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In this study, the effects of various fabrication parameters on the electrical performance of an electrospun nanofiber-based triboelectric nanogenerator (EN-TENG) are systematically investigated through the design of experiments. We selected four fabrication parameters to examine, namely: (i) working distance (needle to collector distance), (ii) needle gauge, (iii) electrospinning time, and (iv) counter materials. A mixed orthogonal array of L18 experiments was designed with respect to the one factor having two level values and three factors having three level values. The open circuit voltage of the EN-TENG was varied from 86.1 to 576.7 V with the aforementioned fabrication parameters. A longer working distance, a larger needle gauge, and a longer electrospinning time increased the open circuit voltage. The power density of the optimized EN-TENG was approximately 2.39 W/m2 at a 100 MΩ load resistance and was sufficient to illuminate a total of 200 LEDs.

This study aims to improve the sensitivity of sensors using porous structures and cone-shaped patterns in the composition of a capacitive pressure sensor. A simple and rapid fabrication method for the production of porous structures and cone-shaped patterns using microwave irradiation of emulsions containing polydimethylsiloxane (PDMS) and a sacrificial solvent is introduced in this study. Through this method, a porous PDMS dielectric layer could be simply fabricated within a few minutes. The sensitivity was greatly improved by both enhancing deformability and increasing the dielectric constant under the external pressure. The effect of pattern distance was investigated, and the sensor with the pattern distance of 600 μm showed a remarkably high sensitivity of approximately 5 kPa−1. Moreover, the effect of aspect ratio and sharpness of the patterns were also studied through a finite element analysis. Finally, we demonstrated the performance of the sensor using a sensor array and finger attached sensors, and they showed sufficient performance for use in wearable devices applicable to artificial skin, surgical robots, and pressure monitoring systems, among others.

In recent years, innovative research has been widely conducted on flexible devices for wearable electronics applications. Many examples of wearable electronics, such as smartwatches and glasses, are already available to consumers. However, strictly speaking, the sensors used in these devices are not flexible. Many studies are underway to address a wider range of wearable electronics and the development of related fields is progressing very rapidly. In particular, there is intense interest in the research field of flexible pressure sensors because they can collect and use information regarding a wide variety of sources. Through the combination of novel materials and fabrication methods, human-machine interfaces, biomedical sensors, and motion detection techniques, it is now possible to produce sensors with a superior level of performance to meet the demands of wearable electronics. In addition, more compact and human-friendly sensors have been invented in recent years, as biodegradable and self-powered sensor systems have been studied. In this review, a comprehensive description of flexible pressure sensors will be covered, and design strategies that meet the needs for applications in wearable electronics will be presented. Moreover, we will cover several fabrication methods to implement these technologies and the corresponding real-world applications.

Surface modification of polyimides (PIs) using electrospinning would significantly improve the performance of TENGs because of the larger surface area of the electrospun friction layer. However, PIs generally have high solvent resistance, so it is complicated to convert them into nanofibers using electrospinning process. This study aims to fabricate PI nanofibers via simple, one-step electrospinning and utilize them as a friction layer of TENGs for better performance. PI nanofibers were directly electrospun from PI ink made of polyimide powder without any additional process. The effect of PI concentration on spinnability was investigated. Uniform and continuous nanofibrous structures were successfully produced at concentrations of 15 wt% and 20 wt%. Electrospun PI nanofibers were then utilized as a friction layer for TENGs. A TENG with 20 wt% produced an open circuit voltage of 753 V and a short circuit current of 10.79 μA and showed a power density of 2.61 W m−2 at a 100 MΩ load resistance. During tapping experiment of 10,000 cycles, the TENG could stably harvest electrical energy. The harvested energy from the proposed TENG is sufficient to illuminate more than 55 LEDs and drive small electronic devices, and the TENGs exhibit excellent performance as a wearable energy harvester.

The objective of this work is to establish a volumetric metal 3-dimensional (3D) printing system based on material extrusion method and to fabricate metal patterns by investigating various process variables. Numerical heat transfer simulation was conducted to design the nozzle system with a minimized heat loss at the nozzle tip. Based on the simulation results, a metal 3D printing system with X, Y, and Z stages was constructed. The effects of lead content in molten metals and printing conditions such as stage speed and flow rate were investigated. The line formation like bulged, uniform, and dashed lines was evaluated using an optical microscope, and the variation in line widths of uniform lines was investigated with the process variables. Various types of 2-dimensional (2D) patterns were fabricated with an optimized process variable. A simple 3D structure was obtained to demonstrate the feasibility of the proposed system and procedure.

Pressure sensors for wearable electronics are mounted on irregular surfaces and exposed to various external stimuli. Therefore, the sensor should have a flexible structure and wide pressure measurement range along with high sensitivity. In this study, we fabricated hierarchically porous structured polydimethylsiloxane (PDMS) composites with a simple and cost-effective method using sugar particles and a water-in-oil emulsion. Hierarchically porous PDMS composites were employed as the dielectric layers of flexible capacitive pressure sensors. The capacitive pressure sensor presents a sensitivity 22.5 times higher (0.18 kPa−1) than the sensors using bulk PDMS with a wide measurement range (0–400 kPa). The finite element analysis was implemented to analyze the non-linearity of sensors by observing the compressive behavior of the PDMS composites. For the practical applications, finger attached-sensor, respiration monitoring system, and sensor array were tested, and the proposed sensors showed sufficient potential for application in wearable electronics.

This work aims to present a flexible, highly sensitive, capacitive pressure sensor based on an elastomeric dielectric layer with uniformly distributed micro-pores. The porous dielectric layer was simply produced by microwave treatment of polydimethylsiloxane (PDMS) mixed with a sacrificial solvent within a few minutes. The pressure sensor using a porous PDMS dielectric layer fabricated with 40 wt% sacrificial solvent had a sensitivity of 0.813 kPa−1, which is 11 times higher than that of the sensor using a non-porous dielectric layer. To further improve the sensitivity, low-cost commercial glass was used as a mold to form microstructures on the surface of the porous dielectric layer. Due to the enhanced deformability, high sensitivity of 1.43 kPa−1 and a fast response time of 70 ms was achieved. The performances of a sensor array as well as finger sensors were also demonstrated by placing light-weight objects on the array and holding a plastic cup. It would be expected that the proposed sensors could be utilized in the application of artificial skins or soft robotics.

An electrohydrodynamic (EHD) patterning method was utilized to obtain high-resolution line patterns in a low electric field regime without an additional mechanical drawing process. Molecular weight and weight percent of a polymer were selected as key parameters to reduce the voltage. EHD patterning was performed using polyethylene oxide (PEO) solutions. The threshold voltages (V th) to initiate jet ejection are almost the same for all solutions. A method verified in this study, reducing the driving voltage (V d) just after the initiation of the jet at the threshold voltage, can make a very thin, continuous jet, while increasing molecular weight and weight percent were enabled to further reduce the input voltage. As the voltage reduction ratio (V d/V th) is decreased, the jet behaves like a solid rather than a liquid due to its fast solidification. The line width of the resultant line pattern could be tuned from 50 nm to 10 μm depending on the substrate moving speed. Contour maps were also developed that show the pattern mode variation as a function of the voltage reduction ratio and key parameters. The results show that well-defined PEO line and grid patterns can be fabricated via the proposed EHD direct patterning under appropriate conditions.

Highly sensitive capacitive pressure sensors with poly(vinylidenefluoride-co-trifluoroethylene) (P(VDF-TrFE)) dielectric layers were prepared. The dielectric layers were directly produced by electrospinning P(VDF-TrFE) nanofibers for various spinning times. A longer spinning time enhanced the deformability of the electrospun P(VDF-TrFE) layers, resulting in higher sensitivity owing to larger changes in the deformation of the dielectric layer. One of the capacitive pressure sensors showed a high sensitivity of 2.81 kPa−1 at a pressure ≤ 0.12 kPa, a good response time of 42 ms, and small hysteresis. The sensitivity of the sensor was five times higher than that of a typical capacitive pressure sensor. The fabricated pressure sensor could detect a tiny water droplet as light as 7 mg. It is expected that the electrospun P(VDF-TrFE) nanofibers can be used as sensing materials for highly sensitive pressure sensors in wearable electronics applications.

In this study, a honeycomb-like nanofiber based triboelectric nanogenerator (HN-TENG) is presented. In order to fabricate the honeycomb-like nanofiber, we utilized self-assembly of electrospun poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) nanofibers. The honeycomb-like P(VDF-TrFE) nanofiber network was directly produced via electrospinning without any additional processing. The HN-TENG showed a maximum voltage, current, and power density of 160 V, 17 μA, and 1.6 W/m2, respectively. The power density was enhanced more than twofold as compared with a typical flat nanofiber network based TENG due to the large surface area and high surface roughness of the honeycomb structure. Finally, we verified that HN-TENG has the potential to be used for practical applications by driving 100 light emitting diodes and charging capacitors.