ON numbers, and eventually two-stage ignition turns into single-stage ignition with sufficiently high ON numbers. Based on the ignition database, the combustion phasing for all PRFs under a wide HCCI operation range are predicted with the staged L–W integral method with satisfactory accuracy, including the first- and second-stage ignition timing as well as the cool flame temperature rise. The sensitivities of each of the engine operation parameters are successfully captured, further demonstrating the applicability of the staged L–W method for realistic fuels with low temperature chemistry and its potential applications for engine combustion control. This study also provides an alternative approach of accommodating low temperature ignition kinetics in combustion simulation, especially useful for those under variable thermodynamic conditions. more...