1. Self-assembly of carbon nanotube-based composites by means of evaporation-assisted depositions: Importance of drop-by-drop self-assembly on material properties
- Author
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Christophe Minetti, Carlo Saverio Iorio, Pierre Dauby, Frank Dubois, Vanja Miskovic, and Hatim Machrafi
- Subjects
Materials science ,Nanocomposite ,Drop (liquid) ,Composite number ,Evaporation ,02 engineering and technology ,Carbon nanotube ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,law.invention ,Electrical resistivity and conductivity ,law ,Electrode ,General Materials Science ,Composite material ,0210 nano-technology ,Material properties - Abstract
Carbon nanotubes and silica nanoparticles are allowed to self-assemble into a nanocomposite by first forming an aqueous suspension, then depositing one drop after the other and finally letting them evaporate. Two types of composites are prepared. One by forming alternate layers and the other by forming several layers of a pre-mixed suspension. The thickness, thermal and electrical conductivity of the composites are measured versus the number of depositions. The pre-mixed composites showed an increase in the values in both the parallel and perpendicular directions of both the electrical and thermal conductivities, making them suitable for electrodes or battery-like applications. The values of the electrical and thermal conductivities in the perpendicular direction for the first composite decrease and increase, respectively, while for the parallel direction the values are significantly constant. As such, they would be useful as electrical insulators for optimal cooling. Thickness measurements showed that the pre-mixed composite is the denser one, due to a better alignment of the carbon nanotubes.
- Published
- 2018