1. Polydopamine-assisted grafting of chitosan on porous poly (L-lactic acid) electrospun membranes for adsorption of heavy metal ions
- Author
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Zhiying Xin, Madeeha Tabassum, Hugh Gong, Jinmin Meng, Qasim Zia, and Jiashen Li
- Subjects
Polydopamine ,Indoles ,Polymers ,Nanofibers ,02 engineering and technology ,Wastewater ,Biochemistry ,Chitosan ,chemistry.chemical_compound ,X-Ray Diffraction ,Structural Biology ,Spectroscopy, Fourier Transform Infrared ,0303 health sciences ,Langmuir adsorption model ,General Medicine ,Hydrogen-Ion Concentration ,021001 nanoscience & nanotechnology ,Electrospinning ,Membrane ,Spectrophotometry ,symbols ,0210 nano-technology ,Porosity ,Materials science ,Surface Properties ,Polyesters ,Metal ions in aqueous solution ,PLLA ,Water Purification ,03 medical and health sciences ,symbols.namesake ,Adsorption ,Metals, Heavy ,Molecular Biology ,030304 developmental biology ,Ions ,Models, Statistical ,Grafting ,technology, industry, and agriculture ,Substrate (chemistry) ,Kinetics ,Chemical engineering ,chemistry ,Polymerization ,Microscopy, Electron, Scanning ,Copper ,Water Pollutants, Chemical - Abstract
In this study, a versatile method for the manufacturing of chitosan-grafted porous poly (L-lactic acid) (P-PLLA) nanofibrous membrane by using polydopamine (PDA) as an intermediate layer has been developed. P-PLLA fibreswere electrospun and collected as nano/micro fibrous membranes. Highly porous fibres could serve as a substrate for chitosan to adsorb heavy metal ions. Moreover, PDA was used to modify P-PLLA surface to increase the coatinguniformity and stability of chitosan. Due to the very high surface area of P-PLLA membranes and abundant amine groups of both PDA and chitosan, the fabricated membranes were utilized as adsorbent for removal of copper(Cu2+) ions from the wastewater. The adsorption capability of Cu2+ ions was examined with respect to the PDA polymerization times, pH, initial metal ion concentration and time. Finally, the equilibrium adsorption data of chitosan-grafted membranes fitted well with the Langmuir isotherm with the maximum adsorption capacity of 270.27 mg/g.
- Published
- 2021
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